• Bulletin of the Korean Chemical Society
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• 제11권6호
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• pp.564-567
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• 1990

A lithiated compound $Li_{0.1}Pr^{3+}Ba_2Cu_3O_y$ has been successfully prepared by electrochemical method, which is achieved with a two electrode cell of the type: Metal(Li)/($Li^+\;,\;ClO_4^-$) + propylene carbonate/$PrBa_2Cu_3O_y$. All Pr ions in the lithiated compound are stabilized with a trivalent state as the other rare earths (Ⅲ) substituted in the 90K superconductor lattice ($Y_{1-x}Ln_x^-Ba_2Cu_3O_{7-{\delta}}$). Powder X-ray diffraction analysis shows that both compounds, $PrBa_2Cu_3O_y$ and $Li_{0.1}PrBa_2Cu_3O_y$ are isostructural with the 90 K superconductor, ($YBa_2Cu_3O_{7-{\delta}}$), nevertheless both of them are non-metallic and also non-superconducting down to 10 K. Magnetic susceptibility ${\chi}$ vs. temperature data indicate that Curie contribution from the magnetic ions (Pr and Cu) is weakened on the one hand, but on the other hand temperature-independent part of susceptibility ${\chi}_o$ increases depending upon the rate of lithium intercalation in $PrBa_2Cu_3O_y$ lattice.

• 한국전기전자재료학회논문지
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• 제35권6호
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• pp.610-615
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• 2022

BaTiO₃ is one of the ferroelectric materials with excellent dielectric properties such as high dielectric constant, low dielectric loss, and is widely used for the manufacturing of capacitors, piezoelectric converters, microsensors, and ferroelectric memories. Inkjet printing is a technology which uses digital and contactless methods which significantly improves flexibility associated with material and structural design, reducing manufacturing costs. Therefore, the top and bottom electrodes, BaTiO₃ ink, and photocurable resin were all printed by an inkjet to produce a BaTiO₃ capacitor. The properties of the printed thin film were analyzed. It was confirmed that the photocurable resin ink was well-infiltrated between the BaTiO₃ powder particles printed by inkjet. The dielectric properties of the capacitor such as dielectric constant which varies in accordance with frequency, polarization and tunability that changes with voltage, were measured.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2003년도 somma/kms meeting
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• pp.129-129
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• 2003

• Elastomers and Composites
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• 제50권1호
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• pp.7-12
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• 2015

The $BaCrO_4$ nanoparticles were synthesized from a 0.1 M $K_2CrO_4$ and 0.1 M $BaCO_3$ solution with stirring for 10 h. The product was washed several times with acetone and heated to $700^{\circ}C$ for 6 h. At that time, the color of mixture was a greenish yellow. The graphene/$BaCrO_4$ nanocomposites were prepared with graphene and $BaCrO_4$ nanoparticles by stirring in tetrahydrofuran and heated in an electric furnace at $700^{\circ}C$ for 2 h. The $BaCrO_4$ nanoparticles, graphene/$BaCrO_4$ and heated graphene/$BaCrO_4$ nanocomposites were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The graphene/$BaCrO_4$ nanocomposites and heated graphene/$BaCrO_4$ nanocomposites were evaluated as a photocatalyst and discussed about kinetics study for the degradation of organic dyes, such as methylene blue and rhodamine B under ultraviolet light irradiation at 254 nm.

• 한국작물학회지
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• 제49권6호
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• pp.482-486
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• 2004

숙주나물의 세근 발생 억제용으로 이용되고 있는 BA의 처리량을 경감시킬 수 있는 가능성을 탐색하고자 3개 공시품중(금성녹두, 어울녹두, 중록1호)을 이용하여 BA 농도 (0, 25, 50, 75, 100 ppm)를 달리하여 5시간 침종시킨 후에 6일간 재배된 숙주나물의 생장과 형태를 조사하였던 바 그 결과를 요약하면 다음과 같다. 1. 공시품종 모두 하배축 길이가 7cm 이상의 개체비율은 50 ppm 이상에서는 처리농도가 증가할수록 감소하였던 반면, 4cm이하의 비율은 오히려 처리농도가 증가할수록 증가하였다. 그러나 4-7cm의 비율은 처리농도가 증가할수록 증가하였던 금성녹두와 중록1호와는 달리 어울녹두는 50ppm까지는 증가하였다가 그 이상의 농도에서는 오히려 감소하였다. 2. 세근은 75ppm 이상의 처리농도에서는 거의 형성되지 않았으며, 세근발생 비율과 개체당 세근수는 50 ppm 처리농도를 기준으로 증감이 큰 것으로 조사되었다. 3. 공시품종 모두 하배축과 뿌리 길이는 BA 처리농도가 증가할수록 감소하였다. 그러나 하배축 중간 부분의 직경은 처리농도가 증가할수록 금성녹두와 중록1호에서는 굵어졌던 반면, 어울녹두는 50ppm 까지는 증가하였다가 그 이상의 농도에서는 오히려 가늘어지는 경향을 보였다. 4. 하배축 및 전체 생체중은 BA를 처리하지 않은 것에 비하여 처리할 경우 많았던 반면, BA를 처리할 경우 처리농도 간에는 차이가 없었다.

• 한국결정성장학회지
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• 제4권3호
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• pp.252-261
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• 1994

본 연구는 수산염법에 의해 화학적으로 균일하며 고순도인 미립의 $(Ba_{1-X}Sr_X)ZrO_3$ 분말을 합성하고 합성된 분말의 미세구조와 유전특성을 조사하여 공진주파수의 온도계수$({gamma}_f)$가 안정한 $(Ba_{1-x}Sr_x)Zr0_3$의 최적 합성조건을 규명하고자 하였다. 6가지 조성의 $(Ba{_1-X}Sr_x)ZrO_3$ (X=0, 0.2, 0.4, 0.6, 0.8, 1) 화합물을 수산염법으로 얻은 후 이를 $1000^{\circ}C$에서 하소하여 결정질 $(Ba_{1-X}Sr_X)ZrO_3$ 분말을 합성하였다. 합성한$(Ba_{1-x}Sr_x)Zr0_3$ 분말은 구형으로 $0.2 {mu}m$이하의 평균 입경을 가졌으며, ${\tau}_c$는 Ba에 대해 Sr이 0.5 정도 치환된 조성에서 0이 되는 조성을 유추할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제26권6호
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• pp.935-938
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• 2005

Nucleophilic addition reactions of benzylamines (BA; $XC_6H_4CH_2NH_2$) to $\alpha-cyano-\beta$-phenylacrylamides (CPA; $YC_6H_4CH=C(CN)CONH_2$) have been investigated in acetonitrile at 25.0 ${^{\circ}C}$. The rate is first order with respect to BA and CPA and no base catalysis is observed. The addition of BA to CPA occurs in a single step in which the addition of BA to $C_{\beta}$ of CPA and proton transfer from BA to $C_{\alpha}$ of CPA take place concurrently with a four-membered cyclic transition state structure. The magnitude of the Hammett ($\rho_X$) and Bronsted ($\beta_X$) coefficients are rather small suggesting an early tansition state (TS). The sign and magnitude of the crossinteraction constant, $\rho_XY$ (= −D0.26), is comparable to those found in the normal bond formation processes in the $S_N2$ and addition reactions. The normal kinetic isotope effect ($k_H/k_D\;{\gt}$ 1.0) and relatively low ${\Delta}H^{\neq}$ and large negative ${\Delta}S^{\neq}$ values are also consistent with the mechanism proposed.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1997년도 한국재료학회 추계학술발표회
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• pp.139-139
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• 1997

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 추계총회 및 연구발표회 초록집
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• pp.157.2-157
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• 2003

• 한국광학회:학술대회논문집
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• 한국광학회 1997년도 Advance Program of 14th optics andquantum Electronics conference, 1997제14 회 광학 및 양자전자 학술 발표회 논문 요약집
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• pp.53-53
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• 1997