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Dielectric Properties with Temperature Variation of $(Ba_xSr_{1-x})$TiO$_3$Thin Films ($(Ba_xSr_{1-x})$TiO$_3$박막의 온도 변화에 따른 유전 특성)

  • 김덕규;전장배;송민종;박춘배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.309-313
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    • 1997
  • (Ba$_{x}$Sr$_{l-x}$)TiO$_3$(BST) thin fi1ms with various Ba/Sr ratios were deposited on Pt(80nm)/SiO$_2$(100nm)/Si by RF magnetron sputtering. BST thin films which have x=0.6, 0.5, 0.4 were studied dielectric properties with temperature variation. The frequency was used from 100Hz to 1MHz for measuring dielectric constant. The measurement conditions of dielectric constant with Temperature Variation were 1KHz and 2$0^{\circ}C$. As a result, the dielectric constant of BST thin film was about 425 and loss factor was 0.013. Also, with increasing Temperature, the dielectric constants of BST thin films were gradually decreased.sed.

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Cation Ordering and Microwave Dielectric Properties of $Ba(Mg_{1/3}Nb_{2/3})O_3$ Ceramics: II. Local Order-Disorder Phase Transition and Second Phase formation ($Ba(Mg_{1/3}Nb_{2/3})O_3$세라믹스의 양이온 규칙구조와 유전특성: II. 국부적 규칙-불규칙 상전이와 이차상 생성 거동)

  • 김영웅;박재환;김긍호;김윤호;박재관
    • Korean Journal of Crystallography
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    • v.12 no.2
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    • pp.81-87
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    • 2001
  • We have studied the effect of sintering temperature and time on the cation ordering and second phase formation in Ba(Mg/sub 1/3/Nb/sub 2/3/)O₃(BMN) microwave ceramics by using transmission electron microscopy. The relationship between the structural-chemical behavior arid microwave dielectric properties has also been investigated. It is revealed that according to the sintering conditions the BMN ceramics show very diverse local ordering behavior, such as the development of domain twinning and "core-shell"-structured grains and the formation of local disordered domains, though having 1 : 2 cation ordering structure basically. The disordered structure is found in Mg-excess region. Such local chemical variation seems to be caused by the formation of BaNb₂O/sub 6/-like second phase in its neigh-boring grain boundary. The microwave dielectric quality factor of the ceramics decreases greatly with the increase of the structural-chemical inhomogeneity and diversity.

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Studies on Hexagonal Ferrite (III) Coprecipitation-Method Preparation of Ferroxplana ZnY $(Ba_2Zn_2Fe_{12}O_{22})$ and Its magnetic Properties (Hexagonal Ferrite에 관한 연구 (III) 공침법에 의한 Ferroxplana ZnY $(Ba_2Zn_2Fe_{12}O_{22})$의 합성과 그 자성)

  • 김태옥;신학기
    • Journal of the Korean Ceramic Society
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    • v.16 no.2
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    • pp.89-98
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    • 1979
  • In order to prepare ferroxplana ZnY $(Ba_2Zn_2Fe_{12}O_{22})$, which would be useful for GHz-band communication, the optimum coprecipitation condition of 1 $BaCl_{2-1} Zn(NO_3)_2-6FeCl_3$ in $NaOH-Na_2CO_3$ solution was investigated by use of a new apparatus invented in our laboratory. By freeze-drying and calcining the coprecitated hydroxide-carbonate, the very reactive powder was obtained, from which the synthesis process of ZnY and the other related crystals were investigated by means of X-ray diffraction. In results, it was found that the reactive powder containing ZnY as the major component can be prepared by this method, which may be used in manufacturing the various magnetic cores for the microwave communication.

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Analysis of Grain Boundary Oxidation in $(Ba, Sr)TiO_3$-based PTCR Ceramics by $\mu-AES$ and $DV-X\alpha$ Energy Simulation ($(Ba, Sr)TiO_3$계 PTCR 세라믹스의 입계산화에 대한 $\mu-AES$ 분석 및 $DV-X\alpha$ 궤도에너지 계산모사)

  • 김명철;강영석;허수형;박순자
    • Journal of the Korean Ceramic Society
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    • v.31 no.6
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    • pp.587-594
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    • 1994
  • (Ba, Sr)TiO3-based PTCR ceramics were sintered and cooled down with various cooling conditions in the air. AES was applied to investigate the composition change in the grain boundary and bulk area of oxidatively cooled samples. Ba component was deficit in grain boundary region, while oxygen was abundant than bulk region. The discrete changes of oxygen binding energies were confirmed in the grain boundary region of the heavily oxidized samples. It was supposed that the large binding energy shift resulted from the oxidation of the segregated Mn in grain boundary region and this idea was supported by the DV-X$\alpha$ molecular energy simulation.

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The Role of Mn on the PTCR Characteristics of La-doped $BaTiO_3$ Ceramics (La-doped $BaTiO_3$ 세라믹스에서 PTCR 특성에 미치는 Mn의 영향)

  • 김성희;이준형;조상희
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.140-144
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    • 1995
  • The role of Mn on the PTCR characteristics of La-doped BaTiO3 ceramics was studied. The calculated Ns value was increased with Mn concentration and consequently pmax and pmin were increased. The behavior of pmin was explained by the Jonker's theory, and Ns value of 6.35×1017m-2 was well agreed with the theoretical estimate of Jonker's. The value state of Mn was measured by ESR, and changed around Tc from +3 in tetragonal phase to +2 in cubic phase. Therefore, the amount of electron trap increased at Tc led to the great improvement of PTC R characteristics.

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Experimental Analysis of Wheel Radiation Noise of HANVIT 200 Train in Curve Lines (곡선부에서의 한빛 200 열차 차륜방사 소음 특성)

  • Lee, Chan-Woo;Kim, Jae-Chul
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.907-910
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    • 2008
  • The wheel radiation noise characteristic of Korean tilting train(Hanvit 200) on curved rail under the field test conditions is analyzed in this paper. The test railroad track was selected from Seodaejon to Songjeongri in Honam line. $5^{th}$ and $6^{th}$ car are decided to measure radiation noise level among a train of six cars. The test subject curve radius executed from R400, R500, R600, R700 and R800 segments. The speed of test trains when from R600 and R800 curves existing operation speed and speed up 20% of existing speed. On curved rail at the time of operation speed of Hanvit 200 trains from below 95km/h wheel radiation noise level at $94dBA{\sim}99dBA$, the operation speed from between $100km/h{\sim}144km/h$ wheel radiation noise level at $100dBA{\sim}106dBA$.

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Studies of Repeated Fed-Batch Fermentation of Cephalosporin C in an Immobilized Cell Bioreactor

  • Park, Hong-Je;Khang, Yong-Ho
    • Journal of Microbiology and Biotechnology
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    • v.5 no.4
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    • pp.229-233
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    • 1995
  • Acremonium chrysogenum was immobilized in ionotropic gel beads to develop semi-continuous production of cephalosporin C (CPC). Barium alginate beads were more stable than calcium alginate or strontium alginate beads in chemically defined media. The gel stability of Ba-alginate was further increased by cross-linking with polyethyleneimine (PEI). The presence of carboxymethyl cellulose inside Ba-alginate beads did not reduce mass transfer resistance. Ba-alginate microbeads that had little diffusion limitation increased CPC production rate 1.6 fold higher than that of normal beads. CPC fermentation with immobilized cells in Ba-alginate microbeads was performed continuously for 40 days by way of repeated fed-batch operations. Mathematical modeling was developed to describe the repeated fed-batch fermentation system. Results of the computer simulation agreed well with the experimental data, which made it possible to predict an optimal feeding rate that could maximize total CPC productions.

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Dielectric Properties of $(Ba,Sr,Ca)TiO_{3}$ Ceramics with Additon of Dopant (불순물 첨가에 따른 $(Ba,Sr,Ca)TiO_{3}$ 세라믹의 유전특성)

  • Lee, Sung-Gap;Lee, Young-Hie;Lim, Sung-Soo;Park, In-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.42-45
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    • 2001
  • $(Ba_{0.6}Sr_{0.4}Ca_{x})TiO_{3}+yZrO_{2}$ wt% (x=0.10, 0.15, 0.20, y=0.5~3.0) specimens were fabricated by the mixed-oxide method and then the structural and dielectric properties as a function of the composition ratio and $ZrO_2$ contents were studied. All BSCT specimens showed dense and homogeneous structure without the presence of the seconds phase. The Curie temperature and the dielectric constant at room temperature decreased with increasing the Ca/Ba composition ratio and $ZrO_2$ content. The BSCT(50/40/10) specimens showed the excellent tunability property. And the tunability were increased with increasing the contents of $ZrO_2$.

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Fabrication of $Ba_{1-x}K_xFe_2As_2$ Thin Films in Various Conditions (다양한 조건에서의 $Ba_{1-x}K_xFe_2As_2$ 박막 제조)

  • Lee, Nam-Hoon;Jung, Soon-Gil;Kang, Won-Nam
    • Progress in Superconductivity
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    • v.12 no.1
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    • pp.32-35
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    • 2010
  • Potassium doped $BaFe_2As_2$ superconducting thin films by using an ex situ pulsed laser deposition technique were fabricated in various conditions to find out an optimal growth condition. Controlled conditions were annealing temperature, annealing time, and mass of potassium. The $Ba_{1-x}K_xFe_2As_2$ thin films which has most good quality is fabricated at a condition of annealing temperature at $700^{\circ}C$, annealing time of 60 minutes, and 0.6 g of potassium lumps. In this condition we were able to fabricate good quality films with high transition temperature of ~ 39 K.

A Study on the Real-time Optical Associative Memory Using Photorefractive Effects in $BaTiO_{3}$ ($BaTiO_{3}$ 의 광굴절 현상을 이용한 실시간 광연상 메모리에 관한 연구)

  • Ihm, J.T.;Oh, C.S.;Kim, S.I.;Park, H.K.
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.410-413
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    • 1988
  • In this paper, the real-time optical associative memory using multiple hologram which is generated with two angular multiplexed reference beams and Fourier transformed object beam in the $BaTiO_{3}$ crystal based on DFWM mechanism. When one image is recorded in the $BaTiO_{3}$ crystal, complete image can be recalled by 9 % partial input of the stored original image without any additional thresholding and optical feedback process. As an experimental result of multiple Fourier hologram which is recorded with two binary images, OHCHAS and PARKHK, we can obtain complete image recalled by 1/6 partial input of the stored image.

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