• Title/Summary/Keyword: 6BA

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The Behavior of the Formation of (111) Twins in $BaTiO_3$ Synthesized by Sol-Gel Route (졸-겔법으로 제조한 $BaTiO_3$에서(111)쌍정의 생성거동)

  • Yoo, Young-Sung;Kim, Young-Jung;Kim, Hwan
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.175-181
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    • 1996
  • Ti(i-OC3H7)와 Ba(OH)2.8H2Or 그리고 공통용매로서 2-Methoxy Ethanol을 이용하여 균일 용액을 제조하고, 이로부터 미세하고 조성비가 균일한 BaTiO3분말을 제조하였다. 이러한 졸-겔법으로 제조된 분말을 TG-DTA와 XRD 분석으로 결정화 및 상변화를 관찰하였다. 각 온도별로 하소된 분말에서 (111)쌍정의 생성여부를 TEM을 이용해 관찰한 결과, 합성된 BaTiO3 분말에서는 하소중(111)쌍정의 생성이 활발히 일어나지 않는 것으로 판단되었다. 특히(111) 쌍정판은 합성된 겔을 120$0^{\circ}C$에서 하소한 후 이를 140$0^{\circ}C$에서 소결한 경우에만 관찰할 수 있었다. 이러한 하소온도의 영향은 원료분말의 입자크기나 형상이 쌍정 생성에 큰 영향을 미침을 의미하는 것으로, 본 연구에서는 이를 근거하여 (111) 쌍정의 생성에 대해서 고찰하였다.

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The Etching Mechanism of $(Ba, Sr)TiO_3$Thin Films in $Ar/CF_4$ High Density Plasma ($Ar/CF_4$ 고밀도 플라즈마에서 $(Ba, Sr)TiO_3$ 박막의 식각 메카니즘)

  • Kim, Seung-Beom;Kim, Chang-Il
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.5
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    • pp.265-269
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    • 2000
  • $(Ba, Sr)TiO_3$thin films were etched with a magnetically enhanced inductively coupled plasma (MEICP) at different CF4/Ar gas mixing ratios. Experimental was done by varying the etching parameters such as rf power, dc bias and chamber pressure. The maximum etch rate of the BST films was $1800{AA}/min$ under $CF_4/(CF_4+Ar)$ of 0.1, 600 W/350 V and 5 mTorr. The selectivity of BST to Pt and PR was 0.6, 0.7, respectively. X-ray photoelectron spectroscopy (XPS) results show that surface reaction between Ba, Sr, Ti and C, F radicals occurs during the (Ba, Sr)TiO3 etching. To analyze the composition of surface residue after the etching, films etched with different CF_4/Ar$ gas mixing ratio were investigated using XPS and secondary ion mass spectroscopy (SIMS).

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Determination Times for Induction of Adventitious Shoots, Roots, Trichomes, and Calli from Segments of Arabidopsis thaliana by NAA and BA (애기장대(Arabidopsis thaliana)잎 절편에서 NAA와 BA에 의한 신초, 부정근, 모용 및 캘러스 형성 결정 시기)

  • Kim, Song-Lim;Han, Tae-Jin
    • Journal of Plant Biotechnology
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    • v.30 no.2
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    • pp.161-165
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    • 2003
  • The effect of NAA and Benzyladenine(BA) for determination times on the formation of adventitious shoots, roots trichmoes and calli in MS basal medium was investigated in leaf segments from ecotype 'Nosses' of Arabidopsis thalliana. Adventitious shoots, roots, trichomes and calli were formed fromed from leaf segments in a wede range of NAA and BA. The optimal combination of hormones for adventitious shoots formation, 20mg/L NAA for trichome formation, 100mg/L for callus formation. Inductive times for formation of adventitious shoots, roots, trichomes and calli were determined at 14, 4, 6 and 18 days respectively by periodical transfer of leaf segments from hormines containing media to hormone free medium.

Surface Reoxidation Mechanism and Electrical Properites of SBLC in $BaTiO_3$ System ($BaTiO_3$계 SBLC의 표면 재산화 형성 기구 및 전기적 성질)

  • 이형규;김호기
    • Journal of the Korean Ceramic Society
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    • v.23 no.5
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    • pp.55-60
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    • 1986
  • A mechanism for formation of surface reoxidation layer in Surface Boundary Layer Capacitor (SBLC) has been studied. SBLC were prepared by reduction of $BaTiO_3$ doped with $Bi_2O_3$ and electrode firing of silver paste containing $Bi_2O_3$ The apparent dielectric constant was in the order of $10^5$ and the insulation resistance larger than $10^6$$\Omega$ It can be expected that $Bi_2O_3$ dopant in $BaTiO_3$ plays the role of inhibition of grain growth and decreasing the resistivity of $BaTiO_3$. In order to confirm the process of surface reoxidation layer effects of atmosphere and annealing time in electrode sintering were investigated.

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Effect of Bi2O3/Li2CO3 on Low Temperature Sintering and Dielectrics of BaTiO3 Ceramics (BaTiO3 저온 소결 및 유전상에 미치는 Bi2O3/Li2CO3의 영향)

  • 윤기현;신현민;강동헌
    • Journal of the Korean Ceramic Society
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    • v.26 no.6
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    • pp.843-849
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    • 1989
  • Effect of Bi2O3/Li2CO3 on low temperature sinteirng and dielectric property of BaTiO3 ceramics has been investigated. For the specimen sintered at 110$0^{\circ}C$, it was densified to 96% of BaTiO3 theoretical density by the addition of 1.0-1.25w/o Bi2O3/Li2CO3. Maximum dielectric constant increased and Curie temperature lowered with the increase of Bi2O3/Li2CO3 content, which probably can be explained by thne substitution of Bi3+, Li1+ on BaTiO3 lattice. The volatilization of Li1+, resulting from the increase of soaking time at 110$0^{\circ}C$ leads to the increase of Curie temperature and tetragonality of the specimen.

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Structural Study of 90K Superconductor Gd1Ba2Cu3O9-x (90K 초전도체 Gd1Ba2Cu3O9-x의 구조에 관한 연구)

  • 이성익;권기정;이기봉;박병규;박병학;신현준
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.577-584
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    • 1988
  • Gd1Ba2Cu3O9-x has been found to be a high Tc superconductor with a transitiion onset at 91K and zero resistance achieved at 87K. The structure as determined from x-ray diffraction is orthorhombic, with lattice constants b=3.842$\pm$0.002$\AA$, b=3.895$\pm$0.003$\AA$, and c=11.684$\pm$0.007$\AA$. The structural similarities between the Gd1Ba2Cu3O9-x compound and the well-studied single phase perovskite, Y1Ba2Cu3O9-x are discussed. A correlation between the observed x-ray spectrum and the effect of oxygen deficiencies in several of the unit cell planes is also discussed.

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Zone-melting Process of NdBaCuO Superconductor under Low Oxygen Pressure

  • Soh, Deawha;Zhanguo, Fan;Yingmei, Li
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2004.05a
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    • pp.6-8
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    • 2004
  • The NdBaCuO superconductor samples were zone-melted in low oxygen partial pressure (1 % $O_2$+99%Ar). The zone-melting temperature was decreased about 12$0^{\circ}C$ from 1, 06$0^{\circ}C$, the zone-melting temperature in air. Thus the loss of liquid phase (BaCu $O_2$and CuO) was reduced during the zone-melting process. The content of non-superconducting phase Nd422 in zone-melted NdBaCuO samples was clearly decreased and, therefore, the substitution of Nd for Ba was occurred. The superconductivity of zone-melted N $d_{1+x}$B $a_{2-x}$C $u_3$ $O_{y}$prepared under low oxygen partial pressure was distinctively improved.d.d.d.

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Crystal structure of the epitaxial $BaTiO_{3}$ thin film on the MgO (100) substrate prepared by the coating-pyrolysis process

  • Kim, S.;Kwon, O.Y.;Choi, S.W.;Manabe, T.;Yamaguchi, I.;Kumagai, T.;Mizuta, S.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.6
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    • pp.378-380
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    • 2000
  • The epitaxial $BaTiO_{3}$ thin film was prepared on the MgO substrate by the coating-pyrolysis process using a mixed solution of Ba-naphthenate and Ti-naphthenate. The crystal structure of the epitaxial $BaTiO_{3}$ thin film was characterized by XRD ${\theta}/2{\theta}$ scan and asymmetric {303} rocking curve scan. The epitaxial $BaTiO_{3}$ thin film had the cubic phase with the lattice parameter of a = c = 0.4018 nm.

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Effects of Growth Regulators on the Tuberization of Perennial Weed, Cyperus serotinus Rottb. (생장조절제(生長調節劑)가 다년생잡초(多年生雜草) 너도방동사니(Cyperus serotinus Rottb.) 괴경형성(塊莖形成)에 미치는 영향(影響))

  • Kim, K.W.;Kim, K.U.
    • Korean Journal of Weed Science
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    • v.6 no.1
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    • pp.18-24
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    • 1986
  • This study was conducted to determine the possible role of growth regulators and the effect of foliar part cutting on the tuber formation of C. serotinus. Foliar application of 6-benzylaminopurine (BA) increased tuber number and fresh weight of C. serotinus by an average of 24.7% and 32.4%, respectively, as compared with the untreated control. However, the tuberization of C. seratinus was inhibited by single treatment of abscisic acid (ABA) and gibberellic acid (GA) as the concentrations increased. As compared with the untreated control, BA at $10^{-4}$M and combination of BA $10^{-5}$ + GA $10^{-5}$M increased 31.8% and 53.7% of tuber number, respectively, but GA at $10^{-5}$M decreased tuber number by 21.9%. 15㎏/10a of nitrogen under three levels of BA resulted in the highest number of tuber formation of C. serotinus, an increase of 24.7% as compared with the untreated control. GA treated increased flowering of C. serotinus by an average of 4.8% based on the untreated control. Tuber number and fresh weight of C. serotinus was markedly inhibited as the number of cutting times increased. Three times cutting inhibited tuber number and fresh weight of C. serotinus by 76.1% and 96.6%, respectively, under nitrogen of 15kg per 10a as compared with the untreated control.

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Bud sprouting and Tuberization of Eleocharis kuroguwai Ohwi (올방개(Eleocharis kuroguwai Ohwi)의 맹아(萌芽) 및 괴경형성(塊莖形成)에 관(關)한 연구(硏究))

  • Kim, Kil-Ung;Kwon, Soon-Tae
    • Korean Journal of Weed Science
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    • v.5 no.1
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    • pp.43-49
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    • 1985
  • This study was conducted to investigate the existance of dormancy in newly collected tubers of Eleocharis kuroguwai Ohwi from paddy fields and to determine the effect of various growth regulators on the bud sprouting and tuberization of E. kuroguwai. The maximum percent sprouting of E. kuroguwai collected at every month during winter was less than 60% regardless of varied collection tunes until 50 days after incubation, suggesting the presence of dormancy in E. kuroguwai tubers. This dormancy was markedly broken as the time went by, probably due to the exposure of tubers the extremly low temperature. The treatment of $BA10^{-3}M$ and $BA10^{-3}+GA10^{-6}M$ increased bud sprouting about 10 and 11 times, respectively, than that of the untreated control indicating that BA seems to be one of the most effective agents among the growth regulators used on the bud sprouting of E. kuroguwai. Foliar application of BA increased tuberization of E. kuroguwai by an average of 34.4% as compared with the untreated control. The highest increase, 39.8% was obtained with BA treatment at $10^{-5}M$.

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