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Hydrothermal Synthesis of Ultra-fine SrAl2O4:Eu Powders and Investigation of their Photoluminescent Characteristics (수열합성법에 의한 SrAl2O4:Eu 초미세 분말 합성공정 및 형광 특성)

  • 박우식;김선재;김정식
    • Journal of the Korean Ceramic Society
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    • v.41 no.5
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    • pp.370-374
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    • 2004
  • Sr$_{l-x}$Ba$_{x}$Al$_2$O$_4$:Eu (x = 0, 0.1, 0.2, and 0.3 mol) phosphor was synthesized by the hydrothermal method and its properties of photoluminescence and long-afterglow were investigated. The mixtures of Sr(NO$_3$)$_2$, Al(NO$_3$)$_3$9$H_2O$, and Eu(NO$_3$)$_3$$.$6$H_2O$ salts dissolved in distilled water, after controlling their pH by NH$_4$OH solution, put into an Autoclave reactor with high temperature and pressure to react. Such synthesized SrAl$_2$O$_4$:Eu powders showed homogeneous and ultra-fine particles of sub-micron size. In order to have the photoluminescence characteristic, powders were heat treated at 1100 -140$0^{\circ}C$ for 2 h in Ar/H$_2$ reduction atmosphere. Photoluminescence spectra showed a excitation along the wide wavelength of 250 ∼ 450 nm, and broaden emission with maxima peak at 520 nm. Also, it showed a good long afterglow with decaying over 1000 sec after excitation illumination for 10 min. In addition, the microstructure and crystal structure of SrAl$_2$O$_4$:Eu powders were investigated by an SEM and XRD, respectively.

An Experimental Study on the Engineering Properties of Concrete according to W/C and Replacement Ratio of Bottom Ash (물-시멘트비 및 바텀애쉬 대체율에 따른 콘크리트의 공학적 특성에 관한 실험적 연구)

  • Choi, Se-Jin;Jeong, Yong;Oh, Bok-Jin;Kim, Moo-Han
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.840-847
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    • 2003
  • Recently, the coal-ash production has been increased by increase of consumption of electric power. So it is important to secure a reclaimed land and treatment utility for coal-ash. This is an experimental study to compare and analyze the engineering properties of concrete according to W/C and replacement ratio of bottom ash. For this purpose, the mix proportions of concrete according to W/C(40, 50, 60%) and replacement ratio of bottom ash(0, 10, 20, 35, 50%) were established, and then tested for slump, chloride content, setting time, bleeding content, compressive strength. Also the durability test of concrete with W/E 60% was performed. According to test results, it was found that the bleeding content of concrete decreased as the replacement ratio of bottom ash increased. And the chloride content of concrete using the bottom ash increased as the replacement ratio of bottom ash increased, but it is satisfied with the chloride content of fresh concrete $0.30kg/m^3$ below("concrete standard specification" regulation value). The compressive strength of concrete using the bottom ash was similar to that of BA0 concrete after 28 days of curing and the carbonation depth of concrete was increased according to increase of the replacement ratio of bottom ash.

New weighting agent for water-based mud, um-bogma area, central Sinai, Egypt

  • Abdou, Mahmoud I.;Ahmed, Hany El Sayed
    • Advances in environmental research
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    • v.6 no.3
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    • pp.159-171
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    • 2017
  • A successful oil well drilling depends largely on a good mud Program. During drilling, mud provides sufficient hydrostatic pressure, removes drill cuttings and cools drill bits. Mud additives are always required to provide sufficient hydrostatic pressure to ensure borehole stability. Barium Sulphate ($BaSO_4$) also known as barite is the prevalent weighting material but there is needed to develop local materials to augment the use of Barite. The present search is concerned on the early Carboniferous succession exposed in Um Bogma Formation, west central Sinai, Egypt as a new weighting agent in drilling fluids. The increases in the cost of drilling fluids and a shortage of using barite have introduced the locale dolomite as alternative weighting materials. The rheological properties of mud drilling samples weighted by local dolomite samples are being examined and investigated to know its potential to be used as a weighting material in drilling mud. Two mud samples were prepared which comprised of fresh water, caustic soda, bentonite and the weighting material. The weighting materials are added to achieve the required density. The first sample: Water-based mud with commercial barite of density between 10.00 lb/gm and 18.00 lb/gm. The second sample: Water-based mud with dolomite of density between 10.00 lb/gm and 18.00 lb/gm. These samples were analyzed and the density, rheological properties, aging of barite and dolomite and solid contents were investigated. At 10.00 lb/gm, the yield point of dolomite was $20.00lb/100ft^2$ and barite $22.00lb/100ft^2$ while the 10 second gel strength of dolomite was $30.00lb/100ft^2$ and $22.00lb/100ft^2$ for barite. Similarly, little difference was observed in plastic and apparent viscosities. At 10.00 lb/gm, the plastic and apparent viscosities of dolomite were 8.00 cp and 20.00 cp while barite was 8.00 cp and 24.00 cp. The result show that dolomite mud sample gave a little higher yield point and gel strength than barite mud sample. Therefore, dolomite has the potential to be used as weighting material in drilling mud in place of barite thereby enhancing the local content initiative of the government. When dolomite is sourced locally and used it will reduce overall mud and drilling costs.

Influences of Asian Dust, Haze, and Mist Events on Chemical Compositions of Fine Particulate Matters at Gosan Site, Jeju Island in 2014 (황사, 연무, 박무 현상이 미세먼지 화학조성에 미치는 영향: 2014년 제주도 고산지역 측정)

  • Song, Jung-Min;Bu, Jun-Oh;Yang, Seung-Hyuk;Lee, Jae-Yun;Kim, Won-Hyung;Kang, Chang-Hee
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.1
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    • pp.67-81
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    • 2016
  • In order to examine the variation characteristics of chemical compositions in accordance with the different meteorological conditions, $PM_{10}$ and $PM_{2.5}$ were collected at Gosan site of Jeju Island in 2014, and then their ionic and elemental species were analyzed. The concentrations of nss-$SO{_4}^{2-}$ and $NH_4{^+}$ were respectively 4.3 and 3.3 times higher in fine particle mode ($PM_{2.5}$) compared to coarse particle mode ($PM_{10-2.5}$), however $NO_3{^-}$ concentration was 1.6 times higher in coarse mode compared to fine particle mode. During Asian dust days, the concentrations of nss-$Ca^{2+}$ and $NO_3{^-}$ increased highly as 7.7 and 4.5 times in coarse particle mode, and 3.0 and 4.9 times higher in fine particles, respectively. Especially, the concentrations of the crustal species (Al, Fe, Ca, K, Mn, Ba, Sr, etc.) indicated a noticeable increase during the Asian dust days. For the haze days, the concentrations of secondary pollutants increased 2.2~2.7 and 2.9~6.0 times in coarse and fine particles, respectively, and they were 0.8~1.1 and 1.8~2.4 times, respectively, during the mist days. The aerosols were acidified largely by sulfuric and nitric acids, and neutralized mainly by ammonia in fine particle mode during the haze days, but neutralized by calcium carbonate in coarse particle mode during the Asian dust days. The clustered back trajectory analysis showed that the concentrations of nss-$SO{_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ were relatively high when the inflow pathway of air mass was from the southern part of China.

Lateral Root Formation and Growth of Soybean Sporouts Treated with Various Solutions (다양한 물질처리에 의한 콩나물의 세근형성 및 생장)

  • Kang, Jin-Ho;Park, Cheol-Jong;Yoon, Soo-Young;Jeon, Seung-Ho;Hong, Dong-Oh
    • Korean Journal of Medicinal Crop Science
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    • v.13 no.1
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    • pp.6-10
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    • 2005
  • Lateral roots of soybean sprouts should deeply affect their quality and marketability. The study was done to compare the effects of ocher, chitosan, corn kennel, tea (Thea sinensis L.) and hard rubber tree (Eucommia ulmoides Oliver) leaf extracts on lateral root formation, growth and morphological characters of the sprouts. Seeds of three cultivars, Pungsannamulkong, Sowonkong and Junjery, were imbibed for 5 hours into their 10% solutions and cultured for 6 days. The cultured sprouts were classified into 4 categories to calculate their composition rates on the base of hypocotyl lengths;>7 cm (A), 4 to 7 cm (B), < 4 cm (C) and not germinated (D), and their morphological characters, fresh and dry weights were measured. Composition rate of A was the lowest in Junjery of the three cultivars, while that of C showed reverse result compared to A. This results was the most distinct in hard rubber tree leaf extracts (HRTLE) of the five treatments. In HRTLE treatment, lateral root formation rate were formed in almost of Sowonkong although reduced in order of Pungsannamulkong and Junjery. However, there was no significant difference between the other treatments. Lateral roots per sprout were the lowest in HRTLE treatment of the 5 treatments. In all treatments except the chitosan treatment, the roots were most formed in Sowonkong but least in Junjery. Sprout length adding hypocotyl and root was the shortest in Junjery compared to the other two cultivars. and was the longest in tea leaf extract treatment but the shortest in HRTLE treatment. The result in total fresh weight of sprouts was similar to that of the sprout length.

Purification and Characterization of the Extracellular Alginase Produced by Bacillus licheniformis AL-577 (알긴산 분해균 Bacillus licheniformis AL-577가 생산하는 균체외 효소의 정제 및 특성)

  • Uo, Meung-Hee;Joo, Dong-Sik;Cho, Soon-Yeong;Min, Tae-Sun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.2
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    • pp.231-237
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    • 2006
  • The extracellular enzyme alginase produced by Bacillus licheniformis AL-577 was purified by ion chromatography on CM-Cellulose column, DEAE-Sepharose column, and followed by gel filtration on Sephadx G-100 column. The optimum pH and temperature for the activity of the purified enzyme were 6.0 and $35^{\circ}C$, respectively. The enzyme was stable at the pH range of $6.0\~9.0$ and at $20^{\circ}C$. The molecular weight of the enzyme was estimated to be about 25,500 daltons by SDS-polyacrylamide gel electrophoresis. NaCl was required for high activity of the enzyme. The enzyme was inhibited by $Ba^{2+},\;Co^{2+},\;Cu^{2+},\;Fe^{2+},\;Mg^{2+},\;Zn^{2+},\;NH_4^+$, EDTA, L-cysteine, and 2-mercaptoethanol, while stimulated by DTT, O-phenanthroline, $K^+$ and $Li^+$. This enzyme was proposed to be an alginase specifically degrading alginic acid.

Effect of Nitrogen Fertilizer Level and Mixture of Small Grain and Forage Rape on Productivity and Quality of Spring at South Region in Korea (남부지방 봄철 질소 시비수준 및 사료작물과의 혼파가 사료용 유채의 생산성 및 사료가치에 미치는 영향)

  • Kim Jong Geun;Chung Eui Soo;Seo Sung;Kim Meing Joong;Chang Young Seok;Chung Byeng Chun
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.25 no.3
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    • pp.143-150
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    • 2005
  • These experiment was conducted to determine the effect of nitrogen fertilizer levels and mixture small grains on productivity and quality of spring forage rape at south region of Korea(Mokpo). The experiment was arranged in a split plot design with three replications. The main plots consisted of three different levels of nitrogen fertilizer(100, 150 and 200 kg/ha). The sub plots consisted of five kinds of mixed small grain species(Rye, Oat, Barley, Italian ryegrass, and Rape monoculture). The results obtained are summarized as follow. Dry matter(DM) content of Rye + Rape and Ba.ley + Rape mixtures were increased by $2\~3\%$ compared to Rape monoculture. The high level of nitrogen application increased the fresh matter yield, and yield of Rye + Rape and Rape monoculture were higher than that of others. Dry matter yield of Rye + Rape mixture and Rape monoculture with 200kg/ha of nitrogen application were higher by 9,449 and 9,227 kg/ha, respectively. The crude protein(CP) content of rape was high as $18.6\%$ while average CP content was $16\%$. The average total digestible nutrient(TDN) content showed high as $70\%$. It is suggested the Rye + Rape mixture or Rape monoculture would recommendable for spring usage of rape at south region of Korea.

Effects of Food Additive Acetic Acids and Propionic Acids on Growth and Morphological Characters of Soybean Sprouts (식품첨가물 Acetic Acid와 Propionic Acid 처리농도에 따른 콩나물의 생장과 형태 변화)

  • Hong, Dong-Oh;Jeon, Seung-Ho;Jeon, Byong-Sam;Lee, Chang-Woo;Kim, Hong-Young;Kang, Jin-Ho
    • Korean Journal of Plant Resources
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    • v.19 no.5
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    • pp.606-611
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    • 2006
  • Decay during soybean sprout culture detracts their quality as well as increases their production costs. This study was done to determine the effects of acetic and propionic acids on growth and morphological characters of the sprouts. The soybean seeds of 3 cultivars (cv. Eunhakong, Pungsannamulkong and Orialtae) imbibed for 2 minutes at their different concentrations (0, 0.1 and 0.2%) were soaked for 6 hours in 4 ppm BA solution after the first 5.5 hour water imbibition and 0.5 hour aeration, and cultured at $20^{\circ}C$. On the 6th day, harvested soybean sprouts were classified into 4 categories on the base of hypocotyl length;>7cm, 4 to 7cm,<4cm and not germinated, and their morphological characters, fresh weights, lesion spots on cotyledons were measured or analyzed. The stronger concentration the higher rate of longer than 4cm although there was no significant difference between the two acids. Pungsannamulkong showed the longest hypocotyls but Eunhakong did the thickest ones, and Orialtae did the greatest total fresh weight, in which all the characters were not influenced by the two acids and their concentrations. Lesion spots on the cotyledons were equal to the two acids although less in their treatments than in no treatment. Utilization of propionic acid was more desirable Dan acetic acid through their treatment cost analysis.

Background $K^+$ channel currents in WEHI-231 cells, immature B lymphocytes

  • Nam, Joo-Hyun;Woo, Ji-Eun;Kim, Tae-Jin;Uhm, Dae-Yong;Kim, Sung-Joon
    • Proceedings of the Korean Biophysical Society Conference
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    • 2003.06a
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    • pp.39-39
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    • 2003
  • In our previous study, WEHI-231, an immature B cell line, showed intractable increase in [C $a^{2+}$]$_{c}$ after the B-cell receptor (BCR) ligation and treatment with 2-aminoethoxydiphenylborate (2-APB), which was never observed in Bal-17, a mature B cell line (Nam et al., 2003, FEBS Lett). In this study, a whole cell voltage clamp study revealed a specific expression of a novel type of $K^{+}$ current, namely voltage-independent background-type $K^{+}$ channels (IK-bg), in WEHI-231 cells. IK-bg was dramatically increase by the application of 2-APB (50 $\square$M), which induced severe hyperpolarization of WEHI-231 from -45 ㎷ to -90 ㎷, When dialyzed with $Mg^{2+}$ and ATP-free pipette solution, a spontaneous development of IK-bg and membrane hyperpolarization were observed. IK-bg was insensitive to classical $K^{+}$ channel blockers (TEA, glibenclamide, $Ba^{2+}$(1 mM)), whereas blocked by quinine and quinidine in a voltage-dependent manner ($IC_{50}$/=6~9 $\square$M at +60㎷). Phorbol myrstate, a PKC activator, decreased the amplitude of IK-bg. Extracellular acidification (pH 6.5) slightly inhibited IK-bg. Arachidonic acid, riluzole, or hyposmotic stress could not affect the IK-bg after the full development by the intracellular dialysis with Mg-ATP-free solution. In a cell-attached mode of single channel recording from WEHI231, we found two types of voltage-independent $K^{+}$ channels with unitary conductance of 300 pS and 120 pS, respectively. Both channels showed very short mean open times and their open probabilities were increase by the application of 2-APB. In Bal-17 cells, no such $K^{+}$ current was observed in 50 cells tested. In summary, WEHI-231 immature B cells express background $K^{+}$ channels. The pharmacological properties and the large unitary conductance suggest that novel types of two-pore domain $K^{+}$ channels (2-P-K channels) might be expressed in WEHI-231, which may provide an intriguing targets of signal transduction in the immature B lymphocytes.e B lymphocytes.

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VARIATION IN THE GROWTH PATTERN OF THE FACE: A LONGITUDINAL COMPUTERIZED RECTILINEAR CEPHALOMETRIC STUDY (안면골의 성장회전에 관한 연구)

  • Kim, Il-Bong;Sung, Jae-Hyun;Chung, Kyu-Rhim
    • The korean journal of orthodontics
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    • v.15 no.1
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    • pp.123-140
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    • 1985
  • Variation in the facial pattern and effect of the rotational jaw growth on the facial proportion were studied in serial cephalometric radiographs of 40 Korean children (25 boys, 15 girls) ranging in age from 6 to 13 years. According to Y-axis (N-S-Gn) growth change during the 7 years of period, the subject who had exhibited 'wave-like' manner of Y-axis growth change within ${\pm}\;2^{\circ}$ was classified to the Parallelwise group and the subject who had exhibited Y-axis increase more than $+2^{\circ}$ was classified to the Clockwise rotation group and the subject who had exhibited Y-axis decrease more than $-2^{\circ}$ was classified to the Counterclockwise rotation group. For the comparison of each group, a total of 22 morphologic variables were employed and the data were analyzed by means of computer morphometrics and statistical methods. On the basis of the finding of this study, the following trends were established. 1. The Parallelwise group was $75\%$, the Clockwise rotation group was $12.5\%$ and the Counter-clockwise rotation group was $12.5\%$. 2. The growth pattern of cranial base was related to the rotation of mandible. 9. Maxillary prognathism was occured in the Counterclockwise rotation group and the rotation of palatal plane was occured in the Clockwise rotation group. 4. Mandibular prognathism was occured in the Parallelwise and the Counterclockwise rotation groups, especially in the Counterclockwise rotation group. 5. The degree of maxillo-mandibular divergency was constant in the Clockwise rotation group but decreased in the Counterclockwise rotation and the Parallelwise groups, especially in the Counterclockwise group. 6. There were no differences in the size of the anterior upper facial height (N-ANS) and the posterior lower facial height ((Go-Me)-PNS) but there were differences in the size of the anterior lower facial height (ANS-Me) and the posterior upper facial height ((S-N)-PNS) between each group. 7. The growth increment and the size of the facial depth was not related to the growth pattern of the face but the growth increment and the size of the facial height was related to the growth pattern of the face. 8. Proportional change due to the facial growth rotation was concentrated in the anterior lower face. 9. The most apparent difference between each group was happened in the size of the posterior cranial base (S-Ba) and the facial length (S-Gn).

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