• Bulletin of the Korean Chemical Society
• /
• v.24 no.6
• /
• pp.832-836
• /
• 2003

To extend the knowledge of triple bonding between group 6 transition metal and heavier group 14 elements, the structural and bonding aspects of ($η^5-C_5H_5$)$(CO)_2$M≡ER (M = Cr, Mo, W; E = Si, Ge, Sn, Pb) are investigated by hybrid density functional calculations at the B3PW91 level. Substituent effects are also investigated with R = H, Me, $SiH_3$, Ph, $C_6H_3-2,6-Ph_2$, $C_6H_3-2,6-(C_6H_2-2,4,6-Me_3)_2$, and $C_6H_3-2,6-(C_6H_2-2,4,6- iPr_3)_2$.

• Korean Journal of Crystallography
• /
• v.10 no.2
• /
• pp.105-109
• /
• 1999

Ar 기류 하에서 Re(N-C6H3-2,6-i-Pr2)2Cl3(py) (1)과 propionaldehyde (C2H5CHO)가 반응하여 생성된 혼합물에서, [cis-ReCl4(py)(N-C6H3-2,6-i-Pr2)·(NH2-C6H3-2,6-i-Pr2)] (2)가 분리되었다. 이 화합물의 구조가 X-ray 회절법으로 규명되었다. 착물 2의 결정학 자료: 단사정계 공간군 P21/n, a=11.555(1) Å, b=27.066(3) Å, c=11.881(1) Å, β=117.991(8)°, Z=4, R(wR2)=0.0332(0.0851.

• Journal of Microbiology and Biotechnology
• /
• v.29 no.6
• /
• pp.856-862
• /
• 2019

A series of thienopyrimidine compounds (6Aa-g and 6Ba-d) were synthesized and characterized by NMR spectroscopy and mass spectrometry. These compounds (6Aa-g and 6Ba-d) potently inhibited STAT3 expression induced by IL-6 in a dose-dependent manner with $IC_{50}$ values of $5.73-0.32{\mu}M$. Among the prepared thienopyrimidine derivatives, 6Aa, 6Ab, 6Ba and 6Bc significantly suppressed the phosphorylation of STAT3 and ERK1/2 stimulated by IL-6 in Hep3B cells. Furthermore, the synthesized compounds might be useful remedies for the treatment of inflammatory diseases by inhibiting the action of IL-6.

• The Journal of the Korea Contents Association
• /
• v.17 no.7
• /
• pp.294-302
• /
• 2017

In this study, latent fingermarks deposited in porous or non-porous surface was developed by cyanoacrylate fuming, and then the developed fingermark is enhanced by using Rhodamine 6G. Between water-based R6G and organic solvent-based R6G, author studied about which material have higher effectiveness in enhancing fingermark. In all seven types of surfaces depositing fingermark, water-based R6G have higher effectiveness in enhancing fingermark and lower surface coloring than organic solvent-based R6G. But because the surfaces found in crime scene have multicolor background and various quality, the additional study about various surfaces is needed.

• Journal of Korean Academy of Nursing
• /
• v.34 no.2
• /
• pp.324-332
• /
• 2004

Purpose: The purpose of this study was to explain differences of cesarean section rates according to San- Yin-Jiao(SP6) acupressure for women in labor. Method: A noneqivalent control group pre test - post test design was used to explain differences of cesarean section rates according to SP6 acupressure. The participants were 209 women who were assigned to one of three groups SP6 acupressure(n=86), SP6 touch(n=47), and control group(n=76). For 30 minutes, the SP6 acupressure group received SP6 acupressure, and the SP6 touch group received SP6 touch for the duration of each uterine contraction. The Control group was encouraged to deep breath and relax for the duration of each uterine contraction for 30 minutes. Result: The rates of cesarean section were 12.8%, 29.8%, and 22.4% for the SP6 acupressure group, SP6 touch group, and control group respectively. There was a significant difference among groups (p=0.049). Cesarean section rateswere significantly different between the SP6 acupressure and non-SP6 acupressure group(p=0.035). Conclusion: This finding shows that 30 minutes of SP6 acupressure was effective in decreasing the cesarean section rate. Therefore, SP6 acupressure during labor could be applied as an effective nursing intervention.

• Journal of Community Nutrition
• /
• v.7 no.2
• /
• pp.79-84
• /
• 2005

A vitamin B-6 (B-6) intake higher than the current Recommended Dietary Allowance (RDA) has been found to provide an improvement in immune system. Seven premenopausal women consumed their usual diet with the exception of foods relatively high in vitamin B-6 for a total of 27 d. After 7 d, all subjects received a multivitamin supplement containing 2mg B-6 and 4 subjects were given an additional 50mg of B-6 supplement for 20 d. Lymphocyte response to phytohemagglutinin (PHA) was measured before and after the supplementation. To determine the effect of different forms of B-6 on lymphocyte proliferation, cell culture media supplemented with pyridoxal (PL) and PLP, as well as B-6 free media, were tested. A 50mg B-6 supplement significantly increased vitamin B-6 status. There was no further enhancement on lymphocyte proliferation when subjects were taking an additional 50mg of vitamin B-6 supplement. In general, lymphocyte proliferation in media with either PLP or PL did not show any prominent difference. These [m-dings suggest that there may be no further benefits of a B-6 dose beyond twice that of the current RDA on lymphocyte proliferation. Further studies are necessary to examine the effect of the B-6 intake level on activities of enzymes involved in cellular B-6 metabolism in lymphocytes to provide substantial insight into the mechanisms underlying the role of B-6 in the lymphocyte proliferation.

• Bulletin of the Korean Chemical Society
• /
• v.18 no.4
• /
• pp.402-405
• /
• 1997

Olefinic and cyclopropyl group substituted arenes (C6H5Y) react with [Cp*Ir(CH3COCH3)3]A2 (A=ClO4-, OTf-) to give η6-arene complexes, [Cp*Ir(η6-C6H5Y)]2+ (1a: Y=-CH=CH2 (a),-CH=CHCH3 (b),-C(CH3)=CH2 (c),-CH-CH2-CH2 (d)). Complex 1b-1d are readily converted into η3-allyl complexes, [Cp*(CH3CN)Ir(η3-CH(C6H5)CHCH2)]+ (2a) and [Cp*(CH3CN)Ir(η3-CH2(C6H5)CH2)]+ (2b), in the presence of Na2CO3 in CH3CN. The η6-styrene complex, 1a reacts with NaBH4 to give η5-cyclohexadienyl complex, [Cp*Ir(η5-C6H6-CH=CH2)]+ (3), while with H2 it gives η6-ethylbenzene complex [Cp*Ir(η6-C6H5CH2CH3)]2+ (4). Complex 1a and 1c react with HCl to give [Cp*Ir(η6-C6H5CH2CH2Cl)]2+ (5a) and [Cp*Ir(η6-C6H5CH(CH3)CH2Cl]2+ (5b), respectively.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2023.05a
• /
• pp.411-411
• /
• 2023

미래 대기 이산화탄소 농도가 증가함에 따라 강수 등 기후의 변화하고, 이는 유출량을 포함한 수문 순환 뿐 아니라 지면 식생 생장에 영향을 줄 것으로 예상된다. 이에 본 연구에서는 미래 CO2 증가에 따른 식생의 변화와 이로 인한 지표 유출량의 변화에 대해 이해하고자 한다. Intergovernmental Panel on Climate Change (IPCC) 6차 평가보고서에서 제시한 표준 온실가스 경로 중 탄소 모듈이 포함된 Coupled Model Intercomparison Project phase 6 biogeochemistry (CMIP6-BGC) 모델과 탄소 모듈이 포함안된 CMIP6 모델 결과를 활용하였다. 공통 사회경제경로 시나리오(Shared Socio-economic Pathway; SSP) 중 고탄소 시나리오인 SSP585에 따른 모델 결과물을 활용하였다. 표면 유출량 자료에 과거 기간 임계수준 방법을 (Threshold Level Method) 적용하여 동아시아 지역 극한 건조 및 습윤 상태의 빈도와 강도를 CMIP6-BGC와 CMIP6에 대해 평가하였다. CMIP6-BGC 경우, 건조 및 습윤 상태의 빈도는 각각 6.17%, 5.03% , CMIP6 경우 각각 9.29%, 6.70% 으로 예측되어, CMIP6-BGC가 CMIP6 보다 극한 상태를 과소평가하는 경향을 보였다. 또한, 잎 면적 지수(Leaf Area Index; LAI), 증산량 등의 변수를 분석하여, 기 도출된 CMIP6-BGC와 CMIP6 간의 극한 건조 및 습윤 상태 예측의 차이가 발생한 메카니즘을 이해하고자 하였다.

• Digital Contents
• /
• no.3 s.142
• /
• pp.30-35
• /
• 2005

휴대인터넷, VoIP(음성데이터통합) 서비스에 새로운 인터넷 주소체계인 IPv6(IP version 6)을 지원하기 위한 2차 KOREAv6(KOREA IPv6) 시범사업이 이달부터 본격화되면서 ‘IPv6 특수’에 대한 기대감이 한껏 커지고 있다. IPv6를 둘러싼 정책 추진 현황과 업계반응을 살펴봤다.

• Electronics and Telecommunications Trends
• /
• v.15 no.6 s.66
• /
• pp.18-25
• /
• 2000

본 고에서는 IPv6 기반 차세대 인터넷 교환노드 구축 동향 및 IPv6 시험망 구성을 위한 방법을 소개한다. 먼저 미국의 6TAP, 유럽의 AMS-IX. 일본의 NSPIXP-6 등 전세계 3대 IPv6 교환노드 구축 기술 및 현황을 살펴보고, IPv6 기반 시험망 구성을 위한 요구사항, 구축 사양 및 환경, 그리고 실제로 구축한 IPv6 시범 사이트의 예를 기술한다.