• 제목/요약/키워드: 6/8 structure

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소결온도에 따른 $0.6TiTe_3O_8-0.4CaWO_4$ 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of $0.6TiTe_3O_8-0.4CaWO_4$ Ceramics with Sintering Temperature)

  • 김재식;이문기;류기원;이성갑;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.342-343
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    • 2005
  • In this study,. the microwave dielectric properties of the $0.6TiTe_3O_8-0.4CaWO_4$ ceramics with sintering temperature were investigated for LTCC application. According to the X-ray diffraction patterns, the $0.6TiTe_3O_8-0.4CaWO_4$ ceramics had columbite structure of the $TiTe_3O_8$ phase and scheelite structure of the $CaWO_4$ phase. Increasing the sintering temperature, the bulk density, the dielectric constant and the quality factor of the $0.6TiTe_3O_8-0.4CaWO_4$ ceramics were increased. In the case of the $0.6TiTe_3O_8-0.4CaWO_4$ ceramics sintered at $810^{\circ}C$, the bulk density, the dielectric constant and the quality factor were 5.72$g/cm^2$, 33.6, 22,013GHz respectively.

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Crystal Structure of Dehydrated Partially Ag$^+$-Exchanged Zeolite A, Ag$_{4.6}Na_{7.4}$-A, Treated with Hydrogen at 350${^{\circ}C}$

  • 김양
    • Bulletin of the Korean Chemical Society
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    • 제6권4호
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    • pp.202-206
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    • 1985
  • The crystal structure of The crystal structure of $Ag^+$-Exchanged Zeolite A, $Ag_{4.6}Na_{7.4}-A$, dehydrated, treated with $H_2$, and evacuated, all at $350^{\circ}C$, has been determined by single crystal x-ray diffraction methods in the cubic space group Pm3m at $24(1)^{\circ}C;$ a = $12.208(2)\AA.$ The structure was refined to the final error indices R1 = 0.088 and R2 (weighted) = 0.069 using 194 independent reflections for which II_0$ > $3{\sigma}(I_0)$. On threefold axes near the centers of 6-oxygen rings, $7.4 Na^+$ ions and $0.6 Ag^+$ ions are found. Two non-equivalent 8-ring $Ag^+$ ions are found off the 8-ring planes, each containing about $0.6 Ag^+$ ions. Three non-equivalent Ag atom positions are found in the large cavity, each containing about 0.6 Ag atoms. This crystallographic analysis may be interpreted to indicate that $0.6 (Ag_6)^{3+}$ clusters are present in each large cavity. This cluster may be viewed as a nearly linear trisilver molecule $(Ag_3)^0$ (bond lengths, 2.92 and 2.94 $\AA;$ angle, $153^{\circ})$ stabilized by the coordination of each atom to a Ag^+$ ion at 3.30, 3.33, and 3.43 $\AA$, respectively. In addition, one of the silver atoms approaches all of the 0(1) oxygens of a 4-ring at $2.76\AA.$ Altogether $7.4 Na^+$ ions, $1.8 Ag^+$ ions, and 1.8 Ag atoms are located per unit cell. The remaining $1.0 Ag^+$ ion has been reduced and has migrated out of the zeolite framework to form silver crystallites on the surface of the zeolite single crystal.

간헐포기MBR공정에서의 하수처리성능과 미생물의 군집구조해석 (Microbial Community Structure and Treatment Characteristics of Domestic Wastewater in the Intermittently Aerated Membrane Bioreactor)

  • 임병란;안규홍
    • 상하수도학회지
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    • 제16권6호
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    • pp.679-685
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    • 2002
  • The objective of this study was investigated for the microbial community structure and treatment performance of domestic wastewater in lab-scale submerged membrane bioreactor operated with anoxic-oxic cycles. Respiratory quinone profiles were applied as tools for identifying different bacterial populations. The cycle time program of bioreactor was control under anoxic/oxic of 60/90 minutes with an hydraulic retention time of 8.4 hrs. The average $COD_{Cr}$ removal efficiency of domestic wastewater was as high as 93%. The results showed complete nitrification of $NH_4^+$-N generated during oxic period and up to 50% of the total nitrogen could be denitrified. The dominant quinone types of suspended microorganisms in bioreactor were ubiquinone (UQ)-8, -10, followed by menaquinone (MK)-6, and MK-7 for anoxic period, but those for oxic period were UQ-8, MK-6, followed by UQ-10 and MK-7. The microbial diversities of bioreactor at anoxic and oxic periods, calculated based on the composition of all quinones were 10.4 and 12.2-11.8, respectively. The experimental results showed that the microbial community structure in the submerged membrane bioreactor treating domestic wastewater was slightly affected by intermittent aeration.

기존 12/8 및 새로운 6/5 SRM의 성능분석 및 비교 (Performance Evaluation and Comparison of Conventional 12/8 and Novel 6/5 Switched Reluctance Motors)

  • 서진요;이동희;안진우
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2016년도 전력전자학술대회 논문집
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    • pp.517-518
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    • 2016
  • In this paper, a novel 6/5 switched reluctance motor (SRM) with segmental rotor is proposed for vehicle cooling fan application. Unlike conventional SRMs, the proposed motor adopts hybrid stator poles and segmental rotor structures, thereby making the motor operate in short flux paths and parts of the flux paths magnetically isolated between the phases. Therefore, compared with conventional SRMs, the proposed structure could improve the output torque density and reduce the core loss, thereby improving the electric utilization of the motor. To verify the proposed structure, the performance of the proposed structure is evaluated. Meanwhile, a conventional 12/8 SRM which has been used for vehicle cooling fan application is also evaluated. Finally, the effectiveness of the proposed SRM is demonstrated by the simulation and experimental results.

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Structure Study of Polycrystalline $Na_3YSi_3O_9$ and Its Substitutes Related to $Na_4CaSi_3O_9,\;Ca_3Al_2O_6$ Structure

  • Kim, Chy-Hyung;Banks, Ephraim
    • Bulletin of the Korean Chemical Society
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    • 제8권1호
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    • pp.6-9
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    • 1987
  • The study of the $Na_3YSi_3O_9$ structure, by x-ray diffraction and infrared spectrum, showed that $Na_3YSi_3O_9$ is similar to $Na_4CaSi_3O_9$ except for its being pseudo-cubic instead of cubic. The peaks in the x-ray diffraction pattern of $Na_3YSi_3O_9$ could therefore be indexed on the basis of the $Na_4CaSi_3O_9$ cell. Also, modified $Na_3MSi_3O_9$ (M = Lu, Yb, Tm, Er, Y, Ho, Dy, Gd, Eu, and Sm) type compounds were synthesized by introducing excess sodium, decreasing M(III) concentration, and substituting small amount of phosphorus for silicon. The unit cell parameters of the composition $Na_{3.2}M_{0.7}Si_{2.9}P_{0.1}O_{8.7}$ were estimated from x-ray powder diffraction patterns using the Cohen method.

팬구동용 저압 8/6 SRM의 설계 및 구동 특성 (Design and Drive Characteristics of Low Voltage 8/6 SRM for Fan Application)

  • 안진우
    • 전기학회논문지
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    • 제63권10호
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    • pp.1371-1376
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    • 2014
  • In this paper, 4-phase switched reluctance motor(SRM) with 8-stator and 6-rotor pole structure is proposed for a high speed fan with a low voltage. The air blower has unidirectional rotation characteristics and requires a low torque ripple and noise as well as high efficiency. To achieve the requirements, voltage and current according to loading condition of limited specification is considered. Design process is to select the bore diameter, pole arc, york of stator and rotor to get a high torque and efficiency. To verify the validity of the proposed structure, finite element method(FEM) is employed to get the performances. And the converter for the proposed SRM is employed a 1.5q power converter for cost effectiveness. Prototype SRM is manufactured and tested, and the test results show this design is within the specification and good for the air blower applications.

기계천수계의 저서성 대형무척추동물 군집구조 (Community Structure of Benthic Macroinvertebrates from Gigye Stream)

  • 김중락
    • 한국환경과학회지
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    • 제17권8호
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    • pp.879-889
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    • 2008
  • Community structure of benthic macroinvertebrates was investigated from Gigye stream, Pohang, Korea from May to November, 2007. As results, total of 108 species of macroinvertebrates under 49 families, 15 orders, 5 classes in 3 phyla were identified. The number of species was the most abundantly revealed in aquatic insects (class Insecta) with 86 species (82.6%) under 7 orders. The phylum Mollusca (10 species, 9.2%) and the phylum Annelida (6 species, 5.6%) were followed in order. In the class Crustacea, 6 species (5.6%) were distributed. In aquatic insects, the order Odonata was the most abundant taxon (20 species, 23.3%). Seventeen species (19.8%) of the order Ephemeroptera and 16 species (18.6%) of the Coleoptera were followed. The primary dominant species in the stream was Cloeon dipterum of Ephemeroptera. For community analysis, the values of diversity index (H'), evenness index (J'), dominance index (DI) and richness index (RI) were studied and the average values of them were 5.65, 0.84, 0.13, and 13.18, respectively.

Theoretical Investigation on the Structure, Detonation Performance and Pyrolysis Mechanism of 4,6,8-Trinitro-4,5,7,8-tetrahydro -6H-furazano[3,4-f]-1,3,5-triazepine

  • Li, Xiao-Hong;Zhang, Rui-Zhou;Zhang, Xian-Zhou
    • Bulletin of the Korean Chemical Society
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    • 제35권5호
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    • pp.1479-1484
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    • 2014
  • Based on the full optimized molecular geometric structures at B3LYP/cc-pvtz method, a new designed compound, 4,6,8-trinitro-4,5,7,8-tetrahydro-6H-furazano[3,4-f ]-1,3,5-triazepine was investigated in order to look for high energy density compounds (HEDCs). The analysis of the molecular structure indicates that the seven-membered ring adopts chair conformation and there exist intramolecular hydrogen bond interactions. IR spectrum and heat of formation (HOF) were predicted. The detonation velocity and pressure were evaluated by using Kamlet-Jacobs equations based on the theoretical density and condensed HOF. The bond dissociation energies and bond orders for the weakest bonds were analyzed to investigate the thermal stability of the title compound. The results show that $N_1-N_6$ bond is the trigger bond. The crystal structure obtained by molecular mechanics belongs to $Pna2_1$ space group, with lattice parameters Z = 4, a = 15.3023 ${\AA}$, b = 5.7882 ${\AA}$, c = 11.0471 ${\AA}$, ${\rho}=2.06gcm^{-3}$. In addition, the analysis of frontier molecular orbital shows the title compound has good stability and high chemical hardness.

탄소-13 핵자기공명 화학적 이동을 이용한 9-바바라릴 양이온의 구조에 관한 연구 (Study on Structure of 9-Barbaralyl Cation by 1$^{13}C$ NMR Chemical Shift)

  • 신정휴;안양수
    • 대한화학회지
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    • 제31권2호
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    • pp.190-196
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    • 1987
  • 9-바바라릴 양이온의 구조를 탄소-13 핵자기공명을 이용한 Hammett-Brown식을 이용해서 조사하였다. 이를 위하여 9-아릴트리시클로$[3.3.1.0^{2,8}]$노난 (5) 및 9-아릴트리시클로 $[3.3.1.0^{2,8}]$노나-3,6-디엔 (6)계 양이온을 영하 $120^{\circ}C$에서 해당 알코올과 불화황산과의 반응에서 얻었고 양하전 탄소에 대한 화학적이동이 측정되었다. 양이온 5와 6에 대한 Hammett-Brown식의 기울기, 즉 ${\rho}^{C+}$값은 각각 -5.01과 -7.52였다. 이들 값의 결과로만 보면 이중결합의 영향이 있는 것처럼 보인다. 그러나, 9-바바라릴과 8, 9데히드로아다만틸 양이온들의 ${\rho}^{C+}$${\rho}^{C_a^+}$ 값들을 비교한 결과에서 9-바바라릴 양이온도 도표 1에서의 4의 구조를 가져야 된다는 결론을 얻어냈다.

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1-Cyclopropyl-7-(2,7-diazabicyclo[3.3.0]oct-4-en-7-yl)-6-fluoro-8-methoxy-4-oxo-1,4-dihydroquinoline-3-carboxylic acid 염산염의 결정구조 (Crystal Structure of 1-Cyclopropyl-7-(2,7-diazabicyclo[3.3.0]oct-4-en-7-yl)-6-fluoro-8-methoxy-4-oxo-1,4-dihydroquinoline-3-carboxylic acid (HCI salt))

  • 김문집;신준철
    • 한국결정학회지
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    • 제6권2호
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    • pp.103-110
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    • 1995
  • 1-Cyclopropyl-7-(2,7-diazabicyclo[3.3.0]oct-4-en-7-yl)-6-fluoro-8-methoxy-4-oxo-1,4-dihydroquinoline-3-carboxylic acid (HCI salt)의 분자 및 결정 구조를 X-선 회절법으로 연구하였다. 이 결정의 분자식은 C20H21N3O4FCl(이하 CDD), 결정계는 단사정계이고 공간군은 C2/c이다. 단위포상수 a=28.349(2)Å, b=11.941(2)Å, c=12.806(2)Å이며 β=96.428(9)°, V=4307.8Å3, T=296(2)K, Z=8이다. 구조해석에 사용한 X-선은 CuKα선(λ=1.5418Å)을 사용하였다. 분자구조는 직접법으로 풀었으며, 최소자승법으로 정밀화하였다. 최종 신뢰도 R값은 F0>4σ(F0)인 2258개의 독립 회절데이타에 대해 R=4.96%이었다. 이 분자는 내부수소결합 O(28)-H(28)…O(25) [2.517(4)Å, 156.7(447)°]를 가지고 있으며, 분자간의 결합은 van der Waals 힘으로 결합되어 있다.

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