• Journal of the Korean Chemical Society
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• v.29 no.4
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• pp.372-381
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• 1985

Oxo molybdenum (V) complexes of substituted 8-quinolinols were synthesized and characterized by means of the investigation of elemental analysis, infrared spectra, electron spectra, electric conductivity and mass spectrometry compared with oxo molybdenum (VI) complexes. Oxo molybdenum(V) complexes were nonelectrolyte and one strong band of stretching mode of molybdenum and terminal oxygen appeared approximately $940cm^{-1}$. Oxo molybdenum(VI) complexes gave two peaks corresponding molybdenum containing ions, a molecular ion (I) of a 2 : 1 (ligand : metal) chelate and a fragment ion (II) of a 1:1 chelate due to the loss of ligand radical from ion (I). Molybdenum(V) complexes were observed the fragment ion(II) of a 1 : 1 chelate partly. The electronic spectra corresponding to d-d transition and charge transfer transition were observed and interpreted.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.220-220
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• 2016

본 연구에서는 녹황색 빛을 내는 NaY(WO4)2:Tb3+ 형광체 파우더를 하소 350도에 1시간 소결 950도에 4시간 고상반응법으로 합성하였으며, 파우더는 X-ray diffraction과 PL 장비를 이용하여 측정하였다. XRD 분석은 Tb3+이온 도핑농도에 의한 순수한 NaYWO4 상을 나타내었다. Fig.1 220-330nm에서 관찰되는 넓은 밴드는 $O2-{\rightarrow}W6+$에 의해 발생한 LMCT(ligand to metal charge transfer)이고, Tb3+에서 WO42-그룹으로 에너지 전달에 의해서 생긴다. 이것의 최대세기는 272nm 이다. LMCT 옆 330-390nm에 관찰되어지는 약한 강도와 넓은 밴드는 Tb3+ 4f8의 f-f transition에 의해 발생한다. Fig.2에서 보여 지듯이$ 5D4{\rightarrow}7F6$, 7F5, 7F4, 7F3는 파장 489nm, main peak인 545nm (Green,초록색), 588nm (orange, 주황색), 620nm (Red, 적색)에서 Peak가 나타났으며, Tb3+이온의 함량비가 0.08mol일 때 최대 발광이 관측 되었다.

• Korean Journal of Materials Research
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• v.19 no.4
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• pp.186-191
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• 2009

Thermoelectric power and resistivity are measured for the perovskite $LaNi_{1-x}Ti_xO_3$ ($x{\leq}0.5$) in the temperature range 77 K - 300 K. The measured thermoelectric power of $LaNi_{1-x}Ti_xO_3$ ($x{\leq}0.5$) increases linearly with temperature and is represented by A + BT. The x = 0.1 sample showed metallic behavior, the x = 0.3 showed metal and insulating transition around 150 K, and x = 0.5 showed insulating behavior the over the whole temperature range. The electrical resistivity of x = 0.1 shows linear temperature dependence over the whole temperature range and $T^2$ dependence. On the other hand, the electrical resistivity of x = 0.3 shows a linear relation between $ln{\rho}$ and $T^{-1/4}$ (variable range hopping mechanism) in the range of 77 K to 150 K. For x = 0.5, the temperature dependence of resistivity is characteristic of insulating materials; the resistivity data was fitted to an exponential law, such as ln(${\rho}/T$) and $T^{-1}$, which is usually attributed to a small polaron hopping mechanism. These experimental results are interpreted in terms of the spin polaron (x = 0.1) and variable range hopping (x = 0.3) or small polaron hopping (x = 0.5) of an almost localized $Ni^{3+}$ 3d polaron.

• Journal of the Korean Magnetics Society
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• v.18 no.2
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• pp.75-78
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• 2008

$AB_2X_4$(A, B=Transition Metal, X=O, S, Se) are cubic spinel normal ferrimagnets, in which M ions occupy the tetrahedral sites and Cr ions occupy the octahedral sites. Recently, they have been investigated for behaviour of B site ions and A-B interaction. Polycrystalline $[Co_{0.9}Zn_{0.1}]_A[Cr_{1.98}{^{57}Fe_{0.02}}]_BO_4$ compound was prepared by wet-chemical process. The ferrimagnetic transition was observed around 90K. $M\"{o}ssbauer$ absorption spectra at 4.2K show that the well-developed two sextets are superposed with small difference in hyperfine fields($H_{hf}$). The hyperfine fields of $CoCr_{1.98}{^{57}Fe_{0.02}}O_4$ and $Co_{0.9}Zn_{0.1}Cr_{1.98}{^{57}Fe_{0.02}}O_4$ were determined to be 488, 478 kOe and 486, 468 kOe, respectively. We notice that the one of the magnetic hyperfine field values changes with Zn ion substitution. These results suggest the incommensurate states and spin-reorientation temperature($T_S=18K$) changes with Zn ions substitution below spin-reorientation temperature($T_S=28K$) of $CoCr_{1.98}{^{57}Fe_{0.02}}O_4$

• Bulletin of the Korean Chemical Society
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• v.29 no.1
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• pp.117-121
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• 2008

Pseudo-first-order rate constants (kobsd) have been measured spectrophotometrically for nucleophilic substitution reactions of 5-nitro-8-quinolyl benzoate (5) with alkali metal ethoxides, EtO?M+ (M+ = Li+, Na+ and K+) in anhydrous ethanol (EtOH) at 25.0 0.1 C. The plots of kobsd vs. [EtO?M+] exhibit upward curvatures, while the corresponding plots for the reactions of 5 with EtO?Na+ and EtO?K+ in the presence of complexing agents, 15-crown-5-ether and 18-crown-6-ether are linear with rate retardation. The reactions of 5 with EtO?Na+ and EtO?Li+ result in significant rate enhancements on additions of Na+ClO4, indicating that the M+ ions behave as a catalyst. The dissociated EtO and ion-paired EtOM+ have been proposed to react with 5. The second-order rate constants for the reactions with EtO (kEtO) and EtOM+ (kEtOM+) have been calculated from ion-pairing treatments. The kEtO and kEtOM+ values decrease in the order kEtONa+ > kEtOK+ > kEtOLi+ > kEtO, indicating that ion-paired EtOM+ species are more reactive than the dissociated EtO ion, and Na+ ion exhibits the largest catalytic effect. The M+ ions in this study form stronger complex with the transition state than with the ground state. Coordination of the M+ ions with the O and N atoms in the leaving group of 5 has been suggested to be responsible for the catalytic effect shown by the alkali metal ions in this study.

• Applied Chemistry for Engineering
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• v.22 no.1
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• pp.67-71
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• 2011

The cathodic active material of $Li/SO_2Cl_2$ battery is $SO_2Cl_2$, which is the solvent of an electrolyte. It is referred to as a catholyte, a compound word of cathode and electrolyte. As the battery discharges, the catholyte burns out. And thus, the characteristics of the $SO_2Cl_2$ in the battery determine the capacity. In addition, the transition minimum voltage (TMV) and the voltage delay deviation of $Li/SO_2Cl_2$ battery are due to the passivation film formed by the reaction between an electrolyte and Li. Impurities in the electrolyte, such as moisture or heavy metal ions, will accelerate the growth of the passivation film. Therefore, a technology must be established to purify an electrolyte and to ensure the effectiveness of the purification method. In this research, $LiAlCl_4/SO_2Cl_2$ was manufactured using $AlCl_3$ and LiCl. Its concentration, the amount of moisture, and the metal amount were evaluated using an ionic conductivity meter, a colorimeter, and FT-IR.

• Progress in Superconductivity
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• v.12 no.1
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• pp.46-50
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• 2010

In the superconducting $Sr_2VO_3FeAs$, containing bimetallic layers, with maximum $T_c{\approx}\;46\;K$ correlation effects on V ions have been investigated using LDA+U method. Within the local density approximation (LDA) this system has the one-third filled $t_{2g}$ manifold of V, decomposed into $d_{xy}$ of bandwidth W=2 eV and nearly degenerate $d_{zx}d_{yz}$ of W=1 eV. Consideration of correlation effects leads to a metal-insulator transition on V ions $t^{2\uparrow}_{2g}\;{\rightarrow}\;d^{1\uparrow}_{xz}\;d^{1\uparrow}_{yz}$ at the critical on-site Coulomb repulsion $U_c$= 3.5 eV. At U=4 eV, the electronic structure, in which V ions are insulating, leads to several van Hove singularities near $E_F$ and similar Fermiology with other pnictides. Applying U to V ions results in increasing Fe moment as well as V moment, indicating somewhat hybridization between Fe and V ions even though this system is strongly 2-dimesional. Our results show possible importance of correlation effects on this system.

• Bulletin of the Korean Chemical Society
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• v.27 no.9
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• pp.1405-1417
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• 2006

The geometrical structures, potential energy surfaces, and energetics for the ligand exchange reactions of tetracoordinated platinum $(PtY_2L_2\;:\;Y,\;L=Cl^-,\;OH^-,\;OH_2,\;NH_3)$ complexes in the ligand-solvent interaction systems were investigated using the ab initio Hartree-Fock (HF) and Density Functional Theory (DFT) methods. The potential energy surfaces for the ligand exchange reactions used for the conversions of $(PtCl_4\;+\;H_2O)^{^\ast_\ast}\;to\;[PtCl_3(H_2O)\;+\;Cl^-]$ and $[Pt(NH_3)_2Cl_2\;+\;H_2O]$$[Pt(NH_3)_2Cl_2\;+\;H_2O]$ to $[Pt(NH_3)_2Cl(H_2O)\;+\;Cl^-] $ were investigated in detail. For these two exchange reactions, the transition states $([PtY_2L_2{\cdot}{\cdot}{\cdot}L^\prime])^{^\ast_\ast} $ correspond to complexes such as $(PtCl_4{\cdot}{\cdot}{\cdot}H_2O)^{^\ast_\ast}$ and $[Pt(NH_3)_2Cl_2{\cdot}{\cdot}{\cdot}H_2O]^{^\ast_\ast}$, respectively. In the transition state, $([PtCl_4{\cdot}{\cdot}{\cdot}H_2O]^{^\ast_\ast}$ and $[Pt(NH_3)_2Cl_2{\cdot}{\cdot}{\cdot}H_2O]]^{^\ast_\ast})$ have a kind of 6-membered $(Pt-Cl{\cdot}{\cdot}{\cdot}HOH{\cdot}{\cdot}{\cdot}Cl)$ and $(Pt-OH{\cdot}{\cdot}{\cdot}Cl{\cdot}{\cdot}{\cdot}HN)$ interactions, respectively, wherein a central Pt(II) metal directly combines with a leaving $Cl^-$ and an entering $H_2O$. Simultaneously, the entering $H_2O$ interacts with a leaving $Cl^-$. No vertical one metal-ligand interactions $([PtY_2L_2{\cdot}{\cdot}{\cdot}L^\prime]) $ are found at the axial positions of the square planar $(PtY_2L_2)$ complexes, which were formed via a vertically associative mechanism leading to $D_{3h}$ or $C_{2v}$-transition state symmetry. The geometrical structure variations, molecular orbital variations (HOMO and LUMO), and relative stabilities for the ligand exchange processes are also examined quantitatively. Schematic diagrams for the dissociation reactions of {PtCl4(H2O)n(n=2,4)} into {$PtCl_3(H_2O)_{(n-2)}\;+\;Cl^-(H_2O)_2$} and the binding energies {$PtCl_4(H_2O)_n$(n = 1-5)} of $PtCl_4$ with water molecules are drawn.

• Current Photovoltaic Research
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• v.5 no.4
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• pp.145-149
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• 2017

Transition metal dichalcogenides (TMDs) have attracted much attention because of their excellent optical and electrical properties, which are the applications of next generation photoelectric devices. In this study, $MoS_2$, which is a representative material of TMDs, was formed by magnetic sputtering method and surface changes and optical characteristics were changed with thickness variation. In addition, by implementing the photodetector of $MoS_2/p-Si$ structure, it was confirmed that the change of the electrical properties rather than the change of the optical properties according to the thickness change of $MoS_2$ affects the photoresponse ratio of the photodetector. This result can be used to fabricate effective photoelectric devices using $MoS_2$.

• Korean Journal of Optics and Photonics
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• v.4 no.2
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• pp.220-225
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• 1993

This is the first reported observation of absorption and emission of glasses with a 4d transition metal ion(rhodium). The optical absorption and photoluminescence spectra, and the lifetimes of rhodium ions in phosphate glasses are interpreted on the basis of strong-field scheme of Sugano-Tanabe diagram. We conclude that rhodium ion is present in its divalent form. $^2 E{\rightarrow}^2 T_1$ and $^2 E{\rightarrow}^2 T_2$ transitions are superimposed and observed at 460 nm. Whereas $^2 T_1{\rightarrow}^2 E$ and $^2 T_1{\rightarrow}^2 E$ transitions are observed at 650 nm and 580 nm, respectively.