• Advances in Energy Research
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• v.5 no.1
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• pp.13-29
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• 2017

The roles of Na, Mn, W and silica, and the synergistic effects between each metal in the $MnNa_2WO_4/SiO_2$ catalyst have been investigated for oxidative coupling of methane (OCM). The crystallisation of amorphous silica during calcination at $900^{\circ}C$ was promoted primarily by Na, but Mn and W also facilitated this process. The interaction between Na and Mn tended to increase the extent of conversion of $Mn_3O_4$ to $Mn_2O_3$. The formation of $Na_2WO_4$ was dependent on the order in which Na and W were introduced to the catalyst. The impregnation of W before Na resulted in the formation of $Na_2WO_4$, but this did not occur when the impregnation order was reversed. $MnWO_4$ formed in all cases where Mn and W were introduced into the silica support, regardless of the impregnation order; however, the formation of $MnWO_4$ was inhibited in the presence of Na. Of the prepared samples in which a single metal oxide was introduced to silica, only $Mn/SiO_2$ showed OCM activity with significant oxygen conversion, thus demonstrating the important role that Mn plays in promoting oxygen transfer in the reaction. The impregnation order of W and Na is critical for catalyst performance. The active site, which involves a combination of Na-Si-W-O, can be formed in situ when distorted $WO_4^{2-}$ interacts with silica during the crystallisation process facilitated by Na. This can only occur if the impregnation of W occurs before Na addition, or if the two components are introduced simultaneously.

• Korean Journal of Human Ecology
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• v.15 no.5
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• pp.811-821
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• 2006

The purpose of this report was to study visual effect and functional effect of waist line location of slacks for females in 20'. 1. Differences of visual effect of slacks waist line change to be expressed that mature, sexual and casual slacks waist line were W4 or W5, looks like long leg and mature and formal slacks waist line was W1, slim lower part of the body and flat slacks waist line was W4. 2. Analysis result of functional effect difference with the location variation of slacks waist line were as follows. In all motions(M1, M2, M3, M4) W2 that downed 7cm-6cm-6cm from natural waist line was valued as the most comfortable, W1 and W5 were valued as discomfortable, where waist line was too high or too low.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.10 no.2
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• pp.224-227
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• 2006

We have chained 459nm blue laser radiation generated by intracavity sum frequency generation( SFG ) due to the mixing of the 1064 nm laser output of a Nd:YVO4 pumped by diode and the 809nm radiation from higg-power semiconductor laser(500mW). The maximum blue output power of 0.95 mW was obtained using 400 mW input power of semiconductor laser at the type II phase matching condition (${\psi}=90^{\circ}\;{\theta}=90^{\circ}$). The threshold input power of blue laser generation was 120 mW.

• Analytical Science and Technology
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• v.7 no.2
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• pp.237-243
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• 1994

The stability of W/O emulsions (milk fat : water=4 : 1, w/w) containing various emulsifiers was compared to determine the effect of different chemical types of emulsifiers in relation to the change of HLB value caused by emulsifier type and the influence of single vs. binary emulsifier systems. These variables were compared at emulsifier HLB values of 0.5~16.7 and at emulsifier concentrations of 1.0~3.0%(w/w). Eleven emulsifiers used as 11 different single mixtures and 16 different binary mixtures were evaluated in W/O type emulsion systems containing 20.0%(w/w) of water in milk fat. This W/O emulsion was stable (more than 90.0 of ESI value) in the range of low value of emulsifier HLB (less than 4.7 of HLB value). All the ESI values of binary emulsifier systems were higher than those of single emulsifier systems. But, the influence pattern of emulsifier HLB on this emulsion stability in single emulsifier systems was very similar to the trend in binary emulsifier systems.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.05b
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• pp.54-56
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• 2001

The $SiH_4$ soak step is widely used during the CVD Tungsten(W) plug deposition process on the Ti/TiN barrier metal to prevent the $WF_6$ attack to the underlayer metal. We tried to reduce or skip the time of $SiH_4$ soak process to optimize W-plug deposition process on Via. The electrical characteristics including Via resistance and the structure of W film are affected according to $SiH_4$ soak time. The elimination possibility of $SiH_4$ soak process was confirmed in the case of that the CVD W film grows on the stable Ti/TiN underlayer.

• Journal of the Korean Society of Safety
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• v.15 no.2
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• pp.70-77
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• 2000

For hazardous air pollutants(HAP) such as NO, $NO_2$ and $SO_2$ decomposition efficiency, power consumption, and applied voltage were investigated by SPCP(Surface induced discharge Plasma Chemical Processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of HAP with various electric frequencies(5~50 kHz), flow rates(100~1,000 mL/min), initial concentrations(100~1,000 ppm) and additive($CH_4$) were measured and the products were analyzed with FT-IR. Experimental results showed that for the frequency of 10 kHz, the highest decomposition efficiency of 94.3 % for NO, 84.7 % for $NO_2$ and 99 % far $SO_2$ were observed at the power consumptions of 19.8, 20 and 19W, respectively, and that decomposition efficiency decreased with increasing frequency above 20 kHz. And decomposition efficiency per unit power were 5.21 %/W for $SO_2$, 4.76 %/W for NO and 4.24 %/W for $NO_2$ and the highest decomposition efficiency was observed with $SO_2$. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. When the additive of $CH_4$ was used, decomposition efficiency was increased with increasing $CH_4$ content, and NO, $NO_2$ and $SO_2$ were almost completely decomposed with the efficiency of 99 %, 98 % and 99 %, respectively and therefore $CH_4$ was a good additive material. The optimum power for the maximum decomposition efficiency were 7.5 W for $SO_2$, 9.5 W for NO and 15.5 W for $NO_2$, respectively. Optimum power with the maximum decomposition efficiency were 9.5 W at 1,000 ppm of NO, 7~8 W at 100~500 ppm of NO and 15.5 W at all concentration range of $NO_2$ and 11.5 W at 1,000 ppm, 4.9 W at 500 ppm, 3.7 W at 100~300 ppm of $SO_2$ and power efficiency was best in these case.

• Korean Journal of Materials Research
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• v.11 no.11
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• pp.953-959
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• 2001

Homogeneous spherical W-Co salt powders were made by spray drying of aqueous solution of ammonium $metatungstate(NH_4)_6(H_2W_{12}O_{40}){\cdot}4H_2O,\; AMT)$ and cobalt nitrate $hexahydrate(Co(NO_3)_2{\cdot}6H_2O)$. The thermal decomposition process of spray dried W-Co salt powders was studied by TG, XRD, SEM, TEM and FT-IR. Spray dried W-Co salt powders were calcined for 1 hour in the temperature from$ 350^{\circ}C$ to $800^{\circ}C$ in atmosphere of air. At the temperatures over $600^{\circ}C$, spherical $CoWO_4/WO_3$ composite oxide powders were obtained. The primary particle size of W/Co composite oxide powders increased with increasing thermal decomposition temperature due to the particle growth. The observed crystallite size by TEM was in the range of 60nm and that of $CoWO_4$ calculated by Scherrer's formula at $800^{\circ}C$ was smaller than 55nm. The crystallite site was identified by XRD and TEM.

• Journal of Energy Engineering
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• v.21 no.4
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• pp.393-397
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• 2012

In this study, an organic Rankine cycle(ORC) for gas engine waste heat recovery for industry has been constructed and a performance analysis test has been carried out. Shell & tube style heat exchanger has been equipped on an engine exhaust manifold in order to absorb heat of engine exhaust gas into the working fluid(refrigerant R134a). Under 60 kW of engine power output, about 63 kW of engine exhaust gas heat was discharged and the proportion of heat recovered was 68~73% while 43~46 kW of heat was absorbed into working fluid. Consequently rated power output of ORC was 4.6 kW while the ratio of rated power output to engine exhaust gas heat was 7.3%.

• Journal of The Korean Astronomical Society
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• v.27 no.1
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• pp.81-102
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• 1994

We have decomposed the 11-cm radio continuum emission of the W51 complex into thermal and non-thermal components. The distribution of the thermal emission has been determined by analyzing HI, CO, and IRAS $60-{\mu}m$ data. We have found a good correlation between the 11-cm thermal continuum and the 60- 11m emissions, which is used to obtain the thermal and non-thermal 11-cm continuum maps of the W51 complex. Most of the thermal continuum is emanating from the compact H II regions and their low-density ionized envelopes in W51A and W51B. All the H II regions, except G49.1-0.4 in W51B, have associated molecular clumps. The thermal radio continuum fluxes of the compact H II regions are proportional to the CO fluxes of molecular clumps. This is consistent with the previous results that the total mass of stars in an H II region is proportional to the mass of the associated molecular clump. According to our result, there are three non-thermal continuum sources in W51: G49.4-0.4 in W51A, a weak source close to G49.2-0.3 in W51B, and the shell source W51C. The non-thermal flux of G49.5-0.4 at 11-cm is $\~28 Jy$, which is $\~25\%$ of its total 11-cm flux. The radio continuum spectrum between 0.15 and 300 GHz also suggests an excess emission over thermal free-free emission. We show that the excess emission can be described as a non-thermal emission with a spectral index ${\alpha}{\simeq}-1.0 (S_v{\propto}V^a)$ attenuated by thermal free-free absorptions at low-frequencies. The non-thermal source close to G49.2-0.3 is weak $(\~9 Jy)$. The nature of the source is not known and the reality of the non-thermal emission needs to be confirmed. The non~thermal shell source W51C has a 11-cm flux of $\~130Jy$ and a spectral index ${\alpha}{\simeq}-0.26$.

• Journal of Korean Ophthalmic Optics Society
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• v.5 no.2
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• pp.157-161
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• 2000

The Eye sensitivity in the difference conditions of a light source intensity consists of two functions by the receptor of cone and rod according to a wavelength. We derived a distribution function of $P({\lambda})=A{\cdot}e^{-({\lambda}-{\lambda}_0)^2/2W^2}$ using a respond probability of the receptor of cone-rod for a photon. It was well applied for a CIE eye's sensitivity curve of a wavelength, we obtained values in case of a relative sensitivity. A = 106.4, ${\lambda}_0=559.2$, W = 83.5 for a photopic and A = 99.3 ${\lambda}_0=502.6$, W = 79.5 for a scotopic, and in case of a sensitivity curve using 1m/W units. $A=7.2{\times}10^4$, ${\lambda}_0=559.2$, W = 83.5 for a photopic and $A=1.6{\times}10^5$, ${\lambda}_0=502.6$. W = 79.5 for a scotopic.