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Hydrophobic and Mechanical Characteristics of Hydrogenated Amorphous Carbon Films Synthesized by Linear Ar/CH4 Microwave Plasma

  • Han, Moon-Ki;Kim, Taehwan;Cha, Ju-Hong;Kim, Dong-Hyun;Lee, Hae June;Lee, Ho-Jun
    • Applied Science and Convergence Technology
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    • v.26 no.2
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    • pp.34-41
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    • 2017
  • A 2.45 GHz microwave plasma with linear antenna has been prepared for hydrophobic and wear-resistible surface coating of carbon steel. Wear-resistible properties are required for the surface protection of cutting tools and achieved by depositing a hydrogenated amorphous carbon film on steel surface through linear microwave plasma source that has $TE_{10}-TEM$ waveguide. Compared to the existing RF plasma source driven by 13.56 MHz, linear microwave plasma source can easily generate high density plasma and provide faster deposition rate and wider process windows. In this study, $Ar/CH_4$ gas mixtures are used for hydrogenated amorphous carbon film deposition. When microwave power of 1000 W is applied, 40 cm long uniform $Ar/CH_4$ plasma could be obtained in gas pressure of 200~400 mTorr. The Vickers hardness measurement of hydrogenated amorphous carbon film on steel surface was evaluated. It was found the optimized deposition condition at $Ar:CH_4=25:25$ sccm, 300 mTorr with microwave power of 1000W and RF bias power of 100W. By deposition of hydrogenated amorphous carbon film, contact angle on steel surfaces increases from $43.9^{\circ}$ to $93.2^{\circ}$.

Effect of Moisture in a Vacuum Chamber on the Deposition of c-BN Thin Film using an Unbalanced Magnetron Sputtering Method (비대칭 마그네트론 스퍼터링 방법에 의한 질화붕소막의 증착시 반응실내의 초기 수분이 입방정질화붕소 박막의 형성에 미치는 영향)

  • Lee, Eun-Sook;Park, Jong-Keuk;Lee, Wook-Seong;Seong, Tae-Yeon;Baik, Young-Joon
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.620-624
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    • 2012
  • The role of moisture remaining inside the deposition chamber during the formation of the cubic boron nitride (c-BN) phase in BN film was investigated. BN films were deposited by an unbalanced magnetron sputtering (UBM) method. Single-crystal (001) Si wafers were used as substrates. A hexagonal boron nitride (h-BN) target was used as a sputter target which was connected to a 13.56 MHz radiofrequency electric power source at 400 W. The substrate was biased at -60 V using a 200 kHz high-frequency power supply. The deposition pressure was 0.27 Pa with a flow of Ar 18 sccm - $N_2$ 2 sccm mixed gas. The inside of the deposition chamber was maintained at a moisture level of 65% during the initial stage. The effects of the evacuation time, duration time of heating the substrate holder at $250^{\circ}C$ as well as the plasma treatment on the inside chamber wall on the formation of c-BN were studied. The effects of heating as well as the plasma treatment very effectively eliminated the moisture adsorbed on the chamber wall. A pre-deposition condition for the stable and repeatable deposition of c-BN is suggested.

A Study on the Navigation Data Transmission-Management System of a Small Vessel (소형선박의 항행정보 전송관리시스템에 대한 연구)

  • 조학현;최조천;최병하;김기문
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.4 no.1
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    • pp.191-200
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    • 2000
  • The marine accident is being highlighted as a serious worldwide problem for the guard station of human safety and the protection of marine environment pollution. Especially, the GMDSS is operated as a international rule for the safety of a large scale ship, but the small size ship's management is required a adaptive national rule because of the complex condition of national circumstance. This study is motivated to develop a ship's position tracking system combined with GPS information for VTS and control the ship navigation, velocity and longitude etc.. In Part of Navigation Data Transmission is GPS data transmission whih ship's ID using microprocessor and TX speed translation for flexibility with 4800∼2400 [bps]. Results show that the our system for data transmission using microprocessor is useful tool in maritime transmission as SSB used the main TX method of small ship and has a cost competitive power. Therefore, we will expected cost and technical competitive power compared to AIS. But those systems are still remained the unsolved problem for protection from marine accident.. Finally, we examined the semi-actual receiving state on simulated sailing in the around sea of Mok-Po harbor.

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New Classes of LC Resonators for Magnetic Sensor Device Using a Glass-Coated Amorphous CO83.2B3.3Si5.9Mn7.6 Microwire

  • Kim, Yong-Seok;Yu, Seong-Cho;Hwang, Myung-Joo;Lee, Hee-Bok
    • Journal of Magnetics
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    • v.10 no.3
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    • pp.122-127
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    • 2005
  • New classes of LC resonators for micro magnetic sensor device were proposed and fabricated. The first type LC resonator (Type I) consists of a small piece of microwire and two cylindrical electrodes at the end of the microwire without direct contact to its ferromagnetic core. In type I resonator the ferromagnetic core of the microwire and cylindrical electrodes act as an inductor and two capacitors respectively to form a LC circuit. The second type LC resonator (Type II) consists of a solenoidal micro-inductor with a bundle of soft magnetic microwires as a core. The solenoidal micro-inductors fabricated by MEMS technique were $500\sim1,000\;\mu{m}$ in length with $10\sim20$ turns. A capacitor is connected in parallel to the micro-inductor to form a LC circuit. A tiny glass coated $CO_{83.2}B_{3.3}Si_{5.9}Mn_{7.6}$ microwire was fabricated by a glass-coated melt spinning technique. A supergiant magneto-impedance effect was found in a type I resonator as much as 400,000% by precise tuning frequency at around 518.51 MHz. In type II resonator the changes of inductance as a function of external magnetic field in micro-inductors with properly annealed microwire cores were varied as much as 370%. The phase angle between current and voltage was also strongly dependent on the magnetic field. The drastic increments of magnetoimpedance at near the resonance frequency were observed in both types of LC resonators. Accordingly, the sudden change of the phase angle, as large as $180^{\circ}C$, evidenced the occurrence of the resonance at a given external magnetic field.

Smart grid and nuclear power plant security by integrating cryptographic hardware chip

  • Kumar, Niraj;Mishra, Vishnu Mohan;Kumar, Adesh
    • Nuclear Engineering and Technology
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    • v.53 no.10
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    • pp.3327-3334
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    • 2021
  • Present electric grids are advanced to integrate smart grids, distributed resources, high-speed sensing and control, and other advanced metering technologies. Cybersecurity is one of the challenges of the smart grid and nuclear plant digital system. It affects the advanced metering infrastructure (AMI), for grid data communication and controls the information in real-time. The research article is emphasized solving the nuclear and smart grid hardware security issues with the integration of field programmable gate array (FPGA), and implementing the latest Time Authenticated Cryptographic Identity Transmission (TACIT) cryptographic algorithm in the chip. The cryptographic-based encryption and decryption approach can be used for a smart grid distribution system embedding with FPGA hardware. The chip design is carried in Xilinx ISE 14.7 and synthesized on Virtex-5 FPGA hardware. The state of the art of work is that the algorithm is implemented on FPGA hardware that provides the scalable design with different key sizes, and its integration enhances the grid hardware security and switching. It has been reported by similar state-of-the-art approaches, that the algorithm was limited in software, not implemented in a hardware chip. The main finding of the research work is that the design predicts the utilization of hardware parameters such as slices, LUTs, flip-flops, memory, input/output blocks, and timing information for Virtex-5 FPGA synthesis before the chip fabrication. The information is extracted for 8-bit to 128-bit key and grid data with initial parameters. TACIT security chip supports 400 MHz frequency for 128-bit key. The research work is an effort to provide the solution for the industries working towards embedded hardware security for the smart grid, power plants, and nuclear applications.

Identification of Maysin and Related Flavonid Analogues in Corn Silks (옥수수 수염에서 Maysin 및 유사물질의 동정)

  • Kim, Sun-Lim;Snook, Maurice E.;Kim, E-Hun;Park, Cheol-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.45 no.3
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    • pp.151-157
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    • 2000
  • This study was carried out to isolate and identify the maysin and related flavonoid analogues in corn silks. Silks were covered with silk bag to prevent pollination and were sampled at 3-5 days after silking. The silks were filled with 100% MeOH and stored at $0^{\circ}C$ until analysis. The MeOH extracts of corn silks were filtered and concentrated at 35-4$0^{\circ}C$. The ${CH}_2$${Cl}_2$ was added on the concentrated aqueous solution to remove the chlorophyll and lipids. The Cis open column (25mm$\times$54 cm) was washed and activated with serial treatment of 500$m\ell$ of 100% MeOH(twice)longrightarrow75% MeOH longrightarrow50% MeOHlongrightarrow30% MeOHlongrightarrow100% $H_2$O(2 times). The concentrated aqueous solution was applied to the $C_{18}$ column and washed with $H_2O$ several times to remove the sugars and water soluble pigments. Neochlorogenic acid, chlorogenic acid and 4-caffeoylquinic acid were eluted with 10% MeOH, and rhamosyl isoorientin was eluted with 30% MeOH, but maysin was eluted with 50% MeOH from the $C_18$ open column. Collected fractions were analyzed with HPLC by using revers-phase Ultras-phere $C_{18}$ column (4.6$\times$250mm, 5$\mu\textrm{m}$) and $H_2$O (10% MeOH containing 0.1% $H_3$${PO}_4$)/MeOH (100% MeOH containing 0.1% H$_3$PO$_4$) linear gradient from 20% to 90% MeOH for 35 minutes, a flow rate of 1 $m\ell$/min and detection at 340nm. The selected fractions were concentrated and applied to the silicic acid column. Maysin was eluted with 500$m\ell$ of 100% ethyl acetate from the silicic acid column for the first purification, and the purity of collected fractions was about 75%, but the purity from the second purification with the Cis column (1/2 $\times$ 43") was greater than 95%. FAB-MS spectral data was obtained with VG7O-VSEQ VG analytical fast atom bombardment mass (UK). $^1$H-NMR and $^{13}$ C-NMR data were obtained with Bruker DPX 400 MHz NMR spectrometers (German) in DMSO-d$_{6}$ at 400 and 100 MHz, respectively.vely.

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GPR Survey for the Assessment of Scour Depth near Bridge Piers (세굴심 추정을 위한 교각 우물통 주변의 GPR 탐사)

  • Park, In-Chan;Cho, Won-Cheol;Lee, Chong-Guk
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.996-1000
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    • 2005
  • 본 연구에서는 마포대교 확장 공사의 인해 일부 교각의 우물통 기초 주변 하상변화와 세굴 현상을 파악하기 위한 심도추정 방법으로 현재 다양하게 토목분야에서 적용되고 있는 치하투과레이더 탐사기법을 사용하였다. 교각 우물통 주변의 안정적인 GPR 탐사를 수행하기 위한 보조장비를 고안하여 마포대교 P6의 우물통 주변을 2004년 6월(1차)과 2004년 10월(2차)에 걸쳐 탐사를 실시하였으며, 탐사 기간 중 약 12,000 cms의 유출량이 발생하여 국부세굴과 하상 변화 가능성을 충분히 검토 할 수 있을 것으로 판단되었다. 수집된 자료를 통해 양질의 자료 획득을 위해서 자료의 보정 과정을 마친 후 각각의 구간에 대해서 1, 2차 탐사된 두 개의 자료를 비교 분석하였다. 전구간의 반사파를 이용하여 기존의 연구결과에서 얻어진 반사파의 양상(Beres and Haeni, 1991)과 비교한 결과 하상 표면은 미사 혹은 실트로 구성되어 있고 주요한 하상 하부 매질은 전석(boulder), 호박돌 등으로 이루어져 있었다. 그리고 1차 및 2차 탐사 자료와 DATAPCS의 세굴센서가 설치된 측점을 기준으로 심도 및 위치 보정을 한 결과 큰 오차는 발생하지 않았으며, 400 MHz 안테나를 활용하여 최대수심 약 10 m 이상 하상을 탐사할 수 있었다. 수심이 깊은 구간은 하상과 가까운 위치에서 탐사를 실시하여 양질의 하상 변화 양상을 파악할 수 있어 하상 재료의 정성적인 평가를 높일 수 있도록 하였다. 마포대교의 탐사 대상 교각 우물통 주변은 계획홍수량의 1/3 수준으로 비교적 적은 홍수량이 발생한 2004년의 호우사상으로 인해 일부구간이 약 $10\~20\;cm$ 정도의 퇴적과 세굴 영향이 나타난 것을 제외하고는 유의할 만한 세굴과 하상 변화가 발생하지 않고 매우 안정적인 상태를 보이고 있으며 되메움이나 두드러진 퇴적층의 양상 또한 확인할 수 없었다. 대상구간에 설치한 유속계 최대유속이 2.0 m/s 이상 발생하였지만 우물통 주변의 자갈 및 호박돌 등과 같은 평균입경이 큰 유사의 이동에 절대적인 한계유속을 초과하지 못한 것으로 판단된다. GPR 탐사의 적용 한계성을 극복한 본 연구는 홍수 전$\cdot$후의 하상변화 및 최대세굴심, 되메움 깊이 및 범위 등의 세굴현상을 현장탐사를 바탕으로 현재 다양하게 적용하고 있는 세굴 실험식과 비교 분석함으로써 우물통 주변의 효율적인 세굴 보호 대책을 강구하는 목적으로 그 활용성을 증대할 수 있을 것이다.

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Optimization of Methane Yield in Anaerobic Digestion of Sewage Sludge with Microwave Pretreatment (극초단파 전처리를 적용한 하수슬러지 혐기성소화에서 메탄수율 최적화)

  • Park, WoonJi;Lee, GwanJae;Lee, DongJun;Lee, SeoRo;Choi, YuJin;Hong, JiYeong;Yang, DongSeok;Lim, KyoungJae
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.2
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    • pp.17-29
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    • 2020
  • The objective of this study was to find an optimum methane yield condition in anaerobic digestion of sewage sludge with microwave pretreatment. The pretreatment process was carried out using a lab scale industrial microwave unit (2,450 MHz frequency). The digestion efficiency of pretreated sludge was evaluated by biochemical methane potential (BMP) test. Box-Behnken design and Response Surface Analysis (RSA) were applied to determine the optimal combination of sludge mixing ratio (0 to 100%), power (400 to 1600 W), holding time (0 to 10 min) and pretreatment temperature (60 to 100℃). BMP test results showed that Volatile Solid (VS) removal efficiency was up to 48% at a condition of 0% for mixing ratio, 1600 W for power, 5 min for holding time, and 80℃ for pretreatment temperature. Methane production was up to 832.3 mL/g VSremoved at a condition of 50% for mixing ratio, 1000 W for power, 5 min for holding time, and 80℃ for pretreatment temperature. The results of the variance analysis (ANOVA) showed that the p-value of the power and pretreatment temperature among the independent variables were significant (p<0.05), and in particular, the pretreatment temperature significantly affected on the solubilization and methane production. The optimum condition for the maximum methane yield (847 mL/g VSremoved) was consist of 38.4% of mixing ratio, 909.1 W of power, 4.1 min of holding time, and 80℃ of temperature within the design boundaries.

Microwave Absorbing Properties of Silver-coated Ni-Zn Ferrite Spheres Prepared by Electroless Plating (무전해 도금법에 의해 제조된 은 피복 Ni-Zn Ferrite Sphere의 전파흡수특성)

  • Kim, Jong-Hyuk;Kim, Jae-Woong;Kim, Sung-Soo
    • Journal of the Korean Magnetics Society
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    • v.15 no.3
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    • pp.202-206
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    • 2005
  • The present investigation provides an electromagnetic radiation absorptive composition which comprises silver-coated ferrite microspheres dispersed in silicon rubber matrix for the aim of thin microwave absorber in GHz frequencies. Ni-Zn ferrite spheres with $50{\mu}m$ size in average were prepared by spray-drying and sintering at $1130^{\circ}C$. Conductive silver layer was plated on ferrite spheres by electroless plating. Conductive Ni-Zn ferrite sphere with uniform silver layer were obtained in the concentration of 10 g/L $AgNO_3$ per 20 g ferrite spheres. For this powder, electrical resistance is reduced as low as $10^{-2}\~10^{-3}\;\Omega$. The most sensitive material parameters with silver plating is real and imaginary parts of complex permittivity. The conductive Ni-Zn ferrite spheres have large values of dielectric constant. Due to this high dielectric constant of microspheres, matching thickness is reduced to as low as 2 mm at the frequency of 7 GHz, which is much thinner than conventional ferrite absorbers.

Combined MRI and Relaxogram: A New Method of Fat Study (MRI와 Relaxogram을 이용한 지질 연구의 새로운 기법에 관한 연구)

  • Yongmin Chang;Yoo, Done-Sik;Kim, Tae-Hun;Kim, Yong-Joo;Kang, Duk-Sik;Robert B. Clarkson
    • Progress in Medical Physics
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    • v.10 no.1
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    • pp.23-32
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    • 1999
  • Combined MRI and Relaxogram approach was introduced as a very useful tool for fat study. The phantoms simulating homogeneous mixture of fat and non-fat environments were measured with spin echo pulse sequence on a 0.15 T whole body imager. From 45 scans, the Tl values were obtained by fitting the data to continuous distribution (CONTIN) of relaxation time. This relaxogram gives broad distributions of relaxation time, which are characterized by a number of peaks with characteristic T1 values. Two distinct peaks in relaxogram were observed and identified as signals from com oil and gelatin gel. This model system can be served as simulating the distribution of fat in muscle. Also the relative ratio of two components, which is proportional to the area under the peak, is estimated and compared to nominal values. Based on the good agreement between two predictions, the values from our proposed method agreed with nominal values within $\pm$7 % error. The effects of different concentration of contrast agent and different region of interest are presented. To optimize total scan times, the minimum required data points and so further reduction in total scan times are discussed.

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