• Title/Summary/Keyword: 4.3 Incident

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Synthesis and Photovoltaic Properties of Alternating Conjugated Polymers Derived from Thiophene-Benzothiadiazole Block and Fluorene/Indenofluorene Units

  • Li, Jianfeng;Tong, Junfeng;Zhang, Peng;Yang, Chunyan;Chen, Dejia;Zhu, Yuancheng;Xia, Yangjun;Fan, Duowang
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.505-512
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    • 2014
  • A new donor-accepter-donor-accepter-donor (D-A-D-A-D) type 2,1,3-benzothiadiazole-thiophene-based acceptor unit 2,5-di(4-(5-bromo-4-octylthiophen-2-yl)-2,1,3-benzothiadiazol-7-yl)thiophene ($DTBTTBr_2$) was synthesized. Copolymerized with fluorene and indeno[1,2-b]fluorene electron-rich moieties, two alternating narrow band gap (NBG) copolymers PF-DTBTT and PIF-DTBTT were prepared. And two copolymers exhibit broad and strong absorption in the range of 300-700 nm with optical band gap of about 1.75 eV. The highest occupied molecular orbital (HOMO) energy levels vary between -5.43 and -5.52 eV and the lowest unoccupied molecular orbital (LUMO) energy levels range from -3.64 to -3.77 eV. Potential applications of the copolymers as electron donor material and $PC_{71}BM$ ([6,6]-phenyl-$C_{71}$ butyric acid methyl ester) as electron acceptors were investigated for photovoltaic solar cells (PSCs). Photovoltaic performances based on the blend of PF-DTBTT/$PC_{71}BM$ (w:w; 1:2) and PIF-DTBTT/$PC_{71}BM$ (w:w; 1:2) with devices configuration as ITO/PEDOT: PSS/blend/Ca/Al, show an incident photon-to-current conversion efficiency (IPCE) of 2.34% and 2.56% with the open circuit voltage ($V_{oc}$) of 0.87 V and 0.90 V, short circuit current density ($J_{sc}$) of $6.02mA/cm^2$ and $6.12mA/cm^2$ under an AM1.5 simulator ($100mA/cm^2$). The photocurrent responses exhibit the onset wavelength extending up to 720 nm. These results indicate that the resulted narrow band gap copolymers are viable electron donor materials for polymer solar cells.

A study on the Design and Application of a TIR Lens for Realizing A Compact Spot-Type UV Curing Machine Optical System (컴팩트한 Spot형 UV 경화기 광학계를 구현하기 위한 TIR 렌즈 설계 및 응용에 관한 연구)

  • Kim, Yu-Rim;Heo, Seung-Ye;Lee, Sang-Wook;Kim, Wan-Chin
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.2
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    • pp.255-264
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    • 2022
  • The conventional spot-type UV curing machine configures a collimator optical system using a plurality of lenses so that the light beam is incident through an optical cable. In order to increase the transmission light efficiency, a collimator optical system composed of three or more lenses is required, and accordingly, it is difficult to align the optical system, and it is difficult to implement the system compactly. In this study, a single TIR lens collimator that can realize the same level of spot diameter and light efficiency as the conventional collimator optical system composed of three lenses was designed. Through this, the light efficiency at the curing area with the minimum illuminance deviation was 33.2 %, which was similar to the performance of the reference collimator optical system, and the illuminance deviation on the curing area was 18.8 %, ensuring acceptable performance. In addition, by arranging a fly-eye lens with field flattening function at the front end of the condensing lens, the effective curing area diameter was reduced from 5.0 mm to 3.0 mm, enabling higher curing energy density to be realized. In addition, it was confirmed that the illuminance deviation can be greatly improved to a level of 14.4%.

Numerical Simulation of Irregular Airflow in OWC Wave Generation System Considering Sea Water Exchange (해수교환을 고려한 진동수주형 파력발전구조물에서 불규칙공기흐름에 관한 수치해석)

  • Lee, Kwang Ho;Park, Jung Hyun;Cho, Sung;Kim, Do Sam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.25 no.3
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    • pp.128-137
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    • 2013
  • Due to the global warming and air pollution, interest in renewable energies has increased in recent years. In particular, the crisis of the depletion of fossil energy resources in the near future has accelerated the renewable energy technologies. Among the renewable energy resources, oceans covering almost three-fourths of earth's surface have an enormous amount of energy. For this reason, various approaches have been made to harness the tremendous energy potential. In order to achieve two purposes: to improve harbor water quality and to use wave energy, this study proposed a sea water exchange structure applying an Oscillating Water Column (OWC) wave generation system that utilizes the air flow velocity induced by the vertical motion of water column in the air chamber as a driving force of turbine. In particular, the airflow velocity in the air chamber was estimated from the time variations of water surface profile computed by using 3D-NIT model based on the 3-dimensional irregular numerical wave tank. The relationship of the frequency spectrums between the computed airflow velocities and the incident waves was analyzed. This study also discussed the characteristics of frequency spectrums in the air chamber according to the presence of the structure, wave deformations by the structure, and the power of the water and air flows were also investigated. It is found that the phase difference exists in the time series data of water level fluctuations and air flow in the air chamber and the air flow power is superior to the fluid flow power.

Clinical and Histological Indicators of Proximal and Distal Gastric Cancer in Eight Provinces of Iran

  • Norouzinia, M.;Asadzadeh, H.;Shalmani, H. Mohaghegh;Al Dulaimi, D.;Zali, M.R.
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.11
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    • pp.5677-5679
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    • 2012
  • Background and Aim: Gastric cancer is the second most common cancer worldwide. In this study the clinical and histological features of gastric cancer in the cardia and distal stomach were evaluated. Method: Proximal and distal gastric cancer diagnosed and treated in eight provinces of Iran from 2010-2011 were reviewed in all collected cases. The age standardized incident rates were calculated and tumor location and histological type were recorded. Results: The age-standardized incidence rate for the eight centers was 40.6 per 100,000 populations per year with an upper and lower range of 22.1 and 102.4 per 100,000 population per year. Thirty four percent of the tumors were located in the cardia, 3% in fundus, and 63% in the distal stomach. In 7 provinces the prevalence of distal tumors was significantly greater than proximal tumors (p=0.006). A significant relationship was observed between diffuse form of gastric cancer and distal gastric tumors (p=0.007) and between poor tumor differentiation and distal gastric tumors (p<0.001). Conclusions: the result of this study shows that distal gastric cancer is more common than proximal gastric cancer in Iran.

Studies on the Interaction of High Energy Electron with Various Matters (물질을 투과한 고에너지 전자선의 선량변화)

  • Chu, S.S.;Kim, G.E.;Park, C.Y.
    • Radiation Oncology Journal
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    • v.1 no.1
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    • pp.11-19
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    • 1983
  • Interaction between high energyelectrons and matters had many complex reactions and the high energy electrons lost their energies with collision and scattering, therefore, electrons distribution in matters was shown as various situation by scattering, exciting and ionizing with moleculars. We experimentally studies with 13 MeV Linear Accelerator and thermoluminescence dosimeter using aluminium and Teflon, etc., and measured energy loss of electrons, electron range, electron scattering and dose distribution in matter. We compared the results with theoretical formular, between 4-qw MeV, the energy loss of electrons was decreased by 2 MeV per $1g/cm^2$ but under 1MeV it was rapidly decreased. Electron range in matter reached to $0.5/cm^2$ per 1MeV of incident energy at 6-12MeV. The dose distribution in matter was increased slightly to some depth by total distribution i.e., the combined intensity of primary and secondary radiant and it was rapidly decreased near the maximum range of electrons. Energy loss of electrons and electron range measured by experiment were coincided with theoretical equations of L. Landau and Feather under 5 and 3% errors respectively. The dose distribution of electrons in matter was similar to L.V. Spencer formular, however, we had found that it was quite different in accordance with the field size and that new formular of dose distribution was induced as empirical function contained experimental factors according to field size.

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Wave Control by an Array of N Bottom-Mounted Porous Cylinders (N개의 투과성 원기둥 배열에 의한 파랑제어)

  • 조일형
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.15 no.4
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    • pp.232-241
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    • 2003
  • The interaction of incident monochromiatic waves with N bottom-mounted porous circular cylinders is investigated in the frame of three-dimensional linear potential theory. The fluid domain is divided into N+l regions i.e. a single exterior region and N interior regions, and the diffraction potential in each fluid region is expressed by an eigenfunction expansion method (Williams and Li,2000). The analytic results show that the porous structure reduces both the wave forces and the run-up wave around the cylinder. To verify the developed model, the systematic model test with a line array of porous cylinders is conducted at the wave tank (30m$\times$7m$\times$1.5m). The analytic results are in good agreement with the experimental results within measured frequency range. It is concluded that the breakwater constructed with an array of porous circular cylinders shows the performance of an effective wave barrier together with the seawater-exchange effect and is considered to have vast potentials for the use of seawater-exchanging breakwater in the future.

Effects of Chilbokyeumgamibang(七福飮加味方) on the Cerebral Cortex Neuron injured by Glucose Oxidase (칠복음가미방(七福飮加味方)이 Glucose Oxidase에 의해 손상(損傷)된 대뇌피질(大腦皮質) 신경세포(神經細胞)에 미치는 영향(影響))

  • Choi Kong-Han;Gang Hyeong-Won;Lyu Yeoung-Su
    • Journal of Oriental Neuropsychiatry
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    • v.10 no.1
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    • pp.53-78
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    • 1999
  • As the average life span have been lengthened and the rate of senile population have been raised, chronic degenerative diseases incident to aging has been increased rapidly and become a social problem. With this social background, recently, the facts that oxygen radicals(OR) have toxic effects on Central Nervous System and Peripheral Nervous System and cause neuropathy such as Parkinson's Disease, Alzheimer Disease have been turned out, and accordingly lots of studies on the mechanism of the toxic effects of OR on nerves, the diseases caused by OR and the approaches to curing the diseases have been made. The purpose of this study is to examine the toxic effects caused by Glucose Oxidase(GO) and the effects of herbal extracts such as Chilbokyeum(CBY), Chilbokyeumga Acori Rhizoma(CAR), Acori Rhizoma(AR) on the treatment of the toxic effects. For this purpose, experiments with the cultured cell from the cerebrums of new born mice were done. The results of these experiments were as follows. 1. GO, a oxygen radical, decreased the survival rate of the cultured cells on NR assay, MTT assay and amount of neurofilaments and increased the amount of total protein, lipid peroxidation and the amount of LDH. 2. CBY have efficacy of increasing the amount of neurofilaments and total protein and decreasing lipid peroxidation and the amount of LDH. 3. CAR have efficacy of increasing the amount of neurofilaments and total protein and decreasing lipid peroxidation and the amount of LDH. 4. AR have efficacy of increasing the amount of neurofilaments and total protein. From the above results, It is concluded that Chilbokyeumgamibang has marked efficacy as a treatment for the damages caused in the GO-mediated oxidative process. And Chilbokyeumgamibang is thought to have certain pharmacological effects on controlling over aging and treating Dementia. Further clinical study of this pharmacological effects of Chilbokyeumgamibang should be complemented.

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A View of the World Shown in the Miyazaki Hayao Director's Animation -Focus on Analytic Discussion about the Character and the Incident- (미야자키 하야오 감독의 애니메이션 <센과 치히로의 행방불명>에 나타난 세계관 -인물과 사건에 관한 분석적 논의를 중심으로-)

  • Kim, Jong-Tae
    • The Journal of the Korea Contents Association
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    • v.11 no.7
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    • pp.110-120
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    • 2011
  • The objective of the thesis is to analyze a view of the world appeared in . The chapter II 'humanism healing to distort the existence' discussed humanism to be contributive to reviving the original form. Haku's love for wandering Chihiro, Chihiro's love for Haku who is physically and mentally distressed, as he changed to the dragon, and Chihiro's love for her mother and father who the Yubaba transformed into pigs show humanism given without qualification. The chapter III 'asceticism oriented coexistence' discussed asceticism contributive to public order. Chihiro's father and mother transformed into pigs, Yubaba exploiting workers, and Gaonasi eating away in sight show harmful consequences of intense desire. On the contrary to this, a naive Chihiro and a simple Jeniva show benefit of asceticism. The chapter IV 'thought of life regretting modern civilization' discussed thought of life reflecting on contradiction of capitalism. The Stink God character asked to thorough reconsider about modern civilization. Haku leaved his home, river, instructs the important of nature and life.

Nationwide incidence estimation of colorectal cancer by subsite of origin in Korea (한국인에서 대장-직장암의 해부학적 부위별 발생률 조사)

  • Park, B.J.;Lee, M.S.;Ahn, Y.O.;Heo, D.S.;Kim, D.H.;Kim, H.;Yew, H.S.;Park, T.S.
    • Journal of Preventive Medicine and Public Health
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    • v.29 no.3 s.54
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    • pp.555-563
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    • 1996
  • Nationwide incidence survey was conducted to estimate the annual incidence rates of colorectal cancer among Koreans between Jan 1, 1988 and Dec 31, 1989. The population of the incidence survey was the beneficiaries of Korea Medical Insurance Corporation (KMIC), which were about 4,500,000 persons. The medical records of patients with diagnosis of either ICD-9 153(colon cancer), 154(rectal caner), 197(secondary malignant neoplasm of digestive and respiratory system), or 211(benign neoplasm of digestive system) were abstracted for the period with the standard format. The diagnosis was confirmed by one oncologist through the review of these abstracts. The numerator of the rate was finally defined as the incident colorectal cancer cases diagnosed between July 1, 1988 and June 30, 1989. The crude annual incidence of colorectal cancer for men was 13.1 per 100,000 and 10.6 for women, which was still low when compared with those of Japan and China during the same period. Age-adjusted sex ratio was 1.2 for right-sided colon cancer and 1.9 for left-sided colon cancer. The excess of right colon cancer among postmenopausal women was remarkable, so further analytical approach would be needed to investigate which factors are related with this phenomenon.

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Design of a 2-Port Frequency Mixer for Active Retrodirective Array Applications (역지향성 능동배열 안테나용 2-Port 주파수 혼합기의 설계)

  • Chun Joong-Chang;Kim Tae-Soo;Kim Hyun-Deok
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.2
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    • pp.397-401
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    • 2005
  • In this paper, we have developed a frequency mixer which can be used as a microwave phase conjugator in the retrodirective array antenna. The retrodirective array, which can reflect the incident wave retrodirertively back to the source direction without any priori information, requires phase conjugators to achieve the phase change of 180 degrees for the incoming signal. frequency mixers can efficiently serve as phase conjugators. The circuit topology is of the 2-port structure to avoid the complexity of LO and Rf signal combination and matching circuits, using a pseudomorphic HEU device. The operating frequencies are 4.0 CHz, 2.01 CHz, and 1.99 CHz for LO, RF, and If signals, respectively. Conversion loss is measured to be -ldB and 1-dB compression point -l5 dBm at the LO power of -10 dBm.