• 제목/요약/키워드: 4-electrodes

검색결과 1,595건 처리시간 0.025초

$AB_5$계 수소저장합금의 Zr, Ti 및 V 첨가에 따른 전기화학적특성 (Electrochemical properties of $AB_5$-type Hydrogen alloys upon addition of Zr, Ti and V)

  • 김대환;조성욱;정소이;박충년;최전
    • 한국수소및신에너지학회논문집
    • /
    • 제17권1호
    • /
    • pp.31-38
    • /
    • 2006
  • There are two types of metal hydride electrodes as a negative electrode in a Ni-MH battery, $AB_2$ Zr-based Laves phases and $AB_5$ LM(La-rich mischmetal)-based alloys. The $AB_5$ alloy electrodes have characteristic properties such as a large discharge capacity per volume, easiness in activation, long cycle life and a low cost of alloy. However they have a relatively small discharge capacity per weight. The $AB_2$alloy electrodes have a much higher discharge capacity per weight than $AB_5$ alloy electrodes, however they have some disadvantages of poor activation behavior and cycle life. Therefore, in order to improve the discharge capacity of the $AB_5$ alloy electrode the Zr, Ti and V which are the alloying elements of the $AB_2$ alloys were added to the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}$ alloy which was chosen as a $AB_5$ alloy with a high capacity. The addition of Zr, Ti and V to $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}$ alloy improved the activation to be completed in two cycles. The discharge capacities of Zr 0.02, Ti 0.02 and V 0.1 alloys in $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) were respectively 346, 348 and 366 mAh/g alloy. The alloy electrodes, Zr 0.02, Ti 0.05 and V 0.1 in $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V), have shown good cycle property after 200 cycles. The rate capability of the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) alloy electrodes were very good until 0.6 C rate and the alloys, Zr 0.02, Ti 0.05 and V 0.1, have shown the best result as 92 % at 2.4 C rate. The charge retention property of the $LaNi_{3.6}Ai_{0.4}Co_{0.7}Mn_{0.3}M_y$ (M = Zr, Ti, V) alloys was not good and the alloys with M content from 0.02 to 0.05 showed better charge retention properties.

전기화확적 방법에 의한 축산폐수의 처리 (Treatment of Livestock Wastewater by Electrochemical Method)

  • 허종수;정태욱;이홍재;백송범;조주식
    • 한국환경농학회지
    • /
    • 제18권4호
    • /
    • pp.332-338
    • /
    • 1999
  • 전기화학적 방법에 의한 축산폐수의 효과적인 처리를 위하여 스테인레스 전극판 및 알루미늄 전극판을 이용한 회분석 실험에서는 전압, 전극판 간격 및 전해용액 주입농도별 오염물질의 처리효율을 조사한 결과는 다음과 같다. 전압별 전기화학반응 실험 결과 두가지 전극재질 모두 전압이 높을수록 전기화학반응조 내의 온도 및 pH는 상승하였으나, EC는 감소하는 경향이었다. COD 및 T-N처리율은 두가지 전극재질 모두 전압이 높을수록 전반적으로 증가하였고, SS처리율은 두가지 전극재질 모두에서 전압의 세기에 관계없이 반응초기에 약 90% 이상이었으나 20V에서는 15분 그리고 30V에서는 12분 이상 전기화학반응을 시켰을 경우에는 그 처리율이 80% 이하로 감소되었다. T-P처리율은 두가지 전극재질 모두에서 전압의 세기에 관계없이 약 90% 이상이었다. 전극판 간격별 전기반응 실험 결과 COD, T-N 및 T-P처리율은 두가지 전극재질 모두 전극판 간격이 좁을수록 대체적으로 증가하였으며, SS처리율은 두가지 전극재질 모두 전극판 간격에 관계없이 반응초기에 약 90% 이상이었다. 전해용액인 PACS의 주입농도별 전기반응 실험 결과 COD, T-N 및 T-P 처리율은 PACS의 주입농도가 증가할수록 대체적으로 증가하였으나 PACS의 주입농도가 200㎎/l 이상에서는 오염물질의 처리효율이 별 차이가 없었고, SS처리율은 두가지 전극재질 모두 약 90% 이상이었다. 이상의 회분식 실험결과 전기화학적 방법에 의한 축산폐수의 최적 처리 조건은 전압 20V, 전극판 간격 1㎝ 그리고 PACS 주입농도 200㎎/l 인 것으로 판단되었다.

  • PDF

부중심소엽 주변 경막하 전극들에서 기록된 후경골신경 체성감각유발전위 (Posterior Tibial Nerve Somatosensory Evoked Potentials Recorded on Subdural Electrodes around Paracentral Lobule)

  • 서대원
    • Annals of Clinical Neurophysiology
    • /
    • 제1권2호
    • /
    • pp.112-117
    • /
    • 1999
  • 부중심소엽 주변의 경막하 전극들에서 기록한 PTSEP는 전극의 위치에 따라 다양한 파형을 나타내며, 파형의 최대치는 주로 부중심소엽의 후 상부에 위치한다. 특히 최대값이 주변보다 확연히 차이 나며 10uV이상의 파형으로 기록될 경우는 40 msec에서 양극성을 나타낸다. 또한 주변의 전극과 상역전을 형성할 수 있는데 최대 전극의 뒤에서 형성될 경우는 더욱 분명한 상역전을 관찰할 수 있다. 따라서 경막하전극을 통한 PTSEP는 내측 반구의 부중심소엽 주변의 위치를 파악하는데 도움을 줄 수 있다고 생각된다.

  • PDF

핀-핀 형 또는 판-판 형 전극에 인가된 AC 전기장이 에틸렌 정상 확산 화염 Soot 입자 배출에 미치는 영향 (Effects of AC Electrostatic Field Applied to fin-to-Pin/Plate-to-Plate Electrodes on Soot Reduction in a C2B4 Normal Diffusion Flame)

  • 이재복;황정호
    • 대한기계학회논문집B
    • /
    • 제26권8호
    • /
    • pp.1062-1068
    • /
    • 2002
  • In our previous study, it was proven that the mean size and the total number concentration of carbon soot particles emitted from a $C_2$H$_4$ normal diffusion flame decreased when a DC corona was discharged to pin-pin electrodes. In this work the effect of AC corona discharge on soot emission was investigated and compared with that of DC corona discharge. For the pin-pin electrodes the size of soot particles and the number concentration decreased by the AC voltage. There were only slight changes in size distribution with frequencies, while the magnitude of applied voltage was constant. When the electric field was applied to plate-plate electrodes, the size and the number concentration also decreased with the applied AC voltages. For applied voltages above 2kV the effect of frequency increase on the soot emission was effective.

A Low-Power Portable ECG Touch Sensor with Two Dry Metal Contact Electrodes

  • Yan, Long;Yoo, Hoi-Jun
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • 제10권4호
    • /
    • pp.300-308
    • /
    • 2010
  • This paper describes the development of a low-power electrocardiogram (ECG) touch sensor intended for the use with two dry metal electrodes. An equivalent ECG extraction circuit model encountered in a ground-free two-electrode configuration is investigated for an optimal sensor read-out circuit design criteria. From the equivalent circuit model, (1) maximum sensor resolution is derived based on the electrode's background thermal noise, which originates from high electrode-skin contact impedance, together with the input referred noise of instrumentation amplifier (IA), (2) 60 Hz electrostatic coupling from mains and motion artifact are also considered to determine minimum requirement of common mode rejection ratio (CMRR) and input impedance of IA. A dedicated ECG read-out front end incorporating chopping scheme is introduced to provide an input referred circuit noise of 1.3 ${\mu}V_{rms}$ over 0.5 Hz ~ 200 Hz, CMRR of IA > 100 dB, sensor resolution of 7 bits, and dissipating only 36 ${\mu}W$. Together with 8 bits synchronous successive approximation register (SAR) ADC, the sensor IC chip is implemented in 0.18 ${\mu}m$ CMOS technology and integrated on a 5 cm $\times$ 8 cm PCB with two copper patterned electrodes. With the help of proposed touch sensor, ECG signal containing QRS complex and P, T waves are successfully extracted by simply touching the electrodes with two thumbs.

롤투롤 그라비어 방식의 인쇄 전극 저항 최소화를 위한 실험계획법 적용 인쇄 공정 조건 최적화 (Optimization of Printing Conditions Using Design Experiments for Minimization of Resistances of Electrodes in Roll-to-roll Gravure Printing Process)

  • 이상윤;김철;김충환
    • 한국생산제조학회지
    • /
    • 제26권4호
    • /
    • pp.351-356
    • /
    • 2017
  • The resistance of printed patterns for electrodes fabricated using printing technology should be minimized. This parameter depends on the pattern width and thickness; however, from the viewpoint of printability, the printed patterns should be printed at the designed width. The resistance of the printed patterns as well as printability is affected by various printing conditions. In this paper, the printing condition is optimized to minimize the resistance of electrodes printed by the roll-to-roll gravure method. This is done by considering the spread ratio of pattern width as a parameter of printability using design experiments. The drying temperature, dryer fan speed, and printing speed are selected as effective factors for the experiment objective. The optimized conditions are obtained and reproducibility test using these demonstrates that the optimized conditions can produce low-resistance electrodes for printability of the pattern width.

비접촉식 4-전극형 전기용량 센서를 이용한 in situ 정밀측정 (Precision in situ Measurement using Non-Contacting Capacitive Sensor with 4-Electrodes)

  • 김재열;이래덕;박기형;마상동;양동조
    • 한국정밀공학회지
    • /
    • 제19권3호
    • /
    • pp.33-38
    • /
    • 2002
  • To establish the national standard of capacitance, four main electrodes of the cross capacitor which were evaluated to linearity and roundness less the $\pm 1 \mu m$ respectively have to be adjusted symmetrically in an inner cylinder. Four LM shafts with diameter of 5 mm were installed between main electrodes of the cross capacitor, and the electrodes were adjusted, as the first step, by means of the measured capacitance. In the second step, the symmetrical adjustment up to $\pm 1.2\mu m$ was performed by using a ball sensor, ball-type movable sensor, non-contacting capacitive sensor and upper guard sensor which were developed in this project.

Effect of Thermal Treatment on the Electrocatalytic Activities and Surface Roughness of ITO Electrodes

  • Choi, Moon-Jeong;Jo, Kyung-Mi;Yang, Hae-Sik
    • Journal of Electrochemical Science and Technology
    • /
    • 제3권1호
    • /
    • pp.24-28
    • /
    • 2012
  • The electrocatalytic activities and surface roughness of indium-tin-oxide (ITO) electrodes have been investigated after thermal treatment at 100, 150, or $200^{\circ}C$ for 30 min, 2 h, or 8 h. To check electrocatalytic activities, the electrochemical behavior of four electroactive species (p-hydroquinone, $Ru(NH_3){_6}^{3+}$, ferrocenemethanol, and $Fe(CN){_6}^{4-}$) has been measured. The electron transfer rate for p-hydroquinone oxidation and ferrocenemethanol oxidation increases with increasing the incubation temperature and the incubation period of time, but the rate for $Ru(NH_3){_6}^{3+}$ is similar irrespective of the incubation temperature and period because $Ru(NH_3){_6}^{3+}$ undergoes a fast outer-sphere reaction. Overall, the electrocatalytic activities of ITO electrodes increase with increasing the incubation temperature and period. The surface roughness of ITO electrodes increases with increasing the incubation temperature, and the thermal treatment generates many towering pillars as high as several tens of nanometer.

전기저항가열 압출점접합공정에 있어서 접합강도에 관한 연구 (A Study of the Weld Strength of Extru-Rivet Spot Welding Using Electrodes Heated by Electric Resistance)

  • 이성준;진인태
    • 소성∙가공
    • /
    • 제22권4호
    • /
    • pp.189-195
    • /
    • 2013
  • In this study, the weld strength of extru-rivet spot welding was investigated by simulation and experiment. In order to obtain hot plasticity flow bonding of the two plates by a single rivet, electrodes are used for heating of the two plates and the rivet by electric resistance. Because weld strength is influenced by the temperature in the weld zone, the diameter of the electrodes and the amount of current supplied to the electrodes are important variables. For the simulation, heat distribution and weld strength were calculated using DEFORM-3D. The weld strength in the weld zone was calculated for various values of the experimental parameters. The simulation results showed that the weld strength was the highest when the weld current was 37kA, the electrode diameter was 12mm, and the welding frequency was 90cycle. Aluminum 5052 was used for the experimental study. A total of three aluminum plates, two welding plates with 1mm thickness and one plate with 2mm thickness for the inserting rivet, were used for the experimental extru-rivet spot welding.

The Investigation of Electro-Oxidation of Methanol on Pt-Ru Electrode Surfaces by in-situ Raman Spectroscopy

  • She, Chun-Xing;Xiang, Juann;Ren, Bin;Zhong, Qi-Ling;Wang, Xiao-Cong;Tian, Zhong-Qun
    • 전기화학회지
    • /
    • 제5권4호
    • /
    • pp.221-225
    • /
    • 2002
  • Assisted by the highly sensitive confocal microprobe Raman spectrometer and proper surface roughening procedure, the Raman investigation on the adsorption and reaction of methanol was performed on Pt-Ru electrodes with different coverages. A detailed description of the roughening process of the Pt electrodes and the underpotential deposition of the Ru was given. Reasonably good Raman signal reflecting the metal-carbon vibration and CO vibration was detected. The appearance of vibrations of the Ru oxides, together with the existence of Ru-C, Pt-C and CO bands, clearly demonstrates the participation of the bi-functional mechanism during the oxidation process of methanol on Pt-Ru electrodes. The Pt-Ru electrode was found to have a higher catalytic activity over Pt electrodes. This preliminary study shows that electrochemical Raman spectroscopy can be applied to the study of rough electrode surface.