• Title/Summary/Keyword: 4극자

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A Study on Magnetic Properties of $Ni_{1-x}Zn_{x}Fe_{2}O_{4}(0{\leq}x{\leq}1)$ Ferrrite ($Ni_{1-x}Zn_{x}Fe_{2}O_{4}(0{\leq}x{\leq}1)$ Ferrrite의 자기적 성질 연구)

  • 조익한;양재석;김응찬;강신규
    • Journal of the Korean Magnetics Society
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    • v.6 no.6
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    • pp.397-404
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    • 1996
  • The magnetic properties of $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ have been studied by X-ray diffractometry and $M\"{o}ssbauer$ Spectroscopy at room temperature. The X-ray diffraction study show that spinel structure is formed in all x, lattice constants linearly increased from $8.3111{$\AA$}~8.4184{$\AA$}({\pm}0.0003)$ with increasing x from 0 to 1, and oxygen parameter increase with increasing x. $M\"{o}ssbauer$ spectrum shows that $Ni_{1-x}Zn_{x}Fe_{2}O_{4}(x=0)$ has two antiparallel magnetic structure due to $Fe^{3+}$ octahedral site and $Fe^{3+}$ tetrahedral site. $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ with $0.2{\leq}x{\leq}0.6$ has magnetic structure of Yafet and Kittel, in particularly, specimen with x=0.6 shows relaxation effect. Specimen with $x{\geq}0.8$ show paramagnetic quadrupole splitting. The isomer shift is independent of x, but quadrupole splittings decrease with increasing x in the range of $0.8{\leq}x{\leq}1$, and nuclear magnetic fields decrease with in¬creasing x in the range of $0{\leq}x{\leq}0.6$. The magnetic properties of $Ni_{1-x}Zn_{x}Fe_{2}O_{4}$ change from ferrimagnetics to pararnagnetics with increasing x.

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The Study of Antiferromagnetic Spin-lattice Coupling of FeCr2Se4 (FeCr2Se4의 반강자성 스핀-격자 상호작용 연구)

  • Kang, Ju-Hong;Son, Bae-Soon;Kim, Sam-Jin;Kim, Chul-Sung;Lee, H.G.;Park, Min-Seok;Lee, Sung-Ik
    • Journal of the Korean Magnetics Society
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    • v.17 no.2
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    • pp.86-89
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    • 2007
  • [ $FeCr_2Se_4$ ] prepared under the high pressure (3 GPa) has been studied with x-ray, neutron diffraction techniques, superconducting quantum interference device (SQUID) magnetometer, resistance, and Mossbauer spectroscopy. The temperature dependence of resistance is explained by Mott-VRH and small polaron model for the regions I (T<20 K) and II (T>42 K), respectively. Neutron diffraction results show an antiferromagnetic spin-lattice coupling near the Neel temperature. So finally the distance of atom is enlarged in region (110$FeCr_2Se_4$ shows convex type of temperature dependence.

Analysis of Selenium in Grain with ORC Collision-Removal of Br Interference using Mathematical Calibration (ORC ICPMS에서의 곡류중의 셀레늄 분석-수학적 보정을 이용한 Br의 간섭제거)

  • Cho, Heon-Hong;Pak, Yong-Nam
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.472-477
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    • 2011
  • The concentration of selenium in grain samples was determined using isotope dilution method in ORC-ICPMS. The experimental conditions were optimized to $H_2$ mode and the flow rate was $4.0\;mL\;min^{-1}$. ORC in $H_2$ mode proved to eliminate most of polyatomic interferences except $BrH^+$ when Br is present in sample matrix. Chemical removal of Br was very difficult and the mathematical correction was successfully employed. The fraction of $BrH^+$ generated from Br at the current experimental condition was 14.1%. The signal on m/z 82 was corrected and calculated for isotope dilution. The analytical reliability of the propose method was successfully evaluated by analyzing the certified standard reference material NIST SRM 1566 and 1567. The method was applied to real samples and the results are $0.034{\pm}0.001\;{\mu}g\;g^{-1}$ for white rice, $0.059{\pm}0.002_5\;{\mu}g\;g^{-1}$ for brown rice, $0.029{\pm}0.001_4\;{\mu}g\;g^{-1}$ for black rice, and $0.034{\pm}0.002\;{\mu}g \;g^{-1}$ for barley. The detection limits ($3\sigma$) for Se was $0.012\;ng\;g^{-1}$.

Shock Reflection and Penetration Impinging into a Vortex(II) - Theoretical Model - (와동에 입사하는 충격파의 반사 및 투과 (II) -이론적 모델-)

  • Jang, Se-Myeong;Lee, Su-Gap
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.9
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    • pp.1319-1324
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    • 2002
  • A theoretical model on shock-vortex interaction is investigated using a numerical technique to solve Navier-Stokes equations. The shock-vortex interaction generated by this model based on the classical Rankin vortex is precisely investigated for a benchmark problem: Dosanjh and Weeks experiment. In terms of shock dynamics, the interaction is categorized to three stages: shock distortion, shock split, and shock-shock interaction. The quadrupolar structure of the sound source produced by the interaction is far supported with the present model, and the difference between experiment and theoretical model is also discussed in this paper.

Characteristics of Low Frequency Aero-acoustic Noise Radiation for a Wind Turbine Generator of NREL Phase VI (NREL Phase VI 풍력발전기 저주파 소음방사 특성)

  • Mo, Jang-Oh;Kim, Byoung-Yun;Ryu, Byeng-Nam;Lee, Young-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.504-507
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    • 2009
  • The purpose of this work is to predict the low frequency aero-acoustic noise generated from the horizontal axis wind turbine, NREL Phase VI using large eddy simulation and Ffowcs-Williams and Hawkings model provided in the commercial code, FLUENT. Calculated aerodynamic performances such as shaft torque and power are compared with experimentally measured value. Performance results show a good agreement with experimental data within about 0.8%. If the distance by two times is changed from 32D to 64D toward the downstream region, sound pressure level is reduced by about 6.4dB.

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Diagnostics of Inductively Coupled $BCl_3/Ar$ Plasma Characteristics Using Quadrupole Mass Spectrometer (사중극자 질량 분석기를 이용한 $BCl_3/Ar$ 유도결합 플라즈마 특성 진단)

  • Kim, Gwan-Ha;Kim, Chang-Il
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.4
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    • pp.204-208
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    • 2006
  • In this study, we investigated the ion energy distributions in a chlorine based inductively coupled plasma by quadrupole mass spectrometer with an electrostatic ion energy analyzer. Ion energy distributions are presented for various plasma parameters such as $BCl_3/Ar$ gas mixing ratio, RF power, and process pressure. As the $BCl_3/Ar$ gas mixing ratio and process pressure decreases, and RF power increases, the saddle-shaped structures is enhanced. The reason is that there are ionized energy difference between $BCl_3$ and Ar, change of plasma potential, alteration of mean free path. and variety of ion collision in the sheath.

Development of a Prototype Mass Spectrometer (질량 분석기의 원형 모델 개발)

  • Jingeun Rhee;Nam-Seok Lee;Sung Won Kang;Seontae Kim;Kyu-Ha Jang;Yu Yi;Ik-Seon Hong;Cheong Rim Choi;Kyoung Wook Min;Jongil Jung
    • Journal of Space Technology and Applications
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    • v.3 no.1
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    • pp.86-99
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    • 2023
  • The mass spectrometer, being an essential scientific instrument for uncovering the origin of the solar system and life, has been used since the early 1970s on board spacecraft to obtain information of neutral and ionized elements in the atmosphere and surface of the moon, planets, asteroids, and comets. According to the 4th Basic Plan for the Promotion of Space Development (2023-2027), Korea plans to conduct lunar landing in 2032 and Mars landing in 2045 as the core goals of the plan and focuses on developing the technologies required for unmanned robotic exploration missions. In this regard, it is crucial to develop the technology of a mass spectrometer, which is the most fundamental payload for space exploration for maximized scientific achievements, however never tried before in any domestic space missions. We describe in this paper the principle of a domestically developed quadrupole mass spectrometer, its prototype model, and the test results of its performance. We conclude this paper with intended future improvements.

optical Simulation on EUV Reflectivity of Mo/Si Multilayer Structure (Mo/Si 다층박막의 극자외선 반사도에 대한 전산모사)

  • 이영태;강인용;정용재;이승윤;허성민
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.2
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    • pp.19-24
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    • 2001
  • The effect of thickness variation and inter-diffusion layer on the reflectivity of Mo/Si multilayer has been investigated. The reflectivity of the imperfect Mo/Si multilayer with thickness variation of 28% was found to be lowered by 10.8% compared to that of ideal Mo/Si multilayers with 40-periods. When the inter-diffusion layer is taken into account, the reflectivity is decreased by 4.7% additionally. We also fecund that the reflectivity continued to increase until the 25th-layer but it showed irregular tendencies about increment and decrement from the 26th-layer of Mo/Si multilayer structures.

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Fabrication of the Plasma Focus Device for Advanced Lithography Light Source and Its Electro Optical Characteristics in Argon Arc Plasma (차세대 리소그래피 빛샘 발생을 위한 플라스마 집속 장치의 제작과 아르곤 아크 플라스마의 발생에 따른 회로 분석 및 전기 광학적 특성 연구)

  • Lee S.B.;Moon M.W.;Oh P.Y.;Song K.B.;Lim J.E.;Hong Y.J.;Yi W.J.;Choi E.H.
    • Journal of the Korean Vacuum Society
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    • v.15 no.4
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    • pp.380-386
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    • 2006
  • In this study, we had designed and fabricated the plasma focus device which can generate the light source for EUV(Extreme Ultra Violet) lithography. And we also have investigated the basic electrical characteristics of currents, voltages, resistance and inductance of this system. Voltage and current signals were measured by C-dot and B-dot probe, respectively. We applied various voltages of 1.5, 2, 2.5 and 3 kV to the anode electrode and observed voltages and current signals in accordance with various Ar pressures of 1 mTorr to 100 Torr in diode chamber. It is observed that the peak values of voltage and current signals were measured at 300 mTorr, where the inductance and impedance were also estimated to be 73 nH and $35 m{\Omega}$ respectively. The electron temperature has been shown to be 13000 K at the diode voltage of 2.5 kV and this gas pressure of 300 mTorr. It is also found that the ion density Ni and ionization rate 0 have been shown to be $N_i = 8.25{\times}10^{15}/cc$ and ${\delta}$= 77.8%, respectively by optical emission spectroscopy from assumption of local thermodynamic equilibrium(LTE) plasma.

Eu3+ Luminescence in Two-Dimensional Sr2-2xEuxKxSnO4 with K2NiF4 Structure (2차원적 K2NiF4형 구조의 Sr2-2xEuxKxSnO4에서 Eu3+ 이온의 Luminescence)

  • Yo, Chul-Hyun;Minh Chau, P.T.;Ryu, Kwang-Hyun;Kim, Anh-T.
    • Journal of the Korean Chemical Society
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    • v.41 no.4
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    • pp.175-179
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    • 1997
  • Luminescence of $Eu^{3+}$ has been studied in $Sr_{2-2x}Eu_xK_xSnO_4$ with two-dimensional $K_2NiF_4$ structure. The $^5D_o$$^7F_o$$Eu^{3+}$ ion represents the J=0 → J=0 transition which is forbidden by a Judd-Ofelt selection rule for electric dipole transition in 4f shell of $Eu^{3+}$ ions. However, the emission line of $^5D_o$$^7F_o$$Eu^{3+}$ emission spectra of Sr2-2xEuxKxSnO4$Sr_{2-2x}Eu_xK_xSnO_4$structure around $Eu^{3+}$ ions.

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