• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2758-2764
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• 2014

We demonstrated the synthesis of organic carbonates using alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates and alcohol in the presence of aluminum chloride. Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates were reacted with alcohol in the presence of $AlCl_3$ in toluene at room temperature to afford the corresponding unsymmetric and symmetric organic carbonates in good to excellent yields. These are efficient and convenient processes. Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates are solid, stable and non-toxic $CO_2/CO_2R$(Ar) source. It is noteworthy that the reaction is carry out under an ambient and acidic conditions, the easy-to prepare and readily available starting materials and the quantitative isolation of reusable 4,5-dichloropyridazin-3(2H)-one.

• Bulletin of the Korean Chemical Society
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• 제24권11호
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• pp.1655-1658
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• 2003

Chemoselective N-benzenesulfonylation of aliphatic amines using 2-(4-nitrobenzenesulfonyl)-4,5-dichloropyridazin-3(2H)-one (2) gave the corresponding 4-nitrobenzenesulfonamides in good or excellent yield. This method is a simple, mild and general procedure for the chemoselective N-benzenesulfonylation of aliphatic amines.

• Bulletin of the Korean Chemical Society
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• 제25권4호
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• pp.501-505
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• 2004

Esterification of aliphatic or aromatic carboxylic acids with alcohols using 2-(4-nitrobenzenesulfonyl)-4,5-dichloropyridazin-3(2H)-one (3) in the presence of base in organic solvents gave the corresponding esters in excellent yields

• 대한화학회지
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• 제58권1호
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• pp.140-144
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• 2014

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3410-3414
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• 2013

Atom-economical esterification is of great importance in green chemistry. In this work, we demonstrated the catalyst and additive free esterification of alcohols by their reaction with 2-acyl-4,5-dichloropyridazin-3(2H)-ones without solvent at $100^{\circ}C$. Aliphatic and aromatic alcohols were converted into the corresponding esters in good to excellent yields. It is noteworthy that the reaction is solvent-free, atom-economic, easy-workup, and rapid and that the process is inexpensive.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2985-2988
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• 2010