• 제목/요약/키워드: 3d-transition metal

검색결과 108건 처리시간 0.025초

Water Oxidation Mechanism for 3d Transition Metal Oxide Catalysts under Neutral Condition

  • Seo, Hongmin;Cho, Kang Hee;Ha, Heonjin;Park, Sunghak;Hong, Jung Sug;Jin, Kyoungsuk;Nam, Ki Tae
    • 한국세라믹학회지
    • /
    • 제54권1호
    • /
    • pp.1-8
    • /
    • 2017
  • Electrochemical water splitting to produce hydrogen energy is regarded as a promising energy conversion process for its environmentally friendly nature. To improve cell efficiency, the development of efficient water oxidation catalysts is essentially demanded. For several decades, 3d transition metal oxides have been intensively investigated for their high activity, good durability and low-cost. This review covers i) recent progress on 3d transition metal oxide electrocatalysts and ii) the reaction mechanism of oxygen evolving catalysis, specifically focused on the proposed pathways for the O-O bond formation step.

절반금속 Fe_2TX 화합물의 전자구조 연구 (T = 3d 전이금속; X = Al, Si) (Electronic Structures of half-metallic phase of ternary Fe_2TX (T = 3d transition metal and X = Al, Si))

  • Park, Jin-Ho;Kwon, Se-Kyun;Byung ll Min
    • 한국자기학회:학술대회 개요집
    • /
    • 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
    • /
    • pp.584-584
    • /
    • 2000
  • Electronic structures of ordered Fe$_3X (X = Al, Si), and their derivative ternary alloys of Fe_2TX (T = 3d transition metal) have been investigated by using the linearized muffin-tin orbital (LMTO) band method. The role of the coupling between substituted transition metal and its neighbors is investigated by calculating the magnetic moments and local density of states (LDOS). It is shown that it is essential to include the coupling beyond nearest neighbors in obtaining the magnetic moment of Fe alloy. The preferential sites of T impurities in Fe_3X are determined from the total energy calculations. The derivative ternary alloys of Fe_2TX have characteristic electronic structures of semi-metal for Fe_2VAI and (nearly) half-metal for Fe_2TAI (T = Cr, Mn) and Fe_2TSi (T = V, Cr, Mn)

  • PDF

2차원 층상구조 전이금속칼코젠의 반도체-도체 구조상전이 기반 응용 기술 (Applications of metal-semiconductor phase transition in 2D layered transition metal dichalcogenides)

  • 조수연;김세라;석진봉;양희준
    • 진공이야기
    • /
    • 제3권1호
    • /
    • pp.4-8
    • /
    • 2016
  • Motivated by two dimensional graphene, layered transition metal dichalcogenides (TMDs) have attracted scientific interests by their diverse electronic, optical and catalytic properties. In particular, group 6 TMDs such as $MoS_2$ and $MoTe_2$ have polymorphs (with metallic octahedral and semiconducting hexagonal phases) which are not present in graphene. Here, we introduce a new concept in 2D materials' studies, structural phase transition, with group 6 TMDs and its current research trend and applications for electric device and electrochemical catalyst.

Metal-insulator Transition in $(Sr_{0.75},\;La_{0.25})TiO_3$ Ultra-thin Films

  • Choi, Jae-Du;Choi, Eui-Young;Lee, Yun-Sang;Lee, Jai-Chan
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2011년도 추계학술발표대회
    • /
    • pp.19.2-19.2
    • /
    • 2011
  • The $(Sr_{0.75},\;La_{0.25})TiO_3$ (SLTO) ultra-thin films with various thicknesses have been grown on Ti-O terminated $SrTiO_3$(100) substrate using Laser-Molecular Beam Epitaxy (Laser MBE). By monitoring the in-situ specular spot intensity oscillation of reflection high energy electron diffraction (RHEED), we controlled the layer-by-layer film growth. The film structure and topography were verified by atomic force microscopy (AFM) and high resolution thin film x-ray diffraction by the synchrotron x-ray radiation. We have also investigated the electronic band structure using x-ray absorption spectroscopy (XAS). The ultra thin SLTO film exhibits thickness driven metal-insulator transition around 8 unit cell thickness when the film thickness progressively reduced to 2 unit cell. The SLTO thin films with an insulating character showed band splitting in Ti $L_3-L_2$ edge XAS spectrum which is attributed to Ti 3d band splitting. This narrow d band splitting could drive the metal-insulator transition along with Anderson Localization. In optical conductivity, we have found the spectral weight transfer from coherent part to incoherent part when the film thickness was reduced. This result indicates the possibility of enhanced electron correlation in ultra thin films.

  • PDF

수용액에서 NTOE, NDOE가 결합된 Merrifield 수지를 이용한 Ag(I)의 흡착 및 분리 특성 (Adsorption and Separation of Ag(I) Using a Merrifield Resin Bound NTOE, NDOE in Aqueous Solution)

  • 이철규;김해중
    • 분석과학
    • /
    • 제12권2호
    • /
    • pp.159-165
    • /
    • 1999
  • 수용액에서 1,12-diaza-3,4:9,10-dibenzo-5,8-dioxacyclopentadecane(NTOE)가 결합된 merrifield 수지와 1,12,15-triaza-3,4:9,10-dibenzo-5,8-dioxacycloheptadecane(NDOE)가 결합된 merrifield 수지를 이용한 전이금속이온들의 흡착 및 분리특성을 조사하였다. 전이금속이온들의 흡착정도(adsorption degree, E)와 분포비(distribution ratio, D)의 순위는 동일하게 Cu(II)$t_R$)이 흡착정도와 분포비에 의해서 영향을 받았으며, 이러한 흡착 및 분리 실험 결과로부터 혼합금속용액에서 Ag(I)의 분리가능성을 확인할 수 있었다.

  • PDF

Vapor Deposition Techniques for Synthesis of Two-Dimensional Transition Metal Dichalcogenides

  • Song, Jeong-Gyu;Park, Kyunam;Park, Jusang;Kim, Hyungjun
    • Applied Microscopy
    • /
    • 제45권3호
    • /
    • pp.119-125
    • /
    • 2015
  • Two-dimensional (2D) transition metal dichalcogenides (TMDCs) have attracted significant attention due to their unique and exotic properties attributed to their low dimensionality. In particular, semiconducting 2D TMDCs such as $MoS_2$, $WS_2$, $MoSe_2$, and $WSe_2$ have been demonstrated to be feasible for various advanced electronic and optical applications. In these regards, process to synthesize high quality 2D TMDCs layers with high reliability, wafer-scale uniformity, controllable layer number and excellent electronic properties is essential in order to use 2D TMDCs in practical applications. Vapor deposition techniques, such as physical vapor deposition, chemical vapor deposition and atomic layer deposition, could be promising processes to produce high quality 2D TMDCs due to high purity, thickness controllability and thickness uniformity. In this article, we briefly review recent research trend on vapor deposition techniques to synthesize 2D TMDCs.