• Design & Manufacturing
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• v.13 no.3
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• pp.1-11
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• 2019

Recently, studies on the development of flexible electronic devices by combining flexible materials and a conductor have been actively performed as interest in wearable devices. Especially, carbon nanotubes (CNT) or graphene coating have been used to construct a circuit to induce improvement in flexibility and rigidity. Various technologies have been developed in the surface coating of conductive materials, which are key to the manufacture of flexible electronic devices. Surface coating products with 3D coating and micro-patterns have been proposed through electrospinning, electrification, and 3D printing technologies. As a result of this advanced surface coating technology, there is a growing interest in manufacturing gradient conductive surfaces. Gradient surfaces have the advantage that they are adapted to apply a gentle change or to inspect optimum conditions in a particular region by imparting continuously changing properties. In this study, we propose a manufacturing technique to produce a continuous gradient conductive surface by combining a partial stretching of elastomer and a conductive material coating, and introduce experimental results to confirm its performance.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.193-194
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• 2012

그래핀(graphene)은 탄소원자가 육각형 벌집 모양 배열의 격자구조를 가지는 원자 한층 두께의 이차원 물질이다. 그래핀은 전도띠(conduction band)와 가전자띠(valence band)가 한 점에서 만나고 에너지와 역격자의 k 벡터가 선형적으로 비례하는 에너지 구조를 가진다. 이로 인해 그래핀은 매우 빠른 전하 이동도를 가지며 원자 한 층의 두께임에도 불구하고 약 2.3%의 빛을 흡수할 수 있으며 자외선 영역부터 적외선 영역까지의 넓은 파장대의 빛을 흡수 할 수 있다. 이와 같은 그래핀의 우월한 성질을 이용하면 광 응답에 고속으로 반응하고 높은 주파수의 광통신에서도 작동 할 수 있는 그래핀 광소자를 제작할 수 있게 된다. 하지만 미래의 고속 그래핀 광소자를 실현하기에 앞서 그래핀의 광응답에 대한 정확한 이해가 필요하다. 그리하여 본 연구에서는 그래핀 광소자를 제작하고 광소자의 광응답 전기적 성질을 분석하여 그래핀의 광응답 특성을 얻어내고자 실험을 진행하였다. 그래핀을 채널 물질로 하고 소스, 드레인, 후면 게이트를 가지는 일반적인 그래핀 전계효과 트랜지스터(field-effect transistor)를 제작하고 채널에 빛을 비추고 비추지 않은 상태에서의 전기적 성질을 측정하고 그 때 얻어진 그래프의 광응답의 원인을 조사하였다. 이 때 얻어지는 $I_D-V_G$ 그래프가 광 조사 시 왼쪽으로 이동하게 되는데 이의 원인을 각 게이트 전압 구간별로 $I_D$-t 그래프를 획득하여 분석하였다. 또한 광원에 펄스를 인가하여 펄스 형태의 광원을 그래핀 전계효과 트랜지스터에 조사시키고 이에 따른 전기적 성질 변화를 관찰하였다 이 때 다양한 게이트 전압이 인가된 상태에서 레이저 펄스 광원에 의한 광전류를 검출하였으며 이를 분석하였다.

• Composites Research
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• v.28 no.3
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• pp.124-129
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• 2015

CNT and GNP have several excellent mechanical properties including, high strength, Young's modulus, thermal conductivity, corrosion resistance, electronic shielding and so on. In this study, CF/CNT, GNP/epoxy composites were manufactured by varying the CNT weight ratio at 2wt% and 3wt%, GNP weight ratio at 0.5wt% and 1 wt%. The composites were manufactured by mechanical method (3-roll-mill). Tensile, impact and wear tests were performed according to ASTM standards D638, D256 and D3181 respectively. The results showed that, CF/GNP0.5 wt%/epoxy composites gave good mechanical property in all composites, e.g., tensile strength, impact and were resistance.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.306-306
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• 2011

Three dimensional(3D) topological insulators(TIs) of Bi binary alloys are characterized by a bulk energy gap with strong spin-orbit coupling and metallic surface states protected by time-reversal symmetry. It was reported that film forms of such materials were advantageous over bulk forms due to less defect density and better crystallinity. So far, the films have been prepared on several substrates including semiconductors and graphene. But, there were no studies on metal substrates. For electronic transport experiments and device applications, it is necessary to know epitaxial relation between TIs and metal electrodes. In this study, Atomically flat films of Bi2Se3 were grown on a Au(111) metal substrate by in-situ molecular beam epitaxy. Using home-built scanning tunneling microscope, we observed hexagonal atomic structures which corresponded to the outmost selenium atomic layer of Bi2Se3. Triangular-shaped defects known as Selenium vacancy were also found.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2018.11a
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• pp.379-379
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• 2018

MXenes are a new family of 2D transition metal carbide nanosheets analogous to graphene (Lv et al., 2017; Sun et al., 2018). Due to the easy availability, hydrophilic behavior, and tunable chemistry of MXenes, their use in applications for environmental pollution remediation such as heavy metal adsorption has recently been explored (Li et al., 2017). In this study, three-dimensional (3D) MXene ($Ti_3C_2T_x$) films with high adsorption capacity, good mechanical strength, and high selectivity for specific radionuclide from aquose solution were successfully fabricated by a polymeric precursor method using vacuum-assisted filtration. The highest removal efficiency on the films was 99.54%, 95.61%, and 82.79% for $Sr^{2+}$, $Co^{2+}$, and $Cs^+$, respectively, using a film dosage of 0.06 g/ L in the initial radionuclide solution (each radionuclide concentration = 1 mg/L and pH = 7.0). Especially, the adsorption process reached an equilibrium within 30 min. The expanded interlayer spacing of $Ti_3C_2T_x$ sheets in MXene films showed excellent radionuclide selectivity ($Cs^+$ and/or $Sr^{2+}/Co^{2+}$) (Simon, 2017). Besides, the MXene films was not only able to be easily retrieved from an aqueous solution by filtration after decontamination processes, but also to selectively separate desired target radionuclides in the solutions. Therefore, the newly developed MXene ($Ti_3C_2T_x$) films has a great potential for radionuclide removal from aqueous solution.

• Structural Engineering and Mechanics
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• v.76 no.5
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• pp.561-578
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• 2020

The present work addresses the surface integrity and chip morphology in finish hard turning of AISI D3 steel under nanofluid assisted minimum quantity lubrication (NFMQL) condition. The surface integrity aspects include microhardness, residual stress, white layer formation, machined surface morphology, and surface roughness. This experimental investigation aims to explore the feasibility of low-cost multilayer (TiCN/Al2O3/TiN) coated carbide tool in hard machining applications and to assess the propitious role of minimum quantity lubrication using graphene nanoparticles enriched eco-friendly radiator coolant based nano-cutting fluid for machinability improvement of hardened steel. Combined approach of central composite design (CCD) - analysis of variance (ANOVA), desirability function analysis, and response surface methodology (RSM) have been subsequently employed for experimental investigation, predictive modelling and optimization of surface roughness. With a motivational philosophy of "Go Green-Think Green-Act Green", the work also deals with economic analysis, and sustainability assessment under environmental-friendly NFMQL condition. Results showed that machining with nanofluid-MQL provided an effective cooling-lubrication strategy, safer and cleaner production, environmental friendliness and assisted to improve sustainability.

• Steel and Composite Structures
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• v.43 no.5
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• pp.639-660
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• 2022

The bending and buckling behaviours of FG-GRNC laminated sandwich plates are investigated by using novel five-variables quasi 3D higher order shear deformation plate theory by considering the modified continuum nonlocal strain gradient theory. To calculate the effective Young's modulus of the GRNC sandwich plate along the thickness direction, and Poisson's ratio and mass density, the modified Halpin-Tsai model and the rule of the mixture are employed. Based on a new field of displacement, governing equilibrium equations of the GRNC sandwich plate are solved using a developed approach of Galerkin method. A detailed parametric analysis is carried out to highlight the influences of length scale and material scale parameters, GPLs distribution pattern, the weight fraction of GPLs, geometry and size of GPLs, the geometry of the sandwich plate and the total number of layers on the stresses, deformation and critical buckling loads. Some details are studied exclusively for the first time, such as stresses and the nonlocality effect.

• Journal of the Korean Physical Society
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• v.73 no.10
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• pp.1437-1443
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• 2018

In this work, $SnO_2$ modified with reduced graphene oxide (rGO) and carbon nanotubes (CNTs) separately and combined sensitized by using the co-precipitation method and their sensing behavior toward ethanol vapor at room temperature were investigated. An interdigitated electrode (IDE) gold substrate is very expensive compared to a fluorine doped tin oxide (FTO) substrate; hence, we used the latter to reduce the fabrication cost. The structure and the morphology of the studied materials were characterized by using differential thermal analyses (DTA) and thermogravimetric analysis (TGA), transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, Brunauer-Emmett-Teller surface area and Barrett-Joyner-Halenda (BJH) pore size measurements. The studied composites were subjected to ethanol in its gas phase at concentrations from 10 to 200 ppm. The present composites showed high-performance sensitivity for many reasons: the incorporation of $SnO_2$ and CNTs which prevents the agglomeration of rGO sheets, the formation of a 3D mesopourus structure and an increase in the surface area. The decoration with rGO and CNTs led to more active sites, such as vacancies, which increased the adsorption of ethanol gas. In addition, the mesopore structure and the nano size of the $SnO_2$ particles allowed an efficient diffusion of gases to the active sites. Based on these results, the present composites should be considered as efficient and low-cost sensors for alcohol.

• Journal of the Korean Ceramic Society
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• v.53 no.3
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• pp.376-380
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• 2016

A composite electrode made of iron oxide nanoparticles/multi-wall carbon nanotube (iNPs/M) delivers high specific capacity and cycle durability. At a rate of $200mAg^{-1}$, the electrode shows a high discharge capacity of ${\sim}664mAhg^{-1}$ after 100 cycles, which is ~ 70% of the theoretical capacity of $Fe_3O_4$. Carbon black, carbon nanotube, and graphene as anode materials have been explored to improve the electrical conductivity and cycle stability in Li ion batteries. Herein, iron oxide nanoparticles on acid treated MWCNTs as a conductive platform are combined to enhance the drawbacks of $Fe_3O_4$ such as low electrical conductivity and volume expansion during the alloying/dealloying process. Enhanced performance was achieved due to a synergistic effect between electrically 3D networks of conductive MWCNTs and the high Li ion storage ability of $Fe_3O_4$ nanoparticles (iNPs).

• Carbon letters
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• v.8 no.2
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• pp.95-100
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• 2007

A series of activated carbons (ACs) were derived from sugarcane bagasse under two activation schemes: steam-pyrolysis at $600-800^{\circ}C$ and chemical activation with $H_3PO_4$ at $500^{\circ}C$. Some carbons were treated at 400, $600^{\circ}C$, or for 1-3 h, and/or in flowing air during pyrolysis of acid-impregnated mass. XRD profiles displayed two broad diffuse bands centered around $2{\theta}=23$ and $43^{\circ}$, currently associated with diffraction from the 002 and 100/101 set of planes in graphite, respectively. These correspond to the interlayer spacing, Lc, and microcrystallite lateral dimensions, La, of the turbostratic (fully disordered) graphene layers. Steam pyrolysis-activated carbons exhibit only the two mentioned broad bands with enhancement in number of layers, with temperature, and small decrease in microcrystallite diameter, La. XRD patterns of $H_3PO_4$-ACs display more developed and separated peaks in the early region with maxima at $2{\theta}=23$, 26 and $29^{\circ}$, possibly ascribed to fragmented microcrystallites (or partially organized structures). Diffraction within the $2{\theta}=43^{\circ}$ is still broad although depressed and diffuse, suggesting that the intragraphitic layers are less developed. Varying the conditions of chemical activation inflicts insignificant structural alterations. Circulating air during pyrolysis leads to enhancement of the basic graphitic structure with destruction and degradation in the lateral dimensions.