• Journal of the Korean Chemical Society
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• v.54 no.4
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• pp.429-436
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• 2010

A series of some biologically active halogenopurines were synthesized from commercially available guanine (1). The reaction of guanine with acetic anhydride yielded 2,9-diacetylguanine (2-1) by acetylation reaction. Further treatment of 2-1 with $POCl_3$ by PEG-2000 phase transfer catalysis furnished the important compound 3a, then 2-amino-6-halogenopurines (3b-d) were obtained through chlorine-exchange halogenations between KX and 3a by TPPB phase transfer catalyst. Further, 2-halogenopurines (2-2a-d, 4-2a-d, 5a-d) were efficiently prepared from 2-amino-6-substituted purines (1, 3a, 4-1) via a diazotization catalyzed by their corresponding CuX, and some new compounds 2-2a, 2-2c, 2-2d, 4-2c, 4-2d, 5b, 5c and 5d have been discovered. The structures of synthesized compounds were mainly established on the basis of their elemental analysis, $^1H$ NMR, as well as their mass spectral data. All the title compounds were screened for their antifungal activities, and some of the compounds showed promising activity.

• Journal of Digital Convergence
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• v.17 no.4
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• pp.255-260
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• 2019

This study is about an efficient synthesis of $360^{\circ}$ video and 3D graphics. First, the video image filmed by a binocular integral type $360^{\circ}$ camera was stitched, and location values of the camera and objects were extracted. And the data of extracted location values were moved to the 3D program to create 3D objects, and the methods for natural compositing was researched. As a result, as the method for natural compositing of $360^{\circ}$ video image and 3D graphics, rendering factors and rendering method were derived. First, as for rendering factors, there were 3D objects' location and quality of material, lighting and shadow. Second, as for rendering method, actual video based rendering method's necessity was found. Providing the method for natural compositing of $360^{\circ}$ video image and 3D graphics through this study process and results is expected to be helpful for research and production of $360^{\circ}$ video image and VR video contents.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.38C no.10
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• pp.920-927
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• 2013

Chroma key technique which composes images by separating an object from its background in specific color has restrictions on color and space. Especially, unlike general chroma key technique, image composition for stereo 3D display requires natural image composition method in 3D space. The thesis attempted to compose images in 3D space using depth keying method which uses high resolution depth information. High resolution depth map was obtained through camera calibration between the DSLR and Kinect sensor. 3D mesh model was created by the high resolution depth information and mapped with RGB color value. Object was converted into point cloud type in 3D space after separating it from its background according to depth information. The image in which 3D virtual background and object are composed obtained and played stereo 3D images using a virtual camera.

• Cartoon and Animation Studies
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• s.40
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• pp.157-176
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• 2015

This research describes render pass synthetic techniques required to use for the effectiveness of them in 3D animation synthetic technology. As the render pass is divided by property and synthesized after rendering, elaborate, rapid synthesis can be achieved. In particular, occlusion pass creates a screen as if it had a soft, light shading, expressing a sense of depth and boundary softness. It is converted into 2D image through a process of pass rendering of animation projects created in 3D space, then completed in synthetic software. Namely, 3D animation realizes the completeness of work originally planned through compositing, a synthetic process in the last half. To complete in-depth image, a scene manufactured in 3D software can be sent as a synthetic program by rendering the scene by layer and property. As recently the occlusion pass can express depth notwithstanding conducting GI rendering of 3D graphic outputs, it is an important synthetic map not omitted in the post-production process. Nonetheless, for the importance of it, currently the occlusion pass leaves much to be desired for research support and books summarizing and analyzing the characteristics of properties, and the principles and usages of them. Hence, this research was aimed to summarize the principles and usages of occlusion map, and analyze differences in the results of synthesis. Furthermore, it also summarized a process designating renderers and the map utilizing the properties, and synthetic software usages. For the future, it is hoped that effective and diverse latter expression techniques will be studied beyond the limitation of graphic expression based on trends diversifying technique development.

• Journal of the Korea Society of Computer and Information
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• v.14 no.6
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• pp.117-123
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• 2009

In this paper, An algorithm which converts 2D video frames into 3D video frames of parallel looking stereo camea is proposed. The proposed algorithm finds the disparity information between two consecutive video frames and generates 3D video frames from the obtained disparity maps. The disparity information is obtained from the modified iterative convergence algorithm. The method of generating 3D video frames from the disparity information is also proposed. The proposed algorithm uses coherence method which overcomes the video pattern based algorithms.

• Proceedings of the Korean Society of Applied Pharmacology
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• 1993.04a
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• pp.111-111
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• 1993

Anthracycline의 합성에 있어서 aglycone 뿐만 아니고 sugar도 대단히 중요한 역할을 한다. Anthracycline에 이용되는 sugar인 daunosamine의 전합성의 확립을 통하여 daunosamine의 anlogue을 합성할 목적으로 daunosamine의 전합성을 검토하고 있다. Methyl D-mannopyranoside을 원료로 하여 0-methylation, PhCH(OMe)$_2$ 에 의한 OH의 보호, n-BuLi을 이용한 위치선택적 deblocking, oxime생성, 이어서 Vitride를 이용한 환원으로 daunosamine 합성에 있어서 중요한 중간체인 methyl-3-amino-4,6-benzylidene-2,3-dideoxy-$\alpha$-D-hexopyranoside을 합성하였다.

• Journal of Animal Science and Technology
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• v.48 no.3
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• pp.345-352
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• 2006

Korean native cattle (Hanwoo) have a good capacity to produce heavily marbled meat of high value. The intramuscular fat in Hanwoo is known to be deposit from 12 months of age by degree of slightly visible and significantly developed in 28 months of age. Lipogenesis gene expression profiling in longissimus dorsi at early and late fattening stage will be helpful to understand the mechanism of intramuscular fat deposition in skeletal muscle. Therefore, we analysed the gene expression patterns of six genes related lipid metabolism (FABP4, GLUT4, LPL, ACC, ACL and SCD) between early and late fattening stage. The mRNA expression of FABP4 at late fattening stage (27 months old) was higher about 3.0 fold than at early fattening stage (12 months old) in each three individuals of Hanwoo. However, GLUT4 mRNA expression was not different at late fattening stage compared with at early fattening stage. On the other hand, The expression patterns of LPL, ACC, ACL and SCD genes related lipid metabolism were significantly over-expressed about 3.5 fold, 2.7 fold, 3.7 fold and 7.5 fold at late fattening stage, respectively. Thus, these results suggested that lipogenesis in skeletal muscle at late fattening stage is due to increasing uptake of fatty acid by FABP4 and lipogenesis gene expression such as LPL, ACC, ACL and SCD.

• Journal of the Institute of Electronics Engineers of Korea SP
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• v.45 no.4
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• pp.22-31
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• 2008

In this paper, we propose a new approach for efficient multiview stereo matching and virtual view generation, which are key technologies for 3DTV. We propose semi N-view & N-depth framework to estimate disparity maps efficiently and correctly. This framework reduces the redundancy on disparity estimation by using the information of neighboring views. The proposed method provides a user 2D/3D freeview video, and the user can select 2D/3D modes of freeview video. Experimental results show that the proposed method yields the accurate disparity maps and the synthesized novel view is satisfactory enough to provide user seamless freeview videos.

• Proceedings of the Korean Society of Computer Information Conference
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• 2012.07a
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• pp.105-106
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• 2012

일반적으로 CG 합성이라 하면 '자연스러운' 것을 잘된 CG영상이라고 한다. 이 때 촬영된 영상이 정지화면 일 수 만은 없다. 카메라가 움직이는 영상에서는 CG합성도 실사카메라 무빙에 맞게 정확한 정합이 되어야 자연스러운 영상이 된다. 이를 위해 합성단계에서 작업할 때 3D 카메라 트래킹 기술이 필요하다. 카메라트래킹은 촬영된 실사영상만으로 카메라의 3차원 이동정보와 광학적 파라미터 등 촬영시의 3차원 공간을 복원하는 과정을 포함하고 있다. 이 과정에서 카메라 트래킹에 대한 오류의 발생으로 실사와 CG의 합성에 대한 생산성에 많은 문제점을 가지고 있다. 본 논문에서는 이러한 문제를 해결하기 위하여 소프트웨어에서 트래킹데이터를 보정하는 방법을 제안한다.

• Journal of the Korean Chemical Society
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• v.55 no.4
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• pp.638-643
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• 2011

The synthesis of biologically active 1H-1,4-diazepines 4a-d and 3H-1,5-benzodiazepines 5a-d in good yields, from the heterocyclization reaction of 2-(4-methylthio benzenesulfonyl)-1,3-dimethyl/1-methyl-3-phenyl/1,3-diphenyl/1-methyl-3-ethoxy propane-1,3-dione 3a-d with ethylenediamine (EDA) and o-phenylenediamine (o-PDA), respectively, in the presence of silica sulfuric acid (SSA) is described. The novel ${\beta}$-diketones/${\beta}$-ketoesters 3a-d were synthesized by the condensation reaction of 4-methylthiobenzenesulfonyl chloride 1 with various ${\beta}$-diketones/${\beta}$-ketoesters 2a-d. All structures of the newly synthesized compounds were elucidated by elemental analysis and spectral studies. The compounds 4a-d and 5a-d have been screened for antimicrobial, antifungal and anthelmintic activity.