• Tribology and Lubricants
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• v.16 no.3
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• pp.194-200
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• 2000

In order to evaluate the effect of Nb on wear properties of high speed steel(HSS) by powder metallurgy, niobium-alloyed HSS have been prepared by adding 0%, 1%, 3% and 5%Nb to HSS of 6%W-5%Mo-4 %Cr-5%V-5%Co. Sliding wear tests were conducted at various sliding speed conditions under the constant pressure using a pin-on-disc type machine. The results of this study show that the wear resistance of HSS by powder metallurgy was increased by the addition of Nb within the range of sliding speed used in this experimental study. However, the amount of Nb did not improve the wear resistance. It may be due to the thermal stability of carbide and high temperature properties of the matrix containing Nb comparing to that without Nb.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.24 no.3
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• pp.281-287
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• 2012

The internal oxide scale of twelve superheater and reheater tubes were tested which were serviced for 30,000~120,000 hours in thermal power plants. The oxide scale was formed in three layers. The Cr-rich area was observed beneath the original metal surface. The hematite ($Fe_2O_3$) phase was formed on the outer surface. The intermediate layer was magnetite ($Fe_3O_4$). The thickness of Cr-rich layer was about half of the total scale. All layers grew during the operation hour of the plant. The thickness of thickest scale was 0.2mm in superheater tubes. This can increase the tube metal temperature about $7^{\circ}C$ more than initial state. $7^{\circ}C$ tube metal temperature can reduce tube life about 30%, but the boiler tube's design margin is big enough therefore it has been analyzed that it would not effect on the life span.

• Journal of Welding and Joining
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• v.15 no.1
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• pp.101-108
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• 1997

In repaired weldment of ASTM A-470 class 8 high pressure stream turbine rotor steel, creep rupture life was studied in relation with carbide morphology. Carbides were identified using carbide extraction replica method. A retired rotor has molybdenum rich carbide $M_2C$, lndacochea vanadium rich carbide $M_4C_3$, and chromium rich carbides $M_{23}C_6$and $M_7C_3$. Weldments ruptured at ICHAZ showed that some of carbides have been transformed into spherical types of coarsened carbides at ruptured area. Those carbides were revealed as molybdenum rich $M_6C$ carbide and they provided cavitation sites due to molybdenum depletion around $(M_6C)$ carbide. However coarsened $M_6C$ and $M_{23}C_6$ carbides were observed at ruptured area in case of ruptured at CGHAZ.

• Applied Microscopy
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• v.45 no.3
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• pp.177-182
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• 2015

The boiler tubes of X20CrMoV12.1 used in fossil-fired power plants were obtained and analyzed for the effect of water treatment on the steam corrosion-induced oxide scale in an effort to better understand the oxide formation mechanism, as well as pertinent method of maintenance and lifetime extension. The specimens were analyzed using various microscopy and microanalysis techniques, with focuses on the effect of water treatment on the characters of scale. X-ray diffraction analysis showed that the scales of specimens were composed of hematite ($Fe_2O_3$), magnetite ($Fe_3O_4$), and chromite ($FeCr_2O_4$). Electron backscatter diffraction analysis showed that the oxides were present in the following order on the matrix: outer $Fe_2O_3$, intermediate $Fe_3O_4$, and inner $FeCr_2O_4$. After all volatile treatment or oxygenated treatment, a dense protective $Fe_2O_3$ layer was formed on the $Fe_3O_4$ layer of the specimen, retarding further progression of corrosion.

• Corrosion Science and Technology
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• v.15 no.6
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• pp.281-289
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• 2016

The effect of nitrogen on the electrochemical corrosion and nanomechanical behaviors of martensitic stainless steel was examined using potentiodynamic polarization and nanoindentation test methods. The results indicate that partial replacement of carbon with nitrogen effectively improved the passivation and pitting corrosion resistance of conventional high-carbon and high- chromium martensitic steels. Post-test observation of the samples after a potentiodynamic test revealed a severe pitting attacks in conventional martensitic steel compared with nitrogen- containing martensitic stainless steel. This was shown to be due to (i) microstructural refinement results in retaining a high-chromium content in the matrix, and (ii) the presence of reversed austenite formed during the tempering process. Since nitrogen addition also resulted in the formation of a $Cr_2N$ phase as a process of secondary hardening, the hardness of the nitrogen- containing steel is slightly higher than the conventional martensitic stainless steel under tempered conditions, even though the carbon content is lowered. The added nitrogen also improved the wear resistance of the steel as the critical load (Lc2) is less, along with a lower scratch friction coefficient (SFC) when compared to conventional martensitic stainless steel such as AISI 440C.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1999.06a
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• pp.14-19
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• 1999

In order to evaluate the effect of Nb on wear properties of high speed steel by powder metallurgy(PM-HSS), niobium-alloyed PM-HSS have been prepared by adding 0%, 1%, 3% and 5%Nb to PM-HSS of 6%W-5%Mo-4%Cr-5%V-5%Co presented in the previous paper. Sliding wear test have been conducted in various sliding speed conditions under the constant pressure using a pin-on-disc type machine. The results of this study shows that the wear resistance of PM-HSS has been increased by the addition of Nb in the range of experimental sliding speed. However, the amount of Nb shows to be unimportant parameter for the improvement of the wear resistance. It may be due to the thermal stability of carbide and high temperature properties of matrix by adding Nb comparing to the case of no addition.

• Journal of the Korean Society for Heat Treatment
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• v.9 no.4
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• pp.229-233
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• 1996

This work has been carried out to reduce the softening of heat affected zone on laser surface alloying. Iron based rapid solidification material with $Cr_{5-10}$, $V_{1-3}$, $Mo_{3-7}$, $W_{2-5}$, $B_{7-8}$, $C_{2-3}$, $Si_{0.5-1}at%$ was alloyed on the surface of SM45C steel. The excellent softening resistance in alloyed and heat affected zone showed, which could be attributed to the formation of stable high temperature precipitates.

• Journal of Ocean Engineering and Technology
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• v.6 no.1
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• pp.78-86
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• 1992

The creep behaviors of 1%Cr-Mo-V and 12%Cr steam turbine rotor steels under static or cyclic load were examined at 600 and $700^{\circ}C$. The relationship between these two kinds of phenomena was studied and the experimental results were summarized as follows: 1) It is confirmed that the cyclic creep strain dependent on time is more available for creep, behavior analysis according to frequency change than that dependent on number of cycles, and the static creep, the special case of cyclic creep with stress ratio of 1 can be also more effectively analyzed by time-dependence. 2) The steady cyclic creep rate vs. the steady static creep rate, increases according to the increase of stress ratio, and this phenomena may occur on occasion of the decrease of the internal stress. 3) The initial strain affects on all the creep properties of the transient region, the steady state region and the rupture time in cyclic creep as well as static creep, and the quantitative relationships among them exist.

• Corrosion Science and Technology
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• v.20 no.6
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• pp.451-465
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• 2021

In this investigation, electrochemical characteristics and damage behavior of 316L stainless steel polymer electrolyte membrane fuel cell(PEMFC) were analyzed by potentiodynamic and potentiostatic tests in cathode operating condition of PEMFC. As the result of potentiodynamic polarization test, range of passive region was larger than range of active region. In the result of potentiostatic test, damage depth and width, pit volume, and surface roughness were increased 1.57, 1.27, 2.48, and 1.34 times, respectively, at 1.2 V compared to 0.6 V at 24 hours. Also, as a result of linear regression analysis of damage depth and width graph, trend lines of damage depth and width according to applied potentials were 16.6 and 14.3 times larger, respectively. This demonstrated that applied potential had a greater effect on pitting damage depth of 316L stainless steel. The damage tendency values were 0.329 at 6 hours and 0.633 at 24 hours with applied potentials, representing rapid growth in depth direction according to the test times and applied potentials. Scanning electron microscopy images revealed that surface of specimen exhibited clear pitting damage with test times and applied potentials, which was thought to be because a stable oxide film was formed by Cr and Mo.

• Journal of Welding and Joining
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• v.21 no.1
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• pp.99-106
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• 2003

This research was aimed to evaluate the material degradation with various microstructures of X20CrMoV121 steel weldment by Advanced Small Punch(ASP) test. Due to the regional limitation on constitutive structures, the minimized loading ball(${\varphi}1.5mm$) and bore diameter of lower die(${\varphi}3mm$) were designed for the ASP test. The micro-hardness test was also performed to assess the mechanical properties with artificial aging heat treatment. Material degradation was estimated by ductile-brittle transition temperature(DBTT). The results obtained from the ASP test were compared with those from conventional small punch(CSP) test and CVN impact test for several weldment microstructures. It was found that the ASP test clearly showed the microstructural dependance on the material degradation in the weldment.