• Elastomers and Composites
• /
• v.40 no.3
• /
• pp.174-180
• /
• 2005

Sonochemical synthesis of fullerene oxides $[C_{70}O_n](n=1{\sim}2)$ by fullerene$[C_{70}]$ and metal hexacarbonyl complexes $M(CO)_6$(M=Cr, Mo, W) took place under air atmosphere. The reactivity of fullerene$[C_{70}]$ and several metal hexacarbonyl complexes $M(CO)_6$(M=Cr, Mo, W) under same ultrasonic condition increased in the order of $Mo(CO)_6$ > $W(CO)_6$ > $Cr(CO)_6$. The MALDI-TOF-MS, UV-visible spectra, and HPLC analysis confirmed that the products of sonochemical reaction were $[C_{70}O_n](n=1{\sim}2)$.

• Journal of the Korean institute of surface engineering
• /
• v.51 no.6
• /
• pp.354-359
• /
• 2018

NaCl-induced hot corrosion behavior of ASTM T22 (Fe-2.25Cr-1Mo), T91 (Fe-9Cr-1Mo), T92 (Fe-9Cr-1.8W-0.5Mo), 347HFG (Fe-18-Cr-11Ni), and 310H (Fe-25Cr-19Ni) steels was studied after spraying NaCl on the surface. During corrosion at $600-800^{\circ}C$ for 50-100 h, thick, non-adherent, fragile, somewhat porous oxide scales formed. All the alloys corroded fast with large weight gains owing to fast scaling and destruction of protective oxide scales. Corrosion rates increased progressively as the corrosion temperature and time increased. Corrosion resistance increased in the order of T22, T91, T92, 347HFG, and 310H, suggesting that the alloying elements of Cr, Ni, and W beneficially improved the corrosion resistance of steels. Basically, Fe oxidized to $Fe_2O_3$, and Cr oxidized to $Cr_2O_3$, some of which further reacted with FeO to form $FeCr_2O_4$ or with NiO to form $NiCr_2O_4$.

• Journal of Magnetics
• /
• v.17 no.3
• /
• pp.206-209
• /
• 2012

Peak interval for reversible permeability is presented for nondestructively evaluating the remanent life of 1Cr-0.5Mo steel. The method to measure the peak interval of reversible permeability is based on the value of reversible permeability is the same as the differential value of the hysteresis loop. The measurement principle is based on the first harmonics voltage induced in a sensing coil using a lock-in amplifier tuned to a frequency of the exciting voltage. Results obtained for the peak interval of reversible permeability and Rockwell hardness on the aged samples decrease as aging time and the Larson-Miller parameter increase. We could estimate the remanent life of 1Cr-0.5Mo steel by using the relationship between the peak interval of reversible permeability and the Larson-Miller parameter, nondestructively.

• Proceedings of the Korean Nuclear Society Conference
• /
• 2002.10a
• /
• pp.282.1-282
• /
• 2002

• Corrosion Science and Technology
• /
• v.19 no.1
• /
• pp.43-50
• /
• 2020

In this study, the effects of KCl(s) and K₂SO₄(s) on the oxidation characteristics of 2.25Cr-1Mo steel were investigated for 500 h in 10O₂ + 10CO₂ (vol%) gas environmen at 650 ℃. Oxidation kinetics were characterized by weight gain, oxide layer thickness, and fitted models for the experiment data were proposed. The fitted models presented considerable agreement with the experimental data. The oxide layer was analyzed using the scanning electron microscope, optical microscope, and energy dispersive X-ray spectroscopy. The oxidation kinetics of 2.25Cr-1Mo steel with KCl and K₂SO₄ coatings showed significantly different oxidation kinetics. KCl accelerated the oxidation rate very much and had linear oxidation behavior. In contrast, K₂SO₄ had no significant effect, which had parabolic kinetics. The oxide layer was commonly composed of Fe₂O₃, Fe₃O₄, and FeCr₂O₄ spinel. KCl strongly accelerated the oxidation rates of 2.25Cr-1Mo steel in the high-temperature oxidation environment. Conversely, K₂SO₄ had little effect on the oxidation rates.

• Journal of Welding and Joining
• /
• v.10 no.3
• /
• pp.40-53
• /
• 1992

고온고압장치(High Temperature and Pressure Vessels)의 적용을 위한 기초연구로서 9Cr-1Mo강 용접부의 연화특성에 대하여 검토하였다. 9Cr-1Mo 강재에 Bead-on-Plate용접을 실시한 후, 용접부의 기계적 성질과 그 현미경조직관찰 및 미세경도를 측정한 결과, As-Welded 및 용접 후열처리(PWHT)등의 조건에 관계없이 용접열향부의 변태역과 템퍼링역의 경계에서 모재의 경 도보다 낮은 경도값(연화역)을 나타내었으며 이러한 원인은 결정립계(Grain boundary)에 석출 되는 탄화물의 형성에 의한 뜨임 현상임이 판명되었다.

• Bulletin of the Korean Chemical Society
• /
• v.14 no.2
• /
• pp.266-271
• /
• 1993

The reaction of $(CO_5$)M=C(OMe)Tol (M=Cr, Mo, W and $Tol=p-C_6H_4Me)$ and $BBr_3$ followed by treatment with tetramethylethylenediamine (TMEDA) yields a mixture of two diastereomers, trans, $cis-Br(CO)_2(tmeda)M{\equiv}$CTol [M=Cr(1a), Mo(2a), W(3a)] and cis, $trans-Br(CO)_2(tmeda)M{\equiv}$CTol [M=Cr(1b), Mo(2b), W(3b)], respectively. These compounds have been isolated as crystalline solids and characterized by spectroscopic (infrared, mass, $^1H$ and $^{13}C-NMR)$ data. The trans, cis-Br(CO)2(tmeda)Cr${\equiv}$CTol (1a), has been examine via a single crystal X-ray diffraction study : $BrCrO_2N_2C_{16}H_{23}$, Mr=407.27, triclinic, $P{\bar{1}},\;a=12.792(2),\;b=13.400(5),\;c= 11.645(4)\;{\AA},\;{\alpha}=101.26(2)^{\circ},\;{\beta}=103.04(2)^{\circ},\;{\gamma}=91.88(2)^{\circ},\;{\nu}=1907(1){\AA}^3,\;Z=2,\;{\rho}(calcd)=1.418\;gcm^{-3},\;{\lambda}(MoK{\alpha})=0.71069\;{\AA},\;{\mu}=26.25 cm^{-1},\;F(000)=831.97,\;T=295K,\;R=0.0977$ for 1332 significant reflections $[F_0>5{\sigma}(F_0)]$. There are two essentially equivalent molecules in the crystallographic asymmetric unit. Each molecule is octahedral with the bromide ligand trans to the alkylidyne carbon, the two cis-carbonyl ligands, and the bidentate TMEDA ligand.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.37 no.3
• /
• pp.353-358
• /
• 2013

The ultrasonic characteristics of 2.25Cr-1Mo steel were investigated in relation to the isothermal heat treatment temperature and time. Charpy impact tests and hardness tests were conducted on individual specimens with three different heat treatment conditions. A pulse-echo method with longitudinal waves was used to measure the attenuation and velocity of ultrasonic waves. The FATT (fracture appearance transition temperature) increased with an increase in the isothermal heat treatment time, which implies that the toughness decreased. As the isothermal heat treatment time and temperature increased, the longitudinal wave velocity and ultrasonic attenuation coefficient were raised.

• Journal of Powder Materials
• /
• v.12 no.1
• /
• pp.43-50
• /
• 2005

Mechanical alloying using high-energy ball mill and subsequent spark plasma sintering (SPS) process was applied to Al-Fe-Cr and Al-Fe-Mo powder mixture to investigate effects of Cr and Mo addition on thermal stability of Al-Fe, and thereby to enhance its thermal stability up to $500^{\circC}$. Various analytical techniques including micro-Vickers hardness test, SEM, TEM, X-ray diffractometry and corrosion test were carried out. It was found that addition of Cr and Mo to Al-Fe system played a role of grain growth inhibitor of matrix Al and some precipitates such as $Al_3Fe$ during SPS and subsequent heat treatment. The inhibition of grain growth resulted in increased Vickers hardness and thermal stability up to $500^{\circC}$ comparing to those of Al-Fe alloy system.

• Transactions of the Korean Society of Machine Tool Engineers
• /
• v.16 no.6
• /
• pp.29-36
• /
• 2007

The present study examined the mechanical properties of the friction welding of Ni-Cr-Mo to SM45C. Friction welding was conducted at welding conditions of 2,000 rpm, friction pressure of 100MPa, friction time of 0.8, 1.0, 1.2, 1.4, 1.6, 1.8, 2.0 seconds, upset pressure of 150MPa, and upset time of 3.0 seconds. When the friction time was 1.6 seconds, the maximum tensile strength of the friction weld happened to be 1,020MPa, which is 120% of the base material's tensile strength(850MPa). At the same condition, the maximum shear strength was 438MPa, which is equivalent to 103% of the base material's shear strength(425MPa). At the same condition, the maximum vickers hardness was Hv490 at Ni-Cr-Mo nearby weld interface, which is higher Hv40 than condition of the friction time 0.8 seconds, and the maximum vickers hardness was Hv305 from weld interface of SM45C, which is higher Hv12 than condition of the friction time 0.8 seconds. The results of microstructure analysis show that the structures of two base materials have fined and rearranged along a column due to heating and axial force during friction, which has affected in raising hardness and tensile strength.