• Title/Summary/Keyword: 355nm

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Temporal Evolution and Ablation Mechanism of Laser-induced Graphite Plume at 355 nm

  • 최영구;임훙선;정광우
    • Bulletin of the Korean Chemical Society
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    • v.20 no.12
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    • pp.1501-1505
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    • 1999
  • Expansion dynamics of C$^{+}$ ions ejected from 355-nm laser ablation of graphite target in vacuum has been investigated by pulsed-field time-of-flight (TOF) mass spectrometry. A strong nonlinear dependence of the amount of desorbed C$^{+}$ ions on laser fluence is interpreted by the mechanism that C$^{+}$ ions are produced directly from the graphite via conversion of the multiphoton energy into thermal energy. The temporal evolution of C$^{+}$ ions was measured by varying the delay time of the ion repelling pulse with respect to the laser irradiation, which provides significant information on the ablated plume characterization. The TOF distributions of ablated ions showed a bimodal shape and could be fitted by shifted Maxwell-Boltzmann distributions. The velocity of the fast component increases with the delay time, whereas the slow component (< 500 m/s) exhibits a constant velocity. Also studied were the effects of the laser fluence on the energetics of C$^{+}$ ions.

Sterilization Effect of Microbial Strains by using Non-ionizing Radiation (비전리방사선을 이용한 미생물 균주 멸균효과)

  • Jeong, Kyeonghwan;Seo, Jeongmin
    • Journal of the Korean Society of Radiology
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    • v.14 no.6
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    • pp.833-839
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    • 2020
  • Globally, infection prevention and social awareness have been greatly changed by the severe acute respiratory syndrome coronavirus, and as a result, the infection control guidelines and procedures for patients with high exposure to hospital-acquired infection are further strengthened and management and monitoring are more thorough. In order to prevent infection, sterilization should be carried out with the highest priority, and we will find a sterilization method that is low in cost, easy to install, and easy to operate, to present appropriate sterilization effects. In this study, the UV sterilizer was used to contaminate the caries bacteria with an output of 4 W and irradiation time of 60, 150, and 300 sec, and the laser was irradiated with outputs of 0.8 and 1.5 W at wavelengths of 266 and 355 nm, respectively. Ultraviolet sterilizer showed safety in infection prevention at over 150 sec, and laser showed safety in prevention at 1.5 W, 0.8 W, and 266 nm. As a result, the higher the output and the wavelength closer to 253.7 nm, the better the sterilization effect.

Classification of Dust/Non-dust Particle from the Asian Dust Plumes and Retrieval of Microphysical Properties using Raman Lidar System (다파장 라만 라이다 시스템을 이용한 황사/비황사입자 구분 및 비황사입자의 미세물리적 특성 연구)

  • Shin, Sungkyun;Shin, Dongho;Lee, Kwonho;Noh, Youngmin
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.6
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    • pp.688-696
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    • 2012
  • The particle depolarization ratios were retrieved from the observation with a multi-wavelength Raman lidar at Gwangju, Korea ($35.11^{\circ}N$, $126.54^{\circ}E$). The measurements were carried out on 24 February and 9 March 2004. Using the particle depolarization ratios, the non-dust aerosol particles were distinguished from the Asian dust plume, and the proportion of the non-dust particle to total dust plume was retrieved. The calculated proportion of the non-dust particle was used for the retrieval of backscatter coefficients at 355, 532, and 1064 nm and extinction coefficients at 355 and 532 nm of non-dust particles in the dust plume. Microphysical parameters of non-dust particles including single-scattering albedo at 532 nm were retrieved using retrieved optical values. The retrieved single-scattering albedo of non-dust particles was 0.92~0.95 below 1 km height and 0.82~0.91 above 1 km height on 24 February 2004 and $0.81{\pm}0.03$ on 9 March 2004.

Hydrolytic Degradation of Synthetic Polytrimethylene Terephthalate and Characterization by MALDI-TOF Mass Spectrometry

  • Yang, Eun-Kyung;Jang, Sung-Woo;Cho, Young-Dal;Choe, Eun-Kyung;Park, Chan-Ryang
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.477-482
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    • 2011
  • The structural analysis of polytrimethylene terephthalate (PTT) and characterization of the hydrolytic degradation products after acid hydrolysis were performed using MALDI-TOF mass spectrometry. Mass spectra of the PTT samples were analyzed using a self-calibration method as well as an internal calibration method with standard materials of known masses. PTT structures constituting the samples were determined from the analyses of the spectra, and their relative compositions were estimated. The MALDI-TOF mass spectra of the acid-hydrolyzed PTT sample showed three main series of oligomer products with different end groups in accordance with the hydrolysis schemes. From the spectra of both $Na^+$ and $K^+$ adducts, it was concluded that the PTT samples have higher affinity for $Na^+$ compared with $K^+$ and therefore show higher ionization efficiency with sodium ions when dithranol is used as a matrix. Two different wavelength laser beams ($\lambda$ = 337 nm and 355 nm) were tested and it was observed that the 355 nm beam was more efficient in obtaining the MALDI spectra of PTT using dithranol as a matrix under our experimental conditions.

A Study on Fabrication of Hydrophobic Modification on the Surface of Copper using 355nm-Pulsed Laser (355nm 펄스 레이저를 이용한 구리 표면의 소수성 개질에 관한 연구)

  • Yun, Dan Hee;Kang, Bo Seok;Park, Jun Han;Gwak, Cheng Yeol;Shin, Bo Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.101-105
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    • 2016
  • Recently, the hydrophobic surface has been attracted because of the excellent opto-physical properties. Various processing methods such as chemical, mechanical, photolithographic and laser processing are competitively introduced for fabrication of hydrophobic surface of polymer, metal and ceramics. In this paper, we fabricated the hydrophobic surface of copper metal by simple method which irradiated 355 nm UV-pulsed laser in order to shape microgrooves and increased surface roughness through oxidation process at room temperature. Finally the contact angle is dramatically increased by maximum $45^{\circ}$, as a result of oxidation which simply created nanostructures on the microstructures without expensive chemical process.

A Study on the Computational Analysis of 355nm UV Laser Multiple-Pulsed Micro Machining Considering the Strain Rate Effect (변형률 속도 효과를 고려한 355nm UV 레이저 다중 펄스 미세가공의 전산해석에 관한 연구)

  • Lee, Jung-Han;Oh, Jae-Yong;Park, Sang-Hu;Nam, Gi-Jung;Ryu, Gwang-Hyun;Shin, Suk-Hun;Shin, Bo-Sung
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.10
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    • pp.29-33
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    • 2010
  • UV laser micromachining of metallic materials has been used in microelectronic and other industries. This paper shows on experimental investigation of micromachining of copper using a 355nm UV laser with 50ns pulse duration. A finite element model with high strain rate effect is especially suggested to investigate the phenomena which are only dominated by mechanically pressure impact in disregard of thermally heat transfer. In order to consider the strain rate effect, Cowper-Symonds model was used. To analyze the dynamic deformation during a very short processing time, which is nearly about several tens nanoseconds, a commercial Finite Element Analysis (FEA) code, LS-DYNA 3D, was employed for the computational simulation of the UV laser micro machining behavior for thin copper material. From these computational results, depth of the dent (from one to six pulsed) were observed and compared with previous experimental results. This will help us to understand interaction between UV laser beam and material.

Absorption Spectroscopic Studies of Prodigiosin Extracted from Serratia Marcescens Strain (Serratia marcescens 균주로부터 추출한 Prodigiosin의 흡수분광학적 연구)

  • Park, Hee-Aurk
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.355-361
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    • 2019
  • The red pigment extracted from Serratia marcescens 2354 (ATCC 25419) was prodigiosin (PG), which was dissolved in methanol and measured for ultraviolet and visible light absorption spectra. It was the typical absorption spectrum of PG in an acid solution with ${\lambda}_{max}=537nm$. When the concentration of PG was increased from $1.0{\times}10-5M$ to $9.0{\times}10-5M$ in the methanol solution, the absorption intensity at 537 nm was increased, the absorption intensity at 467 nm was decreased, and the isosbestic point at 500 nm was observed. This phenomenon can be regarded as a result of reversible acid-base equilibrium reaction considering 537 nm and 467 nm of PG absorption band in acid and base solution respectively and isosbestic point of 500 nm. On the other hand, when the concentration of PG was reduced from $6.0{\times}10-4$ to $1.0{\times}10-4M$ in acetic acid buffer solution at pH 4.75, a new absorption band with ${\lambda}$ max at 500 nm appeared. This absorption band appears only in the aqueous solution of pH 4.75 and does not appear in the pure methanol solution of the same pH. This is due to the conversion of the PG molecule from the ${\alpha}$-isomer to the ${\beta}$-isomer by $H_2O$. In other words, it was confirmed that the color change of the PG can be caused by the concentration of the solution and the characteristics of the solvent.

Multiple Order Diffractions by Laser-Induced Transient Grating in Nematic MBBA Film

  • 김성규;김학진
    • Bulletin of the Korean Chemical Society
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    • v.20 no.6
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    • pp.705-711
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    • 1999
  • The laser-induced transient grating method is applied to study the dynamics of the nematic MBBA film. The nanosecond laser pulses of 355 nm are used to make the transient grating and the cw He-Ne laser of 633 nm is used to probe the dynamics. Strong multiple order diffractions are observed at high nematic temperatures. The reordering process induced by the phototransformed state, which is the locally melted state from the nematic sample, is attributed to the main origin of the multiple order diffractions from the nematic MBBA. The characteristics of the multiple order gratings are discussed with the grating profiles simulated from the multiple diffraction signals.

Determination of the Lidar Ratio Using the GIST / ADEMRC Multi-wavelength Raman Lidar System at Anmyeon Island (GIST/ADEMRC 다파장 라만 라이다 시스템을 이용한 안면도 지역에서의 라이다 비 연구)

  • Noh Young Min;Kim Young Min;Kim Young Joon;Choi Byoung Chul
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.1-14
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    • 2006
  • Tropospheric aerosols are highly variant in time and space due to non-uniform source distribution and strong influence of meteorological conditions. Backscatter lidar measurement is useful to understand vertical distribution of aerosol. However, the backscatter lidar equation is undetermined due to its dependence on the two unknowns, extinction and backscattering coefficient. This dependence necessitates the exact value of the ratio between two parameters, that is, the lidar ratio. Also, Iidar ratio itself is useful optical parameter to understand properties of aerosols. Tropospheric aerosols were observed to understand variance of lidar ratio at Anmyeon island ($36.32^{/circ}N$, $126.19^{/circ}E$), Korea using a multi-wavelength raman lidar system developed by the Advanced Environmental Monitoring Research Center (ADEMRC), Gwangju Institute Science and Technology (GIST), Korea during measurement periods; March 15$\sim$April $16^{th}$, 2004 and May 24$\sim$ $8^{th}$ 2005. Extinction coefficient, backscattering coefficient, and lidar ratio were measured at 355 and 532 nm by the Raman method. Different types of aerosol layers were distinguished by the differences in the optical properties such as Angstrom exponent, and lidar ratio. The average value of lidar ratio during two observation periods was found to be $50.85\pm4.88$ sr at 355 nm and $52.43\pm15.15$ sr at 532 nm at 2004 and $57.94\pm10.29$ sr at 355 nm and $82.24\pm15.90$ sr at 532 nm at 2005. We conduct hysplit back-trajectory to know the pathway of airmass during the observation periods. We also calculate lidar ratio of different type of aerosol, urban, maritime, dust, continental aerosols using OPAC (Optical Properties of Aerosols and Clouds), Remote sensing of atmospheric aerosol using a multi-wavelengh lidar system with Raman channels is quite and powerful tool to characterize the optical propertises of troposheric aerosols.