• Title/Summary/Keyword: 3-MX

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Electronic and Magnetic Structure Calculations of Mn-dimer Molecular Magnet (Mn-dimer 분자자성체의 전자구조 및 자기구조 계산)

  • Park, Key Taeck
    • Journal of the Korean Magnetics Society
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    • v.24 no.4
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    • pp.97-100
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    • 2014
  • We have studied electronic and magnetic structure of Mn-dimer molecule using OpenMX method based on density functional method. The calculated density of states shows that the four O atoms split $e_g$ and $t_{2g}$ energy levels. The energy splitting by the crystal field is smaller than bulk MnO with cubic structure, because of small coordination number of atoms. Total energy with antiferromagnetic spin configuration is lower than that of ferromagnetic configurations. Calculated exchange interaction J between Mn atoms is one order larger than that of the other Mn-O magnetic molecules. That comes from the direct exchange interaction between Mn 3d orbitals and the super-exchange interactions caused by strong ${\sigma}$-bonding of Mn-O orbitals.

Novel Cationic Group 4 Metal Alkyl Complexes for Olefin Polymerizations (올레핀중합용 첨단 양이온형 제4족 유기금속 착물)

  • Kim, Il
    • Polymer Science and Technology
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    • v.5 no.3
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    • pp.236-253
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    • 1994
  • 양이온형 $d^0\;Cp_2M(R)(L)^+$ 착물과 무염기 $Cp_2M(R)^+$ 착물은 $Cp_2M(R)_2$화합물로부터 쉽게 합성할 수 있다. 이들 친전자성 착물에서는 여러가지 리간드 교환반응, 삽입반응, ${\beta}$-H 제거반응 및 ${\sigma}$-결합 복분해반응이 일어날 수 있다. 일반적으로 $Cp2M(R)(L)^+$ 착물은 불포화도와 전하가 크기때문에 중성의 $Cp_2M(R)(X)$$Cp_2M(R)_2$보다 반응성이 크며 $d^0\;{Cp_2}^*M(R)^+$ (M=제 3족과 란탄계) 착물과 여러가지 반응에서 유사한 거동을 보인다. $Cp_2MX_2$를 기초로하여 합성된 Ziegler-Natta 촉매에 의한 올레핀 중합에서 활성점이 $Cp_2M(R)^+$ 양이온이라는 여러가지 직접적인 증거가 발표되었다. 분리가능한 $Cp_2M(R)(L)^+$ 착물은 올레핀중합에서 높은 활성을 보이며, 유기합성의 관점에서 흥미있는 C-C 재조합반응과 같은 다른 여러가지 반응이 일어날 수 있는 기회를 제공한다.

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Child health promotion program in South Korea in collaboration with US National Aeronautics and Space Administration: Improvement in dietary and nutrition knowledge of young children

  • Lim, Hyunjung;Kim, JiEun;Wang, Youfa;Min, Jungwon;Carvajal, Nubia A.;Lloyd, Charles W.
    • Nutrition Research and Practice
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    • v.10 no.5
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    • pp.555-562
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    • 2016
  • BACKGROUND/OBJECTIVES: Childhood obesity has become a global epidemic. Development of effective and sustainable programs to promote healthy behaviors from a young age is important. This study developed and tested an intervention program designed to promote healthy eating and physical activity among young children in South Korea by adaptation of the US National Aeronautics and Space Administration (NASA) Mission X (MX) Program. SUBJECTS/METHODS: The intervention program consisted of 4 weeks of fitness and 2 weeks of nutrition education. A sample of 104 subjects completed pre- and post- surveys on the Children's Nutrition Acknowledgement Test (NAT). Parents were asked for their children's characteristics and two 24-hour dietary records, the Nutrition Quotient (NQ) at baseline and a 6-week follow-up. Child weight status was assessed using Korean body mass index (BMI) percentiles. RESULTS: At baseline, 16.4% (boy: 15.4%; girl: 19.2%) of subjects were overweight or obese (based on $BMI{\geq}85%tile$). Fat consumption significantly decreased in normal BMI children ($48.6{\pm}16.8g$ at baseline to $41.9{\pm}18.1g$ after intervention, P < 0.05); total NQ score significantly increased from 66.4 to 67.9 (P < 0.05); total NAT score significantly improved in normal BMI children (74.3 at baseline to 81.9 after the program), children being underweight (from 71.0 to 77.0), and overweight children (77.1 at baseline vs. 88.2 after intervention, P < 0.001). CONCLUSIONS: The 6-week South Korean NASA MX project is feasible and shows favorable changes in eating behaviors and nutritional knowledge among young children.

The Distribution of Implant Patients and the Type of Implant Site (임플란트 환자의 분포 및 식립부 유형)

  • Park, Ji-Eun;Yun, Jeong-Ho;Jung, Ui-Won;Kim, Chang-Seong;Cho, Kyoo-Sung;Chai, Jung-Kiu;Kim, Chong-Kwan;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.34 no.4
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    • pp.819-836
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    • 2004
  • Nowdays, the awareness of implant treatment has grown rapidly among dentists and patients alike in Korea, as it becomes a widely accepted treatment. The reason is that unlike crown and bridge or denture treatment, implant treatment helps preserve existing bone and improve masticatory functions. So, It is needed understanding about the type, distribution of implant patient. The following results on patient type and implant distribution were compiled from 4433 implant cases of 1596 patients treated at the periodontal dept. of Y University Hospital during 1992 to 2004. 1. There are no dissimilarities between men and women, with patients in their 40, 50s accounting for 52.5% of patients and 57.5% of implant treatments; the largest share of patients and implant treatments. 2. Mn. posterior area accounted for 54.9% of implant treatments followed by Mx. posterior area(27.6%), Mx anterior area(11.9%) and Mn anterior area(5.6%). 3. Partial edentulous patients treated by single crown and bridge-type prosthesis accounted for 97.5% and fully edentulous patient accounted for the remaining 2.5%. 4. The major cause of tooth loss is periodontal disease, followed by dental caries, trauma and congenital missing. Also, older people are more likely to suffer from tooth loss due to periodontal disease rather than dental caries. 5. In the distribution of bone quality for maxillae, type III was most, followed by type II, r type IV and r type I. As for mandible, type II was most, followed by type III, type IV and for type I. 6. In the distribution of bone quantity for maxillae, type C was most, followed by type B, type D, type A, and for type E. As for mandible, type B was 52% most, followed by type C, type D, type A and type E. 7. The majority of implants were those of 1O-14mm in length (85.2%) and regular diameter in width (64%). The results provided us with basic data on patient type, implant distribution, bone condition, etc. We wish that our results coupled with other research data helps assist in the further study for better implant success/survival rates, etc.

Noise Characteristics of 64-channel 2nd-order DROS Gradiometer System inside a Poorly Magnetically-shielded Room (저성능 자기차폐실에서 64채널 DROS 2차 미분계 시스템의 잡음 특성)

  • Kim, J.M.;Lee, Y.H.;Yu, K.K.;Kim, K.;Kwon, H.;Park, Y.K.;Sasada, Ichiro
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.33-39
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    • 2006
  • We have developed a second-order double relaxation oscillation SQUID(DROS) gradiometer with a baseline of 35 mm, and constructed a poorly magnetically-shielded room(MSR) with an aluminum layer and permalloy layers for magnetocardiography(MCG). The 2nd-order DROS gradiometer has a noise level of 20 $fT/{\surd}Hz$ at 1 Hz and 8 $fT/{\surd}Hz$ at 200 Hz inside the heavily-shielded MSR with a shielding factor of $10^3$ at 1 Hz and $10^4-10^5$ at 100 Hz. The poorly-shielded MSR, built of a 12-mm-thick aluminum layer and 4-6 permalloy layers of 0.35 mm thickness, is 2.4mx2.4mx2.4m in size, and has a shielding factor of 40 at 1 Hz, $10^4$ at 100 Hz. Our 64-channel second-order gradiometer MCG system consists of 64 2nd-order DROS gradiometers, flux-locked loop electronics, and analog signal processors. With the 2nd-order DROS gradiometers and flux-locked loop electronics installed inside the poorly-shielded MSR, and with the analog signal processor installed outside it, the noise level was measured to be 20 $fT/{\surd}Hz$ at 1 Hz and 8 $fT/{\surd}Hz$ at 200 Hz on the average even though the MSR door is open. This result leads to a low noise level, low enough to obtain a human MCG at the same level as that measured in the heavily-shielded MSR. However, filters or active shielding is needed fur clear MCG when there is large low-frequency noise from heavy air conditioning or large ac power consumption near the poorly-shielded MSR.

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Development of 6-axis Force/moment Sensor for Humanoid Robot's Head Reacting to a External Force (외력에 반응하는 인간형 로봇의 머리를 위한 6 축 힘/모멘트 센서 개발)

  • Kim, Gab-Soon
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.12
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    • pp.78-84
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    • 2009
  • When external force is applied to humanoid robot's head, humanoid robot's neck is rotated to prevent the damage of it. So, robot's neck have to perceive forces (Fx of x-direction, Fy of y-direction and Fz of z-direction) and moments (Mx of x-direction, My of y-direction and Mz of z-direction) using the attached 6-axis force/moment sensor. Thus, in this paper, 6-axis force/moment sensor was developed to sense the forces and moments applied to robot's head. The structure of 6-axis force/moment sensor was modeled newly, and it was designed using FEM software (ANSYS) and manufactured by attaching straingages on the sensing element, finally, the characteristic test of the sensor was carried out. As a result, it is confirmed that interference error is less than 3%. And, it is thought that the sensor can be used to measure the forces and the moments for humanoid robot's head.

A Study on Kinetic Gait Analysis of the Normal Adult (정상 성인의 운동역학적 보행분석)

  • Kim, Geon;Yoon, Na-Mi
    • The Journal of Korean Physical Therapy
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    • v.21 no.2
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    • pp.87-95
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    • 2009
  • Purpose: This study reports the basic reference data of the specific gait parameters for Korean normal adults. Methods: The basic gait parameters were extracted from 73 Adults (35 men and 38 women), 18 to 33 years of age, using a Vicon MX motion analysis system. The segment kinetics, such as joint moment and power, was analyzed at the hip, knee and ankle. Results: The motion patterns are typically associated with a specific phase of the gait cycle. The temporal-spatial gait parameters of Korean normal adults, such as cadence, walking speed, stride length, single support and double support, were similar to the other western reference data. The kinetic parameters of Korean normal adults, such as joint moments of force, joint mechanical power generation or absorption and ground reaction forces, were also similar to other western reference datasets. Conclusion: This study demonstrates that objective gait analysis can be used to document the gait patterns of normal healthy adults. The techniques of 3-dimensional temporal-spatial gait parameters and kinematic parameters analysis can provide a detailed biomechanical description of a normal and pathological gait.

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Ferroelectric Properties of Substituted Aurivillius Phases SrBi2Nb2-xMxO9 (M=Cr, Mo)

  • Moon, S.-Y.;Choi, K. S.;Jung, K. W.;Lee, H.;Jung, D.
    • Bulletin of the Korean Chemical Society
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    • v.23 no.10
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    • pp.1463-1482
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    • 2002
  • Partially doped Aurivillius phases SrBi2N$b_{2-x}M_xO_9$ (M=Cr and Mo) were successfully synthesized and characterized. The extent of the substitution was limited at ~20 mole % because of the size differences between $Nb^{5+}$ and $Cr^{6+}$, and between $Nb^{5+}$ and $Mo^{6+}$. When the amount of substitution exceeded ~20 mole%, the phases began to collapse and the second phases were made. The dielectric constants of substituted compounds were enlarged nevertheless Cr or Mo is substituted. The increment is bigger in the Mo substituted compound than in the Cr doped one although the Nb(Cr)$O_6$ octahedra could be more strongly distorted than the Nb(Mo)$O_6$ octahedra since the ionic size difference between $Nb^{5+}$ and of $Cr^{6+}$ is much bigger than that between $Nb^{5+}$ and $Mo^{6+}$. Consequently, the dielectric constant of the substituted Aurivillius phase $Bi_2$A_{n-1}B_{n-x}M_xO_{3n+1}$$ depends on the extent of distortion of the B$O_6$ octahedra and more strongly on the polarizability of the metal.

Analysis of Delay Time in the Personal Communications Exchange (개인통신교환기의 지연시간 분석)

  • Jang, Hee-Seon;Suh, Jae-Jun;Lim, Seog-Ku;Yu, Jea-Hoon;Lee, Yoon-Ju
    • IE interfaces
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    • v.9 no.3
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    • pp.180-193
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    • 1996
  • 본 논문에서는 시뮬레이션 모델을 통해 호유형뿐만 아니라 개인통신서비스에서 필수적인 핸드오버 및 위치등록 등의 모든 트래픽 유형을 고래했을 때 개인통신교환기(PCX : Personal Commuincations Exchange)에서의 지연시간을 분석하며, 지연시간에 대한 결과와 프로세서의 이용율로부터 개인통신교환기의 호처리 및 이동성처리용량을 분석하고 그에 따른 가입자의 수용능력을 추정한다. IPC(Inter-Processor Communications) 메시지의 송수신시간 및 메시지의 처리시간등 교환기 제어계의 성능분석에 필요한 입력 파라미터 값은 기존 ISDN(Integrated Services Digital Network) 및 CMS-MX(CDMA Mobile System-Mobile Exchange) 교환기의 측정자료를 이용하였다. 시뮬레이션 분석결과 PCX 교환기의 호처리 성능은 주로 번호번역 기능을 담당하는 프로세서인 NTP(Number Translation Processor)의 용량에 의해 결정되며, 가입자 밀도가 1,500명$/km^2$인 경우 호처리용량은 약 42만 BHC(Busy Hour Call Completion)로 추정되었고, 이에 상응하는 핸드오버 및 위치등록 처리용량은 각각 시간당 약 2만 6천히 및 40만 6천회로 나타났다. 이것은 가입자당 호처리 부하가 1.6BHC일 경우, 약 15만 7천 가입자를 수용할 수 있는 용량에 해당한다.

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CHANGES OF TEMPOROMANDIULAR JOINT SYMPTOMS AFTER ORTHOGNATHIC SURGERY IN THE ASYMMETRIC PROGNATHISM PATIENTS (안면비대칭 환자의 악교정술 후 안면비대칭의 개선에 따른 악관절장애 증상의 변화)

  • Kim, Young-Sam;Ryu, Dong-Mok
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.33 no.5
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    • pp.518-523
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    • 2007
  • Purpose: The purpose of this study is to prove that orthognatic surgery on asymmetric prognathism patients improve the temporomandibular dysfunction. Materials and methods: All 30 patients underwent mandibular setback with B-SSRO including 22 patients Le Fort I surgery in KyungHee medical center. Preoperative and postoperative PA cephalograms & transcranial radiographs were measured midline deviation in Mx and Mn, occlusal canting change, condyle position, the temporomandibular dysfunction were checked before surgery, within 1 month after surgery, $3{\sim}6$ months, 12-24 months after surgery respectively. Results: The temporomandibular dysfunction were relieved after surgery in 17 patients of 25 patients. Conclusion: Orthognatic surgery may benefit the temporomandibular joint dysfunction in facial asymmetry patients by obtaining a postoperative stable occlusion and better physiologic neuromuscular function. Specially impovement of occlusal canting may reduce condyle displacement of midline deviation side and the temporomandibular joint dysfunction.