• Title/Summary/Keyword: 3-D Analytical Method

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Determination and Validation of an Analytical Method for Dichlobentiazox in Agricultural Products with LC-MS/MS (LC-MS/MS를 이용한 농산물 중 Dichlobentiazox 시험법 개발 및 검증)

  • Gu, Sun Young;Lee, Han Sol;Park, Ji-Su;Lee, Su Jung;Shin, Hye-Sun;Kang, Sung Eun;Chung, Yun Mi;Choi, Ha Na;Yoon, Sang Soon;Jung, Young-Hyun;Yoon, Hae Jung
    • Korean Journal of Environmental Agriculture
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    • v.40 no.2
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    • pp.108-117
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    • 2021
  • BACKGROUND: Dichlobentiazox is a newly registered pesticide in Korea as a triazole fungicide and requires establishment of an official analysis method for the safety management. Therefore, the aim of this study was to determine the residual analysis method of dichlobentiazox for the five representative agricultural products. METHODS AND RESULTS: Three QuEChERS methods were applied to establish the extraction method, and the EN method was finally selected through the recovery test. In addition, various adsorbent agents were applied to establish the clean-up method. As a result, it was found that the recovery of the tested pesticide was reduced when using the d-SPE method with PSA and GCB, but C18 showed an excellent recovery. Therefore this method was established as the final analysis method. For the analysis, LC-MS/MS was used with consideration of the selectivity and sensitivity of the target pesticide and was operated in MRM mode. The results of the recovery test using the established analysis method and inter laboratory validation showed a valid range of 70-120%, with standard deviation and coefficient of variation of less than 3.0% and 11.6%, respectively. CONCLUSION: Dichlobentiazox could be analyzed with a modified QuEChERS method, and the method determined would be widely available to ensure the safety of residual pesticides in Korea.

Capsule Train Dynamic Model Development and Driving Characteristic Analysis Considering the Superconductor Electrodynamic Suspension (초전도 유도 반발식 부상특성을 고려한 캡슐트레인 동특성 해석 모델 구축 및 주행 특성 분석)

  • Lee, Jin-Ho;Lim, Jungyoul;You, Won-Hee;Lee, Kwansup
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.7
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    • pp.38-45
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    • 2020
  • A magnetically levitating capsule train, which runs inside the sub-vacuum tube, can reach ultra-fast speeds by dramatically reducing the aerodynamic drag and friction. The capsule train uses the superconductor electrodynamic suspension (SC-EDS) method for levitation. The SC-EDS method has advantages, such as a large levitation gap and free of gap control, which could reduce the infra-construction cost. On the other hand, disadvantages, such as the large variation of the levitation-guidance gap and small damping characteristics in levitation-guidance force, could degrade the running stability and ride comfort of the capsule train. In this study, a dynamic analytical model of a capsule train based on the SC-EDS was developed to analyze the running dynamic characteristics. First, as important factors in the capsule train dynamics, the levitation and guidance stiffness in the SC-EDS system were derived, which depend non-linearly on the velocity and gap variation. A 3D dynamic analysis model for capsule trains was developed based on the derived stiffness. Through the developed model, the effects of the different running speeds on the ride comfort were analyzed. The effects of a disturbance from infrastructure, such as the curve radius, tube sag, and connection joint difference, on the running stability of the capsule train, were also analyzed.

On the particularities of the forced vibration of the hydro-elastic system consisting of a moving elastic plate, compressible viscous fluid and rigid wall

  • Akbarov, Surkay D.;Panakhli, Panakh G.
    • Coupled systems mechanics
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    • v.6 no.3
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    • pp.287-316
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    • 2017
  • This paper studies the particularities of the forced vibration of the hydro-elastic system consisting of a moving elastic plate, compressible viscous fluid and rigid wall. This study is made by employing the discrete-analytical solution method proposed in the paper by the authors (Akbarov and Panakhli (2015)). It is assumed that in the initial state the fluid flow is caused by the axial movement of the plate and the additional lineally-located time-harmonic forces act on the plate and these forces cause additional flow field in the fluid and a stress-strain state in the plate. The stress-strain state in the plate is described by utilizing the exact equations and relations of the linear elastodynamics. However, the additional fluid flow field is described with linearized Navier-Stokes equations for a compressible viscous fluid. Numerical results related to the influence of the problem parameters on the frequency response of the normal stress acting on the plate fluid interface plane and fluid flow velocity on this plane are presented and discussed. In this discussion, attention is focused on the influence of the initial plate axial moving velocity on these responses. At the same, it is established that as a result of the plate moving a resonance type of phenomenon can take place under forced vibration of the system. Moreover, numerical results regarding the influence of the fluid compressibility on these responses are also presented and discussed.

FE validation of the equivalent diameter calculation model for grouped headed studs

  • Spremic, Milan;Pavlovic, Marko;Markovic, Zlatko;Veljkovic, Milan;Budjevac, Dragan
    • Steel and Composite Structures
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    • v.26 no.3
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    • pp.375-386
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    • 2018
  • Existing design codes for steel-concrete composite structures give only general information about the shear connection provided by headed studs in group arrangement. Grouting of the openings in prefabricated concrete slabs, where the grouped headed studs are placed in the deck pockets is alternative to cast-in-place decks to accomplish fast execution of composite structures. This paper considers the possibility to reduce the distance between the studs within the group, bellow the Eurocode limitations. This may lead to increased competitiveness of the prefabricated construction because more studs are placed in the group if negative effectives of smaller distances between studs are limited. The main purpose of this work is to investigate these limits and propose an analytical calculation model for prediction of the shear resistance of grouped stud arrangements in the deck pockets. An advanced FEA model, validated by results of push-out experiments, is used to analyze the shear behavior of the grouped stud with smaller distance between them than recommended by EN 1994-1. Calculation model for shear resistance, which is consistent with the existing Eurocode rules, is proposed based on a newly introduced equivalent diameter of the stud group, $d_G$. The new calculation model is validated by comparison to the results of FE parametric study. The distance between the studs in the longitudinal direction and the number of stud rows and columns in the group are considered as the main variables.

Digital Competencies Required for Information Science Specialists at Saudi Universities

  • Yamani, Hanaa;AlHarthi, Ahmed;Elsigini, Waleed
    • International Journal of Computer Science & Network Security
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    • v.21 no.2
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    • pp.212-220
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    • 2021
  • The objectives of this research were to identify the digital competencies required for information science specialists at Saudi universities and to examine whether there existed conspicuous differences in the standpoint of these specialists due to years of work experience with regard to the importance of these competencies. A descriptive analytical method was used to accomplish these objectives while extracting the required digital competency list and ascertaining its importance. The research sample comprised 24 experts in the field of information science from several universities in the Kingdom of Saudi Arabia. The participants in the sample were asked to complete a questionnaire prepared to acquire the pertinent data in the period between January 5, 2021 and January 20, 2021. The results reveal that the digital competencies required for information science specialists at Saudi universities encompass general features such as the ability to use computer, Internet, Web2, Web3, and smartphone applications, digital learning resource development, data processing (big data) and its sharing via the Internet, system analysis, dealing with multiple electronic indexing applications and learning management systems and its features, using electronic bibliographic control tools, artificial intelligence tools, cybersecurity system maintenance, ability to comprehend and use different programming languages, simulation, and augmented reality applications, and knowledge and skills for 3D printing. Furthermore, no statistically significant differences were observed between the mean ranks of scores of specialists with less than 10 years of practical experience and those with practical experience of 10 years or more with regard to conferring importance to digital competencies.

A Behavioral Analysis of Curved Steel Box Bridge Associated with Diaphragm's Shape and Spacing (다이아프램 형상 및 간격에 따른 곡선 강박스거더의 거동해석)

  • Kim, Yun-Tae;Kim, Sang-Chel
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.1
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    • pp.205-215
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    • 2006
  • In this study 3-D shell FEM model was applied to analyze the behavior of curved steel box girders stiffened by diaphragms. The reliability of the analytical method has been proved by comparing with the existing results. It was also found from this analysis that main factors affecting a distortional stress are length of a girder, curvature of the girder, and spacing of diaphragms. A modelled bridge with 30m of span length and 40m of radius was analyzed to find an optimum spacing of diaphragm, and as a result of applying different spacings, 5m was found to be most appropriate to control the stress ratio regulated by specifications. In the effect of diaphragm shape, the rhamen-typed diaphragm is found to be more effective than the fully filled-up one in the range of opening ratio of 0.4 to 0.6. But, the fully filled-up diaphragm had more efficiency in terms of reducing the distortional stress than X-truss typed diaphragm.

Quantitative Analysis of Vitamin B5 and B6 Using High Performance Liquid Chromatography (고속액체크로마토그래피를 이용한 비타민 B5 및 B6의 정량 분석)

  • Kim, Gi-Ppeum;Hwang, Young-Sun;Choung, Myoung-Gun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.10
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    • pp.1186-1194
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    • 2017
  • Recently, many people have demanded reliable nutritional data even for minor-components. On the other hand, an analytical method for the analyses of vitamin $B_5$ and $B_6$ is lacking. Therefore, this study attempted to validate with accuracy and precision the analysis of vitamin $B_5$ and $B_6$ using a high-performance liquid chromatography (HPLC) method. The vitamin $B_5$ and $B_6$ contents were analyzed using an Agilent 1260 series HPLC system. YMC-Pack ODS-AM ($250{\times}4.6mm$ I.D.) and YMC-Pack Pro RS $C_{18}$ ($250{\times}4.6mm$ I.D.) columns were used for the analyses of vitamin $B_5$ and $B_6$, respectively. In the case of vitamin $B_5$, the flow rate was set to 1.0 mL/min by isocratic elution using the 50 mM $KH_2PO_4$ solution (pH 3.5)/acetonitrile (ACN) (95:5, v/v) with monitoring at 200 nm using HPLC/DAD, whereas the flow rate for vitamin $B_6$ was set to 1.0 mL/min of flow rate by isocratic elution using a 20 mM $CH_3CO_2Na$ solution (pH 3.6)/ACN (97:3, v/v) with monitoring by excitation at 290 nm and emission at 396 nm using HPLC/FLD. The column temperature was set to $30^{\circ}C$. The injection volume was $20{\mu}L$ for each experiment. The specificity of the accuracy and precision for vitamin $B_5$ and $B_6$ were also validated by HPLC. The results showed high linearity in the calibration curve for vitamin $B_5$ ($R^2=0.9998^{{\ast}{\ast}}$), the limit of detection (LOD) and limit of quantitation (LOQ) were 0.4 mg/L and 1.3 mg/L, respectively, In contrast, for the calibration curve of vitamin $B_6$, which showed high linearity ($R^2=0.9999^{{\ast}{\ast}}$), the LOD and LOQ were 0.006 mg/L and 0.02 mg/L, respectively.

Evaluation of Reinforced Concrete Beam's Inelastic Behavior Characteristics using Beam-column Fiber Finite Element considering Shear Deformation Effect (전단변형 효과가 고려된 보-기둥 섬유유한요소를 이용한 철근콘크리트 보의 비탄성 거동특성 평가)

  • Cheon, Ju-Hyun;Hwang, Cheol-Seong;Park, Kwang-Min;Shin, Hyun-Mock
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.130-137
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    • 2017
  • The purpose of this study is to provide a reasonable analytical method for the reinforced concrete beams which shows failure mode of shear and flexure-shear by proposing a modified formulation to consider the effect of shear deformation on the beam-column fiber element based on the flexibility method and a new constitutive law of inelastic shear response history for the section. A total of 6 specimens of reinforced concrete beams which is designed to cause shear failure before yielding longitudinal reinforcement to investigate the influence of the main experimental variables on the shear behavior characteristics and the analysis was performed by using a non-linear finite element analysis program (RCAHEST) applying the newly modified constitutive equation by the authors. The failure mode and the overall behavior characteristics until fracture are predicted appropriately for all specimens and the results are expected to be useful enough for the 3 - D analysis to carry out reliable results of large-scale and complicated structures in the future.

Theory of X-ray microcomputed tomography in dental research: application for the caries research (치과 분야 연구에서 미세전산화 단층촬영술의 이론: 치아우식증에 대한 적용)

  • Park, Young-Seok;Bae, Kwang-Hak;Chang, Ju-Hea;Shon, Won-Jun
    • Restorative Dentistry and Endodontics
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    • v.36 no.2
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    • pp.98-107
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    • 2011
  • Caries remains prevalent throughout modern society and is the main disease in the field of dentistry. Although studies of this disease have used diverse methodology, recently, X-ray microtomography has gained popularity as a non-destructive, 3-dimensional (3D) analytical technique, and has several advantages over the conventional methods. According to X-ray source, it is classified as monochromatic or polychromatic with the latter being more widely used due to the high cost of the monochromatic source despite some advantages. The determination of mineral density profiles based on changes in X-ray attenuation is the principle of this method and calibration and image processing procedures are needed for the better image and reproducible measurements. Using this tool, 3D reconstruction is also possible and it enables to visualize the internal structures of dental caries. With the advances in the computer technology, more diverse applications are being studied, such automated caries assessment algorithms.

An Analysis on the Determinants of Innovation -Medium Core Firms in Material and Component Industry- (부품소재 중핵기업의 기술혁신 결정요인 분석 -기업규모와 시장구조를 중심으로-)

  • Song, Chi-Ung
    • Journal of Korea Technology Innovation Society
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    • v.10 no.3
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    • pp.431-457
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    • 2007
  • The main purpose of this study is to analyze the determinants of innovation in the medium core firms that belong to components and materials industry. For this purpose, we introduce the Schumpeterian hypothesis as a theoretical background at first. According to the Schumpeterian hypothesis, large firms in concentrated markets are likely to have more innovative activities. That means, firm site and market structure are the main determinant of innovation. Then, we propose other economic factors that have been considered to have effects on firms' innovative activities in previous studies. Those factors are export, profit, growth rate, R&D expenditure and capital intensity. In order to analyze the determinants of innovation, we estimate whether firm size, market structure, export, profit, growth rate, R&D expenditure and capital intensity affect to the possibility of creating innovation in medium core firms. In order to do this, our study uses survey data from 'Korean Innovation Survey(2005)' conducted by STEPI as well as utilizes the probit model as an analytical method. According to the empirical results, firm size has a positive relationship with innovative activities of medium core firms but market concentration does not. We find the negative correlation between market concentration and innovative activities in this study. Thus, was have to say that we do not fully support the Schumpeterian hypothesis in this case. Among other variables, profit and R&D expenditure are estimated to have positive relationship with innovative activities, while export and capital intensity are estimated to have negative relationship with innovative activities. In case of growth rate, we do not find any significant relationship with innovative activities. In conclusion, larger firm size, higher market competition, more access to the financial market and additional R&D investment would facilitate innovative activities of medium core firms. However, we have to review the relationship between export and innovative activities that has been estimated in this study. While the estimated effect of export on innovative activities can be explained by the own characteristics of medium core firms that produce and supply capital goods to final manufacturer, we have address this issue in the future.

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