• Korean Journal of Environmental Agriculture
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• v.32 no.3
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• pp.214-223
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• 2013

BACKGROUND: This study focused on the development of an analytical method about dichlorprop (DCPP; 2-(2,4-dichlorophenoxy)propionic acid) which is a plant growth regulator, a synthetic auxin for agricultural commodities. DCPP prevents falling of fruits during their growth periods. However, the overdose of DCPP caused the unwanted maturing time and reduce the safe storage period. If we take fruits with exceeding maximum residue limits, it could be harmful. Therefore, this study presented the analytical method of DCPP in agricultural commodities for the nation-wide pesticide residues monitoring program of the Ministry of Food and Drug Safety. METHODS AND RESULTS: We adopted the analytical method for DCPP in agricultural commodities by gas chromatograph in cooperated with Electron Capture Detector(ECD). Sample extraction and purification by ion-associated partition method were applied, then quantitation was done by GC/ECD with DB-17, a moderate polarity column under the temperature-rising condition with nitrogen as a carrier gas and split-less mode. Standard calibration curve presented linearity with the correlation coefficient ($r^2$) > 0.9998, analysed from 0.1 to 2.0 mg/L concentration. Limit of quantitation in agricultural commodities represents 0.05 mg/kg, and average recoveries ranged from 78.8 to 102.2%. The repeatability of measurements expressed as coefficient of variation (CV %) was less than 9.5% in 0.05, 0.10, and 0.50 mg/kg. CONCLUSION(S): Our newly improved analytical method for DCPP residues in agricultural commodities was applicable to the nation-wide pesticide residues monitoring program with the acceptable level of sensitivity, repeatability and reproducibility.

• Ocean Systems Engineering
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• v.10 no.2
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• pp.201-226
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• 2020

A systematic numerical comparative study of the performance of semicircular and rectangular submerged breakwaters interacting with solitary waves is the basis of this paper. To accomplish this task, Nwogu's extended Boussinesq model equations are employed to simulate the interaction of the wave with breakwaters. The finite difference technique has been used to discretize the spatial terms while a fourth-order predictor-corrector method is employed for time discretization in our numerical model. The proposed computational scheme uses a staggered-grid system where the first-order spatial derivatives have been discretized with fourth-order accuracy. For validation purposes, five test cases are considered and numerical results have been successfully compared with the existing analytical and experimental results. The performances of the rectangular and semicircular breakwaters have been examined in terms of the wave reflection, transmission, and dissipation coefficients (RTD coefficients) denoted by K_R, K_T, K_D. The latter coefficient K_D emerges due to the non-energy conserving K_R and K_T. Our computational results and graphical illustrations show that the rectangular breakwater has higher reflection coefficients than semicircular breakwater for a fixed crest height, but as the wave height increases, the two reflection coefficients approach each other. un the other hand, the rectangular breakwater has larger dissipation coefficients compared to that of the semicircular breakwater and the difference between them increases as the height of the crest increases. However, the transmission coefficient for the semicircular breakwater is greater than that of the rectangular breakwater and the difference in their transmission coefficients increases with the crest height. Quantitatively, for rectangular breakwaters the reflection coefficients K_R are 5-15% higher while the diffusion coefficients K_D are 3-23% higher than that for the semicircular breakwaters, respectively. The transmission coefficients K_T for rectangular breakwater shows the better performance up to 2.47% than that for the semicircular breakwaters. Based on our computational results, one may conclude that the rectangular breakwater has a better overall performance than the semicircular breakwater. Although the model equations are non-dissipative, the non-energy conserving transmission and reflection coefficients due to wave-breakwater interactions lead to dissipation type contribution.

• Science of Emotion and Sensibility
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• v.22 no.3
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• pp.3-20
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• 2019

With advancements in technology of virtual reality, it is used for various purposes in many fields such as medical care and healthcare, but as the same time there are also increasing reports of nausea, eye fatigue, dizziness, and headache from users. These symptoms of motion sickness are referred to as cybersickness, and various researches are under way to solve the cybersickness problem because it can cause inconvenience to the user and cause adverse effects such as discomfort or stress. However, there is no official standard for the causes and solutions of cybersickness at present. This is also related to the absence of tools to quantitatively measure the cybersickness. In order to overcome these limitations, this study proposed quantitative and objective cybersickness evaluation method. We measured 128-channel EEG waves from ten participants experiencing visually stimulated virtual reality. We calculated the relative power of delta and alpha in 11 regions (left, middle, right frontal, parietal, occipital and left, right temporal lobe). Multiple regression models were obtained in a stepwise manner with the motion sickness susceptibility questionnaire (MSSQ) scores indicating the susceptibility of the subject to the motion sickness. A multiple regression model with the highest under the area ROC curve (AUC) was derived. In the multiple regression model derived from this study, it was possible to distinguish cybersickness by accuracy of 95.1% with 11 explanatory variables (P_D.MF, P_D.LP, P_D.MP, P_D.RP, P_D.MO, P_A.LF, P_A.MF, P_A.RF, P_A.LP, P_A.RP, P_A.MO). In summary, in this study, objective response to cybersickness was confirmed through 128 channels of EEG. The analysis results showed that there was a clearly distinguished reaction at a specific part of the brain. Using the results and analytical methods of this study, it is expected that it will be useful for the future studies related to the cybersickness.

• Analytical Science and Technology
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• v.13 no.1
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• pp.12-21
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• 2000

The PIGE (Proton Induced Gamma ray Emission) method was applied for the measurement of light elements Li ~ K. A test measurement has been performed for geological, biological, environmental and material samples by using a standard sample for each element. The measurement was performed for the two proton energies of 2.4 and 3.4 MeV, and 3.4 MeV was found to yield better result for multielemental analysis. The result shows a fair agreement within 15% for all elements with standard values. The detection limits of Li, B, F and Na are less than 100 ppm, while those of the other elements are from a few hundred ppm to a few percents.

• Analytical Science and Technology
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• v.19 no.5
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• pp.422-432
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• 2006

The volatile organic compounds(VOCs) have been recognized as a major contributor to air pollution. The catalytic oxidation is one of the most important processes for VOCs destruction due to getting high efficiency at low temperature. In this study, monometallic Pt and bimetallic Pt-Ru, Pt-Ir were supported to ${\gamma}-Al_2O_3$. Xylene, toluene and MEK were used as reactants. The monometallic or bimetallic catalysts were prepared by the excess wetness impregnation method and were characterized by XRD, XPS, TEM and BET analysis. As a result, Pt-Ru, Pt-Ir bimetallic catalysts showed higher conversion than Pt monometallic catalyst. Pt-Ir bimetallic catalyst showed the highest conversion on the ${\gamma}-Al_2O_3$ support. In the VOCs oxidation, Pt-Ru, Pt-Ir bimetallic catalyst had multipoint active sites, so it improved the range of Pt metal state. Therefore, bimetallic catalysts showed higher conversion of VOCs than monometallic ones. In this study, the use of small amount of Ru, Ir to Pt promoted oxidation conversion of VOCs.

• Analytical Science and Technology
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• v.25 no.6
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• pp.460-466
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• 2012

An environmentally friendly, so-called green, high performance liquid chromatography method was developed and validated for the determination of trans, trans-muconic acid (t,t-MA) in human urine as a biomarker of benzene exposure. After urinary t,t-MA was extracted and enriched using solid-phase extraction, a MF-Ph1 SG80 ($150mm{\times}2.0mm$ I.D., 5 ${\mu}m$) column with a mobile phase of 10 mM $KH_2PO_4$ containing 0.1% $H_3PO_4$ was used for isocratic separation of t,t-MA with UV detection at 259 nm. The calibration curve was constructed in the range of 0.1-5.0 mg/L with good linearity ($r^2$=0.9992). The intra-day and inter-day precision (as RSD) were 0.9-8.5% and 3.1-4.5%, respectively. The average recovery ranged from 97.5% to 101.7%. The green sample preparation and separation with no organic solvents were successfully achieved. The validated method would be suitable for the routine biological monitoring of benzene exposure in the occupational settings.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.4
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• pp.353-360
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• 2011

The prediction of binary droplet collisions is important in the formation of falling drops and the evolution of sprays. The droplet velocity, impact parameter, and drop-size ratio influence the interaction between the droplets. The effect of these parameters results in complicated collision phenomena. Droplet collisions can be classified into four types of interactions: bouncing, coalescence, reflexive separation, and stretching separation. In the present study, the interfacial flow problem of the droplet collision was numerically simulated by using the level set method. 2D axisymmetric simulations on the head-on collisions and 3D simulation on the off-center collisions were performed. The numerical results of droplet behavior after the collision agreed well with the experimental and analytical results. The mixing of the mass of the initial droplets after the collision was also predicted by using different species index of colliding droplets.

• 한국지구물리탐사학회:학술대회논문집
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• 2004.06a
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• pp.165-169
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• 2004

Marine magnetic survey were carried out at Sokotra Basin offshore Korea between latitudes $31^{\circ}$ 42'32' N and $32^{\circ}$ 46'29' N, and longitudes $123^{\circ}$ 56'26" E and $125^{\circ}$ 49'16" E in order to estimate the depth of basement complex and as well as to configure it surface and produce the thickness of sedimentary sequence at the study area. Two methods have been used for depth estimation and basement configuration: the power spectrum and the 3-D analytical signal. The estimated depths resulted from the power spectrum method range from 1.4 km to 6.0 km for deep sources (basement troughs), and from 0.3 km to 1.75 km for shallow source (basement peaks). An isopach map was prepared for estimating the thickness of the sedimentary sequence at the study area; it ranges from 1.2 to 4.66 km. The estimated depths resulted from the analytic signal method range from 1.0 to 6 km. A basement configuration map was constructed for the study area in the basin. They show a well agreement with the geology of the study area.

• Journal of Korean Association for Spatial Structures
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• v.13 no.3
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• pp.73-81
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• 2013

In paper after the strong earthquake of recently the Korea neighborhood, the Korean government survey show that the 86% of school buildings in Korea are in potential damage risk and only 14% of them are designed as earthquake-resistance buildings. Earthquake Reinforcing projects of school have been a leading by the ministry of education, however their reinforcing methods done by not proved a engineering by experiment which results in uneconomical and uneffective rehabilitation for the future earthquake. An experimental and analytical study have been conducted for the shear reinforcing method of column by axis and horizontal axis load using attaching composite beam. Based on the previous research, in this study, Design examples are given to show the performance evaluation for the column reinforcing of old school buildings using nonlinear analysis is going to be conducted and strengthening method is going to be on the market after their performance is proved by the test.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.15 no.5 s.98
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• pp.604-611
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• 2005

The relationship between floor impact sound and vibration has been studied by field measurements, and the vibration modal characteristics have been analyzed. Vibration levels impacted by a standard heavy-weight impact source have been predicted according to the main design parameters using finite element method. Experimental results show that the dominant frequencies of the heavy impact sounds range below 100 Hz and that they are coincident with natural frequencies of the concrete slab. In addition, simple 2-dimensional finite element models are proposed to substitute 2 types of 3-dimensional models of complicated floor structural slabs those by The analytical result shows that the natural frequencies from first to fifth mode well correspond to those by experiments with an error of less than $12\%$, and acceleration peak value iscoincident with an error of less than $2\%$. Using the finite element model. vibration levels areestimated according to the design Parameters, slab thickness, compressive strength, and as a result, the thickness is revealed as effective to increase natural frequencies by $20\~30\%$ and to reduce the vibration level by 3$\~$4 dB per 30 mm of extra thickness.