• Journal of the Korea Concrete Institute
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• v.13 no.4
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• pp.314-320
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• 2001

In this paper, the properties of an expansive agent (CaO-CaS $O_4$) for dry shrinkage compensation were investigated by a series of experimental program, which might be used at On-Dol heating system as mortar type. The expansion principle of the CaO-CaS $O_4$ was mainly verified. As a result of this study, the correlation between the content of the expansive agent and the compressive strength was obtained in the form of exponential function(Y = A $e^{-x}$), showing that as the content of expansive agent increased as the expansion performance with the compressive strength increased by only a certain amount. Also, as a results of the analysis of a correlation between the expansive performance and the chemical properties which generally accompanied a part of quality management in manufacturing the expensive cement, the expansive performance was relative to only the contents of the F-CaO among chemical properties(Blaine, +44$\mu\textrm{m}$R, F-CaO, S $O_3$,L.O.I). And it was clarified that the results were relative to the second order function, showing that if the contents of the F-CaO increased the expansive performance Increased.d.

• Korean Journal of Materials Research
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• v.26 no.9
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• pp.455-459
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• 2016

The deposition process for the gap-filling of sub-micrometer trenches using DMDMOS, $(CH_3)_2Si(OCH_3)_2$, and $C_xH_yO_z$ by flowable chemical vapor deposition (F-CVD) is presented. We obtained low-k films that possess superior gap-filling properties on trench patterns without voids or delamination. The newly developed technique for the gap-filling of submicrometer features will have a great impact on IMD and STI for the next generation of microelectronic devices. Moreover, this bottom up gap-fill mode is expected to be universal in other chemical vapor deposition systems.

• Bulletin of the Korean Chemical Society
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• v.16 no.6
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• pp.518-523
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• 1995

New square planar nickel(Ⅱ) complexes with various 1-alkyl (4a-4c) and 1-hydroxyalkyl (4d-4f) derivatives of the 14-membered pentaaza macrocycle 8-ethyl-8-nitro-1,3,6,10,13-pentaazacyclotetradecane have been synthesized by two-step metal template condensation reactions of ethylenediamine, nitroethane, formaldehyde, and appropriate primary amines. The nitro group and/or hydroxyl group of 4a-4f are not directly involved in the coordination. The nickel(Ⅱ) complexes exist in coordinating solvents such as MeCN, Me2SO, and H2O as equilibrium mixtures of the square planar [Ni(L)]2+(L=4a-4f) and octahedral species [Ni(L)S2]2+(S=solvent molecule). Although the ligand field strength and redox potentials of the complexes are not affected by the nature of the substituents, the formation of octahedral species for 4d-4f in MeCN is strongly restricted by the hydroxyl group. Synthesis, characterization, and solution behaviors of the nickel(Ⅱ) complexes are described.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.30 no.4
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• pp.131-135
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• 2020

Single crystal phased CaZrO₃ : Eu³⁺ phosphor have been synthesized by skull melting method. The crystal structure, morphology and optical properties of synthesized phosphor were investigated XRD (X-ray diffraction), SEM (scanning electron microscopy), UV (ultraviolet) fluorescence reaction and PL (photo luminescence). The starting materials having chemical composition of CaO: ZrO₂ : Eu₂O₃= 0.962 : 1.013 : 0.025 mol% were charged into a cold crucible. The cold crucible was 120 mm in inner diameter and 150 mm in inner height, and 3 kg of mixed powder (CaO, ZrO₂ and Eu₂O₃) was completely melted within 1 hour at an oscillation frequency of 3.4 MHz, maintained in the molten state for 2 hours, and finally air-cooled. The XRD results show that synthesized phosphor is stabilized in orthorhombic perovskite structure without any impurity phases. The synthesized phosphor could be excited by UV light (254 or 365 nm) and the emission spectra results indicated that bright red luminescence of CaZrO₃ : Eu³⁺ due to magnetic dipole transition ⁵D₀→⁷F₂ at 615 nm was dominant.

• Bulletin of the Korean Chemical Society
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• v.18 no.7
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• pp.730-733
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• 1997

Monofluoroiron(Ⅲ) tetraphenylporphyrin, Fe(TPP)F, and difluoroiron(Ⅲ) tetraphenylporphyrin, [Fe(TPP)F2]- were generated in a various non-aqueous solvents by the reaction between Fe(TPP)Cl and tetrabutylammonium fluoride TBAF 3H2O. Formation of the these complexes was detected by the appearance of the ν(F-Fe) (ν, stretching vibration) at 506 cm-1 for Fe(TPP)F and the ν(F-Fe-F) at 448 cm-1 for [Fe(TPP)F2]-, simultaneously, with 441.6 nm excitation by Resonance Raman (RR) spectroscopy. These assignments were confirmed by observed frequency shifts due to 56Fe/54Fe and TPP/TPP-d8/TPP-N15 isotopic substitutions. Difluoroiron complex is an iron(Ⅲ) high-spin complex with the oxidation sensitive band at 1347 cm-1 for ν4 and core size/spin state sensitive band at 1541 cm-1 for ν2.

• Journal of the korean Society of Automotive Engineers
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• v.12 no.3
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• pp.21-29
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• 1990

Equipments of passenger cars with modern technologies are gaining their importance. Related with such developments, the four-wheel steering system (4WS) was introduced recently to a few passenger cars in the market. The most important research goal on this new steering system is improvement of active safety, in other words, improvement of handling characteristics of vehicle stability and maneuverability. This paper presents a computer-based study about the effects of 4WS system on the vehicle handling characteristics. A simple bicycle model of 2 d.o.f. is used for the development of four wheel control algorithms of 4WS system, and the rear wheel control strategies are applied to a complex vehicle model of 16 d.o.f. for simulation of selected ISO-driving tests. The 4WS systems, which reduce the sideslip angle at the mass center of vehicle to almost zero, show much improved handling characteristics compared to that of the conventional 2WS system. These 4WS systems, however, result in vehicles with eigen-steer characteristics of extreme understeer behaviour.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.3
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• pp.158-164
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• 2000

In recent year, desire and request fer micro automation are growing rapidly covering the whole range of the industry. This has been caused mainly by request of more accurate manufacturing process due to a higher density of integrated circuits in semiconductor industry. This paper presents a six d.o.f fine motion stage using magnetic levitation technique, which is one of actuating techniques that have the potential for achieving such a micro motion. There is no limit in motion resolution theoretically that the magnetically levitated part over a fixed stator can realize. In addition, it Is possible to manipulate the position and the force of the moving part at the same time. Then, the magnetic levitation technique is chosen into the actuating method. However, we discuss issues of design, kinematics, dynamics, and control of the proposed system. And a few experimental results fur step input are given.

• 제어로봇시스템학회:학술대회논문집
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• 1996.10b
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• pp.1519-1522
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• 1996

In this paper, we have developed a tele-robotic system for nozzle dam installation/removal works and tube relating maintenance works inside unclear power plant steam generator. Developed tele-robotic system consists of many hardwares including robot and a control system. Based on the 3 dimensional graphic simulation, a 6 D.O.F. hydraulic actuated robot and a 2 D.O.F. robot install/removal device have been developed. And also we deviced special tools for nozzle dam carry and bolting. For the tele-robot and other devices to be controlled at the nonradioactive area outside reactor containment building, we developed a tele-robot control system consisting of supervisory controller and remote controller.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.1823-1824
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• 2008

We propose a remote controlled robot manipulator using force feedback joystick. User can control easily 5 d.o.f robot manipulator in 3 demensional space using general joystick. A force sensor attached in developed gripper sends signal to main robot controller so as to know gripper grasp the object. The signal also sent to user through force feedback joystick. We designed a dexterous 5 d.o.f robot manipulator analysis the kinematics and inverse kinematics. The robot was simply developed using serial RC motor. As a main robot controller, we use 32bit MPU(AT91SAM7256) and micro C/OS. To show the validity of our developed robot, a several experiments were demonstrated.

• Microbiology and Biotechnology Letters
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• v.49 no.1
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• pp.24-31
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• 2021

This study aimed to investigate the melanogenesis inhibitory activity of epicatechin-3-O-gallate (ECG) isolated from Polygonum amphibium L. ECG was isolated from the ethanol extract of P. amphibium L, and its chemical structure was determined using spectroscopic methods such as LC-ESI-MS, 1D-NMR, and UV spectroscopy. ECG inhibited the melanogenesis of B16F10 cells in a dose-dependent manner. Particularly, it decreased the melanin content by 27.4% at 200 µM concentration, compared with the control, in B16F10 cells, without causing cytotoxicity. It is noteworthy that the expression of three key proteins, including tyrosinase, tyrosinase-related protein-1 (TRP-1), TRP-2, and microphthalmia-associated transcription factor (MITF), involved in melanogenesis, is significantly inhibited by ECG. The ECG isolated in this study caused the inhibition of body pigmentation and tyrosinase activity in vivo in the zebrafish model. These results suggest that the ECG isolated from P. amphibium L. is an effective anti-melanogenesis agent.