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Electronic structures of Na adsorbed 6H-SiC(0001) $\sqrt{3}$$\times$$\sqrt{3}$ and 3$\times$3 surfaces

  • 조은상;임규욱;황찬국;김용기;이철환;박종윤;임규욱
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.144-144
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    • 2000
  • 이전에 수행된 연구에서 표면에 수직하게 dangling bond를 가지는 adatom으로 장식된 6H-SiC(0001) {{{{ SQRT { 3} }}}}$\times${{{{ SQRT { 3} }}}} 표면은 단일 전자 모형으로는 설명되어지지 않는 반도체적 성질을 가지는 것으로 보고되어졌다. 최근의 많은 이론적, 실험적 결과는 이 표면이 Mott-Hubbard 모형으로 설명되어질 수 있음이 보고되어졌다. 이 표면에서 Si이 좀 더 풍부한 3$\times$3 표면의 여러 모형들에 대해 이론적, 실험적 연구는 Energy적으로 E-J 모형이 가장 안정하다고 보고하였다. E-J모형은 표면에 수직인 dagling bond를 가지며 6H-SiC(0001) {{{{ SQRT { 3} }}}}$\times${{{{ SQRT { 3} }}}} 표면에 비해 1/3배의 밀도를 지닌다. 또한 최근의 연구에서 3$\times$3 표면 또한 단일 전자모형은 이 표면의 반도체적 성질에 위배되며 Mott-Hubbard 모형으로 설명되어질수 있음이 보고되어졌다. 이러한 표면 위에 알칼리금속인 Na을 흡착시키면서 일함수의 변화와 Valence Band의 변화를 측정하였다. XPS를 이용하여 Na이 흡착되면서 발생되는 Si과 C의 내각준위의 변화를 측정하였다. 6-SiC(0001) {{{{ SQRT { 3} }}}}$\times${{{{ SQRT { 3} }}}} 과 3$\times$3 표면 구조 모델을 Na을 흡착한 6H-SiC(0001) {{{{ SQRT { 3} }}}}$\times${{{{ SQRT { 3} }}}} 과 3$\times$3 표면으로부터 측정한 UPS, XPS data들로부터 지금까지 제기되어 있는 각 재배열 구조 모형들을 비교 검토하였다.

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Effect of Y2O3 and La2O3 on the Sintering Behavior of Alumina (Y2O3 및 La2O3 첨가가 알루미나의 소결거동에 미치는 영향)

  • Lee, Keun Bong;Kang, Jong Bong
    • Korean Journal of Materials Research
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    • v.26 no.2
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    • pp.90-94
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    • 2016
  • In this study, to increase the strength and enhance the sintering property of $Al_2O_3$, $Y_2O_3$ and $La_2O_3$ were added; the effects of these additions on the sintering characteristics of $Al_2O_3$ were observed. Adding 1% of $Y_2O_3$ to $Al_2O_3$ repressed the development of abnormal particles and reduced the grain boundary migration of $Al_2O_3$, curbing pores to capture particles; as such, the material showed a fine microstructure. But, when over 2% of $Y_2O_3$ was added, the sintering property was reduced because of abnormal particle grain growth and pore formation in particles. Adding 1% of $Y_2O_3$ and $La_2O_3$ to $Al_2O_3$ led to the development of abnormal particles and formed pores in the particles; when over 3% of $La_2O_3$ was added, the sintering property was reduced because the shape of the $Al_2O_3$ particles changed to angled plates.

Dialkylaminomethylation of 1,4-Dihydropyridine (1,4-Dihydropyridine의 Dialkylaminomethyl화 유도체의 합성)

  • Suh, Jung-Jin;Hong, You-Hwa
    • YAKHAK HOEJI
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    • v.33 no.5
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    • pp.280-284
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    • 1989
  • When 2,6-Dimethyl-4-(3'-nitrophenyl)-1,4-dihydropyridine-3,5-dicarboxylic acid 3-mono methyl ester(3) was reacted with dimethyl methylene ammonium chloride (5a) and $K_2CO_3$ in DMF, 2,6-dimethyl-4-(3'-nitrophenyl)-5-(N,N-dimethylamino)methyl-1,4-dihydropyridine-3-carboxylic acid methyl ester (6a) was obtained in 41% yield. As the same procedure with compound (3) and the other dialkylaminomethylating reagents (5b, c, d, e), 2,6-dimethyl-4-(3'-nitrophenyl)-5-(N,N-diethylamino)methyl-1,4-dihydropyridine-3-carboxylic acid methylester(6b), 2,6-dimethyl-4-(3'-nitrophenyl)-5-(1'-pyrrolidinyl)methyl-1,4-dihydropyridine-3-carboxylic acid methyl ester (6c), 2,6-dimethyl-4-(3'-nitrophenyl)-5-(1'-piperidinyl)methyl-1,4-dihydropyridine-3-carboxylic acid methyl ester (6d) and 2,6-dimethyl-4-(3'-nitrophenyl)-5-(1'-morpholinyl)methyl-1,4-dihydropyridine-3-carboxylic acid methyl ester (6e) were obtained in 28%, 49%, 48% and 18% yield respectively.

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Standardization Trends of 3D Video Coding in MPEG (3D 비디오 MPEG 표준화 동향)

  • Um, G.M.;Bang, G.;Hur, N.H.;Kim, J.W.
    • Electronics and Telecommunications Trends
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    • v.24 no.3
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    • pp.61-68
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    • 2009
  • UHDTV와 함께 HDTV 이후의 차세대 방송기술로서 전세계적으로 연구되고 있는 3DTV 방송 기술은 시청자에게 보다 사실적 이고 현장감 있는 3D 비디오 콘텐츠를 제공한다. 최근 미국 헐리우드를 중심으로 활성화되고 있는 3D 입체 영화 시장 성장, 다수의 디스플레이 업체들에 의한 3D 지원 디스플레이 발표, 휴대단말에서의 3D 데이터 및 비디오 서비스, 가정에서의 3D 비디오 서비스를 위한 3D@Home 표준화 작업, 3D4YOU를 중심으로 한 3D 비디오 콘텐츠의 생성기술과 배포 포맷에 관한 연구, 다시 점 3DTV 서비스 등을 위한 MPEG에서의 3DV 표준화 등 관련 기술 개발 및 표준화가 이뤄지고 있다. 본 고에서는 MPEG 3DV 그룹에서 진행중인 3DV부호화 기술 표준화 진행 현황과 기고 주요 기술에 대해 설명하고, 향후 3D 비디오 표준화 진행 전망에 대해 다루기로 한다.

Influence on Dielectric Properties and Evaporation of PbO According to Substituting $Nd^{3+}$ for $Pb^{2+}$ in $Pb(Mg_{1/3}Nb_{2/3})O_3$ System ($Pb(Mg_{1/3}Nb_{2/3})O_3$계 세라믹스의 $Pb^{2+}$$Nd^{3+}$로 치환함에 따른 유전특성 및 PbO 휘발에 관한 연구)

  • 김성열;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.175-180
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    • 1993
  • Influence of Nd3+ substitution for Pb2+ on the dielectric properties and the PbO evaporation according to substituting Nd3+ for Pb2+ in Pb(Mg1/3Nb2/3)O3 system ceramics have been investigated. The dielectric constant at the curie temperature and evaporation of PbO were decreased with increase of Nd3+ amounts. The percentage of PbO evaporation was 2.5wt% in the PMN system substituted Nd3+ for Pb2+, while it was 3.7wt% in the PMN system.

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Modeling and Animation Implementation of 3D Humanoid base on the X3D (X3D 기만에서의 3차원 Humanoid 모델링과 애니메이션 구현)

  • 이성태;오근탁;김이선;이윤배
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.6 no.7
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    • pp.1089-1094
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    • 2002
  • We can travel every imaginary world and do every impossible thing via 3D character. People interest in 3D character animation for modeling like real world due to the increase of 3D game and imaginary Virtual Reality on the internet. In this paper, new framework for present of 3D character of high quality is applied. I represent 3-dimensional Humanoid modeling and animation technology and show the adequacy via simulation for various and natural representation certificate using VRML as a Web3D information type and XML.

Synthesis of Anticoagulant 2-Chloro-3-(N-Arylamino)-1,4-Naphthoquinones (항응고성의 2-Chloro-3-(N-Arylamino)-1,4-Naphthoquinone 유도체 합성)

  • Ryu, Chung-Kyu
    • YAKHAK HOEJI
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    • v.32 no.4
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    • pp.245-250
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    • 1988
  • Naphthoquinone derivatives have been found to be anticoagulant. In this report, several new 2-chloro-3-(N-arylamino)-naphthoquinone derivatives were synthesized in oder to develope mild anticoagulant. 2, 3-dichloro-1, 4-naphthoquinone was reacted with p-aminobenzoic acid, m-aminobenzoic acid, toluidine, m-nitroaniline, sulfanilamide, sulfathiazole, sulfaguanidine, phenetidine, 2-aminopyrimidine and 3-amino-5-methylisoxazole in EtOH or AcOH afford 2-chloro-3-(p-carboxy anilino)-naphthoquinone (1), 2-chloro-3-(m-carboxyanilino)-naphthoquinone (2),2-chloro-3-(toluidino)-naphthoquinone (3),2-chloro-3-(m-nitroanilino)-naphthoquinone (4), 2-chloro-3-(4-sulfanilanilino)-naphthoquinone (5), 2-chloro-3-(4-sulfathiazolino)-naphthoquinone (6),2-chloro-3-(4-sulfaguanidino)-naphthoquinone (7),2-chlro-3-(phenetidino)-naphthoquinone (8), 2-chloro-3-(pyrimidine-2-amino)-naphthoquinone (9) and 2-chloro-3-(5-methylisoxazole-3-amino)-naphthoquinone (10) in good yield.

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3D Active Appearance Model for Face Recognition (얼굴인식을 위한 3D Active Appearance Model)

  • Cho, Kyoung-Sic;Kim, Yong-Guk
    • 한국HCI학회:학술대회논문집
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    • 2007.02a
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    • pp.1006-1011
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    • 2007
  • Active Appearance Models은 객체의 모델링에 널리 사용되며, 특히 얼굴 모델은 얼굴 추적, 포즈 인식, 표정 인식, 그리고 얼굴 인식에 널리 사용되고 있다. 최초의 AAM은 Shape과 Appearance가 하나의 계수에 의해서 만들어 지는 Combined AAM이였고, 이후 Shape과 Appearance의 계수가 분리된 Independent AAM과 3D를 표현할 수 있는 Combined 2D+3D AAM이 개발 되었다. 비록 Combined 2D+3D AAM이 3D를 표현 할 수 있을지라도 이들은 공통적으로 2D 영상을 사용하여 모델을 생산한다. 본 논문에서 우리는 stereo-camera based 3D face capturing device를 통해 획득한 3D 데이터를 기반으로 하는 3D AAM을 제안한다. 우리의 3D AAM은 3D정보를 이용해 모델을 생산하므로 기존의 AAM보다 정확한 3D표현이 가능하고 Alignment Algorithm으로 Inverse Compositional Image Alignment(ICIA)를 사용하여 빠르게 Model Instance를 생산할 수 있다. 우리는 3D AAM을 평가하기 위해 stereo-camera based 3D face capturing device로 촬영해 수집한 한국인 얼굴 데이터베이스[9]로 얼굴인식을 수행하였다.

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Reaction Mechanism in the Formation of PMN-PT-BT Solid Solution (PMN-PT-BT 고용체의 합성반응기구)

  • Park, Hyun;Lee, Eung-Sang
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1443-1448
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    • 1994
  • Pb(Mg1/3Nb2/3)O3-PbTiO3-BaTiO3 solid solution was formed by mixed-oxide method. The phase during formation was analysed by XRD and formation mechanism was investigated. While heat-treating Pb(Mg1/3Nb2/3)O3 composition, the first, Pb2Nb2O7 and Pb3Nb2O8 pyrochlore phases are formed, and finally Pb(Mg1/3Nb2/3)O3 perovskite phase with containing Pb3Nb4O13 pyrochlore phase is obtained at 80$0^{\circ}C$. When Pb(Mg1/3Nb2/3)O3 composition is modified with PbTiO3 which have strong ionic bonding and high tolerance factor, the amount of pyrochlore phase is decreased by increasing of stability in perovskite structure.

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Synthesis of Novel 1,2-Diazepino[3,4-b]quinoxaline and Pyridazino[3,4-b]quinoxaline Derivatives (새로운 1,2-Diazepino[3,4-b]quinoxaline과 Pyridazino[3,4-b]quinoxaline)

  • Kim, Ho Sik;Jeong, Geuk
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.302-306
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    • 1999
  • The 1,3-dipolar cycloaddition reaction of the quinoxaline 4-oxide 10 with 2-chloroacrylonitrile gave the 2,3-dihydro-lH-1,2-diazepino[3,4-blquinoxalines lla, b, respectively, which were converted into the 2,3,4,6-tetrahydro-lH-l,2-diazepino[3,4-b]quinoxaline 12. The reaction of compound lla with selenium dioxide in acetic acid/water resulted in ring transformation to give the 1,4-dihydro-4-oxopyridazino[3,4-blquinoxaline 13.

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