• Title/Summary/Keyword: 2nd phase

Search Result 592, Processing Time 0.024 seconds

Electrochemical Behavior of Li-B Alloy Anode - Liquid Cadmium Cathode (LCC) System for Electrodeposition of Nd in LiCl-KCl

  • Kim, Gha-Young;Shin, Jiseon;Kim, Tack-Jin;Shin, Jung-Sik;Paek, Seungwoo
    • Journal of the Korean Electrochemical Society
    • /
    • v.18 no.3
    • /
    • pp.102-106
    • /
    • 2015
  • The performance of Li-B alloy as anode for molten salt electrolysis was firstly investigated. The crystalline phase of the prepared Li-B alloy was identified as $Li_7B_6$. The potential profile of Li-B alloy anode was monitored during the electrodeposition of $Nd^{3+}$ onto an LCC (liquid cadmium cathode) in molten LiCl-KCl salt at $500^{\circ}C$. The potential of Li-B alloy was increased from -2.0 V to -1.4 V vs. Ag/AgCl by increasing the applied current from 10 to $50mA{\cdot}cm^{-2}$. It was found that not only the anodic dissolution of Li to $Li^+$ but also the dissolution of the atomic lithium ($Li^0$) into the LiCl-KCl eutectic salt was observed, following the concomitant reduction of $Nd^{3+}$ by the $Li^0$ in Li-B alloy. It was expected that the direct reduction could be restrained by maintaining the anode potential higher that the deposition potential of neodymium.

Design and Performance Analysis of CPSK Transmitter for RF-CBTC System in ISM Band (RF-CBTC 시스템을 위한 ISM 대역에서의 CPSK 송신기의 설계 및 성능분석)

  • Kim, Seong-Cheol
    • The Journal of The Korea Institute of Intelligent Transport Systems
    • /
    • v.16 no.5
    • /
    • pp.152-161
    • /
    • 2017
  • The CBTC(Communication based Train Control) system employed on 2.4GHz ISM band adopt the IEEE802.11.x standard. Therefor communication time delay, distortion and data losses will be produced. To overcome these problems, CPSK(Continuous Phase shift keying) modulated DS/SS(Direct Sequence Spread Spectrum) transmitter with 908MHz carrier frequency is proposed. Through the eye diagram and scatter diagram the performance is analysed. And the phase noise characteristic of the local oscillator is measured about 60dBc/Hz, this means that the phase noise performance is very good compared to the signal. Reference frequency suppression of the 2nd local oscillator is 50dB below compared to the signal. Through the polarities of the complementary signal equally probable, the line spectrum of the output spectrum is eliminated. The nonlinear effects which introduce the spectral spreading or spectral regeneration is reduced remarkably.

MULTI-SCALE MODELING AND ANALYSIS OF CONVECTIVE BOILING: TOWARDS THE PREDICTION OF CHF IN ROD BUNDLES

  • Niceno, B.;Sato, Y.;Badillo, A.;Andreani, M.
    • Nuclear Engineering and Technology
    • /
    • v.42 no.6
    • /
    • pp.620-635
    • /
    • 2010
  • In this paper we describe current activities on the project Multi-Scale Modeling and Analysis of convective boiling (MSMA), conducted jointly by the Paul Scherrer Institute (PSI) and the Swiss Nuclear Utilities (Swissnuclear). The long-term aim of the MSMA project is to formulate improved closure laws for Computational Fluid Dynamics (CFD) simulations for prediction of convective boiling and eventually of the Critical Heat Flux (CHF). As boiling is controlled by the competition of numerous phenomena at various length and time scales, a multi-scale approach is employed to tackle the problem at different scales. In the MSMA project, the scales on which we focus range from the CFD scale (macro-scale), bubble size scale (meso-scale), liquid micro-layer and triple interline scale (micro-scale), and molecular scale (nano-scale). The current focus of the project is on micro- and meso-scales modeling. The numerical framework comprises a highly efficient, parallel DNS solver, the PSI-BOIL code. The code has incorporated an Immersed Boundary Method (IBM) to tackle complex geometries. For simulation of meso-scales (bubbles), we use the Constrained Interpolation Profile method: Conservative Semi-Lagrangian $2^{nd}$ order (CIP-CSL2). The phase change is described either by applying conventional jump conditions at the interface, or by using the Phase Field (PF) approach. In this work, we present selected results for flows in complex geometry using the IBM, selected bubbly flow simulations using the CIP-CSL2 method and results for phase change using the PF approach. In the subsequent stage of the project, the importance of effects of nano-scale processes on the global boiling heat transfer will be evaluated. To validate the models, more experimental information will be needed in the future, so it is expected that the MSMA project will become the seed for a long-term, combined theoretical and experimental program.

Performance Analysis of Incremental Cooperative Communication with Relay Selection Based on The Relays Arrangement (중계기 선택 기법이 적용된 증분 협력 통신의 중계기 배치에 따른 성능 분석)

  • Kim, Lyum;Kong, Hyung-Yun
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.22 no.10
    • /
    • pp.941-950
    • /
    • 2011
  • In this paper, we analysis the end-to-end performance of the incremental cooperative communication with relay selection. In the conventional cooperative scheme, the source(S) broadcasts the signal to the relay(R) and the destination(D) at 1st phase, and the R forwards the signal to the D at 2nd phase. Although this scheme can improve performance and provide diversity gain, it suffers from decreasing spectrum efficiency. In order to overcome this problem, the incremental cooperative model can be used. In this paper, we study two incremental cooperative method : the first uses ARQ with threshold SNR and the second uses HARQ with channel coding. we also evaluated performance of the incremental cooperative communication based on the R arrangement by using both methods.

A study of the synthesis and the properties on microwave dielectric material of $BaO-Sm_2O_3-TiO_2$ system ($BaO-Sm_2O3-TiO_2$계 마이크로파 유전체의 합성 및 그 특성에 관한 연구)

  • 이용석;김준수;이병하
    • Electrical & Electronic Materials
    • /
    • v.10 no.3
    • /
    • pp.274-283
    • /
    • 1997
  • These days, according to surprising development of communication enterprises, every soft of devices is getting smaller and cheaper. Among these Devices, microwave dielectric ceramics are studied and progressed briskly as the materials of dielectric resonator. Dielectric properties of BaO-S $M_{2}$ $O_{3}$-Ti $O_{2}$, one of the BaO Lnsub 2/ $O_{3}$-Ti $O_{2}$ (Ln=La, Sm, Nd, Pr…) system, synthesized by solid-reaction and coprecipitation method were investigated. Disk-type samples were sintered at 1250-1400.deg. C for 2hrs. As a result, single phase was not synthesized in both method. First created the second phase of S $M_{2}$ $Ti_{2}$ $O_{7}$, and then the last phase of $Ba_{3.75}$S $m_{9.5}$ $Ti_{18}$ $O_{54}$, Ti $O_{2}$, and $Ba_{2}$ $Ti_{9}$ $O_{20}$. When the sample was sintered at 1280.deg. C (in solid reaction method) and at 1310.deg. C (in coprecipitation method), it obtained highest dielectric constant (72.96 and 71.70, respectively) and high Q value. Above that temperature, dielectric constant and Q value decreased because of lattice defect according to oxygen vacancies........

  • PDF

A Study on the Formation of Octanenitrile as a Precursor for Synthesis of Carboxylic Acid (카르복실산 합성전구체(合成前驅體)로서의 옥탄니트릴의 생성반응(生成反應)에 관(關한) 연구(硏究))

  • Kim, Yong-In;Oh, Yang-Hwan;Kim, Kwang-Sik;Lee, Dong-Woo
    • Journal of the Korean Applied Science and Technology
    • /
    • v.6 no.2
    • /
    • pp.29-37
    • /
    • 1989
  • Using the quarternary ammonium salts as phase transfer catalyst, the nucleophilic substitution reaction of 1-chlorooctane with sodium-cyanide was investigate kinetically with respect to the formation of octanenitrile. The product was analyzed with gas chromatograph, and quantity of octanenitrile was measured. The reaction condition was considered by the effect of the reaction temperature, of the species and the amount of catalyst, of the speed of strirring, and of the concentration of reactants. The reaction was carried out in the first order on the concentration of 1-chlorooctane and sodium cyanide, respectively. The over-all order was 2nd. The activation energies for the nucleophilic substitution reaction of 1-chlorooctane and 1-bromooctane under tetrabutylammonium hydrogen-sulfate were calculated as 2.05 and 10.08kcal/mol, respectively. The effect of various caltalysts was decreased in the order of tetrabutylammonium bromide, terabutylammonium, tetrabutylammonium hydrogensulfate, and tetrabutylammonium iodide. The reaction rate was dependent on the concentration of sodium-cyanide dissolved in the aqueous phase, and the good result was shown when the mol ratio between 1-chlorooctane and sodium cyanide was one per three.

CAVITATION FLOW SIMULATION FOR A 2-D HYDROFOIL USING A HOMOGENEOUS MIXTURE MODEL ON UNSTRUCTURED MESHES (비정렬 격자계에서 균질혼합 모델을 이용한 2차원 수중익형 주위의 캐비테이션 유동 해석)

  • Ahn, S.J.;Kwon, O.J.
    • Journal of computational fluids engineering
    • /
    • v.17 no.1
    • /
    • pp.94-100
    • /
    • 2012
  • In this paper, the cavitating flows around a hydrofoil have been numerically investigated by using a 2-d multi-phase RANS flow solver based on pseudo-compressibility and a homogeneous mixture model on unstructured meshes. For this purpose, a vertex-centered finite-volume method was utilized in conjunction with 2nd-order Roe's FDS to discretize the inviscid fluxes. The viscous fluxes were computed based on central differencing. The Spalart-Allmaras one equation model was employed for the closure of turbulence. A dual-time stepping method and the Gauss-Seidel iteration were used for unsteady time integration. The phase change rate between the liquid and vapor phases was determined by Merkle's cavitation model based on the difference between local and vapor pressure. Steady state calculations were made for the modified NACA66 hydrofoil at several flow conditions. Good agreements were obtained between the present results and the experiment for the pressure coefficient on a hydrofoil surface. Additional calculation was made for cloud cavitation around the hydrofoil. The observation of the vapor structure, such as cavity size and shape, was made, and the flow characteristics around the cavity were analyzed. Good agreements were obtained between the present results and the experiment for the frequency and the Strouhal number of cavity oscillation.

Improving Thermal Resisting Property of PZT Ceramics by Thermal Aging (열에이징에 의한 PZT세라믹스의 내열특성 개선)

  • Lee, Gae-Myung;Kim, Byung-Hyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.18 no.1
    • /
    • pp.43-49
    • /
    • 2005
  • Temperature stabilities of resonance frequencies of the substrates are very important in piezoelectric ceramics oscillators and fitters. In this study, it was investigated thermal resisting property of the length-extensional vibration mode of PZT ceramics. The mode can be utilized in fabricating ultra-small 55 kHz IF devices. We fabricated the ceramic specimens with x = 0.51, 0.52, 0.53, 0.54, and 0.55 in the Pb(Zr$\sub$x/Ti$\sub$1-x/)O$_3$ system. And their resonance frequencies were measured before 1st thermal aging, after 1st and 2nd thermal aging. In order to investigate the influence of thermal aging on thermal resisting properties, thermally aged specimens were once mote thermally aged. Before 1st thermal aging, the specimens of the compositions with morphotropic phase, x = 0.53 and rhombohedral phase, x = 0.54 have weak thermal resisting property of resonance frequency, while tetragonal phase, x = 0.51 has robust thermal resisting property of resonance frequency. 1st thermal aging improved thermal resisting property of resonance frequency in all specimens.

ACCURACY AND EFFICIENCY OF A COUPLED NEUTRONICS AND THERMAL HYDRAULICS MODEL

  • Pope, Michael A.;Mousseau, Vincent A.
    • Nuclear Engineering and Technology
    • /
    • v.41 no.7
    • /
    • pp.885-892
    • /
    • 2009
  • This manuscript will discuss a numerical method where the six equations of two-phase flow, the solid heat conduction equations, and the two equations that describe neutron diffusion and precursor concentration are solved together in a tightly coupled, nonlinear fashion for a simplified model of a nuclear reactor core. This approach has two important advantages. The first advantage is a higher level of accuracy. Because the equations are solved together in a single nonlinear system, the solution is more accurate than the traditional "operator split" approach where the two-phase flow equations are solved first, the heat conduction is solved second and the neutron diffusion is solved third, limiting the temporal accuracy to $1^{st}$ order because the nonlinear coupling between the physics is handled explicitly. The second advantage of the method described in this manuscript is that the time step control in the fully implicit system can be based on the timescale of the solution rather than a stability-based time step restriction like the material Courant limit required of operator-split methods. In this work, a pilot code was used which employs this tightly coupled, fully implicit method to simulate a reactor core. Results are presented from a simulated control rod movement which show $2^{nd}$ order accuracy in time. Also described in this paper is a simulated rod ejection demonstrating how the fastest timescale of the problem can change between the state variables of neutronics, conduction and two-phase flow during the course of a transient.

Application of a solid-phase fluorescence immunoassay to determine ampicillin residues in muscle tissue of olive flounder (Paralichthys olivaceus)

  • Jung, Won Chul;Ha, Ji Young;Chung, Hee Sik;Heo, Sung Hyeok;Kim, Suk;Lee, Hu Jang
    • Korean Journal of Veterinary Research
    • /
    • v.46 no.3
    • /
    • pp.291-294
    • /
    • 2006
  • $Parallux^{TM}$, a solid-phase fluorescence immunoassay(SPFIA) developed for antibiotics residue detection in milk, was applied for analysis of fish muscle. The recommended therapeutic dose of ampicillin(100 mg/kg body weight, withdrawal period 7 days) was orally administered to a group of 25 olive flounders(Paralichthys olivaceus) for consecutive five days. Muscle was sampled after drug treatment 1st, 2nd, 3rd, 4th and 5th day. The concentration of ampicillin in muscle, determined by SPFIA, was compared with that of internal standard(10 ppb as ampicillin). The absorbance ratio of sample to internal standard(Bs/Bo) was employed as an index to determine the muscle residue in olive flounder. To investigate the recovery rate, the standard solutions were added to muscle samples to give final concentrations in muscle of 10 and 50 ng/ml. The recovery rates of all spiked samples were > 89% of the spiked value. Ampicillin was detected in muscle of fishes treated until the 3rd day of withdrawal period. The present study showed that the SPFIA can be easily adopted in predicting tissue residues for ampicillin in farmed fishes.