• Title/Summary/Keyword: 2D solid

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Electrochemical Lithium Intercalation within Graphite from Ionic Liquids containing BDMI+ Cation (BDMI+ 양이온을 함유한 이온성 액체로부터 흑연으로의 전기화학적 리튬 삽입)

  • Lee, You-Shin;Jeong, Soon-Ki;Lee, Heon-Young;Kim, Chi-Su
    • Journal of the Korean Electrochemical Society
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    • v.13 no.3
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    • pp.186-192
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    • 2010
  • In situ electrochemical atomic force microscopy (ECAFM) observations of the surface of highly oriented pyrolytic graphite (HOPG) was performed before and after cyclic voltammetry in lithium bis(fluorosulfonyl)imide (LiTFSI) dissolved in 1-buthyl-2,3-dimethylimidazolium (BDMI)-TFSI to understand the interfacial reactions between graphite and BDMI-based ionic liquids. The formation of blisters and the exfoliation of graphene layers by the intercalation of $BDMI^+$ cations within HOPG were observed instead of reversible lithium intercalation and de-intercalation. On the other hand, lithium ions are reversibly intercalated into the HOPG and de-intercalatied from the HOPG without intercalation of the $BDMI^+$ cations in the presence of 15 wt% of 4.90 mol/$kg^{-1}$ LiTFSI dissolved in propylene carbonate (PC). ECAFM results revealed that the concentrated PC-based solution is a very effective additive for preventing $BDMI^+$ intercalation through the formation of solid electrolyte interface (SEI).

Effect of Gas Channel/Rib Width in Solid Oxide Fuel Cells (고체산화물 연료전지에서 가스채널/리브 폭의 영향에 관한 연구)

  • Jeon, Dong Hyup;Shin, Dong-Ryul;Ryu, Kwang-Hyun;Song, Rak-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.2
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    • pp.109-115
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    • 2017
  • Using the computational fluid dynamics (CFD) technique, we performed a numerical simulation in anodesupported solid oxide fuel cell (SOFC). The effect of gas channel/rib width on the cell performance and temperature uniformity was investigated in planar type SOFC. The open source CFD toolbox, OpenFOAM, was used as a numerical analysis tool. As a result, the effect of gas channel/rib width on the cell performance and temperature uniformity was not significant if the oxygen depletion is not occurring. On the other hand, the usage of a wide rib and operation at high current density may lead to performance degradation due to oxygen depletion.

Development of SSPA-based X-band Transmitter with Graceful Degradation (점진적 성능저하 기능을 가지는 X-대역 SSPA 송신장치 개발)

  • Song, Hyeong-Min;Kim, Ji-Deok;Kang, Hyun-Chul;Song, Jae-Gyeong;Park, Chul-Soon;Rhee, Kye-Jin;Lee, Choung-Hyun;Kim, Dong-Gil
    • The Journal of the Korea institute of electronic communication sciences
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    • v.14 no.5
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    • pp.853-862
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    • 2019
  • In this paper, we designed a 4.5kW X-band SSPA transmitter to replace the TWTA search radar transmitter with low MTBF and high maintenance cost. The transmitter is designed for the performance of over 520W average transmission output and 4.0kW maximum transmission output. In particular, by implementing a graceful degradation, it is designed to maintain better performance than conventional TWTA transmitter up to 40% (13 assembly modules) failure level of 200W power amplifier assembly. Through an experiment on the effective range of X-band, the performance of proposed transmitter verified the values of the maximum transmission output 6.1kW, spurious output 69.16dBc, RF pulse rising time 15.2ns and RF pulse falling time 16.3ns. The experiment confirmed the change of output power according to the graceful degradation due to fault injection.

Study on design of the composite torque link for a landing gear system of a helicopter (헬리콥터 착륙장치를 위한 복합재 토크링크의 설계에 대한 연구)

  • Kim, Jin-Bong;Um, Moon-Kwang;Lee, Sang-Yong;Kim, Tae-Uk;Shin, Jeong-Woo
    • Composites Research
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    • v.22 no.2
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    • pp.30-36
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    • 2009
  • In this paper, we propose the design method for the composite torque link of a landing gear for a helicopter. The composite torque link has to be light weighted and very stiff to keep the shock absorber in the landing gear of helicopter. The configuration and structural shape has to be designed in consideration of the RTM (Resin Transfer Molding) manufacturing process which is adopted to minimize the manufacturing cost. The mechanical properties are obtained through the coupon tests with the specimens made by the same manufacturing process for the composite structure. The optimal design process was performed through iterative modifications of the models which were verified by stress analysis using FEM. The composite torque link has lug-shaped parts and is very thick, so 3D Layered solid elements of ABAQUS were used to get the stress field including the stress components in thickness direction and non-linear static analysis using contact B.C. of rigid-deform condition was used to get the optimal design.

A Study on Methanogenic Bacteria-Activated Leachate Recirculation Method for Enhancing Waste Stabilization and Landfill Gas Production from a Solid waste Landfill (매립가스 발생량 및 폐기물 안정화 촉진을 위한 메탄생성균 활성 침출수 재순환 공법에 관한 연구)

  • Park, Jin-Kyu;Kang, Jeong-Hee;Chong, Yong-Gil;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.2
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    • pp.66-75
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    • 2012
  • The objective of this study was to assess the effects of methanogenic bacteria-activated leachate recirculation method for enhancing waste stabilization and landfill gas production from a solid waste landfill. To simulate a conventional landfill (Lys-A), a landfill recirculated only fresh leachate (Lys-B), and two landfills recirculated leachate after pretreating with ASBR (Lys-C and Lys-D), four lysimeters were operated over a period of 4 years. Lys-D was recirculated two times of pretreated leachate volume than that of Lys-C. In the case of the landfill recirculated only fresh leachate and the landfill recirculated leachate after pretreating with ASBR, methane productions were increased until about 600 days, but there were not effect of leachate recirculation for enhancing methane production after about 600 days. It was assumed that leachate recirculation into fewer biodegradable organic wastes had not effect to enhance landfill gas production. Lys-C and Lys-D showed the highest performance for enhancing cumulative methane yield as well as acceleration waste stabilization. In cumulative methane yield, Lys-C (35.51 mL $CH_4/g$ VS) and Lys-D (36.12 mL $CH_4/g$ VS) were much higher than Lys-A (28.37 mL $CH_4/g$ VS) and Lys-B (30.07 mL $CH_4/g$ VS). In case of between Lys-B and Lys-C with the same recirculation rate, COD concentration in Lys-C was more rapidly decreased compared with that in Lys-B. This was attributed to the presence of methanogenic bacteria as well as dilution of inhibitory substances by the methanogenic bacteria-activated leachate recirculation. Therefore, the landfill recirculated leachate after pretreating with ASBR was found to be the most appropriate operating techniques for enhancing waste stabilization and landfill gas production.

A Study on Combustion Characteristics of Hybrid Rocket with the Variation of L/D Ratio (하이브리드 로켓의 L/D 비 변화에 따른 연소특성 연구)

  • Kim Soo-Jong;Kim Jin-Kon;Lee Seung-Chul;You Woo-Jun;Lee Jung-Pyo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.4
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    • pp.31-38
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    • 2005
  • In this paper, the combustion characteristics of a hybrid propulsion system were studied with various L/D(length vs diameter) ratio of the single po.1 type solid fuel. Experiments were performed for 2 cases with the fixed grain port diameter and fuel length respectively. For the first case, results show that there are no large variations for regression rates as the L/D ratio changes. And as the L/D ratio increases, the O/F ratio decreases and thrust, characteristic velocity tends to increase. For the second case, there is no large change for O/F ratio, thrust and characteristic velocity as L/D ratio changes. On the other hand, as the L/D ratio decreases, only the regression rate tends to increase. Experimentally, exponent n in $\dot{r}=a{G_0}^n$ was found about 0.5 and then the O/F ratio was shown nearly constant. In the experiment, PE and gas oxygen were used as a fuel and an oxidizer.

Effect of Mn on Dielectric and Piezoelectric Properties of 71PMN-29PT [71Pb(Mg1/3Nb2/3)O3-29PbTiO3] Single Crystals and Polycrystalline Ceramics

  • Oh, Hyun-Taek;Joo, Hyun-Jae;Kim, Moon-Chan;Lee, Ho-Yong
    • Journal of the Korean Ceramic Society
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    • v.55 no.2
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    • pp.166-173
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    • 2018
  • In order to investigate the effect of Mn on the dielectric and piezoelectric properties of PMN-PT [$Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$], four different types of 71PMN-29PT samples were prepared using the solid-state single crystal growth (SSCG) method: (1) Undoped single crystals, (2) undoped polycrystalline ceramics, (3) Mn-doped single crystals, and (4) Mn-doped polycrystalline ceramics. In the case of single crystals, the addition of 0.5 mol% Mn to PMN-PT decreased the dielectric constant ($K_3{^T}$), piezoelectric charge constant ($d_{33}$), and dielectric loss (tan ${\delta}$) by about 50%, but increased the coercive electric field ($E_C$) by 50% and the electromechanical quality factor ($Q_m$) by 500%, respectively. The addition of Mn to PMN-PT induced an internal bias electric field ($E_I$) and thus specimens changed from piezoelectrically soft-type to piezoelectrically hard-type. This Mn effect was more significant in single crystals than in ceramics. These results demonstrate that Mn-doped 71PMN-29PT single crystals, because they are piezoelectrically hard and simultaneously have high piezoelectric and electromechanical properties, have great potential for application in fields of SONAR transducers, high intensity focused ultrasound (HIFU), and ultrasonic motors.

Influence of Lighting Schedule and Nutrient Density in Broiler Chickens: Effect on Growth Performance, Carcass Traits and Meat Quality

  • Li, Wen-Bin;Guo, Yan-Li;Chen, Ji-Lan;Wang, Rong;He, Yao;Su, Dong-Ge
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.11
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    • pp.1510-1518
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    • 2010
  • The study was conducted to evaluate the effect of lighting schedule and nutrient density on growth performance, carcass traits and meat quality of broiler chickens. A total of 576 day old Arbor Acre male chickens was used with a $4{\times}2$ factorial arrangement. The four lighting schedules were continuous (23 L:1 D, CL), 20 L:4 D (12 L:2 D:8 L:2 D), 16 L:8 D (12 L:3 D:2 L:3 D: 2 L:2 D) and 12 L:12 D (9 L:3 D:1 L:3 D:1 L:3 D:1 L:3 D) and provided by incandescent bulbs. The two nutrient densities were high (H, starter diet: 13.39 MJ/kg apparent metabolisable energy (AME), 23.00% crude protein (CP); finisher diet: 13.39 MJ AME/kg, 19.70% CP) and low energy and protein level (L, starter diet: 12.03 MJ AME/kg, 20.80% CP; finisher diet: 12.14 MJ AME/kg, 18.30% CP). Houses with dark curtains and solid sidewalls were used. Chickens were randomly allocated to the 8 treatments with each treatment comprising 6 replicates of 12 chickens. Feed and water were available ad libitum. Lighting schedules showed no difference (p>0.05) in growth performance at the end of the experiment. 12 L:12 D significantly reduced (p<0.05) the concentration of malondialdehyde (MDA) compared to 23 L:1 D treatment. Intermittent lighting (IL) schedules produced higher protein content (p<0.001) in breast meat. Birds on high density diets had higher body weight (BW), feed intake (FI) (p<0.001), and feed conversion ratio (FCR) (p<0.001) throughout the experiment with the exception of 36 to 42 d. High nutrient density increased (p<0.05) abdominal fat, decreased (p<0.05) the moisture loss of meat, and reduced percentage of wings and legs. There was a significant lighting schedule${\times}$diet interaction (p<0.001) on FCR for days 8 to 14 and 15 to 21. Results indicated that IL can give similar growth performance in comparison with CL, meanwhile with positive effects on meat quality by increasing protein content and decreasing the concentration of MDA. High nutrient density resulted in greater growth performance.

Study on Adsorption Characteristics of Perfluorinated Compounds(PFCs) with Structural Properties (과불화화합물 구조적 속성에 따른 흡착 특성 연구)

  • Choi, HyoJung;Kim, Deok Hyun;Yoon, JongHyun;Kwon, JongBeom;Kim, Moonsu;Kim, Hyun-Koo;Shin, Sun-Kyoung;Park, Sunhwa
    • Journal of Soil and Groundwater Environment
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    • v.26 no.5
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    • pp.20-28
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    • 2021
  • Perfluorinated compounds(PFCs), an emerging environmental pollutant, are environmentally persistent and bioaccumulative organic compounds that possess a toxic impact on human health and ecosystems. PFCs are distributed widely in environment media including groundwater, surface water, soil and sediment. PFCs in contaminated solid can potentially leach into groundwater. Therefore, understanding PFCs partitioning between the aqueous phase and solid phase is important for the determination of their fate and transport in the environment. In this study, the sorption equilibrium batch and kinetic experiment of PFCs were carried out to estimated the sorption coefficient(Kd) and the fraction between aqueous-solid phase partition, respectively. Sorption branches of the PFDA(Perfluoro-n-decanoic acid), PFNA(Perfluoro-n-nonanoic acid), PFOA(Perfluoro-n-octanoic acid), PFOS(Perfluoro-1-octane sulfonic acid) and PFHxS(Perfluoro-1-hexane sulfonic acid) isotherms were nearly linear, and the estimated Kd was as follow: PFDA(1.50) > PFOS(1.49) > PFNA(0.81) > PFHxS(0.45) > PFOA(0.39). The sorption kinetics of PFDA, PFNA, PFOA, PFOS and PFHxS onto soil were described by a biexponential adsorption model, suggesting that a fast transport into the surface layer of soil, followed by two-step diffusion transport into the internal water and/or organic matter of soil. Shorter times(<20hr) were required to achieve equilibrium and fraction for adsorption on solid(F1, F2) increased with perfluorinated carbon chain length and sulfonate compounds in this study. Overall, our results suggested that not only the perfluorocarbon chain length, but also the terminal functional groups are important contributors to electrostatic and hydrophobic interactions between PFCs and soils, and organic matter in soils significantly affects adsorption maximum capacity than kinetic rate.

Development of Automatic System for 3D Visualization of Biological Objects

  • Choi, Tae Hyun;Hwnag, Heon;Kim, Chul Su
    • Agricultural and Biosystems Engineering
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    • v.1 no.2
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    • pp.95-99
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    • 2000
  • Nondestructive methods such as ultrasonic and magnetic resonance imaging systems have many advantages but still much expensive. And they do not give exact color information and may miss some details. If it is allowed to destruct some biological objects to get interior and exterior informations, constructing 3D image form a series of slices sectional images gives more useful information with relatively low cost. In this paper, a PC based automatic 3D model generator was developed. The system was composed of three modules. The first module was the object handling and image acquisition module, which fed and sliced the object sequentially and maintains the paraffine cool to be in solid state and captures the sectional image consecutively. The second one was the system control and interface module, which controls actuators for feeding, slicing, and image capturing. And the last was the image processing and visualization module, which processed a series of acquired sectional images and generated 3D volumetric model. Handling module was composed of the gripper, which grasped and fed the object and the cutting device, which cuts the object by moving cutting edge forward and backward. sliced sectional images were acquired and saved in a form of bitmap file. 2D sectional image files were segmented from the background paraffine and utilized to generate the 3D model. Once 3-D model was constructed on the computer, user could manipulated it with various transformation methods such as translation, rotation, scaling including arbitrary sectional view.

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