• Title/Summary/Keyword: 2D solid

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Eu Doping Effect on $CaAl_2O_4:Eu^{2+}$ Phosphor Material

  • Bartwal, Kunwar Singh;Ryu, Ho-Jin
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.2 s.19
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    • pp.65-68
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    • 2007
  • High brightness and long persistent luminescence phosphor $CaAl_2O_4:Eu^{2+}$ was prepared with varying $Eu^{2+}$ concentration by solid state reaction technique. Synthesized materials were investigated by powder X-ray diffractometer (XRD), SEM, TEM, photoluminescence excitation and emission spectra. Broad band UV excited luminescence of the $CaAl_2O_4:Eu^{2+}$ was observed in the blue region (${\lambda}_{max}\;=\;440\;nm$) due to transitions from the $4f^65d^1$ to the $4f^7$ configuration of the $Eu^{2+}$ ion. The decay time of the persistence indicated that the persistent luminescence phosphor has bright phosphorescence and maintains a long duration. These materials have great potential for outdoor night time displays.

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Property of Optical Spectroscopy on the Lanthanum Tungstate doped Eu3+ Ion (Eu3+ 이온이 첨가된 란타넘텅스텐산화물의 분광학 특성)

  • Seo, Hyojin;Park, Cheolwoo
    • Journal of the Korean Society of Radiology
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    • v.9 no.1
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    • pp.39-45
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    • 2015
  • $La_2W_3O_{12}:Eu^{3+}$ phosphors were prepared by solid state reaction method. The crystal structure was characterized by XRD pattern and ICSD card (78180). Luminescence properties of $La_2W_3O_{12}:Eu^{3+}$ are investigated by optical and laser-excitation spectroscopy in which emission and excitation spectra and time-resolved spectra are measured. The 1 mol % $Eu^{3+}$-doped $La_2W_3O_{12}$ phosphor exhibits broad excitation band peaking at 286 nm due to the ligand-to-metal charge transfer transition. The excitation lines due to the $^7F_0{\rightarrow}{^5D_4},{^5D_4},{^5L_6},{^5G_4},{^5D_3},{^5D_2}$ transitions of $Eu^{3+}$ are observed in the wavelength region 350-500 nm. The strong line emission is observed at 618 nm corresponding to the due to the $^5D_0{\rightarrow}^7F_2$ transition. The lifetime of 618 nm emission decreases with increasing temperature as 7 K ($114{\mu}s$), 100 K ($94{\mu}s$), 200 K ($10{\mu}s$) and 300 K ($0.5{\mu}s$).

Impact of Screw Type on Kyphotic Deformity Correction after Spine Fracture Fixation: Cannulated versus Solid Pedicle Screw

  • Arbash, Mahmood Ali;Parambathkandi, Ashik Mohsin;Baco, Abdul Moeen;Alhammoud, Abduljabbar
    • Asian Spine Journal
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    • v.12 no.6
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    • pp.1053-1059
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    • 2018
  • Study Design: Retrospective review. Purpose: To detect the effect of cannulated (poly-axial head) and solid (mono-axial head) screws on the local kyphotic angle, vertebral body height, and superior and inferior angles between the screw and the rod in the surgical management of thoracolumbar fractures. Overview of Literature: Biomechanics studies showed that the ultimate load, yield strength, and cycles to failure were significantly lower with cannulated (poly-axial head) pedicle comparing to solid core (mono-axial head). Methods: The medical charts of patients with thoracolumbar fractures who underwent pedicle screw fixation with cannulated or solid pedicle screws were retrospectively reviewed; the subjects were followed up from January 2011 to December 2015. Results: Total 178 patients (average age, $36.1{\pm}12.4years$; men, 142 [84.3%]; women, 28 [15.7%]) with thoracolumbar fractures who underwent surgery and were followed up at Hamad Medical Corporation were classified, based on the screw type as those with cannulated screws and those with solid screws. The most commonly affected level was L1, followed by L2 and D12. Surgical correction of the local kyphotic angle was significantly different in the groups; however, there was no significant difference in the loss of correction of the local kyphotic angle of the groups. Surgical correction of the reduction in the vertebral body height showed statistical significance, while the average loss of correction in the reduction of the vertebral body height was not significantly different. The measurement of the angles made by the screws on the rods was not significantly different between the cannulated (poly-axial head) and solid (mono-axial head) screw groups. Conclusions: Solid screws were superior in terms of providing increased correction of the kyphotic angle and height of the fractured vertebra than the cannulated screws; however, no difference was noted between the screws in the maintenance of the superior and inferior angles of the screw with the rod.

Synthesis and Photoluminescence Studies on Sr1-xBaxAl2O4 : Eu2+, Dy3+

  • Ryu, Ho-Jin;Singh, Binod Kumar;Bartwal, Kunwar Singh
    • Journal of the Korean Ceramic Society
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    • v.45 no.3
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    • pp.146-149
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    • 2008
  • Strontium-substituted $Sr_{1-x}Ba_xAl_2O_4:Eu^{2+},\;Dy^{3+}$ compositions were prepared by the solid state synthesis method. These compositions were characterized for their phase, crystallinity and morphology using powder x-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. Photoluminescence properties were investigated by measuring excitation spectra, emission spectra and decay time for varying Ba/Sr concentrations. Photoluminescence results show higher luminescence and long decay time for $Sr_{1-x}Ba_xAl_2O_4:Eu^{2+},\;Dy^{3+}$(x=0). This is probably due to the influence of the 5d electron states of $Eu^{2+}$ in the crystal field. Long persistence was observed for these compositions due to $Dy^{3+}$ co-doping.

Conductivity Behavior of Sodium and Potassium Aluminosilicate Glass Melts

  • Kim, Ki-Dong
    • The Korean Journal of Ceramics
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    • v.1 no.4
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    • pp.209-213
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    • 1995
  • The electrical conductivity was investigated in two series of alkali aluminosilicate glass melts, $25R_2O(R: Na and K)-xAl2O3-(75-x)SiO_2$ at temperatures ranging from 1000 to 140$0^{\circ}C$. The dependences of conductivity or activation energy on $Al_2O_3/R_2O$ of both series in the molten state showed a same behavior. These results in the molten state were compared with previous studies for sodium alkali aluminosilicate glasses in the molten and solid state, and explained in terms of the binding state: $[-O]-R^+\; and\; [AlO_4]-R^+$.

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Design of a Cooling System for a portable HTS Superconducting Magnetic Energy Storage Using a Solid Nitrogen (고체질소를 이용한 이동형 초전도 에너지 저장장치용 냉각 시스템 설계)

  • Kim, K.L.;Song, J.B.;Kim, K.J.;Lee, J.H.;Lee, H.G.;Koh, D.Y.;Kim, S.H.;Seong, K.C.
    • Progress in Superconductivity and Cryogenics
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    • v.10 no.3
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    • pp.27-31
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    • 2008
  • In order to cool the SMES coil to the operating temperature, conduction cooling is generally used. However, it often consumes a large amount of electric power because of it's continuous cryocooler operation. This can also lead to poor thermal stability and serious protection problems of the system. Solid nitrogen (SN2) can counter those disadvantages in the conduction cooling system because it has a large heat capacity. Particularly, a large amount of enthalpy with a minimal weight to the cold body of SN2 makes a compact and portable system by increase a recooling to recooling time period (RRTP) value. A conceptual design of the proto-type SN2 cooling system for a portable HTS superconducting magnetic energy storage (SMES) system will be introduced in this paper.

A Study on Operation Condition of Blast Furnace According to Burden Distribution (장입물 층상구조에 따른 고로내 운전상황 변화 연구)

  • Yang, Kwang-Heok;Choi, Sang-Min;Jung, Jin-Kyung
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.145-150
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    • 2006
  • At the furnace top, the distribution of charging coke and ore is adjusted to control the reducing gas flow distribution in the furnace. It is necessary to predict operation condition of blast furnace according to the burden profile to judge whether charging is properly conducted In this study, We propose the model for predicting while layer structures whithin furnace when top burden profile was given. Layer structure of coke and ore could be predicted by top burden profile and solid velocity. Solid velocity is assumed as potential flow. Potential function distribution and timeline are also calculated using solid velocity field. The Calculation is conducted for different burden profile cases. As the result burden distribution and grid structure, which is deformed to match the layer structure in shaft and deadman profile. Gas flow was calculated using this grid, and calculated results are compared with each other.

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Parametric design of 3D solid objects using orthographic views (삼면도를 이용한 3차원 물체의 Parametric design)

  • 김병인;김광수
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 1994.04a
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    • pp.208-218
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    • 1994
  • 기계부품의 설계는 일반적으로 정면도, 평면도, 측면도로 구성되는 삼면도를 이용하여 이루어진다. 본 연구에서는 삼면도를 이용한 3차원 물체의 parametric design 방법을 제시한다. parametric design 기법을 구현하기 위 하여 인공지능기법을 이용하고, 삼면도로부터 입체를 생성하기 위하여는 기 하학적이고 단계적인 접근방법을 이용한다. 본 연구에서 제시한 방법은 삼면 도를 사용하여 설계하기 때문에 기존의 설계방법과 같을 뿐 아니라, 파라메 트릭 기능을 가지고 있어서 설계가 완성된 이후에 형상의 수정을 쉽게 할 수 있는 장점이 있다. 또한 기존의 2차원 도면을 입체모델(solid model)로 바 꾸어 줄 수 있는 기능도 수행할수 있다.

Solid-state NMR Studies of Miscibility and Morphology in Blends of Bisphenol-A type Polycarbonate and Poly (ester-ether) Elastomer

  • Kim, Yongae
    • Journal of the Korean Magnetic Resonance Society
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    • v.5 no.1
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    • pp.19-28
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    • 2001
  • Miscibility and morphology in blends of bisphenol-A type polycarbonate and poly (ester-ether) elastomer with different compositions are studied by solid-state NMR spectroscopy. $^{13}$ C Solid-state NMR of CP/MAS/TOSS/DD, CP/MAS/DD, inversion recovery CP/MAS/DD, and 2D rotor driven spin diffusion techniques are used to identify the miscibility, morphology, and transesterification in blends. The blends of PC /BT elastomer with 15% to 42% of soft segment seem to be single phase miscible mixing and those of PC/PBT and PC/PBT elastomer with 62% of soft segment are cocontinuous two phase immiscible mixing. No significant transesterification reactions are observed in blends with different compositions.

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Prediction of Cutting Force in Ball-end mill Cutting using the Commercial Solid Modeler (상용 Solid Modeler를 이용한 볼 엔드밀 가공의 절삭력 예측)

  • ;;;H. S. Park
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.347-350
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    • 2003
  • Many researches on the prediction of cutting forces of ball-end mil is have been achieved since before several decades ago. These kinds of researches have been concentrated on the study on how to make the prediction equations for the cutting forces based on 2-D cutting experimentation. The results of them were really good and impressive. But it's not proper to practical uses for industrial fields, because if sculptured surface were to be machined, then it would be very difficult to understand the complicated kinematical interaction between the sculptured surface and the flutes of a ball-end mill. So, we propose the method for solving these kind of problems using existed commercial CAD/CAM software; Unigraphics. Furthermore, the modification of tool path which is done off line is offered to increase the precision of cutting.

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