• 제목/요약/키워드: 2D crystals

검색결과 247건 처리시간 0.025초

${\mu}-PD$ 법으로 성장시킨 near-stoichiometric 조성 $Zn:LiNbO_3$ fiber 단결정 성장 및 광손상 특성 (Crystal growth and optical properties of near-stoichiometric $Zn:LiNbO_3$ fiber single crystal by ${\mu}-PD$ method)

  • 이호준;서중원;신동익;송원영;윤대호
    • 한국결정성장학회지
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    • 제16권6호
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    • pp.235-239
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    • 2006
  • Micro-pulling down$({\mu}-PD)$법을 이용하여 직경 $0.8{\sim}1.0mm$, 길이 $30{\sim}35mm$의 ZnO가 첨가된 near-stoichiometric $LiNbO_3$, 단결정을 성장하였다. 성장된 결정의 결정구조를 powder x-tay diffraction(XRD) patterns으로 확인하였고, electron probe micro analysis(EPMA)를 이용하여 결정내 Zn 이온들이 균일하게 분포되었음을 확인하였다. 또한 2 mol% 이상의 ZnO 첨가시 $OH^-$ 흡수밴드의 특성이 크게 변화함을 관찰함으로써 ZnO 첨가량에 일치한 역치(threshold)가 존재함을 확인하였다.

Beam Characteristics of Polychromatic Diffracted Neutrons Used for Prompt Gamma Activation Analysis

  • S. H. Byun;G. M. Sun;Park, H. D.
    • Nuclear Engineering and Technology
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    • 제34권1호
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    • pp.30-41
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    • 2002
  • The neutron beam is fully characterized for the prompt gamma activation analysis facility at Hanaro in the Korea Atomic Energy Research Institute(KAERI). The facility uses thermal neutrons which are diffracted vertically from a horizontal beam port by a set of pyrolytic graphite(PG) crystals positioned at the Bragg angle of 45" Neutron spectra, neutron flux and Cd-ratio are determined for the three extraction modes of diffracted beam by means of the theoretical and experimental efforts. To obtain theoretical result, the reflectivity of pyrolytic graphite is calculated in the diffraction model for mosaic crystal and the angular divergence after diffraction by mosaic crystal is estimated from Monte Carlo simulation. The time-of-flight spectrometer and gold activation wire are used for measuring the neutron spectra. Both the calculated and measured spectra have proven that the unique feature of polychromatic beam obtained by PG crystals are useful for PGAA. The thermal neutron flux of 7.9$\times$107 n/cm$^2$s and the Cd-ratio of 266 for gold have been achieved at the sample position while the reactor operates at 24 MW The uniformity of beam flux is 12% in the central 1$\times$1 cm$^2$ area. Finally, the beam is briefly characterized by the effective velocity and temperature which are determined by measuring the prompt Y-ray spectra for thin and thick boron samples.ples.

Convection in the growth of zinc telluride single crystal by physical vapor transport

  • Kim, Geug-Tae
    • 한국결정성장학회지
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    • 제13권4호
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    • pp.187-198
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    • 2003
  • Zinc selenide (ZnSe) single crystals hold promise for many electro-optics, acousto-optic and green laser generation applications. This material is prepared in closed ampoules by the physical vapor transport (PVT) growth method based on the dissociative sublimation. We investigate the effects of diffusive-convection on the crystal growth rate of ZnSe with a low vapor pressure system in a horizontal configuration. Our results show that for the ratios of partial pressures, s=0.2 and 2.9, the growth rate increases with the Peclet number and the temperature differences between the source and crystal. As the ratio of partial pressures approaches the stoichiometric value of 2, the rate increases. The mass fluk based on one dimensional (1D model) flow for low vapor pressure system fall within the range of the predictions (2D model) obtained by solving the coupled set of conservation equations, which indicates the flow fields would be advective-diffusive. Therefore, the rate and the flow fields are independent of gravity acceleration levels.

꽃피는식물 색소체 내 결정구조와 미세소관의 발달양상 조사 연구 (A Survey of Plastid Crystals and Microtubules in Flowering Plants)

  • 김인선
    • Applied Microscopy
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    • 제39권2호
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    • pp.73-80
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    • 2009
  • 다양한 색소체 내에 형성되는 결정체와 미세소관의 분포 및 발달양상을 식물이 수행하는 광합성 양식과 연계하여 꽃피는식물 종들에서 밝혀진 결과에 의하면, 색소체 결정체는 대개 격자 구조를 이루며 기질 또는 티라코이드 내에 형성되나, 미세소관은 비교적 규칙적인 형태로 기질에만 발달한다고 알려져 있다. 격자구조는 막으로 둘러싸이거나 막과는 무관하게 발달하며, 계통학적인 유연관계를 형성하지 않고 C-3 또는 C-4 또는 CAM 광합성을 수행하는 26개의 식물과, 약 56종에서 독립적으로 나타난다는 사실이 조사되었다. 색소체 결정체 및 미세소관 형성에 대한 지속적인 연구는 이들의 구조와 기능에 대하여 새로운 정보를 제공하나, 결정체에 대한 3차원적 입체구조 연구와 미세소관에 대한 분자생물학적인 실험법들이 요구되고 있는 실정이다. 특히, HVEM 고압전자현미경 및 tomography에 의한 연속절편 연구는 결정체의 3-D 입체구조 구현이 가능하여 심도 있는 구조정보를 제공하는 것으로 알려져 있다. 극히 일부의 식물에서만 보고되어 있는 색소체 내 미세소관에 대한 연구에 관해서는 먼저 색소체 기질에서 이들의 형성 시점을 알아내어 기질에서의 식별 및 분리 연구 등이 가능하게 돼야함이 강조되고 있다. 본 논문에서는 꽃피는식물 종들의 여러 색소체 유형에서 보고된 결정체와 미세소관을 조사하여 색소체 내에서 이들의 기능을 광합성과 연계하여 종합적으로 논의하였다.

잉크젯 프린팅을 이용한 연속 조성 세라믹 화합물 구조체 형성 (Additive Manufacturing of Various Ceramic Composition Using Inkjet Printing Process)

  • 박재현;최정훈;황광택;김진호
    • 한국재료학회지
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    • 제30권11호
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    • pp.627-635
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    • 2020
  • 3D printing technology is a processing technology in which 3D structures are formed by fabricating multiple 2D layers of materials based on 3D designed digital data and stacking them layer by layer. Although layers are stacked using inkjet printing to release various materials, it is still rare for research to successfully form a product as an additive manufacture of multi-materials. In this study, dispersion conditions are optimized by adding a dispersant to an acrylic monomer suitable for inkjet printing using Co3O4 and Al2O3. 3D structures having continuous composition composed of a different ceramic material are manufactured by printing using two UV curable ceramic inks whose optimization is advanced. After the heat treatment, the produced structure is checked for the formation and color of the desired crystals by comparing the crystalline analysis according to the characteristics of each part of the structure with ceramic pigments made by solid phase synthesis method.

오목표면에 분사되는 난류원형충돌제트에 대한 국소열전달계수 측정에 관한 연구 (Measurement of the Local Heat Transfer Coefficient on a Concave Surface with a Turbulent round Impinging Jet)

  • 임경빈
    • 설비공학논문집
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    • 제7권1호
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    • pp.112-119
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    • 1995
  • Measurements of the local heat transfer coeffcients on a spherically concave surface with a round impinging jet are presented. The liquid crystal transient method was used for these measurements. This method, which is a variation on the transient method, suddenly exposes a preheated wall to an impinging jet while video recording the response of liquid crystals for the measurement of the surface temperature. The Reynolds numbers used were 1,000, 23,000 and 50,000 and the nozzle-to-jet distance was L/d=2, 4, 6, 8, 10. Presented results are compared to previous measurements for flat plate. In the experiment, the local heat transfer Nusselt numbers on a concave surface are higher than those on a flat plate. Maximum Nusselt number at all region occured at L/d=6 and second maximum in the Nusselt number occured at R/d=2 for both Re=50,000 and Re=23,000 in case of L/d=2 and for only Re=50,000 in case of L/d=4. All other cases exhibit monotonically decreasing value of the Nusselt number along the curved surface.

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Solution-Processed Two-Dimensional Materials for Scalable Production of Photodetector Arrays

  • Rhee, Dongjoon;Kim, Jihyun;Kang, Joohoon
    • 센서학회지
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    • 제31권4호
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    • pp.228-237
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    • 2022
  • Two-dimensional (2D) nanomaterials have demonstrated the potential to replace silicon and compound semiconductors that are conventionally used in photodetectors. These materials are ultrathin and have superior electrical and optoelectronic properties as well as mechanical flexibility. Consequently, they are particularly advantageous for fabricating high-performance photodetectors that can be used for wearable device applications and Internet of Things technology. Although prototype photodetectors based on single microflakes of 2D materials have demonstrated excellent photoresponsivity across the entire optical spectrum, their practical applications are limited due to the difficulties in scaling up the synthesis process while maintaining the optoelectronic performance. In this review, we discuss facile methods to mass-produce 2D material-based photodetectors based on the exfoliation of van der Waals crystals into nanosheet dispersions. We first introduce the liquid-phase exfoliation process, which has been widely investigated for the scalable fabrication of photodetectors. Solution processing techniques to assemble 2D nanosheets into thin films and the optoelectronic performance of the fabricated devices are also presented. We conclude by discussing the limitations associated with liquid-phase exfoliation and the recent advances made due to the development of the electrochemical exfoliation process with molecular intercalants.

Enhancement of Off-Axis Viewing Quality with Temporal Dual Gamma Drive in Patterned Vertical Alignment Mode

  • Yang, Young-Chol;Lee, Baek-Woon;Park, Dae-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.286-289
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    • 2006
  • Temporal dual gamma drive technology employing the 120Hz refresh rate was developed to enhance the off-axis viewing quality in patterned vertical alignment mode. The color shift ${\Delta}u'v'$ from on-axis to off-axis (60 deg.) for pale orange color, (R,G,B) = (196,124,96), was below 0.01, and the power exponent of gamma curve for off-axis viewing angle (60 deg.) was about 1.8, when the gamma curve for on-axis was set with power exponent of 2.4. The off-axis image distortion index was below 0.180 in contrast to the normal case ${\sim}0.23$. To elevate the response speed of liquid crystal in the intra-frame, the voltage below threshold voltage of liquid crystals was used.

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AI-Si계 리오캐스팅합금의 초정입자의 응고조직 및 기계적성질 (Microstructural evolution of primary solid particles and mechanical properties of AI-Si alloys by rheocasting)

  • 이정일;이호인;류영호;김도향;김문일
    • 열처리공학회지
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    • 제7권4호
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    • pp.244-252
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    • 1994
  • The morphological changes of primary solid particles as a fuction of process time on Al-Si alloys during semi-solid state processing with a shear rate of 200s were studied. In hypereutectic Al-15.5wt%Si alloy, it was observed that primary Si crystals are fragmented in the early stage of stirring and morphologies of primary Si crystals change from faceted to spherical during isothermal shearing for 60 minutes. In quaternary Al-12.5wt%Si-2.9wt%Cu-0.7wt%Mg alloy system, it was observed both primary silicon and ${\alpha}$-alumunum particles. Microstructural evolution of primary Si crystals was similar to that of the hypereutectic Al-Si alloy but equiaxed ${\alpha}$-Al dendrites are broken into nearly spherical at the early stage of shearing and later stage of the isothermal shearing ${\alpha}$- Al particles are slightly coarsoned by Ostwald ripening. Mechanical properties of Al-Si-Cu-Mg alloy were compared to those from other processes (squeeze casting and gravity casting). After T6 heat treatment, comparable values of hardness were obtained while slightly lower compressive strength values were observed in rheocast alloy. The elongation, on the other hand, exhibited significant increasement of 15% over gravity cast alloy.

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