• 제목/요약/키워드: 2D Materials

검색결과 6,150건 처리시간 0.035초

Molecular Orientation of Intercalants Stabilized in the Interlayer Space of Layered Ceramics: 1-D Electron Density Simulation

  • Yang, Jae-Hun;Pei, Yi-Rong;Piao, Huiyan;Vinu, Ajayan;Choy, Jin-Ho
    • 한국세라믹학회지
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    • 제53권4호
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    • pp.417-428
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    • 2016
  • In this review, an attempt is made to calculate one-dimensional (1-D) electron density profiles from experimentally determined (00l) XRD intensities and possible structural models as well in an effort to understand the collective intracrystalline structures of intercalant molecules of two-dimensional (2-D) nanohybrids with heterostructures. 2-D ceramics, including layered metal oxides and clays, have received much attention due to their potential applicability as catalysts, electrodes, stabilizing agents, and drug delivery systems. 2-D nanohybrids based on such layered ceramics with various heterostructures have been realized through intercalation reactions. In general, the physico-chemical properties of such 2-D nanohybrids are strongly correlated with their heterostructures, but it is not easy to solve the crystal structures due to their low crystallinity and high anisotropic nature. However, the powder X-ray diffraction (XRD) analysis method is thought to be the most powerful means of understanding the interlayer structures of intercalant molecules. If a proper number of well-developed (00l) XRD peaks are available for such 2-D nanohybrids, the 1-D electron density along the crystallographic c-axis can be calculated via a Fourier transform analysis to obtain structural information about the orientations and arrangements of guest species in the interlayer space.

은나노와이어와 2차원 구조 루테늄산화물 하이브리드 재료의 광전기적 특성 (Optoelectric properties of hybrid materials with Ag-nanowire and 2-dimensional structured RuO2)

  • 이정민;박희정
    • 한국결정성장학회지
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    • 제34권2호
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    • pp.55-60
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    • 2024
  • 화학적 박리법을 이용하여 나노미터 두께를 갖는 2차원(2D) RuO2 나노시트를 합성하였다. 차세대 투명전극 소재로 주목받고 있는 Ag-nanowire(NW)와 본 연구에서 합성된 2D-RuO2를 하이브리드화하였다. 기판 위에 Ag-NW 코팅 후 2D-RuO2를 추가로 코팅하였다. 광투과도의 감소는 있었지만 2D-RuO2를 하이브리드화하여 면저항 감소 효과를 확인할 수 있었다. 또한 제조된 투명전극의 유연성 실험도 진행하였다. 벤딩 후 면저항 변화로 확인하였다. 2D-RuO2의 추가 코팅으로 투명전극 유연성이 향상되었다.

안테나 결합형 볼로미터 방식 테라헤르츠 센서를 이용한 이차원 주사 방식의 투과형 테라헤르츠 영상 취득에 관한 연구 (Terahertz Transmission Imaging with Antenna-Coupled Bolometer Sensor)

  • 이경일;임병직;원종석;홍성민;박재현;이대성
    • 센서학회지
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    • 제27권5호
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    • pp.311-316
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    • 2018
  • An antenna-coupled bolometer-type terahertz sensor was designed, fabricated, evaluated, and utilized to obtain terahertz transmission images. The sensor consists of a thin film bowtie antenna that resonates accordingly in response to an incident terahertz beam, a heater that converts the applied current in the antenna into heat, and a microbolometer that converts the rise in temperature into a change in resistance. The device is fabricated by a bulk micromachining process on a 4-inch silicon wafer. The fabricated sensor chip has a size of $2{\times}2mm$ and an active area of $0.1{\times}0.1mm^2$. The temperature coefficient of resistance (TCR) of the bolometer film (VOx) is 2.0%, which is acceptable for bolometer applications. The output sensor signal is proportional to the power of the incident terahertz beam. Transmission images were obtained with a 2-axis scanning imaging system that contained the sensor. The small active area of the sensor will enable the development of highly sensitive focal plane array sensors in terahertz imaging cameras in the future.

Microstructure and Tensile Properties in Low Pressure Cast Al-Si Alloy through Cooling Rate Control

  • Suh, Jun-Young;Park, Sung Jin;Lee, Hee-Kwon;Chang, Si Young
    • 한국재료학회지
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    • 제30권2호
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    • pp.51-56
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    • 2020
  • In this study, three kinds of metal chills such as SS400, AC4CH and brass, with different thicknesses of 40 ~ 80 mm, were applied for low pressure casting of Al-Si alloy to control cooling rate. The microstructural characteristics with increasing cooling rate were represented using factors including D1, D2, size of primary α phases and shape factor and size of eutectic Si. The tensile properties were investigated and additionally analyzed based on the microstructural characteristics. As the cooling rate increased, D1, D2, and sizes of primary α phases and eutectic Si apparently decreased and the shape factor of eutectic Si increased to over 0.8. The ultimate tensile strength (UTS) and yield strength (YS) increased with decreasing D1, D2, and size of primary α phases, while elongation increased with decreasing size of eutectic Si and concurrently increasing shape factor of eutectic Si. This indicated that the primary α phases and eutectic Si in Al-Si alloy were refined with increasing cooling rate, resulting in improvement of UTS and YS without sacrificing elongation. After the tensile test, preferential deformation of primary α phases was observed in the Al-Si alloy produced at higher cooling rates of more than 0.1 K/s.

참당귀로부터 분리한 Demethylsuberosin의 멜라닌 생성 억제 효과 (Inhibitory Effects on Melanin Production of Demethylsuberosin Isolated from Angelica gigas Nakai)

  • 김유아;박성하;김보윤;김아현;박병준;김진준
    • 생약학회지
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    • 제45권3호
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    • pp.209-213
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    • 2014
  • The anti-melanogenic substance was isolated from the root of Angelica gigas Nakai by silica gel column chromatography, preparative HPLC and TLC. As a result of the structure analysis by mass, $^1H$-NMR, and $^{13}C$-NMR spectrometry, the compound was identified as demethylsuberosin. Demethylsuberosin reduced melanin contents of B16F1 melanoma cells in a dose-dependent manner and decreased to about 74% at a concentration $5{\mu}g/ml$. Demethylsuberosin inhibited the expression in microphthalmia associated transcription factor (MITF), tyrosinase, tyrosinase related protein-1 (TRP-1), and tyrosinase related protein-2 (TRP-2) in melanocytes. These results suggest that the whitening activity of demethylsuberosin may be due to the inhibition of the melanin synthesis by down-regulation of MITF, tyrosinase, TRP-1 and TRP-2 expression. Thus, our results provide evidence that demethylsuberosin might be useful as a potential skin-whitening agent.

2D 및 3D 직조형 복합재료의 충격특성 (Impact Properties of 2D and 3D Textile Composites)

  • 변준형;엄문광;황병선;송승욱;강형
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
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    • pp.91-94
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    • 2003
  • Laminated composites are liable to fatal damage under impact load due to the fact that they have no reinforcement in the thickness direction. To overcome the inherent weakness, three dimensional (3D) textile reinforcements have drawn much interests. In this paper, impact performance of 2D and 3D textile composites has been characterized. For 2D composites, fiber bundle size and fiber pattern have been varied. For 3D composites, orthogonal woven preforms of different density and type of through-thickness fibers have been studied. To assess the damage after the impact loading, specimens were subjected to C-scan nondestuctive inspection. Compression after impact (CAI) were also conducted in order to evaluate residual compressive strength.

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알루미늄의 Sb 첨가에 따른 미세조직, 전기전도도 및 기계적 특성 변화 (Influence of Sb Addition on Microstructure, Mechanical Properties and Electric Conductivity of Aluminum)

  • 유효상;김용호;이병권;고은찬;이성희;이상찬;손현택
    • 한국재료학회지
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    • 제32권11호
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    • pp.489-495
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    • 2022
  • This research investigated how adding Sb (0.75, 1.0, 2.0 and 5.0 wt%) to as-extruded aluminum alloys affected their microstructure, mechanical properties, electric and thermal conductivity. The addition of Sb resulted in the formation of AlSb intermetallic compounds. It was observed that intermetallic compounds in the alloys were distributed homogenously in the Al matrix. As the content of Sb increased, the area fraction of intermetallic compounds increased. It can be clearly seen that the intermetallic compounds were crushed into fine particles and homogenously arrayed during the extrusion process. As the Sb content increased, the average grain size decreased remarkably from 282.6 ㎛ (0.75 wt%) to 109.2 ㎛ (5.0 wt%) due to dynamic recrystallization by the dispersed intermetallic compounds in the aluminum matrix during the hot extrusion. As the Sb content increased from 0.75 to 2.0 wt%, the electrical conductivity decreased from 61.0 to 59.8 % of the International Annealed Copper Standard. Also, as the Sb content increased from 0.75 to 2.0 wt%, the ultimate tensile strength did not significantly change, from 67.3 to 67.8 MPa.

A Study on the Optimization of Metalloid Contents of Fe-Si-B-C Based Amorphous Soft Magnetic Materials Using Artificial Intelligence Method

  • Young-Sin Choi;Do-Hun Kwon;Min-Woo Lee;Eun-Ji Cha;Junhyup Jeon;Seok-Jae Lee;Jongryoul Kim;Hwi-Jun Kim
    • Archives of Metallurgy and Materials
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    • 제67권4호
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    • pp.1459-1463
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    • 2022
  • The soft magnetic properties of Fe-based amorphous alloys can be controlled by their compositions through alloy design. Experimental data on these alloys show some discrepancy, however, with predicted values. For further improvement of the soft magnetic properties, machine learning processes such as random forest regression, k-nearest neighbors regression and support vector regression can be helpful to optimize the composition. In this study, the random forest regression method was used to find the optimum compositions of Fe-Si-B-C alloys. As a result, the lowest coercivity was observed in Fe80.5Si3.63B13.54C2.33 at.% and the highest saturation magnetization was obtained Fe81.83Si3.63B12.63C1.91 at.% with R2 values of 0.74 and 0.878, respectively.