• Proceedings of the Korean Ceranic Society Conference
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• 2002.10a
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• pp.189.1-189
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• 2002

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.178.1-178
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• 2003

• Progress in Superconductivity and Cryogenics
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• v.21 no.4
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• pp.1-5
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• 2019

We investigated the effect of Fe₃O₄ addition on the critical temperature of (Bi, Pb)-2223 polycrystalline samples. Bi_1.6Pb_0.4Sr₂Ca₂Cu₃O_10+δ + x wt. % Fe₃O₄ (x = 0.0, 0.2, 0.4, 0.6, and 0.8) samples were prepared by using a solid-state reaction method. The analysis of X-ray diffraction data indicates that as Fe₃O₄ is added, dominant phase of the sample changes from Bi-2223 to Bi-2212 with an increasing Bi-2201 phase. The transition temperature of the samples drastically decreased with the Fe₃O₄ addition. The resistance data of samples with x = 0.2 and 0.4 showed a double transition indicating a coexistence of Bi-2223 and Bi-2212 phase while the samples with x = 0.6 and 0.8 showed a single transition with a semiconducting behavior. This phase transition may originate from changes in local structure of the Bi-2223 system by Fe₃O₄ addition. Analysis of the pair distribution function of the Cu-O pair in the CuO₂ plane calculated from extended X-ray absorption fine structure data revealed that the oxygen coordination of copper ion changes from CuO₄ planar type (x = 0.0 - 0.4) to CuO₅ pyramidal type (x = 0.6, 0.8). The correlated Debye-Waller factor, providing information on the atomic disorder within the CuO₂ plane, shows an inverse relation to the coordination number. These results indicate that addition of Fe₃O₄ changes the oxygen distribution around Cu in the CuO₂ plane, causing a phase transition from Bi-2223 to more stable Bi-2212/Bi-2201 phases.

• Progress in Superconductivity and Cryogenics
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• v.5 no.1
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• pp.31-34
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• 2003

Bi-2223 superconducting wires with 55 filaments were fabricated by stacking, drawing process with different heat-treatment histories. Two kinds of powders were prepared. One was pre-annealed at 760-820 $^{\circ}C$ and low oxygen partial pressure, and the other was only calcined state. Before rolling process, round wires were pre-annealed at 760 -820 $^{\circ}C$ and in a low oxygen partial pressure. We confirmed that pre-annealing step was to transform Bi-2212 orthorhombic structure from Bi-2212 tetragonal structure and to reduce the formation of second phases at superconducting wire. However Bi-2223 phases were formed at higher pre-annealing temperature. Bi-2223 conductor was needed frequently annealing at low temperature because pre-annealing at precursor powder brought about decrease in workability. We could achieve highest Je of 6500 A/$\textrm{cm}^2$ at the tape using Bi-2212 orthorhombic phase by introduced slightly overheating at the 1st sintering process.

• Progress in Superconductivity and Cryogenics
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• v.7 no.4
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• pp.4-9
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• 2005

The degradation behavior of the critical current $(I_c)$ of Bi-2223 superconducting tapes under pressurized liquid nitrogen were investigated using a newly developed p-shaped sample holder which gives a series of bending strains to a sample. Three kinds of commercially available multi-filamentary Bi-2223 superconducting tapes were used. At atmospheric pressure, the Ie degradation behavior depended on the manufacturing process undergone by each tape. The tapes externally reinforced or densified by over pressure showed better bending strain tolerance than the Ag alloy-sheathed Bi-2223 tape. But these tapes showed a significant $I_c$ degradation when pressurized to 1 MPa in liquid nitrogen. For all samples, after depressurization to atmospheric pressure from 1 MPa, the Ie was completely recovered to its initial values at atmospheric pressure. When the samples were subjected to a thermal cycle wherein the tape was warmed up to room temperature after being depressurized from 1 MPa, it was found that the larger degradation of $I_c$ occurred at the regions where significant ballooning occurred, such as $0\%\;and\;0.2\%$. However, an improved ballooning damage tolerance was observed in the highly-densified tape.

• Progress in Superconductivity and Cryogenics
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• v.1 no.2
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• pp.1-7
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• 1999

we evaluated the effects of joining process such as contact method. shape of joined area and pressure on the electrical and mechanical properties of Bi-2223 superconducting tape, Specifically. the current capacity of the jointed tape was measured as a function of uniaxial pressure. and the thermal shock, bonding strength and the thermal of the tape were evaluated and correlated to the microstructural evolution. It was observed that the current capacity was significanrly dependent on the uniaxial pressure The jointed tape, fabricated with a pressure of 1,000-1,600 Mpa. showed the highest value of current capacity results from improvements in core density, contacting area and grain alignment, ect. In addition, the strength of jointed tape was measured to be 86 Mpa, which is about 88% of the unjoined ape's strength. The irreversible strain($\varepsilon$irrev) for the jointed tape was measured to be 0.1%, smaller than that of unjoined tape ($\varepsilon$irrev= 0.3%). The decrease in the strength and irreversible strain for jointed tape is believed to be due to the irregular geometry/morphology of the transition area of the tape.

• Progress in Superconductivity and Cryogenics
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• v.7 no.1
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• pp.32-36
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• 2005

With the successful commercialization of Bi-2223 powder-in-tube wire , various attempts in the R & D of the high-Tc superconducting (HTS) magnets for high magnetic field applications are being implemented actively. Operating temperature of HTS magnet has to be maintained at the designed level but the magnetic energy and mechanical disturbance can cause unstable operational temperature of HTS magnet. Especially the generated heat energy of inner HTS winding Is apt to be accumulated . so the normal region appears in HTS winding. This paper deals with the quenching characteristics of three kinds of selected Bi-2223 wires : the High Current Density Wire (HC-A) and the High Strength Wire (HS-A) made by AMSC and HTS wire(HW-I) made by Innost The Innost wire has the highest minimum quench energy (MQE). The High Current Density Wire has the highest normal zone Propagation velocity (NZPV).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07a
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• pp.67-73
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• 2002

The development of high performance HTS wire is a key factor for various electrical applications of coils and cables. The purpose of this paper is to review and consider the main manufacturing technologies of HTS wire and its current status. A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. According to this, long Bi-2223 wires having Ic of 130 A were recently produced and their mass production has been underway in US. The current status performance of Bi-2223 wire is supposed to be used in power transmission cable because of its lower self-field property. Y-123 second generation conductor is extensively being developed throughout the world and many fabrication processes are competed with each other. 30 m-long Y-123 wire with Ic of 0.8 MA/$\textrm{cm}^2$ was recently fabricated using IBAD and PLD techniques in Japan. This result offers promise of scalable processing of practical multi-layer coated conductor.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.51 no.4
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• pp.159-164
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• 2002

This paper presents the design and fabrication of a high-Tc superconducting (HTS) power supply for charging of the HTS magnet load, and its characteristics have been analyzed through experiments. HTS power supply consists of two heaters, an electromagnet, a Bi-2223 solenoid and a Bi-2223 pancake magnet load. In this experiment, 331 mH electromagnet and 0.8 A dc heater current were used, and 8.5 sec and 17 sec were used for pumping period. Mechanism of the superconducting switch is used for heater-trigger. In order to measure the pumping-current with respect to the magnet flux changes, hall sensor was installed at the center of the Bi-2223 pancake load. The experimental observations have been compared with the theoretical predictions. In this experiment, the pumping-current has reached about 1.2 A. In computer simulation, the maximum pumping-current of the system has been predicted to be about 2.7 A.

• 한국초전도학회:학술대회논문집
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• v.10
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• pp.276-279
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• 2000

When high temperature superconducting tapes is fabricated using the PIT (Powder In Tube) method, the length of HTS tapes is increased more than 500 ${\sim}$ 1,000 times of initial powder packed billet. On mechanical processing, heterogeneous properties between the ceramic superconducting core and Ag/Ag alloy sheath occur the non-uniformity deformation as like sausaging that deteriorate the critical current properties of HTS tapes. In this study, we investigated the workability of Bi-2223/Ag/Ag alloy sheath tapes fabricated by the PIT method involving a number of different mechanical processes, multi drawing and rolling. In order to obtain the high critical current density and high uniformity of Bi-2223/Ag sheath tapes, the influences of powder packing density, drawing die angle and rolling parameters were studied. We found that the roll diameter is an important variable in the rolling process, as critical current of tapes rolled using 250 mm rolls was higher than that using 150 mm rolls.