• 대한화학회지
• /
• 제37권12호
• /
• pp.1025-1034
• /
• 1993

정상 액체 크로마토그래피에 사용되는 2-propanol / hexane 혼합용매계와 ethyl acetate / hexane 혼합용매계에 대하여 전 용매조성에 대한 극성도 지수 ${\pi}^*$, $\alpha$ , $\beta$값을 측정하였다. 이 중 hexane/ethyl acetate계는 전 조성에 대하여 $\alpha$ 가 0으로 정의되므로 ${\pi}^*$와 $\beta$값만을 측정하였다. 기존의 문헌치 ${\pi}^*$, $\alpha$ , $\beta$와 일관성이 있는 극성도 지수를 구하기 위하여 본 연구의 실측치와 문헌치간에 좋은 직선상관성을 가정하여 보정하였으며 최종 보정된 혼합용매 극성도 지수의 용매 조성에 따른 변화는 각 용매성분의 화학적 성질에서 예측할 수 있는 경향에 부합하는 결과를 보였다. 이들 두 용매계에 대하여 관찰된 일반적인 경향은 다음과 같다. 극성도 대 조성배의 그래프에서 ${\pi}^*$값은 더 극성인 용매의 조성비가 증가할수록 증가하는 경향을 보이고, $\alpha$ 와 $\beta$ 값은 더 극성인 용매의 조성비가 0일 때 최소값을 갖고 조성비의 증가에 따라 극대치를 이룬 다음 다시 감소하는 특이한 경향을 보였다.

• Bulletin of the Korean Chemical Society
• /
• 제30권11호
• /
• pp.2613-2616
• /
• 2009

FeOOH/$TiO_2$, a heterojunction structure between FeOOH and $TiO_2$, was prepared by covering the surface of the $\sim$100-nm-sized FeOOH particles with Degussa P25 by applying maleic acid as an organic linker. Under visible light irradiation (${\lambda}{\geq}$ 420 nm), FeOOH/$TiO_2$ showed a notable photocatalytic activity in removal of gaseous 2-propanol and evolution of $CO_2$. It was found that FeOOH reveals a profound absorption in the spectral range of 400 - 550 nm, and its valence band (VB) level is located relatively lower than that of $TiO_2$. The considerable photocatalytic efficiency of the FeOOH/$TiO_2$ under visible light irradiation was therefore deduced to be caused by the hole transfer between the VB of FeOOH and $TiO_2$.

• 한국환경과학회지
• /
• 제11권7호
• /
• pp.749-755
• /
• 2002

The effects of noble gas (such as helium, neon, argon, krypton, and xenon) on the sonolytic decomposition of water and 2-methyl-2-propanol(t-butanol) with 200 KHz high power ultrasound were investigated. The physical properties of the noble gas have an effect on the formation rate of products $(H_2O_2,\;H_2,\;O_2)$ and the decomposition rate on the sonolytic decomposition of water. The pyrolysis products, such as methane, ethane, ethylene, and acetylene are formed during the sonolytic decomposition of t-butanol. From the estimation of the ratio $[C_2H_4+C_2H_2] / [C_2H_6]$, the cavitation temperature would be varied by the used noble gas. In all cases for the sonolytic decomposition of water, t-butanol, and diethyl phthalate, the decomposition rates were xenon > krypton > argon > neon > helium with a significant difference and were closely correlated with the formation rate of OH radical and high temperature inside the cavitation bubble under each noble gas.

• 한국환경과학회지
• /
• 제19권12호
• /
• pp.1403-1407
• /
• 2010

The adsorption characteristics of $CO_2$ gas on impregnated activated carbons with MEA (Mono-ethanolamine) and AMP (2-Amino 2-methyl 1-propanol) were studied to improve the adsorption ability of $CO_2$ gas on activated carbon. The equilibrium adsorption capacity of $CO_2$ gas was increased by increment of impregnation concentration up to 40 %, but decreased above 50 %. The adsorption capacity of activated carbon impregnated with AMP was higher than activated carbon impregnated with MEA. The breakthrough was fast according to increment of inlet concentration of $CO_2$ gas.

• Rapid Communication in Photoscience
• /
• 제2권1호
• /
• pp.1-8
• /
• 2013

Transparent $TiO_2$ films in various thicknesses were prepared by sol-gel and MOCVD method, respectively, and their photocatalytic activities in decomposing gaseous 2-propanol were evaluated. The surfaces and grain structures of the prepared films were characterized by FESEM, XRD, and AFM. It was found that the photocatalytic activities of $TiO_2$ films were greatly dependent on the film thickness and surface roughness: The photocatalytic activity increases with the increase of film thickness, while it decreases with the increase of surface roughness. We have proposed that these phenomena originate from the transfer of photogenerated electron and hole pairs from the bulk to the surface of $TiO_2$ film. Several experimental evidences supporting this mechanism have also been provided.

• 한국미생물·생명공학회지
• /
• 제24권2호
• /
• pp.213-216
• /
• 1996

Optically active carboxylic acid, D-(-)-$\beta$-hydroxyisobutyric acid {(D)-(-)-HIBA} is a useful chiral starting material for the preparation of enantiomerically pure bioactive compounds which have a chiral methyl carbon center in the molecule such as captopril, $\alpha$-tocopherol, erythromycin A, muscone and so on. (S)-3-Acetoxy-2-methylpropanol can be used as the precursor of (D)-(-)-HIBA, that is, chemical oxidation of the hydroxyl group and subsequent hydrolysis of acyl group in (S)-3-acetoxy-2-methylpropanol affords D-(-)-$\beta$-hydroxyisobutyric acid. (S)-3-Acetoxy-2-methyl-propanol was prepared by lipase-catalyzed asymmetric hydrolysis. In the enzymatic hydrolysis system, lipase AY (Candida rugosa) provided the expected (S)-3-acetoxy-2-methylpropanol in 60% e.e. of the enantiomeric purity under the phosphate buffer and organic co-solvent system.

• Bulletin of the Korean Chemical Society
• /
• 제18권2호
• /
• pp.203-208
• /
• 1997

A series of MgO-SiO2 catalysts were prepared by coprecipitation from the mixed solution of magnesium chloride and sodium silicate. Some of the sample were modified with 1 N H2SO4 and used as modified catalysts. The addition of MgO to SiO2 caused the increase of acidity and the shift of O-H and Si-O stretching bands of the silanol group to a lower frequency in proportion to the MgO content. The acid structure of MgO-SiO2 agreed with that proposed by Tanabe et al.. Catalytic activity for 2-propanol dehydration increased in relation to the increase of acidity and band shift to a lower frequency.

• 대한화학회지
• /
• 제34권2호
• /
• pp.203-210
• /
• 1990

의약 전달체에 사용되는 생체분해성 고분자로서 L-lactic acid 와 L-glutamic acid가 각기 다른 조성비로 이루어진 공중합체를 합성하였다. Poly (L-lactide)는 zink oxide를 이용하여 합성하였으며, Poly (L-lactide) 말단에 3-Amino-l-propanol을 도입시킨 다음 이미 합성된 γ-benzyl-L-glutamate-N-carboxyanhydride (γ-BLG-NCA)를 개환중합시켜서 block copoly (L-lactide-γ-benzyl-L-glutamate)를 합성하였다. NMR로써 L-lactide와 γ-BLG-NCA가 서로 일정한 비율로 이루어진 공중합체가 합성되었음을 확인하였으며, 생성된 공중합체들의 열적성질은 시차주사열량계법 및 열무게 측정법으로 조사하였다.

• 한국세라믹학회지
• /
• 제32권3호
• /
• pp.281-288
• /
• 1995

to prepare the TiO2 thin films, acetyl-acetone(2.4-pentanedione)(1 : 1 molar ratio) was dissolved in the propanol solution of titanium(IV)isopropoxide(Ti[OCH(CH3)2]4). Al, Cr and Sb in the form of soluble salt and niobium ethoxide were added s dopants, respectively. Thin films were coated by the dip-coating method and characteristics were investigated by XRD, SEM and conductance meter. As a result, viscosity of sol was maintained below 4 centi Poise more than 20 days, and crystal growth and diminution of resistivity occurred as the heat treatment temperature increased. The grains grew over 1${\mu}{\textrm}{m}$ and the lowest resistivity was obtained when Nb was added at 130$0^{\circ}C$.

• 한국결정성장학회지
• /
• 제22권1호
• /
• pp.15-18
• /
• 2012

Transparent conductive indium zinc oxide thin films were prepared by spin-coating a sol-gel solution. Zinc acetate dihydrate [$Zn(CH_3COO)_2{\cdot}2H_2O$] and indium acetate [In$(CH_3COO)_3$] were used as starting precursors, and 2-methoxyethanol with 1-propanol as solvents. Upon annealing in a temperature range from 500 to $1000^{\circ}C$, the thin film crystallizes into polycrystalline $In_2O_3$(ZnO). The lowest electrical resistivity was obtained at an annealing temperature of $700^{\circ}C$ as $2{\Omega}{\cdot}cm$. Average optical transmittances were higher than 80% at all annealing temperatures. These experimental results confirm that the sol-gel spin-coating can be a good simplified practical method for forming transparent electrodes.