• Bulletin of the Korean Chemical Society
• /
• v.6 no.2
• /
• pp.63-67
• /
• 1985

The NMR chemical shift arising from 3d electron spin dipolar nuclear spin angular momentum interactions for a 3d$^2$ system in a strong crystal field environment of octahedral symmetry has been investigated when the fourfold axis is chosen to be our axis of quantization. The NMR shift is separated into the contribution of 1/R$^5$ and 1/R$^7$ terms. A comparision of the multipolar terms with nonmultipolar results shows that the 1/R$^5$ term contributes dominantly to the NMR shift and there is in good agreement between the exact solution and the multipolar results when R ${\ge}$ 0.25. A temperature dependence analysis may lead to the results that the 1/T$^2$ term has the dominant contribution to the NMR shift for a paramagnetic 3d$^2$ system but the contribution of the 1/T term may not be negligible.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.21 no.9
• /
• pp.56-62
• /
• 2022

This study analyzed the output precision of 3D printing methods. The inner impeller of the centrifugal compressor was printed in as a sheet with 100% packing density using two methods: field deposition modelling and stereolithography. Dimensional differences between the initial CAD and printed models were evaluated using a 3D scanner. To investigate the dimensional characteristics of the 3D printed impeller, 3D dimension analysis and point dimension analysis were performed. The point dimension analysis was divided into 3D and 2D for comparative analysis.

• Proceedings of the PSK Conference
• /
• 2003.04a
• /
• pp.250.1-250.1
• /
• 2003

In this work, we have conducted 3D-QSAR studies on a series of acanthonic acid derivatives that act as COX-2 inhibitors, using two different methods: comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA). CoMFA and CoMSIA analysis of twenty five pimarane analogues produced good models with high predictive abilities. (omitted)

• Bulletin of the Korean Chemical Society
• /
• v.31 no.5
• /
• pp.1361-1367
• /
• 2010

A series of O,O-dialkyl-1-phenoxyacetoxy-1-methylphosphonate analogues (1~22) as a new class of potent inhibitors of pyruvate dehydrogenase were synthesized and 3D-QSARs (three dimensional qantitative structure-activity relationships) models on the pre-emergency herbicidal activity against the seed of cucumber (Cucumus Sativa L.) were derived and discussed quantitatively using comparative molecular field analysis (CoMFA) and comparative molecular similarity indeces analysis (CoMSIA) methods. The statistical values of CoMSIA models were better predictability and fitness than those of CoMFA models. The inhibitory activities according to the optimized CoMSIA model I were dependent on the electrostatic field (41.4%), the H-bond acceptor field (26.0%), the hydrophobic field (20.8%) and the steric field (11.7%). And also, it was found that the optimized CoMSIA model I with the sensitivity to the perturbation ($d_q{^{2'}}/dr^2{_{yy'}}$ = 0.830) and the prediction ($q^2$ = 0.503) produced by a progressive scrambling analyses were not dependent on chance correlation. From the results of graphical analyses on the contour maps with the optimized CoMSIA model I, it is expected that the structural distinctions and descriptors that subscribe to herbicidal activities will be able to apply new an herbicide design.

• Journal of Power Electronics
• /
• v.3 no.2
• /
• pp.115-123
• /
• 2003

This paper presents analysis, design and simulation for the indirect field orientation control (IFOC) of induction machine drive system. The dynamic performance of the IFOC under nominal and detuned parameters of the induction machine is established. A conventional proportional plus integral-derivative (PI-D) two-degree-of-freedom controller (2DOFC) is designed and analysed for an ideal IFOC induction machine drive at nominal parameters with the desired dynamic response. Varying the induction machine parameters causes a degredation in the dynamic response for disturbance rejection and tracking performance with PI-D 2DOF speed controller. Therefore, conventional controllers can nut meet a wide range of speed tracking performance under parameter variations. To achieve high- dynamic performance, a proposed robust fuzzy logic controllers (RFLC) for d-axis rotor flux, d-q axis stator currents and rotor speed have been designed and analysed. These controllers provide robust tracking and disturbance rejection performance when detuning occurres and improve the dynamic behavior. The proposed REL controllers provide a fast and accurate dynamic response in tracking and disturbance rejection characteristics under parameter variations. Computer simulation results demonstrate the effectiveness of the proposed REL controllers and a robust performance is obtained fur IFOC induction machine drive system.

• Journal of Korea Water Resources Association
• /
• v.54 no.7
• /
• pp.495-507
• /
• 2021

With the recent industrial development, accidental pollution in riverine environments has frequently occurred. It is thus necessary to simulate pollutant transport and dispersion using water quality models for predicting pollutant residence times. In this study, we conducted a field experiment in a meandering reach of the Sum River, South Korea, to validate the field applicability and prediction accuracy of RAMS+ (River Analysis and Modeling System+), which is a two-dimensional (2D) stream flow/water quality analysis program. As a result of the simulation, the flow analysis model HDM-2Di and the water quality analysis model CTM-2D-TX accurately simulated the 2D flow characteristics, and transport and mixing behaviors of the pollutant tracer, respectively. In particular, CTM-2D-TX adequately reproduced the elongation of the pollutant cloud, caused by the storage effect associated with local low-velocity zones. Furthermore, the transport model effectively simulated the secondary flow-driven lateral mixing at the meander bend via 2D dispersion coefficients. We calculated the residence time for the critical concentration, and it was elucidated that the calculated residence times are spatially heterogeneous, even in the channel-width direction. The findings of this study suggest that the 2D water quality model could be the accidental pollution analysis tool more efficient and accurate than one-dimensional models, which cannot produce the 2D information such as the 2D residence time distribution.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2000.11a
• /
• pp.389-392
• /
• 2000

This paper presents a performance Analysis of electrically exhaust gas recirculation valve using commercial electromagnetic simulation software, Flux2D. Under the assumption of 2D axi-symmetric magnetic field, the characteristics of EEGR valve by revising the design parameter, has ken investigated by estimating the variation of thrust force with respect to the pintle position. The mode shapes and the frequency response functions were computed by using three dimensional finite element modeling of the whole EEGR valve and their accuracies were verified with experimental FFT analysis technique.

• Architectural research
• /
• v.13 no.3
• /
• pp.19-29
• /
• 2011

Visibility of a space have been defined in several different ways: such as the axial line covering a convex space, a convex space defining the fattest shape in a space and an Isovist field formed by a field of vision at a given vantage point. Isovist fields are referred to as a descriptive medium to describe a movement by reviewing and analyzing geometric properties in them. Many descriptive methods for analysis of three-dimensional isovist are applied to analyzing the morphological properties in a 3D space more realistically. Although these models are regarded as a more advanced method for describing spatial properties, they have pros and cons such as complex mathematical calculations and somewhat arbitrary calibration in addition to huge consumption of memory space. These difficulties lead to the development of a three-dimensional visual accessibility model that explores the implication of building shape on the calculation of isovist fields drawn on a 2D plane. We propose a conceptual framework of how to measure the isovist field not as a 3D volume but as a combination of 2D plane on the ground with the 3D building shape of it's facade.

• Journal of the Korean Geotechnical Society
• /
• v.24 no.8
• /
• pp.43-52
• /
• 2008

In this study, the verification test and creep test for both a single-rebar nail and a multi-rebar nail are carried out to investigate a tensile strength for both nails. The adhesion effects between a rebar and a cement grout, a mobilized frictional force induced by pull-out load, and load transfer characteristics are examined. The results obtained from the field pull-out tests and from the numerical analysis using $FLAC^{2D}$ which is one of the programs developed based on the finite difference method are analyzed and compared for a single-rebar nail and a multi-rebar nail. The field pull-out test results for a multi-rebar nail relative to a single-rebar nail show that a tensile failure load is relatively large and the pull-out loads are well transferred to the ground in deep depth.

• Journal of Astronomy and Space Sciences
• /
• v.29 no.4
• /
• pp.329-336
• /
• 2012

Korea Astronomy and Space Science Institute researchers have installed and operated magnetometers at Bohyunsan Observatory to measure the Earth's magnetic field variations in South Korea. In 2007, we installed a fluxgate magnetometer (RFP-523C) to measure H, D, and Z components of the geomagnetic field. In addition, in 2009, we installed a Overhauser proton sensor to measure the absolute total magnetic field F and a three-axis magneto-impedance sensor for spectrum analysis. Currently three types of magnetometer data have been accumulated. In this paper, we use the H, D, Z components of fluxgate magnetometer data to investigate the characteristics of mid-latitude geomagnetic field variation. To remove the temporary changes in Earth's geomagnetic filed by space weather, we use the international quiet days' data only. In other words, we performed a superposed epoch analysis using five days per each month during 2008-2011. We find that daily variations of H, D, and Z shows similar tendency compared to previous results using all days. That is, H, D, Z all three components' quiet intervals terminate near the sunrise and shows maximum 2-3 hours after the culmination and the quiet interval start from near the sunset. Seasonal variations show similar dependences to the Sun. As it becomes hot season, the geomagnetic field variation's amplitude becomes large and the quiet interval becomes shortened. It is well-known that these variations are effects of Sq current system in the Earth's atmosphere. We confirm that the typical mid-latitude geomagnetic field variations due to the Sq current system by excluding all possible association with the space weather.