• Journal of the Korea Institute of Building Construction
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• v.16 no.2
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• pp.185-192
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• 2016

The semi-adiabatic calorimetry technique is a robust and easy technique that can be used to measure the temperature rise of concrete. This method is often used for investigating the maturity of concrete, as well as to predict maximum temperature rise of mass concrete using various heat loss compensating models. Semi-adiabatic calorimetry can also be used for predicting setting time of concrete. However, it has seldom been used to investigate the hydration characteristics of various cement paste samples. In this research, semi-adiabatic calorimetry and X-ray diffraction methods were used to investigate the hydration characteristics of 3 different ASTM type I Portland cements. First derivative of temperature rise (dT/dt) curve was used to isolate individual peaks. Based on the results of the experiments, a combination of dT/dt curve with XRD could be used to successfully identify hydration at a specific time period, showing its potential to be used as an alternative tool for hydration studies of cement-based materials.

• Smart Structures and Systems
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• v.24 no.2
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• pp.157-171
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• 2019

This study investigated the effects of the geometric parameters of superelastic shape memory alloy (SE SMA) fibers on the pullout displacement recovering and self-healing capacity of reinforced cementitious composites. Three diameters of 0.5, 0.7 and 1.0 mm and two different crimped lengths of 5.0 and 10.0 mm were considered. To provide best anchoring action and high bond between fiber and cement mortar, the fibers were crimped at the end to create spear-head shape. The single fiber cement-based specimens were manufactured with the cement mortar of a compressive strength of 84 MPa with the square shape at the top and a dog-bone shape at the bottom. The embedded length of each fiber was 15 mm. The pullout test was performed with displacement control to obtain monotonic or hysteretic behaviors. The results showed that pullout displacements were recovered after fibers slipped and stuck in the specimen. The specimens with fiber of larger diameter showed better displacement recovering capacity. The flag-shaped behavior was observed for all specimens, and those with fiber of 1.0 mm diameter showed the clearest one. It was observed that the length of fiber anchorage did not have a significant effect on the displacement recovery, pullout resistance and self-healing capacity.

• Journal of Energy Engineering
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• v.28 no.1
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• pp.17-21
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• 2019

Calcium sulfaluminate (CSA) was synthesized to improve the shrinkage of OPC. In this study, the setting time, the compressive strength and the length change ratio were confirmed by replacing the synthesized CSA with OPC by 10% and 13% by 16%. In the case of shrinkage-reducing type cement, formation of Ca-Al-$H_2$-based hydrate was activated. Therefore, the setting time was shortened. The compressive strength of the shrinkage - reducing type cement is comparable to that of OPC after 7 days' strength. However, shrinkage reducing type cement showed improved initial strength compared to OPC. The length change ratio was found to be improved by drying shrinkage from -0.075% to -0.047% on the 28th day.

• Advances in concrete construction
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• v.11 no.5
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• pp.419-428
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• 2021

The pH of cement-based materials (CBMs) is an important factor for their durability, sustainability, and long service life. Currently, the use of supplementary cementitious materials (SCMs) is becoming mandatory due to economic, environmental, and sustainable issues. There is a decreasing trend in pH of CBMs due to incorporation of SCMs. The determination of numerical values of pH is very important for various low and high volume SCMs blended cement mortars for the better understanding of different defects and durability issues during their service life. In addition, the effect of cement hydration and pozzolanic reaction of SCMs on the pH should be determined at initial and later ages. In this study, the effect of low and high-volume fly ash (FA) and ground granulated ballast furnace slag (GGBFS) cement mortars in different curing conditions on their pH values has been determined. Thermal gravimetric analysis (TGA) was carried out to support the findings from pH measurements. In addition, thermal conductivity (k-value) and strength activity indices of these cement mortars were discussed. The results showed that pH values of all blended cement mortars were less than ordinary Portland cement (OPC) mortar in all curing conditions used. There was a decreasing tendency in pH of all mortars with passage of time. In addition, the pH of cement mortars was not only dependent on the quantity of Ca(OH)₂. The effect of adding SCMs on the pH value of cement mortar should be monitored and measured for both short and long terms.

• Magazine of the Korean Society of Agricultural Engineers
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• v.26 no.1
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• pp.52-72
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• 1984

This study was performed to obtain the basic data which can be applied to the use of epoxy resin mortars. The data was based on the properties of epoxy resin mortars depending upon various mixing ratios to compare those of cement mortar. The resin which was used at this experiment was Epi-Bis type epoxy resin which is extensively being used as concrete structures. In the case of epoxy resin mortar, mixing ratios of resin to fine aggregate were 1: 2, 1: 4, 1: 6, 1: 8, 1:10, 1 :12 and 1:14, but the ratio of cement to fine aggregate in cement mortar was 1 : 2.5. The results obtained are summarized as follows; 1.When the mixing ratio was 1: 6, the highest density was 2.01 g/cm$^3$, being lower than 2.13 g/cm$^3$ of that of cement mortar. 2.According to the water absorption and water permeability test, the watertightness was shown very high at the mixing ratios of 1: 2, 1: 4 and 1: 6. But then the mixing ratio was less than 1 : 6, the watertightness considerably decreased. By this result, it was regarded that optimum mixing ratio of epoxy resin mortar for watertight structures should be richer mixing ratio than 1: 6. 3.The hardening shrinkage was large as the mixing ratio became leaner, but the values were remarkably small as compared with cement mortar. And the influence of dryness and moisture was exerted little at richer mixing ratio than 1: 6, but its effect was obvious at the lean mixing ratio, 1: 8, 1:10,1:12 and 1:14. It was confirmed that the optimum mixing ratio for concrete structures which would be influenced by the repeated dryness and moisture should be rich mixing ratio higher than 1: 6. 4.The compressive, bending and splitting tensile strenghs were observed very high, even the value at the mixing ratio of 1:14 was higher than that of cement mortar. It showed that epoxy resin mortar especially was to have high strength in bending and splitting tensile strength. Also, the initial strength within 24 hours gave rise to high value. Thus it was clear that epoxy resin was rapid hardening material. The multiple regression equations of strength were computed depending on a function of mixing ratios and curing times. 5.The elastic moduli derived from the compressive stress-strain curve were slightly smaller than the value of cement mortar, and the toughness of epoxy resin mortar was larger than that of cement mortar. 6.The impact resistance was strong compared with cement mortar at all mixing ratios. Especially, bending impact strength by the square pillar specimens was higher than the impact resistance of flat specimens or cylinderic specimens. 7.The Brinell hardness was relatively larger than that of cement mortar, but it gradually decreased with the decline of mixing ratio, and Brinell hardness at mixing ratio of 1 :14 was much the same as cement mortar. 8.The abrasion rate of epoxy resin mortar at all mixing ratio, when Losangeles abation testing machine revolved 500 times, was very low. Even mixing ratio of 1 :14 was no more than 31.41%, which was less than critical abrasion rate 40% of coarse aggregate for cement concrete. Consequently, the abrasion rate of epoxy resin mortar was superior to cement mortar, and the relation between abrasion rate and Brinell hardness was highly significant as exponential curve. 9.The highest bond strength of epoxy resin mortar was 12.9 kg/cm$^2$ at the mixing ratio of 1:2. The failure of bonded flat steel specimens occurred on the part of epoxy resin mortar at the mixing ratio of 1: 2 and 1: 4, and that of bonded cement concrete specimens was fond on the part of combained concrete at the mixing ratio of 1 : 2 ,1: 4 and 1: 6. It was confirmed that the optimum mixing ratio for bonding of steel plate, and of cement concrete should be rich mixing ratio above 1 : 4 and 1 : 6 respectively. 10.The variations of color tone by heating began to take place at about 60˚C, and the ultimate change occurred at 120˚C. The compressive, bending and splitting tensile strengths increased with rising temperature up to 80˚ C, but these rapidly decreased when temperature was above 800 C. Accordingly, it was evident that the resistance temperature of epoxy resin mortar was about 80˚C which was generally considered lower than that of the other concrete materials. But it is likely that there is no problem in epoxy resin mortar when used for unnecessary materials of high temperature resistance. The multiple regression equations of strength were computed depending on a function of mixing ratios and heating temperatures. 11.The susceptibility to chemical attack of cement mortar was easily affected by inorganic and organic acid. and that of epoxy resin mortar with mixing ratio of 1: 4 was of great resistance. On the other hand, when mixing ratio was lower than 1 : 8 epoxy resin mortar had very poor resistance, especially being poor resistant to organicacid. Therefore, for the structures requiring chemical resistance optimum mixing of epoxy resin mortar should be rich mixing ratio higher than 1: 4.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.93-94
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• 2023

Through the industrial revolution that began in the 18th century, the amount of carbon dioxide in the atmosphere increased rapidly as humans used fossil energy such as coal and oil as fuel for steam engines and factory machines. The amount of carbon dioxide emitted while producing cement, the main material of concrete used in construction, is large enough to account for 5-8% of the world's carbon dioxide emissions. In this study, Non cement-based matrix were used to reduce carbon dioxide emissions from cement production. Red mud is an industrial by-product generated in the manufacturing process of aluminum hydroxide using bauxite, and more than 120 million tons are produced worldwide. In addition, red mud is a porous material that can be physically adsorbed, and causes a photocatalytic reaction of TiO₂ to remove harmful substances such as nitrogen oxide formaldehyde in the air and chemically adsorbs ammonia and hydrogen sulfide. Therefore, this study aims to examine the physical properties of the matrix by mixing red mud, an industrial by-product with good adsorption performance, into the Non cement-based matrix.

• Journal of Korean Tunnelling and Underground Space Association
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• v.20 no.2
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• pp.485-500
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• 2018

The behavior of cement-based permeation grouting is divided into three different groups depending on the grain size distribution of the soils: (1) zone of cement-based permeation grouting not feasible; (2) zone of cement-based permeation grouting feasible; and (3) zone in which an accelerating agent should be added to limit the penetration depth. In the cement-based permeation grouting feasible zone, the concept of a representative pore radius was proposed. The ratios of the representative pore radius to the mean pore radius were obtained by performing laboratory test and comparing with clogging theory; these values were in the range of 1.07 and 1.35 depending on the grain size distribution of the soils. In addition, a functional relationship between the lumped parameter (${\theta}$), the representative pore radius and the w/c ratio were derived by comparing and matching experimental results with predictions from theory. In the zone in which the accelerating agent should be added, the controlling process of gel time to limit the penetration depth was experimentally verified. The test results matched well with those obtained from theory utilizing the developed grout penetration program on condition that the viscosity increasing tendency of grout suspension with time is properly taken into account.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.2
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• pp.27-34
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• 2024

This study was conducted to examine the feasibility of using Fe-activated wood-derived biochar as a conductive filler for manufacturing cement-based strain sensor. To evaluate the compressive and electrical properties of cement composite with 3% Fe-activated biochar, three cubic specimens of size 50 x 50 x 50mm³ and three prismatic cement-based sensors of size 40 x 40 x 80mm³ were prepared respectively. The four-probe method of electrical resistance measurement was used for cement-based sensors. For cement-based sensors with FE-activated biochar, the conductive performance such as electrical resistance and impedance under different water content and repeated compression was investigated. Results showed that the fractional changes in the DC electrical resistivity of cement-based sensors increase with increasing time and the maximum fractional changes in the resistivity decrease with increasing the moisture contents during 900s. At moisture content of 7.5% range, the conductive performance of cement composite including 3% Fe-activated biochar as a conductive filler showed the most stable, while the strain detection ability tended to decrease somewhat as the repeated compressive stress increased between repeated compressive strain and fractional change in resistivity (FCR).

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.5
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• pp.144-152
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• 2010

In this study, cement-based filler is used as an adhesive instead of organic adhesive, epoxy because there were problems under wet condition. First, the bond strength of cement-based filler was measured and the result was satisfied with KS F 4716. However, in case of wet condition, bond strength of epoxy adhesive decreased $0.73N/mm^2$ in 7 days and $0.84N/mm^2$ in 14 days from pilot test. This implies that there would be a problem on reinforced concrete structure in wet condition, such as tunnel and sewage box. In the second experiment, the flexural strength of RC beams with GFRP using different thickness of cement-based filler was investigated, and the result was indicated 113%, 66%, 75% increase in 10mm, 20mm, 30mm thickness, respectively. From the result, it was known that 10mm filler thickness produces stable bond performance.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.6
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• pp.111-119
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• 2023

Recently, a variety of new cement-based materials have been developed, and attempts to predict the properties of these new materials are increasing. In this study, we aimed to predict the rheological properties of binary blended pastes. The cementitious materials used in the study included Portland cement (PC), fly ash (FA), blast furnace slag (BS), and silica fume (SF). The three binder components, fly ash, blast furnace slag, and silica fume, were blended with cement as the foundational composition. We predicted the yield stress and plastic viscosity of the pastes using the YODEL (Yield stress mODEL) and Krieger-Dougherty's equation. The predictive model's performance was validated by comparing it with experimental results obtained using a rheometer. When the rheological properties of the binary blended paste were predicted by reconstructing the properties and parameters used to predict the individual materials, it was evident that the predictions made using the proposed method closely matched the experimental results.