• Title/Summary/Keyword: 2 order system

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Thermodynamic Comparison of Silicon Carbide CVD Process between CH3SiCl3-H2 and C3H8-SiCl4-H2 Systems (탄화규소 CVD 공정에서 CH3SiCl3-H2과 C3H8-SiCl4-H2계의 열역학적 비교)

  • Choi, Kyoon;Kim, Jun-Woo
    • Korean Journal of Metals and Materials
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    • v.50 no.8
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    • pp.569-573
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    • 2012
  • In order to understand the difference in SiC deposition between the $CH_3SiCl_3-H_2$ and $C_3H_8-SiCl_4-H_2$ systems, we calculate the phase stability among ${\beta}$-SiC, graphite and silicon. We constructed the phase-diagram of ${\beta}$-SiC over graphite and silicon via computational thermodynamic calculation considering pressure (P), temperature (T) and gas composition (C) as variables. Both P-T-C diagrams showed a very steep phase boundary between the SiC+C and SiC region perpendicular to the H/Si axis, and also showed an SiC+Si region with a H/Si value of up to 6700 in the $C_3H_8-SiCl_4-H_2$, and 5000 in the $CH_3SiCl_3-H_2$ system. This difference in phase boundaries is explained by the ratio of Cl to Si, which is 4 for the $C_3H_8-SiCl_4-H_2$ system and 3 for the $C_3H_8-SiCl_4-H_2$ system. Because the C/Si ratio is fixed at 1 in the $CH_3SiCl_3-H_2$ system while it can be variable in the $C_3H_8-SiCl_4-H_2$ system, the functionally graded material is applicable for better mechanical bonding during SiC coating on graphite substrate in the $C_3H_8-SiCl_4-H_2$ system.

Kinetics and Mechanism for Redox Reaction of cis-$[Co(en)_2(N_3)_2]^+$ with Fe(II) in Acidic Solution (산 촉매하에서 cis-$[Co(en)_2(N_3)_2]^+$ 와 Fe(II) 와의 산화-환원반응에 대한 반응속도와 메카니즘)

  • Byung-Kak Park;Kwang-Jin Kim;Joo-Sang Lim
    • Journal of the Korean Chemical Society
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    • v.33 no.3
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    • pp.309-314
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    • 1989
  • A kinetic study was carried out for the redox reaction of cis-$[Co(en)_2(N_3)_2]^+$ with Fe(II) in acidic solution by spectrophotometric methods. This redox reaction system have been found to show a third order for overall reaction as the respective first order with respect to reactant cis-$[Co(en)_2(N_3)_2]^+$, Fe(II), and $H^+$ catalyst. The activation parameters, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$, were obtained as 14.2Kcal/mol and -16.7 e.u., respectively. On the basis of the kinetic data, we suggest that the redox reaction system proceeds via inner sphere mechanism. The rate equation derived from the proposed mechanism is in agreement with the observed rate equation.

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A Study on the Management System and Participatory Self-Management of the Recreational Fishing in Korea (유어낚시의 관리유형과 자율적 관리진흥에 관한 연구)

  • Lee, Sang-Go;Park, Jeong-Seok
    • The Journal of Fisheries Business Administration
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    • v.36 no.2 s.68
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    • pp.71-95
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    • 2005
  • As one of the most popular outdoor leisure activities in the world, recreational fishing has a lof of significant meaning in terms of social, economic, and cultural views. However, both not considering an indiscreet fishing activity and environment and not thinking our next generation, fishing circumstance has been deteriorating more and more. Unlike Korea, most advanced countries enact various recreational fishing management and support policies in order to keep sustainable recreational fishing and develop eco-tourism through cooperation with government, fishing industries and civil organizations. This paper consist of the following contents. First, the study attempted to investigate how to operate management system of the recreational fishing dividing into in - land fishing and sea fishing respectively. And it exhibits issues and troubles of the realities of recreational fishing management and related fishing laws and ordinances in Korea. And then, it examines various fishing management schemes in representative advanced nations; U.S., Germany, and Japan. Also, it analyzes the advantages and disadvantages of respective recreational fishing management systems; market - based license system, qualification - based management system, and self- regulatory based management system. In addition, after these three systems are adopted to Korea's recreational fishing condition, we analyzes whether respective management systems fit or not. As a result of this, the optimal management for recreational fishing is the participatory self - management scheme in Korea. Finally, in order to support recreational fishing promotion and encouragement, issues and complementary policies with respect to recreational fishing are introduced.

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Hydraulic feasibility study on the open-loop geothermal system using a pairing technology (복수정 페어링 기술을 이용한 개방형 지열 시스템의 수리적 타당성 검토)

  • Bae, Sangmu;Kim, Hongkyo;Kim, Hyeon-woo;Nam, Yujin
    • KIEAE Journal
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    • v.17 no.3
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    • pp.119-124
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    • 2017
  • Purpose: Groundwater heat pump (GWHP) system has high coefficient of performance than conventional air-source heat pump system and closed-loop type geothermal system. However, there is problem in long-term operation that groundwater raise at the diffusion well and reduced at the supply well. Therefore, it is necessary to accurately predict the groundwater flow, groundwater movement and control the groundwater level in the wells. In this research, in consideration of hydrogeological characteristic, groundwater level and groundwater movement were conducted analysis in order to develop the optimal design method of the two-well system using the pairing pipe. Method: For the optimum design of the two-well system, this research focused on the design method of the pairing pipe in the simulation model. Especially, in order to control the groundwater level in wells, pairing pipe between the supply well and diffusion well was developed and the groundwater level during the system operation was analyzed by the numerical simulation. Result: As the result of simulation, the groundwater level increased to -2.65m even in the condition of low hydraulic conductivity and high pumping flow rate. Consequently, it was found that the developed system can be operated stably.

An Attitude Determination GPS and INS Integration Scheme: Design and Flight Experiment (자세측정용 GPS/INS 통합시스템 구성 및 비행 시험)

  • Kim, Jeong Won;Hwang, Dong-Hwan;Lee, Sang Jeong;Park, Chansik;Oh, Sang Heon;Kim, Se Hwan;Ahn, Lee-Ki;Lee, Jang-Ho
    • Journal of Advanced Navigation Technology
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    • v.8 no.2
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    • pp.112-119
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    • 2004
  • This paper proposes an attitude determination GPS/INS integrated system scheme for a UAV and presents experimental flight test results. The proposed system is designed as a part of an autopilot system and comprises a GPS attitude determination receiver, an off-the-shelf inertial measurement unit (IMU), and a navigation computer unit (NCU). UAV requires accurate attitude information for stable automatic flight control. The proposed system can provide accurate attitude information for the flight control computer (FCC) so that stable automatic flight control can be achieved. In order to verify the performance of the proposed scheme, an integrated navigation system has been developed. In order to evaluate the developed navigation system, the flight test has been performed. In the flight test, the developed system was shown to provide the position, the velocity and the attitude satisfactorily enough for stable flight control. The accuracy of the attitude information of the developed system was confirmed by comparing attitude of vertical gyro.

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The Study of Emission Characteristics of Biodiesel Fuel in Diesel Engines

  • Yeom, Jeong-Kuk
    • Journal of Power System Engineering
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    • v.19 no.1
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    • pp.56-63
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    • 2015
  • In this study, the exhaust characteristics of the diesel engine for the change of the mixing ratio of biodiesel fuel were quantitatively analyzed by using the numerical analysis method. As the fuel used in the experiment, the diesel and biodiesel(waste oil, soybean oil), the mixed fuel BD2(Diesel only), BD3, BD5, BD20, BD50 and BD100 were used. The injection pressure($p_{inj}$) was set to 400bar, 600bar, 800bar, 1000bar and 1200bar as the experimental variable. Also the concept of the standard deviation, Pearson's correlation coefficient and Spearman rank-order correlation coefficient based on the statistics was introduced in order to analyze the exhaust characteristics of the quantitative NOx and Soot according to the injection pressure and the mixing ratio variation of biodiesel blending fuel. It is considered that as a result of studies, for the waste oil, NOx and Soot can be simultaneously reduced through control of the mixing ratio at the regions of $p_{inj}=400bar$ and $p_{inj}=600bar$, and the Soot can be reduced without affecting on the emission of NOx at more than $p_{inj}=800bar$. For the soybean oil, NOx and Soot can be simultaneously reduced at $p_{inj}=400bar$ and the Soot can be reduced without affecting on the emission of NOx at $p_{inj}=600bar$.

Structuring of BOM and Routings for CIM System In Make to Order Environments -Application of CIM System for Ship Production- (수주생산 환경에서의 CIM 시스템을 위한 BOM과 라우팅의 구조화 -조선산업 사례 중심-)

  • Hwang, Sung-Ryong;Kim, Jae-Gyun
    • IE interfaces
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    • v.15 no.1
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    • pp.26-39
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    • 2002
  • Two key data areas of the integrated production database in computer-integrated manufacturing (CIM) systems are the product structure in the forms of bills of material(BOM) and the process structure in the forms of routings. The great majority of existing information systems regard the BOM and routing as two separate data entities, possibly with some degree of cross-referencing. This paper proposes new information structure called the bills of material and routings(BMR) that logically integrates the BOM and routings for the CIM systems in ship production. The characteristics of ship production are described as: 1) make-to-order production type, 2) combined manufacturing principles (workshop production and construction site production), 3) significant overlapping of design, planning and manufacturing, 4) very long order throughput time, 5) complex product structure and production process. The proposed BMR systematically manages ail parts and operations data needed ship production considering characteristics of ship production. Also, the BMR situated on the integrated production database more efficiently supports interface between engineering and production functions, and integrates a wide variety of functions within production such as production planning, process planning, operation scheduling, material planning, costing etc., and simplifies information flow between sub-systems in CIM systems.

Deployment Strategy of ARGO Floats in the East Sea (동해 ARGO 플로트의 투하 전략)

  • Park, Jong Jin;Park, Jong Sook
    • Ocean and Polar Research
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    • v.37 no.3
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    • pp.179-188
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    • 2015
  • This study was carried out to determine the optimal number of ARGO floats in the East Sea in order to maximize their applications. The dominant spatio-temporal scale, size of the domain, and the typical float lifetimes in the East Sea were taken into consideration. The mean spatial de-correlation scale of temperature on isobaric surfaces reaches about 60 km. The minimum necessary number of floats is about 82 on average in order to secure independent ARGO profiles with the de-correlation scale. Considering the float lifetimes, about 27 floats per year should be deployed to maintain the 82 ARGO float array every year. To obtain spatially uniform distribution of ARGO float data, mean residence time and dispersion rate (basin area/residence time) of ARGO floats were evaluated in each basin of the East Sea. A faster (slower) dispersion rate requires more (less) ARGO floats to maintain the spatially uniform number of floats. According to the analysis, it is likely that the optimal ratio of the number of floats for each basin is 1:2:4 corresponding to Ulleung Basin:Yamato Basin:Japan Basin. In order to maintain relatively uniform ARGO observing networks, it is necessary to establish a long-term plan for deployment strategy based on float pathways and the dispersion rate parameters estimated by using currently active ARGO float trajectory data as well as reanalysis data.

The Effects of Fertility Policies on Childbirth by Birth Order (저출산 대응정책이 출산순위별 출산에 미치는 영향)

  • Yoo, Gye-Sook
    • Journal of Families and Better Life
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    • v.27 no.2
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    • pp.191-201
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    • 2009
  • The Korean Government has recently prepared the comprehensive five-year basic plan (2006-2010) to deal with low fertility and population ageing. The basic plan aims at recovering the fertility rate to the appropriate level and improving the social and economic systems in preparation for the aged society. The main objective of this study was to examine the effects of fertility policies on childbirth by birth order. The data came from 1,729 adults who gave birth to babies in 2007 and 991 adults as the control group. The serial logistic regression analyses revealed that establishing the health and nutrition system for maternity and children, and expanding of tax and social insurance benefit were effective policy measures to increase childbirths of first children, while the policy measures establishing the health and nutrition system for maternity and children, supporting for daycare and pre-school education, and work-life balance were effective to childbirths of second or third children in 2007. However, the policies of supporting for costs of test-tube baby and expanding childcare infra didn't have any significant influences on childbirths in 2007. The implications of study results were discussed.

A Study of Authorized Stockage List Selection using Market Basket Analysis (장바구니 분석을 활용한 ASL 선정 연구)

  • Choi, Myoung-Jin
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.35 no.2
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    • pp.163-172
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    • 2012
  • In this study, It is assumed that customers are both usage unit of spare parts and stores of displaying and selling the goods that are installation unit of having the spare parts. The demand pattern through the effective order of spare parts and issue list in installation unit is investigated based on the assumption. Current ASL (Authorized Stockage List) selection of the army has been conducted in the way of using the analysis result of real usage experiences on spare parts used during the Korea War. For this study, ASL selection criteria and procedures based on army regulations and field manuals are specified. Since the traditional method does not presents the association analysis on spare parts used for the current equipment operating and does not have the clear criterion and analysis system about the ASL selection, in order to solve these problems, it was carried out that the association rule is employed for analyzing relationship between the effective order and issue list of the spare parts in point of the spare parts between usage unit and occurring month about purchase spare parts based on the star-schema table. Finally the new ASL selection way using the analysis result is proposed.