• Title/Summary/Keyword: 2중 입상

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Granulation of Artificial Zeolite for the Simultaneous Removal of Nitrogen and Phosphorous from the Wastewater (질소, 인 동시 제거용 입상 인공제올라이트 제조)

  • Lee, Deog-Bae;Lee, Kyeong-Bo;Han, Sang-Soo;Henmi, Teruo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.67-71
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    • 1998
  • This study was carried out to granulate artificial zeolite powder that remove ammonium nitrogen and phosphorous simultaneously in wastewater treatment. Optimum water content was required for 30 percent volume to granulate artificial zeolite with 1.7mm diameter and 1~2cm length using granulator. Portland cement could remove much $NH_4{^+}$ and $PO_4{^{3-}}$ from the wastewater than other binding materials. Mixed 33, 25. 20. 16 percent of portland cement to artificial zeolite powder(v/v), cation exchange capacity of the granulars were 66.5, 81.4, 126.8, $151.2cmol^+kg^{-1}$ and hardness of that were 176.1, 24.4, 4.1, $0.4kg\;cm^{-2}$, respectively. Content of portland cement in the granular were related with removal of $PO_4{^{3-}}$ positively and that of $NH_4{^+}$ negatively. Shaked 1g of the granulars that made of portland cement 33 percent with 40ml synthetic wastewater containing $NH_4{^+}$ $1545mgl^{-1}$ and $PO_4{^{3-}}$ $417mgl^{-1}$, 99.4 percent of $NH_4{^+}$ and 90.3 percent of $PO_4{^{3-}}$ were removed simultaneously after 48 hours shaking. The longer shaking, the more $NH_4{^+}$ and $PO_4{^{3-}}$were removed. The artificial zeolite granular had both micropore and macropore that could be useful in the wastewater purification.

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Comparison of Application Effects among Three Products of Granular Fused Magnesium Phosphate on Soybean Cultivation (대두(大豆)에 대한 입상(粒狀), 용성인비(熔成燐肥) 제품간(製品間)의 비효(肥效) 비교(比較))

  • Lim, Dong-Kyu;Kim, Seok-Cheol;Song, In-Kwan;Moon, Jae-Hyon;Choi, Du-Hoi;Kang, Hang-Won;Jung, Yeun-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.3
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    • pp.255-263
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    • 1996
  • This study was conducted to evaluate the application effects of three different granular fused magnesium phosphate products on soybean in a volcanic ash upland soil(Namweon series) of Cheju island. They were two domestic products(Kyunggi Chemical Industrial Co., LTD, Pungnong Biryo Industrial Co., LTD) and an imported Chinese product that were manufactured from different added materials. A powder fused magnesium phosphate. a single superphosphate(water soluble phosphatic fertilizer) and a fused superphosphate(mixed water soluble phosphate and 2% citric acid soluble phosphate) were presented as check fertilizers. Yield of soybean was the highest in the Pungnong product of granular fused magnesium phosphate. the next was the Chinese product imported and the Kyunggi product was the lowest but there was no statistical significance among the three granular products of fused magnesium phosphate. There was no clear tendency between yield and yield components of soybean plant however, the effects on the number of mainstem nodes, number of branches nodes and number of pods per plant were observed in the increased yield treaments. Phosphate concentration in stems and pods of soybean plant at harvesting stage was higher than those in stems of soybean plant during growing period. Uptake amounts and recovery rates of phosphate in stems and pods of soybean plant at harvesting stage were similar with the yield increasing tendency on soybean. In the changes of soil pH at different periods, the application of phosphatic fertilizers was increased soil pH. Soil pH in Chinese product was higher than domestic products, but it was similar to single superphosphate. The available silicate concentrations of soil were higher in the plot of Pungnong product than Chinese product.

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유가금속 회수공정 폐액중 셀레늄 제거에 관한 연구

  • Han, Sang-Uk;Lee, Hak-Seong
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2008.11a
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    • pp.495-498
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    • 2008
  • 여러 가지 흡착제를 사용한 회분식 흡착성능 측정 실험에서 흡착성능은 음이온교환수지 > 입상활성탄 > Biomass > 분말활성탄 > 제올라이트 순으로 나타났으며, 모든 흡착제는 30분 안에 흡착평형 상태에 도달 하였다. 음이온교환수지를 이용한 회분식 흡착실험에서 최대흡착량은 pH 10에서 0.0483 mmol/g로 가장 높았고, 대체적으로 pH가 높은 범위에서 흡착이 잘 되는 것으로 밝혀졌다. 이것은 산화물 상태의 셀레늄이 pH 6 이하의 영역에서는 HSeO$_3^{-}$가 존재하며, PH 6$\sim$10 영역에서는 HSeO$_3^{-}$와 SeO$_3^{-2}$가 공존하며, pH 10 이상에서는 SeO$_3^{-2}$만 존재함을 알 수 있는데, 실험에서도 유사한 결과가 나온 것으로 사료된다. 입상활성탄을 이용한 흡착실험에서 최대흡착량은 pH 4.5에서 0.0574 mmol/g으로 가장 높았다. pH 4.5$\sim$6.5 범위에서는 대체적으로 비슷한 성능을 나타내었다. 입상활성탄의 표면전위 특성상 음이온으로 존재하는 셀레늄과 정전기적 반발력으로 인해 흡착이 거의 일어나지 않는 것으로 보이지만, 음이온 상태로 존재하는 셀레늄 이외의 금속간 화합물이나 물리적인 결합상태의 미세입자들이 흡착된 것으로 보인다.

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The Study of Microstructure Influence at Fretting Contacts using Crystal Plasticity Simulation (결정 소성 시뮬레이션을 이용한 프레팅 접촉에서의 마이크로 구조 영향에 관한 연구)

  • Ko, Jun-Bin;Goh, Chung-Hyun;Lee, Kee-Seok
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.8 s.173
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    • pp.84-91
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    • 2005
  • The role of microstructure is quite significant in fretting of Ti-6Al-4V since its material properties depend strongly on crystallographic texture. In this study, we adopt crystal plasticity theory with a 2-D planar triple slip idealization to account fur microstructure effects such as grain orientation distribution, grain geometry, as well as $\alpha$ colony size. Crystal plasticity simulations suggest strong implications of microstructure effects at fretting contacts.

Morphology and Crystal Orientation of Mg Films formed on Hot Dip Galvanized Steel by PVD Method at Ar or N2 Gas Pressures and Their Corrosion Resistances (Ar 및 N2 가스압 중에서 PVD법에 의해 용융아연 도금 강재상 형성한 Mg 막의 모폴로지 및 결정배향성과 그 내식성)

  • Hwang, Seong-Hwa;Park, Jae-Hyeok;Park, Jun-Mu;Choe, In-Hye;Kim, Sun-Ho;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.166-166
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    • 2017
  • 금속 재료 중 철강은 기계적 특성이 우수하고 대량생산이 가능하여 선박, 건축, 자동차 등 다양한 분야에 기초재료로써 널리 사용되고 있다. 그러나 스테인리스강 등과 같은 일부 특수한 용도의 강을 제외하고는 부식환경에 취약한 특성을 가지기 때문에 내식성을 향상을 위한 표면처리에 관한 연구가 활발히 진행되고 있다. 가장 일반적으로 습식법(wet process)을 통해 표면상에 아연(Zn)을 도금해 사용하며, 아연이 자체적으로 포함한 희생양극(sacrificial anode) 및 차폐(barrier) 효과가 철강의 부식을 방지하게 된다. 하지만 산업의 고도화에 따라 더욱 가혹해진 노출환경으로 인해 고내식 강재에 대한 수요가 점차 증가하고 있으며, 아연코팅 층의 두께를 증가하여 내식성을 확보하는 방안은 미래 환경 및 자원적인 측면에서 근본적인 해결책으로 제시하기 어려움이 있다. 한편, 건식 프로세스(wet process)로 대별되는 PVD(physical vacuum deposition)에 의해 내식성을 향상시키고자 하는 연구들이 다양하게 진행되고 있다. 이것은 표면에 고순도 양질의 금속 막을 형성시킴으로써 외부환경과의 반응을 효과적으로 제어가 가능하며, 형성된 막은 그 물질의 고유 특성뿐만 아니라 제작 조건에 따른 표면의 기하학적 혹은 결정학적 구조에 의해 크게 영향을 받게 된다. 본 연구에서는 실용금속 중 이온화 경향이 가장 크고 산소와 반응하여 투과성이 작은 산화 피막 형성이 유리한 마그네슘(Mg)을 활용해 표면의 전기화학적 특성을 향상시켰다. 또한 금속 증착 중 진공도조절을 위해 도입되는 불활성 가스로 아르곤(Ar) 및 질소($N_2$)를 사용하여 표면에 형성한 막의 모폴로지 및 결정배향성이 내식성에 미치는 상관관계를 해석하고자 하였다. 실험방법으로 PVD법 중 비교적 간편하고 기초적인 지침을 제시하기 적합할 것으로 고려된 진공증착(vacuum evaporation)법을 이용해 아르곤 및 질소 분위기에서 진공도를 조절하며 용융아연도금상 Mg막을 형성하였다. 제작조건별 막의 기초 특성을 분석하기위해 SEM, EDS, XRD를 이용하였고, 결정배향성(crystal orientation) 분석을 위해 면간격(d-value)과 상대강도(relative intensity)를 확인하였다. 또한 내식성 평가로 염수분무(salt sprat test) 및 양극분극(anode polarization)을 각각 실시하였다. 실험결과에 따르면, Ar 및 $N_2$ 모두에서 가스압이 증가할수록 코팅층의 증착량은 적어지고 입상정(granular structure)의 모폴로지 형성 및 면간격과 상대강도가 증가하는 것이 확인되었다. 또한 쳄버 내 동일 진공도에서, $N_2$ 도입 시 Mg막은 더욱 치밀하고 미세한 입상정의 모폴로지로 형성되며 면간격과 상대강도는 더욱 증가한 것으로 나타났다. 내식성 평가에서 저진공 $N_2$ 조건에서 형성시킨 막이 가장 우수한 내식성이 나타났는데, 이는 상대적으로 불안정하고 반응하기 유리한 입계면적을 많이 포함한 입상정 모폴로지 및 표면에너지가 높은면의 면점유율 증가로 인해 외부환경과의 신속한 반응은 물론 안정적인 피막형성이 용이하였기 때문일 것으로 사료된다. 이상으로 Ar 및 $N_2$ 가스압 조건에 따른 고내식 Mg 막의 유효성을 확인하였고 향후 내식성을 향상시키는 방법으로 응용 가능할 것으로 생각된다.

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Analysis of the Composting Effect on Cow Manure by Aeration and Comparison of Characteristics of Cow Manure Pellet Composts According to Granulation Processing Method (송풍유무에 따른 우분퇴비화 효과분석 및 우분퇴비의 입상화방법별 특성비교)

  • Jeong, Kwang-Hwa;Kim, Jung-Kon;Lee, Dong-jun;Ravindran, B.;Kwag, Jung-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.2
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    • pp.69-76
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    • 2017
  • In the Korea, 80 percent of livestock manure were converted into compost and used as organic fertilizers. The livestock manure compost has two types of powder and pellet type (ID= 5~10 mm). The aim of this study was to investigate the properties of two types of cow manure compost pellet (cylinder and sphere type). Nitrogen concentrations of cylinder type and sphere type of compost pellets were 1.23 and 1.24%, respectively. There were similar with nitrogen concentration of cylinder and sphere types of compost pellets. As a result of analyzing the effect of granulation processing, it was found that the moisture content of the raw material was the most influential factor in the granulation processing in both of the processing types of the screw pressing method and the rotating cylinder method. When the cylinder and sphere types of compost pellets were dry to 20% of moisture content, the specific gravities of these compost pellets were 1.38 and 1.13, respectively. The compressive strength of cylinder type pellet and sphere type pellet were 27.6 and $11.3kg/cm^2$, respectively.

특집 - 송도 4공구 1.2 단지 쓰레기관로 수송 설비공사

  • 우양기건(주)
    • 월간 기계설비
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    • s.235
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    • pp.57-65
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    • 2010
  • 송도 신도시는 도시 전체를 '친환경 개발'로 기획함에 따라 쾌적한 주거환경 조성 및 편의성 제공을 위해 쓰레기관로수송 설비가 도입되었다. 쓰레기관로수송 설비는 투입구에 버려진 쓰레기를 중앙 집중제어 시스템에 의해, 아파트 입상 지하횡주관을 통해 중앙집하장으로 운반, 컨테이너에 자동적재 후 최종처리 됨으로써 위생적이고 쾌적한 주거환경을 구현하는 친환경적 설비 시스템이다. 쓰레기관로수송 설비는 과천시와 광명시도 의무화하여 시행중에 있으며, 송도 신도시 등의 성공적인 시공에 힘입어 인천광역시, 대구광역시, 파주시 등의 지방자치단체 및 구청에서도 폐기물 수집 운반 처리 방법의 개선을 위해 설치 의무화에 관한 행정 조례를 제정 추진 중에 있다.

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Effects of the Different Substrates on the Plant Growth and Mineral Contents of Hydroponically Grown Plantago asiatica in Aggregate Culture (배지종류가 추식 수경재배 질경이의 생장과 무기성분 함량에 미치는 영향)

  • Cho, Ja-Yong;Kim, Hong-Gi;Yu, Sung-Oh;Yang, Seung-Yul;Yang, Won-Mo;Kim, Byoung-Woo;Heo, Buk-Gu
    • Journal of Bio-Environment Control
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    • v.16 no.1
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    • pp.40-46
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    • 2007
  • This study was conducted to clarify the effects of the different substrates in terms of perlite (100%), peat moss (100%), granular rock wool (100%) and mixing perlite (50%) with peat moss (50%) on the growth responses and mineral contents of hydroponically grown Plantago asiatic in aggregate culture. Overall early plant growth such as plant height, stem diameter, number of leaves, root length, fresh and dry weight of shoot and root were increased in the order of that miked perlite and peat moss (50%:50%, v/v)>peat moss (100%)>granular rock wool (100%)>perlite (100%). Ca and Mg contents in plants became highest in the plants grown in the peat moss, however, Mg and Na in the granular rock wool. $P_2O_5$ content in plants were most increased in proportion to the plant growth increment in the peat moss (100%) and the mixing substrates of perlite and peat moss (50:50, v/v).

Adsorption Characteristics for Nitrosamines in Granular Activated Carbon Process (입상활성탄 공정에서의 nitrosamine류 흡착 특성)

  • Kim, Kyung-A;Son, Hee-Jong;Lee, Sang-Won;Bin, Jae-Hoon;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.10
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    • pp.709-714
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    • 2012
  • This study accessed the adsorption characteristics of the nine nitrosamine species on coal-based granular activated carbon (GAC). The breakthrough appeared first for NDMA and sequentially for NMOR, NPYR, NMEA, NDPA, NDEA, and NPIP. On the other hand, NDBA and NDPHA were not detected in the treated effluent for the operation period. The maximum adsorption capacity (X/M) for the seven nitrosamine species with apparent breakthrough points ranged from $27.5{\mu}g/g$ (for NDMA) to $671.0{\mu}g/g$ (for NPIP). Carbon usage rate (CUR) for NDMA was 1.07 g/day, 13.4 times higher than that for NPIP (0.08 g/day). The X/M values for the seven nitrosamine species were fitted well with a linear regression ($r^2$ = 0.94) by their octanol-water partitioning coefficient ($K_{ow}$).

Growth Characteristics of Hydroponically Grown Melon according to Volume of Granular Rockwool and Substrates of Coir and Rockwool (입상 암면 용량과 코이어 및 암면 배지 종류에 따른 수경재배 멜론의 생육 특성)

  • Dae Ho Jung;Su Hwan Oh;Da Mi Kim;Su Oh Lee;Chul Hee Cho;Hye Won Cho;Chul Kyoo Ha;Hyun-Ah Lee
    • Journal of Bio-Environment Control
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    • v.32 no.1
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    • pp.72-80
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    • 2023
  • Melons, a rich source of vitamins and fibers, are commonly grown in the soil. Hydroponic cultivation could improve yield and quality of melon and selection of substrate volume and the kind of substrates is important for hydroponic cultivation of melons. This study investigated the effect on melon growth according to volume of granular rockwool and substrates of coir and rockwool slab. 'Geumsegye' melon (Cucumis melo L. cv. Geumsegye) was cultivated hydroponically according to volume of granular rockwool to 1.0, 1.5, 2.0, 3.0, and 4.0 L, and was also cultivated using coir and rockwool slabs. Logistic model was applied to estimate the growth characteristics of melons such as plant height, leaf length, leaf width, and the characteristics of fruit. The growth characteristics of melons were significantly increased at 4.0 L compared to those grown of 1.0 L volume of on granular rockwool, and the results were the highest in coir and rockwool slabs. Melons grown in rockwool slabs showed the largest fruit fresh weight, fruit length, and fruit width. During hydroponic cultivation, growth characteristics of melon appropriate at the 4.0 L volume of granular rockwool, and the highest at coir and rockwool slabs. This study provides a basis for understanding the effect of root zone environment to the growth characteristics and fruit quality of non-netted melon.