• Title/Summary/Keyword: 2성분계

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Prediction of Autoignition Temperature of n-Decane and sec-Butanol Mixture (n-Decane과 sec-Butanol 혼합물의 최소자연발화온도의 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.85-90
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    • 2012
  • The autoignition temperature (AIT) of a material is the lowest temperature at which the material will spontaneously ignite. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs of n-Decane+sec-Butanol system by using ASTM E659 apparatus. The AITs of n-Decane and sec-Butanol which constituted binary system were $212^{\circ}C$ and $447^{\circ}C$, respectively. The experimental AITs of n-Decane+sec-Butanol system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

Prediction of Lower Explosion Limits of Binary Liquid Mixtures by Means of Solution Thermodynamics (용액열역학에 의한 2성분계 혼합물의 폭발하한계 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Journal of the Korean Institute of Gas
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    • v.13 no.5
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    • pp.20-25
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    • 2009
  • Low explosion limits of flammable liquid mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this paper, Raoult's law, van Laar equation and Wilson equation are shown to be applicable for the prediction of the lower explosion limits for ethylacetate+ethanol and ethanol+toluene systems. The calculated values based on Raoult's law were found to be better than those based on van Laar and Wilson equations.

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Comparison of principle components and quality of eggs by laying hen breeds (산란계 품종별에 따른 계란의 주요 성분과 품질 비교)

  • Kim, Byung Ki;Ha, Jae Jung;Yi, Jun Koo;Oh, Dong Yep;Jung, Dae Jin;Choi, Seong Bok;Hwang, Eun Gyoung;Kim, Soo Jung;Lee, Jea Young
    • Journal of the Korean Data and Information Science Society
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    • v.27 no.5
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    • pp.1307-1316
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    • 2016
  • This study was to execute the random arrangement of total 120 heads (10 heads per treatment plot ${\times}$ 3 repeats ${\times}$ 4 treatment plots) for four breeds [Blue arakana commercial Fowl (BC), Yeonsan silky fowl (YS), Korean native fowl (KN), White leghorn fowl (WL)] with the initiation of laying hens at 32 weeks old in order to comparatively analyze egg quality and composition by sorts of laying hens. In case of evaluation of the quality of eggs, this study has shown that BC had higher degree of Haugh unit coefficient (82.82) and in case cholesterol content of eggs, BC had significantly low content as 317.55mg/100g, but YS had rather higher content as 381.30mg/100g. Furthermore, this study has found out that BC had significantly low Oleic acid (C18:1n9) and WL had higher Amino acid content by breeds than those of other breeds (p<0.05).

The Prediction of Flash point of Binary systems by Using Regression Analysis (회귀분석을 이용한 2성분계 인화점 예측)

  • Park, Sang-Hun;Lee, Myung-Ho;Cho, Young-Se;Na, Byoung-Gyun;Kim, Kyu-Hyun;Kim, Wan-Seop;Lee, Sung-Jin;Ha, Dong-Myeong
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2013.04a
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    • pp.41-41
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    • 2013
  • 화학산업이 발달함에 따라 화학 산업 현장에서 사용되고 있는 가연성물질들의 여러 가지 화재 및 폭발 위험이 증가되고 있으며, 화재 및 폭발의 예방 안전을 위한 화학공정설계 및 대처에 있어, 물질의 연소특성치 데이터를 필요로 한다. 인화점은 가연성 액체를 다루는 공정에서 안전한 취급과 사고방지를 위해 중요한 자료가 되며, 화재의 위험을 나타내는 지표로서 가연성액체의 액면 가까이서 인화할 때 필요한 증기를 발산하는 액체의 최저온도, 그리고 가연성증기의 포화증기압이 공기와 혼합기체의 폭발한계 하한농도와 같게 되는 온도로 정의한다. 본 연구에서는 2성분계 혼합물에 대해 인화점을 측정하였고, 측정값을 Raoult의 법칙과 다중회귀분석(Multiple Regression)을 도입하여 이론값과 비교 하였다. 따라서 본 연구에서 제시된 방법론에 의해 아직까지 밝혀지지 않은 순수가연성액체와 가연성혼합물의 인화점을 예측하는 방법을 전개하고자 하며, 실험에서 찾고자하는 자료에 도움을 주고자 한다. 본 연구를 바탕으로 혼합물의 인화점 예측 방법과 실험에서 측정한 자료를 화재 및 폭발을 방지하는 기초 자료로 제공하고자하며, 산업현장에서 취급되고 있고 위험성 평가가 되지 않은 보다 많은 물질에 대한 이론 및 실험 연구에 활용 되도록 하는데 그 목적이 있다.

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Spalling Properties of 60, 80MPa High Strength Concrete with Fiber (복합섬유(PP, NY)를 혼입한 60, 80MPa 3성분계 고강도콘크리트의 내화특성)

  • Kim, Seong-Deok;Kim, Sang-Yun;Bae, Ki-Sun;Park, Su-Hee;Lee, Bum-Sik
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.4
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    • pp.3-9
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    • 2010
  • Fire resistance and material properties of high-strength concrete (W/B 21.5%, 28.5%) with OPC, BS and FA were tested in this study. Main factors of the test consisted of fiber mixing ratio and W/B. Two types of fiber (NY, PP) mixed with the same weight were used for the test. The fiber mixing ratios were 0%, 0.05%, 0.1%, and 0.2% of the concrete weight. After performing the test, Under the W/B level of 21.5% and 28.5%, the spalling was effectively resisted by using the high strength concrete with fiber mixing ratios of 0.05%~0.1%. Compressive strength, flowability and air content are similar those of the fiberless high-strength concrete with the same W/B.

Sea Level Variabilities in the East Asian Marginal Seas by Topex/Poseidon Altimeter Data (Topex/Poseidon 고도계자료를 이용한 동북아시아 연변해역의 해수면 변화 연구)

  • Yoon, Hong-Joo
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.5 no.6
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    • pp.1190-1194
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    • 2001
  • The first 7 years of altimeter data from the TOPEX/POSEIDON(T/P) were analyzed to study the surface circulation and its variability in the East Asian Marginal Seas. Long term averaged T/P sea level time series data where compared with in situ sea level measurements from a float-operated type tide gauge around of south Korea and Japan. T/]P data are a large contaminated by 60-day tidal aliasing effect, very near the alias periods of M2 and 52. When this 60-day effect is removed, the data agree well with the tide gauge data with 4.6 cm averaged RMS difference. The T/P derived sea level variability reveals clearly the well-known, strong current-topography such as Kuroshio. The T/P mean sea level of North Pacific(NP) was higher than Yellow Sea(YS) and East Sea(ES). The T/P sea level variability, with strong eddy and meandering, was the largest in eastern part of Japan and this variability was mainly due to the influence of bottom topography in Kuroshio Extension area.

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Analysis and Measurement of the Magnetic Fields Cause by Operation of Electromotive Installations (電動力設備의 運轉에 의해 發生되는 磁界의 測定과 解析)

  • Lee, Bok Hui
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.9 no.2
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    • pp.146-146
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    • 1995
  • 본 논문은 유도전동기의 운전조작시에 발생되는 자계변화특성에 대하여 기술하였다. 본 측정시스템은 자기적분형 자계센서, 증폭기, 능동형 적분기로 이루어졌으며, 교정실험에 대한 측정계의 주파수대역과 감도는 각각 20[Hz]∼0.234[mV/μT]이다. 유도전동기의 기동과 정상운전중에 발생하는 자계성분을 측정하였으며, 고조파 성분을 고속 푸리에 변환기법으로 분석하였다. 유도전동기의 직입기동시에는 단일성 펄스자계가 강하게 발생하였으며, 이의 피크치는 정상상태의 값보다 5배이상 크게 나타났다. 이러한 긴 과도시간과 강한 자계의 세기는 전동기의 큰 인덕턴스와 동특성에 기인된다. 유도전동기의 정상운전시에는 유도전동기의 극수에 의존하는 기본파에 대한 분조파의 자계성분이 관측되었다. 또한, 자계의 분조파 성분은 전동기의 토크 변동으로 불균일한 회전토크로 인해 생기는 맥동전류와 전압플리커에 의해서 발생하는 것으로 생각된다. 인버터구동형 유도전동기에서는 직입기동에 비하여 많은 고조파 성분이 발생되고 있었으며, 특히 전동기의 구동주파수가 낮을수록 맥동토크에 의한 전류변화로 고조파 성분은 더욱 증가하였다.

Interpretation of the Magnetic Logs for a Finite Line of Magnetic Dipoles Model (유한 선형 자기쌍극자 모델에 대한 검층자료의 해석)

  • Kim, Jin Hu
    • Journal of the Korean Geophysical Society
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    • v.2 no.2
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    • pp.135-142
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    • 1999
  • Interpretations of 3-component magnetic logging data obtained for a reinforced bar as a model of the line of the magnetic dipoles are conducted using a least squared inversion technique. The length of the bar is 1.12 m, sampling interval is 0.05 m, the distance between the bar and the borehole is 0.3 m, and the top of the bar is fixed at 0 m of depth. The bar is set to be approximately vertical. Magnetic anomalies smoothed with FFT are used as input data for the inversion. For the interpretation of magnetic logging data the depth to the top, the length, the magnetic moment per unit length, the direction of the magnetization (declination and inclination), and the bearing and plunge of the line of magnetic dipoles are left as unknown parameters. The comparison of the results obtained from the individual inversion of the horizontal component or the vertical component of the magnetic anomalies, and those from the simultaneous inversion of horizontal and vertical component of the magnetic anomalies shows that there exist some disagreements between each inversion result. The depth to the bottom of the bar, which is actually 1.12 m, is estimated as 1.18 m, and the inclination of the magnetization is estimated as -76°by simultaneous inversion. The negative value of the inclination indicates that the strength of the remnant magnetization is much greater than that of the induced magnetization, so that the direction of the resultant magnetization points to the top of the bar.

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Determination of the Nucleation Rate Curve for Lead Titanate in the PbO-TiO$_2$-B$_2$O$_3$-BaO by Diffferential Thermal Analysis (PbO-TiO$_2$-B$_2$O$_3$-BaO 계 유리에서 PbTiO$_3$ 결정의 핵생성 곡선 결정을 위한 열시차분석법의 응용)

  • 이선우;심광보;오근호
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.640-646
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    • 1998
  • Nucleation and crystallzation of a quaternary glass system for lead titanate glass-ceramics were in-vestigated using DTA(differential thermal analysis ) with variation of nucleation temperature and crystal growth time. Glass samples containing 60mol% of PbO-{{{{ { TiO}_{2 } }} were prepared from melts by the conventional normal cooling method in a cylindrical brass mould. The glass sample was nucleated between 40$0^{\circ}C$ and 50$0^{\circ}C$ for a given time and showed the maximum nucleation rate at 46$0^{\circ}C$ The DTA crystallization peak temperature decreased with increasing nucleating time and decreasing heating rate during DTA runs which indicated an increase of the number of nuclei produced in the system.

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Physio-chemical studies on the seed browning in mature green peppers stored at low-temperature (Part 1) -Changes in between-step metabolites and substrates in the seed-browning effect- (녹숙(綠熟)고추의 저온저장(低溫貯藏)에 따른 종자갈변(種子褐變)에 관(關)한 생리화학적연구(生理化學的硏究) -제 1 보(第 1 報) 종자갈변(種子褐變)에 관계(關係)되는 기질(基質)과 중간대사성분(中間代謝成分)의 변화(變化)-)

  • Lee, Sung-Woo
    • Korean Journal of Food Science and Technology
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    • v.3 no.1
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    • pp.29-36
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    • 1971
  • When a low-temperature treatment was given to a small sweet pepper variety Zairaisisi, the seed browning effect appeared soon. This change attracted the studies to determine and discuss the browning metabolites, polyphenolic compounds, and changes in their between-step components. (1) Chlorogenic acids were found as a polyphenolic compound in seed, whereas no flavanol-type polyphenol was observed. (2) There was sharp increase in total polyphenol content and chlorogenic acid with a low-temperature treatment. The contents of these substrates dropped below that of room-temperature treatment after the browning effect took place. (3) A marked increase in between-step metabolites phenylalanine, tyrosine, shikimic acid contents, and thus assumed activated shikimate pathway in this process. (4) It was suggested by determining the effect of specific metabolic inhibition and respiratory inhibitor administrations on enzymes that active biosynthesis of polyphenolic compounds takes place in shikimate pathway with combination of phosphoenolpyruvate and erythrose-4-phosphate connected to TCA cycle jaming after an active EMP pathway was gone through with sugars in pepper seeds at a low-temperature. (5) It was also suggested from the observation of increased K ion flow-out in pepper seeds with a low-temperature treatment that there is an abnormality in the plasma membrance.

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