• Title/Summary/Keyword: 2상 공존

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재벌기업(財閥企業)의 과잉투자(過剩投資) 및 그 원인(原因)에 관한 실증분석(實證分析)

  • Han, Jin-Hui
    • KDI Journal of Economic Policy
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    • v.21 no.1
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    • pp.3-58
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    • 1999
  • 본고는 위기 이전 우리나라의 상위 재벌기업이 과연 정부의 암묵적 투자손실보전(implicit loss-protection)에 기인하여 위험이 큰 사업에 과다하게 투자하였는가를 실증적으로 규명하여 보고자 하였다. 본고는 먼저 이론적 모형을 통하여 한 경제에 투자손실보전에 대한 기대하에서 투자를 한 기업과 그렇지 않은 기업이 공존할 때, 전자는 후자에 비하여 1) 투자를 많이 하게 될 뿐 아니라, 2) 불확실성의 증가에 대하여 투자를 더욱 늘릴 유인이 존재한다는 것을 보여주었다. 본고는 실증분석에서는 우리나라 상장기업(제조업 및 전산업)의 투자함수를 1992년~97년 기간에 대해 매출액 가속도모형(sales accelerator model)을 이용하여 추정한 결과, 투자손실보전에 대한 기대가 투자결정시 가장 중요하게 작용하였을 것으로 선험적으로 판단되는 5대 재벌기업과 이러한 기대가 가장 작았을 것으로 판단되는 독립기업간에 이론적으로 예상되었던 차이가 관찰되었다. 먼저 전체표본기업에 대한 분석(pooled regressions)에서는 5대 재벌기업은 여타기업에 비하여 매출액의 시차분포와 같은 통상적인 투자의 결정요인으로 설명될 수 없는 높은 투자수준의 차이가 두 그룹간 미래 수익성 전망의 차이, 유동성제약의 정도에 있어서의 차이, 기업규모에서의 차이 등에 기인할 가능성은 작은 것으로 나타났다. 한편 그룹별 분석(regressions by group)에서 5대 재벌기업은 수익률의 불확실성이 증가할 때 오히려 투자를 늘리는 것으로 관찰되었는데, 이는 여타기업에서 불확실성의 계수가 유의하지는 않지만 음수로 추정된 것과는 대조적이었다. 위의 결과는 과거 우리나라의 상위 재벌기업들이 재벌의 부도를 정부가 정치 경제적으로 수용하기 어려울 것이라는 대마불사(大馬不死)의 기대하에 고위험사업에 과다하게 투자하였다는 주장을 뒷받침한다고 판단된다. 향후 유사한 문제의 재발 방지를 위해서는 투자결과에 대한 책임을 투자자인 기업이 져야 함을 철저히 인식하도록 제도 및 관행상 개선노력이 필요하다고 판단되며, 특히 부실기업정리과정에서 부실에 대한 책임을 투자자가 지는 선례(先例)를 확립해 나가는 것이 무엇보다 중요할 것이다.

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Effect of nitrogen content on pitting formation at low nickel duplex stainless steel (듀플렉스상 스테인리스강에서 질소의 함량이 공식의 형성에 미치는 영향)

  • Choe, Jong-Beom;Lee, Gyeong-Hwang;Gang, Hyeong-Gu;Lee, Myeong-Hun;Yang, Jeong-Hyeon;Gang, Jun;Yun, Yong-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.61-61
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    • 2018
  • 듀플렉스 스테인리스강은 페라이트와 오스테나이트 상이 공존하는 특징을 갖는다. 그러한 구조에 의해서 페라이트와 오스테나이트상의 장점을 동시에 갖는 특성이 있다. 높은 강도와, 우수한 내식성, 응력 부식 균열 그리고 낮은 니켈의 함량 때문에 안정적인 가격을 갖는 장점을 갖기 때문에 운송, 기름과 가스, 해양플랜트, 건축 그리고 높은 강도와 우수한 내식성이 필요한 분야에서 수요가 증가할 것으로 사료된다. 이러한 듀플렉스 스테인리스강의 형성에서 페라이트와 오스테나이트상의 균형과 내식성을 개선하기 위해 질소가 첨가된다[1,2]. 본 연구는 저니켈 듀플렉스 스테인리스강(STS 329 FLD)의 공식 형성 과정에서 질소의 함량이 공식 형성과 내식특성에 미치는 영향을 동전위분극, XPS(X-ray Photoelectron Spectroscopy) 그리고 GDOES(Glow Discharge Optical Emission Spectrometry)를 이용하여 규명하였다. GDOES를 이용하여 깊이별 원소 분포를 정량적으로 비교한 결과, 부동태막에서 질소는 기저에 비하여 증가하였고, 질소의 함량이 증가함에 따라 wt.% 또한 증가하였다. 이러한 부동태막의 깊이별 원소 분포특성이 내식특성과 공식의 크기에 미치는 영향을 동전위분극을 이용하였다. 질소의 함량이 증가하였을 경우, 부식전위는 증가하였으며, 부식전류는 감소하였다. 또한 부동태전류가 감소한 것을 확인할 수 있었다. 이러한 차이의 원인을 확인하기 위하여 XPS를 이용하여 질소의 화학적 상태를 확인하였다. 질소는 암모니아의 형태로 존재하는 것으로 확인되었다. 암모니아 상태로 부동태막에 존재함에 따라 공식이 형성될 때, 암모늄 화함물을 형성하여 공식 내부의 산성도를 낮춤으로써 공식의 형성이 억제된 것으로 사료된다. 또한 공식 이후의 표면을 관찰 할 경우 질소의 함량이 증가함에 따라 표면에서 공식이 거의 관찰되지 않았다.

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Adaptive Packet Transmission Interval for Massively Multiplayer Online First-Person Shooter Games

  • Seungmuk, Oh;Yoonsik, Shim
    • Journal of the Korea Society of Computer and Information
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    • v.28 no.2
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    • pp.39-46
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    • 2023
  • We present an efficient packet transmission strategy for massively multiplayer online first-person shooter (MMOFPS) games using movement-adaptive packet transmission interval. The player motion in FPS games shows a wide spectrum of movement variability both in speed and orientation, where there is room for reducing the number of packets to be transmitted to the server depending on the predictability of the character's movement. In this work, the degree of variability (nonlinearity) of the player movements is measured at every packet transmission to calculate the next transmission time, which implements the adaptive transmission frequency according to the amount of movement change. Server-side prediction with a few auxiliary heuristics is performed in concert with the incoming packets to ensure reliability for synchronizing the connected clients. The comparison of our method with the previous fixed-interval transmission scheme is presented by demonstrating them using a test game environment.

Skarn Formation in Metamorphic Rocks of the Chungju Mine Area (충주광산 지역 계명산층의 텅스텐 스카른화작용)

  • Kim, Gun-Soo;Park, Maeng-Eon
    • Economic and Environmental Geology
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    • v.28 no.3
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    • pp.185-197
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    • 1995
  • Tungsten skarns in the Chungju mine which consists mainly of strata-bound type iron ore deposits are found in the vicinity of the contact between the age-unknown Kyemeongsan Formation and granitic rock intrusions of Mesozoic age($134{\pm}2Ma$). Tungsten skarns were formed extensively from alumina and silica-rich schistose rocks by the introduction of calcium and iron from hydrothermal solution. The skarns comprise a metasomatic column and are subdivided into four facies; garnet facies, wollastonite facies, epidote facies and chlorite facies. The skarn process in time-evolutional trend can be divided broadly into the four facies in terms of the paragenetic sequence of calc-silicates and their chemical composition. Skarn and ore minerals were formed in the following sequence; (1) garnet facies, adjacent to biotite granite, containing mainly garnet(>Ad96) and magnetite, (2) wollastonite facies containing mainly wollastonite and garnet(Ad95~60), (3) epidote facies, containing mainly epidote(Ps35~31), quartz, andradite-grossular(Ad63~50), and scheelite, (4) chlorite facies, adjacent to and replacing schist, containing mainly chrolite, muscovite, quartz, calcite, epidote(Ps31~25), hematite and sulfides. The mineral assemblage and mineral compositions. suggest that the chemical potentials of Ca and Fe increased toward the granitic rock, and the component Al, Mg, K, and Si decreased from the host rock to granitic rock. The homogenization temperature and salinity of fluid inclusion in scheelite, quartz and epidote of epidote facies skarn is $300-400^{\circ}C$ and 3-8wt.% eqiv. NaCl, respectively. ${\delta}^{34}S$ values of pyrite and galena associated with chlorite facies skarn is $9.13{\sim}9.51%_{\circ}$ and $5.85{\sim}5.96%_{\circ}$, respectively. The temperature obtained from isotopic com· position of coexisting pyrite-galena is $283{\pm}20^{\circ}C$. Mineral assemblages and fluid inclusion data indicate that skarn formed at low $X_{CO_2}$, approximately 0.01. Temperature of the skarn mineralization are estimated to be in the range of $400^{\circ}C$ to $260^{\circ}C$ and pressure to be 0.5 kbar. The oxygen fugacity($fo_2$) of the skarn mineralization decreased with time. The early skarn facies would have formed at log $fo_2$ values of about -25 to -27, and late skarn facies would have formed at log $fo_2$ values of -28 to -30. The estimated physicochemical condition during skarn formation suggests that the principal causes of scheelite mineralization are reduction of the ore·forming fluid and a decrease in temperature.

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Synthesis of Fe­Garnet for tile Immobilization of High Level Radioactive Waste (고준위 방사성폐기물의 고정화를 위한 Fe­석류석 합성 연구)

  • ;;;Yudintsev, S. V.
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.4
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    • pp.307-320
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    • 2003
  • Garnet has been considered as a possible matrix for the immobilization of radioactive actinides. It is expected that Fe­based garnet be able to have the high substitution ability of actinide elements because ionic radius of Fe in tetrahedral site is larger than that of Si of Si­based garnet. Accordingly, we synthesized Fe­garnet with the batch composition of $Ca_{2,5}$C $e_{0.5}$Z $r_2$F $e_3$ $O_{12}$ and $Ca_2$CeZrFeF $e_3$ $O_{12}$ and studied their phase relations and properties. Mixed samples were fabricated in pellet forms under the pressure of 400 kg/$\textrm{cm}^2$ and were sintered in the temperature range of 1100∼140$0^{\circ}C$ in atmospheric conditions. Phase identification and chemical composition of synthesized samples were analyzed by XRD and SEM/EDS. In results, where the compounds were sintered at 130$0^{\circ}C$, we optimally obtained Fe­garnets as the main phase, even though some minor phases like perovskite were included. The compositions of Fe­garnets synthesized from the batch compositions of $Ca_{2,5}$C $e_{0.5}$Z $r_2$F $e_3$ $O_{12}$ and $Ca_2$CeZrFeF $e_3$ $O_{12}$, are $Ca_{2.5­3.2}$C $e_{0.3­0.7}$Z $r_{1.8­2.8}$F $e_{1.9­3.2}$ $O_{12}$ and $Ca_{2.2­2.5}$C $e_{0.8­1.0}$Z $r_{1.3­1.6}$ F $e_{0.4­.07}$ F $e_{3­3.2}$ $O_{12}$, respectively. Ca contents were exceeded and Ce contents were exceeded or depleted in 8­coodinated site, comparing to the initial batch composition. These results were caused by the compensation of the difference of ionic radius between Ca and Ce.

A Study on the Adsorption Characteristic of Cobalt on ZrO2 in High-Temperature Water (고온수중에서 ZrO2의 코발트흡착 특성에 대한 연구)

  • Kim, Yu-Hwan;Bae, Seong-Youl
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.267-275
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    • 1997
  • $ZrO_2$ Powder was Prepared by sol-gel process and the adsorption characteristic of cobalt($Co^{2+}$) by $ZrO_2$ adsorbent in high-temperature water was investigated using batch adsorption experiment with a stirred autoclave. The prepared $ZrO_2$ was calcined at $600{\sim}1400^{\circ}C$ and analyzed by X-ray diffractometry, SEM, BET surface area, FT-IR and TG-DTA measurement. The tetragonal Phase of $ZrO_2$ is produced $480^{\circ}C$ from amorphous gel at temperature $480^{\circ}C$. Both tetragonal and monoclinic phase of $ZrO_2$ exist at temperature between $600^{\circ}C$ and $1000^{\circ}C$. At temperature $1200^{\circ}C$, tetragonal to monoclinic phase trasition is occurred. The $Co^{2+}$ adsorption capacity of $ZrO_2$ calcined at $600^{\circ}C$ for 4 hours is 0.16 meq $Co^{2+}/g$ adsorbent in the high temperature at $250^{\circ}C$. The adsorption of $Co^{2+}$ on the $ZrO_2$ adsorbent is irreversible endothermic in the temperature range ($125-175^{\circ}C$). The standard enthalpy change (${\Delta}H^{\circ}$) of $ZrO_2$ calcined at $600^{\circ}C$ for 4 hours is 18 kJ/gmol.

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Mineralogy and Geochemistry of the Jeonheung and Oksan Pb-Zn-Cu Deposits, Euiseong Area (의성(義城)지역 전흥(田興) 및 옥산(玉山) 열수(熱水) 연(鉛)-아연(亞鉛)-동(銅) 광상(鑛床)에 관한 광물학적(鑛物學的)·지화학적(地化學的) 연구(硏究))

  • Choi, Seon-Gyu;Lee, Jae-Ho;Yun, Seong-Taek;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.25 no.4
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    • pp.417-433
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    • 1992
  • Lead-zinc-copper deposits of the Jeonheung and the Oksan mines around Euiseong area occur as hydrothermal quartz and calcite veins that crosscut Cretaceous sedimentary rocks of the Gyeongsang Basin. The mineralization occurred in three distinct stages (I, II, and III): (I) quartz-sulfides-sulfosalts-hematite mineralization stage; (II) barren quartz-fluorite stage; and (III) barren calcite stage. Stage I ore minerals comprise pyrite, chalcopyrite, sphalerite, galena and Pb-Ag-Bi-Sb sulfosalts. Mineralogies of the two mines are different, and arsenopyrite, pyrrhotite, tetrahedrite and iron-rich (up to 21 mole % FeS) sphalerite are restricted to the Oksan mine. A K-Ar radiometric dating for sericite indicates that the Pb-Zn-Cu deposits of the Euiseong area were formed during late Cretaceous age ($62.3{\pm}2.8Ma$), likely associated with a subvolcanic activity related to the volcanic complex in the nearby Geumseongsan Caldera and the ubiquitous felsite dykes. Stage I mineralization occurred at temperatures between > $380^{\circ}C$ and $240^{\circ}C$ from fluids with salinities between 6.3 and 0.7 equiv. wt. % NaCl. The chalcopyrite deposition occurred mostly at higher temperatures of > $300^{\circ}C$. Fluid inclusion data indicate that the Pb-Zn-Cu ore mineralization resulted from a complex history of boiling, cooling and dilution of ore fluids. The mineralization at Jeonheung resulted mainly from cooling and dilution by an influx of cooler meteoric waters, whereas the mineralization at Oksan was largely due to fluid boiling. Evidence of fluid boiling suggests that pressures decreased from about 210 bars to 80 bars. This corresponds to a depth of about 900 m in a hydrothermal system that changed from lithostatic (closed) toward hydrostatic (open) conditions. Sulfur isotope compositions of sulfide minerals (${\delta}^{34}S=2.9{\sim}9.6$ per mil) indicate that the ${\delta}^{34}S_{{\Sigma}S}$ value of ore fluids was ${\approx}8.6$ per mil. This ${\delta}^{34}S_{{\Sigma}S}$ value is likely consistent with an igneous sulfur mixed with sulfates (?) in surrounding sedimentary rocks. Measured and calculated hydrogen and oxygen isotope values of ore-forming fluids suggest meteoric water dominance, approaching unexchanged meteoric water values. Equilibrium thermodynamic interpretation indicates that the temperature versus $fs_2$ variation of stage I ore fluids differed between the two mines as follows: the $fs_2$ of ore fluids at Jeonheung changed with decreasing temperature constantly near the pyrite-hematite-magnetite sulfidation curve, whereas those at Oksan changed from the pyrite-pyrrhotite sulfidation state towards the pyrite-hematite-magnetite state. The shift in minerals precipitated during stage I also reflects a concomitant $fo_2$ increase, probably due to mixing of ore fluids with cooler, more oxidizing meteoric waters. Thermodynamic consideration of copper solubility suggests that the ore-forming fluids cooled through boiling at Oksan and mixing with less-evolved meteoric waters at Jeonheung, and that this cooling was the main cause of copper deposition through destabilization of copper chloride complexes.

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A Study on Mossbauer Spectra of the ${Ni_{1+x}}{Ti_x}{Fe_{2-2x}}O_4$ System (${Ni_{1+x}}{Ti_x}{Fe_{2-2x}}O_4$계의 $\M"{o}ssbauer$ 스펙트럼 연구)

  • Baek, Seung-Do;Ko, Jeong-Dae;Hong, Sung-Rak
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.3-7
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    • 2001
  • $M\"{o}ssbauer$ spectra of the $Ni_{1+x}Ti_xFe_{2-2x}O_4$ systems ($0{\leqq}x{\leqq}0.7$), which appear as single phase spinel structure, were examined at RT. The $M\"{o}ssbauer$ spectra reveal two sextet for $0{\leqq}x{\leqq}0.3$, two sextet and a doublet for $0.4{\leqq}x{\leqq}0.6$, and a doublet for x=0.7 As x increases, the area ratio of B-site and A-site($A_B/A_A$) of the sextet decreases, and the area ratio of the doublet and the total areas($A_{doublet}/A_{tot.}$) increases. The isomer shift(I.S.) of A-site slightly increases and magnetic hyperfine fields($H_{hf}$) of two sites decrease as the increasing x. From these results, we have obtained the cation distributions of the samples and concluded that the increasing x leads to the decrease of covalency of $Fe^{3+}-O^{2-}$ bond in A-sites and A-B superexchange interactions.eractions.

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Hydrothermal Synthesis of Kaolinite (캐올리나이트의 수열합성)

  • Jang, Young-Nam;Ryu, Gyoung-Won;Chae, Soo-Chun;Lee, Sung-Ki;Suh, Yong-Jae;Bae, In-Kook
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.3
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    • pp.147-153
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    • 2007
  • Kaolinite [$Al_2Si_2O_5(OH)_4$] was successfully synthesized by a hydrothermal process from amorphous $Al(OH)_3$ and $SiO_2$ at $230^{\circ}C$ under the pressure of $30 kg/cm^2$. The experiments were performed varying temperatures ($180{\sim}280^{\circ}C$), pressure ($10{\sim}60kg/cm^2$), chemistry ($Al_2O_3/SiO_2 = 0.5{\sim}0.38$) and pH ($0.3{\sim}9.5$) of the solution. The autoclaving was carried out in a closed stainless steel vessel. Kaolinite appears from the starting composition of $Al_2O_3/SiO_2= 0.5$ with boehmite and was stable as a single phase with the composition of $Al_2O_3/SiO_2=0.45$. Boehmite was a stable phase below $200^{\circ}C$ for the 240 h period of autoclaving, but kaolinite appeared even in 20 h at $230^{\circ}C$. The single kaolinite phase of a good crystallinity was observed at pH ranging 2 to 6. That indicates that pH is one of the most critical parameters for the successful formation of kaolinite. The optimal molar ratio of $Al_2O_3$ to $SiO_2$ was determined to be 0.45. The XRD pattern of the synthesized kaolinite coincided with that of natural one and its morphology was the cluster type of the kaolinite crystals (diameter = ${\sim}3{\mu}m$), irrespective of starting material, composition and temperature.

Indication of Immanent Picture in Rural Settlement According to the Corelation between Man and his Environment (자연과 인간의식과의 관계로 본 “취락경관에서의 내적의미”에 관한여)

  • 정기호
    • Journal of the Korean Institute of Landscape Architecture
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    • v.14 no.2
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    • pp.17-26
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    • 1986
  • Landscape around a settlement is not only a natural object, but also a matters of the man in the co-relation with his environment. Man perceives the landscape rational or sensible. Then it changes into the substance for him and influences him: as we see often in the folklore, that is of importance in the mind. Man reacts against his surroundings deceidedly, selfassurd or commonly, and uses sometimes the landscape to the elements for realization, physical or symbolical. Out of one character of korean villages, adaption to the circumstances, we can notice also its inner image, the reflection of the mind. Seeing and perceiving the environment emotional or reasonable and, reflecting and descreibing the inner self on the space. Here, the landscape and the nature are matter of the man, a scale for his ethical estimation or a mailer of the realization his mind. It is difficult, but important, such a immanent picture in(or of) the landscape to find. This is a preliminary study in such a way.

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