• Journal of Magnetics
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• v.16 no.3
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• pp.225-228
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• 2011

Magnetic properties and Rockwell hardness of 1Cr-0.5Mo steel have been investigated as a function of isothermal aging time. Our results showed that coercivity, hysteresis loss and Rockwell hardness in the aged samples decreased as aging time increased. This phenomenon was analyzed using optical microscopy and scanning electron microscopy. A significant diffusion of Cr and Mo atoms formed $M_2C$ and $M_7C$ carbides, lowering the matrix strength. $M_2C$ and $M_7C$ carbides partially segregated inside grains, diffused into grain boundaries, and finally resulted in a soft ferrite matrix and a hard grain boundary. The magnetic and mechanical softening of the matrix is likely to govern the properties of the sample more than the hardening of the grain boundary by carbide precipitations.

• Journal of the Korean Society for Nondestructive Testing
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• v.21 no.5
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• pp.532-541
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• 2001

Developments of nondestructive evaluation techniques for reduction of strength or toughness by aging of material have been carried out, and the method using electrical resistivity is one of them. In this study, to examine the application of electrical resistivity to the evaluation of degradation of metallic alloy, ten different non-magnetic materials were selected as test materials. Electrical resistivities measured by DC two-point probe method and those measured by non-contact type eddy current method were compared with each other. In addition, to examine the application possibility of four-point probe technology in field, the electrical resistivities for 1Cr-lMo-0.25V steel measured by DC two-point probe method and four-point probe method were compared with each other Differences between two measured values for the 1Cr-1Mo-0.25V steel were 0.6%. Therefore, the four-point probe method can be applied to the estimation of the degradation of metallic alloy. ect.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.6
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• pp.1107-1113
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• 2002

This study presents the hydrogen emblittlement in the metal, which decreases the ductility and then induces the brittle fracture. The contribution deals with the effect of strain rate and notch geometry on hydrogen emblittlement of 1.25Cr-0.5Mo and 2.25Cr-1Mo steels, which are in use at high pressure vessel. Smooth and notched specimens were examined to obtain the elongation and tensile strength. For charging the hydrogen in the metal, the cathodic electrolytic method was used. In this process, current density is maintained constant. The amount of hydrogen penetrated in the specimen was detected by the hydrogen determenator(LECO RH404) with the various charging time. The distribution of hydrogen concentration penetrated in the specimen was obtained by finite element analysis. The amount of hydrogen is high in smooth specimen and tends to concentrate in the vicinity of surface. The elongation and tensile strength decreased with the passage of charging time in 1.25Cr-0.5Mo and 2.25Cr-1Mo steels. The elongation increased and tensile strength decreased as strain rate increased. As a result of this study, it is supposed that 1.25Cr-0.5Mo steel is more sensitive than 2.25Cr-lMo steel in hydrogen embrittlement. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

• Journal of the Korean Society for Nondestructive Testing
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• v.20 no.5
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• pp.445-450
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• 2000

The integrity of the turbine rotors can be assessed by measuring reversible permeability and Vickers hardness of the aged rotors at service temperature. The measurement system of reversible permeability, which measured by applied alternating perturbing magnetic field, was constructed in order to evaluate material degradation, nondestructively. The test specimen was 1Cr-1Mo-0.25V steel used widely for turbine rotor material, and the specimens were prepared by the isothermal heat treatment at $630\;^{\circ}C$. The reversible permeability of the test materials were measured at room temperature. The peak interval of reversible permeability and Vickers hardness decreased with the increase of degradation. The degradation of test material may be determined nondestructively by the lineality of Vickers hardness and the peak interval of reversible permeability.

• Journal of the Korean institute of surface engineering
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• v.51 no.3
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• pp.149-156
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• 2018

The corrosion and strength degradation characteristics of 1.25Cr-0.5Mo steels were studied under $650^{\circ}C$ in $76%N_2+6%O_2+16%CO_2+2%SO_2$ gas condition up to 500 hrs. Corroded specimens were characterized by weight gain, scanning electron microscope(SEM), energy dispersive X-ray spectroscopy(EDS), and X-ray diffraction(XRD). The tensile test was conducted to evaluate the mechanical strength and fracture mode with corrosion at high temperature. As the results of the experiments, thick Fe-rich oxide layers over $200{\mu}m$ were formed on the surface within 500 hrs. The thick oxide layers are formed with reduction of the cross-sectional area of the specimens. Thus, the strength tended to decrease with reduction of the cross-sectional area.

• Proceedings of the KWS Conference
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• 2005.11a
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• pp.65-66
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• 2005

In order to evaluate disbonding properties caused by hydrogen on the Electro Slag Strip Welding for 1.25Cr-0.5Mo steel, two kinds of welding consumables were selected and tested under the disbonding condition of $97.2kgf/cm^{2}$ at $425^{\circ}C$. Chemical composition of the welds showed that they have similar chemical compositions. The microsturucture investigation, however, indicated that 'A' weld has high ratio of coarse grain area, while B weld has low. Disbonding results showed that high ratio coarse grain welds showed unacceptable, while low ratio coarse grain welds showed acceptable.

• Journal of the Korean Society for Heat Treatment
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• v.11 no.3
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• pp.207-215
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• 1998

13%Cr martensitic stainless steel was microalloyed with 0~1.5%Mo, and the mechanical properties were tested at the various heat treated conditions. Mo addition increased austenitization temperature(Ac1), and had little influence on the hardness and tensile properties at the annealed condition. The higher the austenitizing temperature, the higher the hardness and tensile strength, but Mo addition decreased those properties. The impact energy after austenitization increased with addition of Mo. The decrease of mechanical properties and increase of impact energy of Mo-alloyed steel after austenitization are thought to be caused by formation of ductile ${\delta}$-ferrite phase in the microstructure.

• Nuclear Engineering and Technology
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• v.37 no.4
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• pp.375-384
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• 2005

To investigate the flow-accelerated corrosion (FAC) dependency of carbon steel (A106 Gr. B) and low-alloy steels (1Cr-1/2Mo, 21/4Cr-1Mo) on pH, orifice distance, and material, experiments were carried out. These experiments were performed using a flow velocity of 4 m/sec (partly 9 m/sec) at pH $8.0\~10.0$ in an oxygen-free aqueous solution re-circulated in an Erosion-Corrosion Test Loop at $130^{\circ}\;{\ldots}$ for 500 hours. The weight loss of the carbon steel specimens appeared to be positively dependent on the flow velocity. That of the carbon and low-alloy steel specimens also showed to be distinguishably dependent on the pH. At pH levels of $8.0\~9.5$ it decreased, but increased from 9.5 to 10.0. Utility water chemistry personnel should carefully consider this kind of pH dependency to control the water system pH to mitigate FAC of the piping system material. The weight loss of the specimens located further from the orifice in the distance range of $6.8\~27.2$ mm was shown to be greater, except for 21/4Cr-1Mo, which showed no orifice distance dependency. Low alloy steel specimens exhibited a factor of two times better resistance to FAC than that of the carbon steel. Based on this kind of FAC dependency of the carbon and low-alloy steels on the orifice distance and material, we conclude that it is necessary to alternate the composition of the secondary piping system material of NPPs, using low-alloy steels, such as 21/4Cr-1Mo, particularly when the system piping has to be replaced.

• Journal of Energy Engineering
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• v.26 no.4
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• pp.1-6
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• 2017

This study evaluated hydrogen effect of metal and non-metallic materials used in the hydrogen blended natural gas vehicle. Hydrogen penetrated concentration of 34Cr-Mo steel(850MPa tensile strength) for winter driving conditions was measured 0.0018ppm and summer driving conditions was 5.3ppm. The critical hydrogen concentration of high strength metal used in this study was measured 1.03ppm by CLT. Therefore, 34CrMo steel cas cause problems in the 30% HCNG(25MPa) environment. In case of the test for non-metallic materials, all materials met the criteria of the gas resistance test, but Fluorocarbon Rubber material had a significant change in the volume. So if it is used, extra care is needed.

• Journal of the Korean institute of surface engineering
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• v.49 no.2
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• pp.147-151
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• 2016

The T91 steel (Fe-9%Cr-1%Mo) was corroded at 600 and $700^{\circ}C$ for 5 - 70 h in the $N_2$/(0.5, 2.5)%$H_2$Smixed gas at one atm. It was corroded fast, forming the outer FeS layer and the inner (FeS, $FeCr_2O_4$)-mixed layer. The formation of the outer FeS layer facilitated the oxidation of Cr to $FeCr_2O_4$ in the inner layer. Since the nonprotective FeS scale was present over the whole scale, T91 steel displayed poor corrosion resistance.