• Title/Summary/Keyword: 13MeV

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$^{13}C$ and $^{51}V$ Nuclear Magnetic Resonance Studies of Vanadium(V) Complexes of Iminodiacetate Analogues

  • Lee, Man-Ho
    • Bulletin of the Korean Chemical Society
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    • v.13 no.1
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    • pp.22-26
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    • 1992
  • The solution structures of the vanadium(V) complexes of iminodiacetate analogues, such as iminodiacetate (IDA), methyliminodiacetate (MeIDA), ethyliminodiacetate (EtIDA), benzyliminodiacetate (BzIDA), pyridine-2,6-dicarboxylate (DPA), and 2-hydroxyethyliminodiacetate (HEIDA), have been studied by $^{13}C-$ and $^{51}V$-NMR spectroscopy. Assuming that the complexes have a $cis-VO_2$ core, IDA, MeIDA, EtIDA, and BzIDA act as facial tridentate ligands to form octahedral complexes, whereas DPA coordinates to $VO_2^+$ as a meridional tridentate. And one water molecule fulfills the remaining site to satisfy the coordination number of six. But HEIDA coordinates to $VO_2^+$ through one IDA moiety and one hydroxyl group, acting as a tetradenate.

A Mechanism of the Bound Exciton Interaction with Longitudinal Optical Lattice Vibrations in Cathodoluminescence of Cadmium-Sulphide

  • Chung, Kie-Hyung
    • Nuclear Engineering and Technology
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    • v.6 no.1
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    • pp.9-13
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    • 1974
  • The exciton emission spectra of CdS single crystals excited by electrons were measured at 80$^{\circ}$K as a function o: the wave length. The measured dissociation energy of exciton bound to neutral donor was 2.0 meV, compared to the corresponding theoretical value of 2.4 to 3.2 meV. An exciton bound to neutral donor and a longitudinal optical (LO) phonon may not interact, but a free exciton dissociated from a neutral donor and a LO phonon is expected to interact each other. Therefore the origin of the spectra consisting of interaction term was located at the spectrum consisting of a free exciton dissociated from a neutral donor (I$_2$d). From the analysis of the spectra the LO phonon energy of CdS was found to be 40.5 meV.

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Spectroscopic Properties of a Silicon Photomultiplier-based Ce:GAGG Scintillation Detector and Its Applicability for γ-ray Spectroscopy (감마선 분광분석을 위한 실리콘 광 증배소자 기반 Ce:GAGG 섬광검출기의 분광특성 연구)

  • Park, Hye Min;Kim, Jeong Ho;Kim, Dong Seong;Joo, Koan Sik
    • Journal of Radiation Protection and Research
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    • v.40 no.2
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    • pp.73-78
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    • 2015
  • In this study, a scintillation detector was fabricated using a silicon photomultiplier (SiPM) and a Ce:GAGG scintillator single crystal, and its spectroscopic properties were compared with those of commercially available LYSO and CsI:Tl scintillators using ${\gamma}$-ray spectroscopy. The energy resolutions of the self-produced scintillation detector composed of the scintillator single crystal (volume: $3{\times}3{\times}20mm^3$) and SiPM (Photosensitive area: $3{\times}3mm^2$) for standard ${\gamma}$-ray sources, such as $^{133}Ba$, $^{22}Na$, $^{137}Cs$ and $^{60}Co$ were measured and compared. As a result, the energy resolutions of the proposed Ce:GAGG scintillation detector for g-rays, as measured using its spectroscopic properties, were found to be 13.5% for $^{133}Ba$ 0.356 MeV, 6.9% for $^{22}Na$ 0.511 MeV, 5.8% for $^{137}Cs$ 0.662 MeV and 2.3% for $^{60}Co$ 1.33 MeV.

Anti-invasive Effect of Artemisia scoparia Halophyte Extract and its Solvent-partitioned Fractions in Human Fibrosarcoma Cells (인간 섬유육종세포에서 비쑥 추출물과 유기용매 분획물의 암전이 억제 효과)

  • Kim, Junse;Kong, Chang-Suk;Sim, Hyun-Bo;Seo, Youngwan
    • Journal of Life Science
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    • v.31 no.12
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    • pp.1100-1109
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    • 2021
  • The halophyte Artemisia scoparia is an edible medicinal plant, with insecticidal, anti-inflammatory, anticholesterol, antipyretic, and antibacterial effects. The aim of this study was to assess the inhibitory effect of crude extract and solvent-partitioned fractions obtained from A. scoparia on MMP-2 and MMP-9 activity in phorbol-12-myristate-13-acetate (PMA)-stimulated human fibrosarcoma HT-1080 cells using four different activity tests: gelatin zymography, MMP enzyme-linked immunosorbent assay (ELISA), wound healing assay, reverse transcription-polymerase chain reaction (RT-PCR), and Western blot assay. A. scoparia samples were extracted twice with methylene chloride (MC) and twice with methanol (MeOH). After the MC and MeOH crude extracts were combined, the combined crude extracts showed a significant inhibitory effect against MMP-2 and MMP-9 enzymes. They were then fractionated into n-hexane, 85% (v/v) aqueous methanol (85% (v/v) aq.MeOH), n-butanol, and water according to solvent polarity. Among the four solvent-partitioned fractions, n-hexane and 85% (v/v) aq. MeOH fractions significantly inhibited MMP-2 and MMP-9 activity and cell mobility. In addition, the n-hexane and 85% (v/v) aq.MeOH fractions effectively inhibited MMP-2 and -9 activity in the gelatin zymography and MMP ELISA assay. In the wound healing assay, RT-PCR, and Western blot assay, all solvent-partitioned fractions, except the H2O fraction, significantly suppressed cell migration, as well as the expression levels of MMP-2 and -9 mRNA and proteins.

Investigation of Various Radiation Proton Energy Effect on n, p Type Silicon by Positron Annihilation Method (양전자 소멸 측정법으로 양성자 조사에너지 변화에 대한 n, p형 실리콘 구조 특성)

  • Lee, Chong Yong
    • Journal of the Korean Vacuum Society
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    • v.22 no.6
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    • pp.341-347
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    • 2013
  • The n-type and p-type silicon samples were exposed by 40.0, 3.98 MeV proton beams ranging between 0 to $20.0{\times}10^{13}protons/cm^2$. Coincidence Doppler Broadening Positron Annihilation Spectroscopy (CDBPAS) were applied to study of defect characteristics of p type and n type silicon samples. In this investigation the numerical analysis of the spectra was employed to the determination of the shape parameter, S, defined as the ratio between the amount of counts in a central portion of the gamma spectrum and the total counts of whole gamma spectrum. The S-parameter values strongly depend on the irradiated proton beam that indicated the defects generate more, rather than the energy intensity. 40 MeV irradiated proton beam in the n-type silicon at $20.0{\times}10^{13}protons/cm^2$ was larger defects than 3.98 MeV irradiated proton beam. It was analysis between the proton irradiation beams and the proton intensities of the irradiation. Because of the Bragg peak, SRIM results shows mainly in a certain depth of the sample to form the defect by the proton irradiation, rather than the defects to appear for the entire sample.

말단선량계의 광자에 대한 선량환산인자의 이론적 계산

  • 김광표;이원근;이상윤;윤석철
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.883-888
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    • 1995
  • 본 연구에서 말단선량계에 대한 선량평가시 선량환산인자를 산출하기 위해 1995년의 ANSI N13.32 기준인 “말단선량계의 성능평가를 위한 기준”에서 제안된 기준 팬덤을 가지고 MCNP 전산코드를 이용하여 커마근사법에 의해 수행하였다. ANSI N13.32의 기준팬텀은 손·발 그리고 손가락을 대표하는 원통형으로서 특히 손·발 팬텀에 대해서는 뼈등가물질로 알루미늄을 삽입한 것을 제안함에 따라 본 계산 목적을 위하여 팬텀설계를 똑같이 모사하였으며 사용된 광자빔 에너지는 20keV에서부터 1.5MeV에 걸쳐 14개의 단일에너지를 선택하여 수행하였다. 본 연구에서 전산수행한 결과를 ANSI N13.32의 실험적 결과와 비교해 볼 때 50keV에서부터 1.5 MeV까지의 에너지 영역에서는 최대오차 6% 이내에서 거의 일치함을 보였다.

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The Stopping Power and Cross-section Measurement of $\alpha$-particle in Ar, He and $N_2$ gases (Ar, He 및 $N_2$ 가스의 $\alpha$-입자 저지능과 저지 단면적 측정)

  • Lee, Jung-Hoon;Hwang, Jae-Kwang;Hwang, Han-Yull;Chung, Won-Mo;Joo, Koan-Sik
    • Journal of Radiation Protection and Research
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    • v.13 no.2
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    • pp.1-8
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    • 1988
  • The energy losses of ${\alpha}$-particle with 3 to 5.4 MeV energy were measured as a function of gas absorber thickness and ${\alpha}$-particle energy in three light gaseous media; He, Ar, and $N_2$. The stopping powers and stopping cross-sections were determined by analyzing these data. For Ar gas, the experimental values are very well consistent with the corresponding values of Srivastava's stopping-power theory with the condition of the completely and partially stripped ion. For $N_2$ and He gases, these experimental values express the inconsistencies of about $13{\sim}36%$ and $27{\sim}28%$, respectively.

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Studies on the Interaction of High Energy Electron with Various Matters (물질을 투과한 고에너지 전자선의 선량변화)

  • Chu, S.S.;Kim, G.E.;Park, C.Y.
    • Radiation Oncology Journal
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    • v.1 no.1
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    • pp.11-19
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    • 1983
  • Interaction between high energyelectrons and matters had many complex reactions and the high energy electrons lost their energies with collision and scattering, therefore, electrons distribution in matters was shown as various situation by scattering, exciting and ionizing with moleculars. We experimentally studies with 13 MeV Linear Accelerator and thermoluminescence dosimeter using aluminium and Teflon, etc., and measured energy loss of electrons, electron range, electron scattering and dose distribution in matter. We compared the results with theoretical formular, between 4-qw MeV, the energy loss of electrons was decreased by 2 MeV per $1g/cm^2$ but under 1MeV it was rapidly decreased. Electron range in matter reached to $0.5/cm^2$ per 1MeV of incident energy at 6-12MeV. The dose distribution in matter was increased slightly to some depth by total distribution i.e., the combined intensity of primary and secondary radiant and it was rapidly decreased near the maximum range of electrons. Energy loss of electrons and electron range measured by experiment were coincided with theoretical equations of L. Landau and Feather under 5 and 3% errors respectively. The dose distribution of electrons in matter was similar to L.V. Spencer formular, however, we had found that it was quite different in accordance with the field size and that new formular of dose distribution was induced as empirical function contained experimental factors according to field size.

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