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Crystal Structure of Ca1.29Bi0.14VO4

  • Kim, Myung-Seab;Lah, Myoung-Soo;Kim, Ho-Kun
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.98-102
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    • 2002
  • The structure of a single crystal, grown by a slow cooling a melt of $Ca_{1.29}Bi_{0.14}VO_4$ composition, was analyzed. The crystals belong to the rhombohedral space group R3c and the dimensions of the unit cells are a = 10.848(1)${\AA}$, c = 38.048(6)${\AA}$, V = 3877.6(8)${\AA}^3$ for the pale yellow crystal, and a = 10.857(1), c = 38.063(6)${\AA}$, V = 3885.6(8)${\AA}^3$ for the yellow crystal, respectively. Unit cell dimensions of the crystal were larger than those of the host crystal, $Ca_3(VO_4)_2$, owing to the Bi that replaced Ca in the unit cell. Ca in the unit cell formed six, eight and nine coordinated polyhedra with O atoms and Bi replacing Ca entered the eight or nine coordinated Ca sites with different crystallographic environments in the unit cell. All the V in the unit cell formed four coordinated tetrahedra with O atoms, however V-O bond lengths in the tetrahedra were different from one another.

Influence of Microstructure and Extender Oil on Cure Characteristics of Solution SBR Compounds

  • Ko, Eunah;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.50 no.2
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    • pp.87-91
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    • 2015
  • Cure characteristics of non-oil-extended solution SBR (S-SBR_NO) and oil-extended solution SBR (S-SBR_ EO) compounds reinforced with silica/carbon black were investigated. Minimum and maximum torques of S-SBR_ EO compounds were much smaller than those of S-SBR_NO ones. Delta torques of S-SBR_NO compounds were greater than those of S-SBR_EO ones, and that of S-SBR_NO compound increased with increase in the 1,2-unit content. Optimum cure time ($t_{90}$) of S-SBR compound decreased with increase in the 1,4-unit content, whereas it increased with increase in the 1,2-unit content. Cure rate index of S-SBR compound increased with increase in the 1,4-unit content, whereas it decreased with increase in the 1,2-unit content. Comparing cure characteristics of S-SBR_NO and S-SBR_EO compounds with the same 1,2-unit content, $t_{90}$s of S-SBR_EO compounds were longer than those of S-SBR_NO ones and cure rate indices of S-SBR_EO compounds were smaller than those of S-SBR_NO ones.

Measurement of the Nursing Workload by Patient Classification System in a Secondary Hospital;As a Preliminary Step for Computerization of Nursing Staffing and Scheduling (환자분류에 의한 일개 2차 의료기관의 간호업무량 조사;전산화를 위한 기초작업으로서)

  • Park, Jung-Ho;Joe, Hyon;Park, Hyeoun-Ae;Han, Hye-Rah
    • Journal of Korean Academy of Nursing Administration
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    • v.1 no.1
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    • pp.132-146
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    • 1995
  • Even though Korean medical law stipulates that number of patients attended by a nurse is 2.5 for hospitalization and 30 for ambulatory care, the number of patients cared by a nurse per day is much greater than the standard prescribed by the medical law. Current productivity of nurses is not desirable unless the quality of care is considered. And nursing manpower staffing based on neither current nurses' productivity nor standard of medical law cannot respond properly to dynamic situation of the medical services. Under this background, the necessity of more efficient management of nursing manpower occupying 1/3 of total hospital workers has been recognized by many nursing administrators. Many nursing researchers have studied to foretell the nursing manpower objectively on the basis of measured nursing workload according to patient classification as well. Most of These researches, however, have been conducted in the tertiary hospitals, so it is imperative to conduct other researches to predict necessary nursing manpower in the secondary and the primary hospitals. The study was performed to measure nursing workload and predict pertinent nursing manpower to a secondary hospital with 400beds. Nursing workload was surveyed using measuring tool for direct and indirect care hours in a surgical unit and a medical unit. Survey was conducted from Sep.10 to Sep.16 and from Oct.5 to Oct.11, 1994 respectively by two skilled nurses, Subjects were patients, patients' family members and nursing personnels. Results are follows : 1. Patient classification distributed as 22% of class I (mildly ill patient), 57% of class II (moderately ill patient), and 21% of class III (acutely ill patient) in the medical nursing unit, while 23% of class I, 29% of class II, 12% of class III, and 36% of classIV (critically ill patient) in the surgical nursing unit. There was no difference of inpatient number between weekday and weekend. Bed circulation rate was 89% in both units and average patients number per day was 37.4 (total 42beds) in the medical nursing unit, 32.9 (total 37beds) in the medical nursing unit. 2. Direct care hours per day measured as 2.8hrs for class I, 3.3hrs for class II, and 3.5hrs for class III in the medical nursing unit, while 3.1hrs for class I, 3hrs for class II, 2.7hrs for class III, and 2.2hrs for classIV in the surgical nursing unit. Meanwhile, hours for nursing assistant activities per patient by patients' family members were 11mins and 200mins respectively. Direct care hour rate by shift was day 36%, evening 25%, and night 39% in the medical nursing unit, while 40%, 29%, and and 31% respectively in the surgical nursing unit. 3. Measurement and observation activity held 44.2% of direct care activities of nurses and medication 36.7%, communication 11.7%, exercise 1.8%, treatment 1.3%, hygiene 1.3%, elimination and irrigation 1.1%, suction 1%, nutrition 0.5%, thermotherapy 0.3%, oxygen therapy 0.1% in order. 4. Indirect care hours per day were 294.2mins in the medical nursing unit, and 273.9mins in the surgical nursing unit. By shift, evening was the highest in both units. Indirect care hours for each patient were 44.5mins in the medical nursing unit and 46mins in the surgical nursing unit. 5. checking activities including doctor's order, medication, and delivering patients to the next shift occupied 39.7% of indirect care activities, and preparation 26%, recording 23.8%, communication and conference 6.7%, managing equipments 2.1%, messenger activity 1.7% in order. 6. On the ground of these results, nursing manpower needed in a secondary hospital was estimated ; 27 nursing personnels for the medical nursing unit of 37beds, and 20 nursing personnels for the surgical nursing unit of 33beds.

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Establishment of optimal soybean Koji manufacturing conditions (콩 코오지의 최적 제조조건 설정)

  • Kim, Do-Yoon;Park, Geuk-Yeol;Jang, Sang-Won;Hong, Seong-Cheol;Kwon, Dong-Jin
    • Food Science and Preservation
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    • v.20 no.3
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    • pp.379-385
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    • 2013
  • To establish the optimal manufacturing conditions of soybean koji, soybean Koji prepared with Aspergillus oryzae 6-M-1 and Bacillus subtilis 3-B-1 isolated from traditional Korean meju. During 7 days of making Koji, the amount of amino-type nitrogen was getting more increase. The amount of amino-type nitrogen of Koji prepared with A. oryzae 6-M-1 was 686.16 mg% (w/w), that of Koji with B. subtilis 3-B-1 was 643.46 mg% (w/w) at seventh day of making Koji. The ${\alpha}$-amylase activity of Koji prepared with A. oryzae 6-M-1 was 1472.54 unit/g, that of Koji with B. subtilis 3-B-1 was 791.00 units/g on the seventh day of the making. The acidic protease activity of Koji prepared with A. oryzae 6-M-1 was 309.00 unit/g, that of Koji with B. subtilis 3-B-1 was 135.88 unit/g at 7th day of making. The amount of amino-type nitrogen and enzyme activities of soybean Koji prepared with A. oryzae 6-M-1 and B. subtilis 3-B-1 were produced more than those of wheat flour Koji made in factory. Sensory evaluation on a commercial doenjang and doenjangs prepared with A. oryzae 6-M-1 and B. subtilis 3-B-1 was not significantly different at p<0.05.

Analyses of SGTR Accident With Mihama Unit Experience (미하마 원전경험에 대한 SGTR 사고해석)

  • Lee, S.H.;Kim, K.;Kim, H.J.;Eun, Y.S.
    • Nuclear Engineering and Technology
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    • v.26 no.1
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    • pp.41-53
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    • 1994
  • A SGTR accident postulated at Kori unit 1 is simulated with Mihama unit experience, which occurred on February 1991, to evaluate the capability of plant to cope with the transient. The system design and plant conditions of Kori Unit 1 are much similar with those of Mihama Unit 2. Therefore, special concern has been given to evaluate the sequence and the resulting consequence of the postulated SGTR accident at the Kori unit 1 An analysis is peformed as realistically as possible, with following the EOP of Kori unit 1. The result indicates that the leak through tube break terminates within about forty minutes, and the Kori unit 1 may be sufficient to cope with SGTR accident with same type of sequence. However, the reconsideration may be required for the design of Kori unit 1 which disconnects non-safety AC power from off-site power on SI signal generation. It may be pointed out that the content of EOP for SGTR accident is not enough to require operator's proper judgements. An analysis of SGTR accident tested in the LSTF which simulated the SGTR accident at the Mihama Unit 2 is peformed using the RELAP5/MOD3. The results indicates that the code yields in general good agreement with the test, except the break flowrate at the early stage of the event.

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Synthesis of a novel non-conjugated Blue emitting material Copolymer and Fabrication of mono color OLED by doping various Fluorescent Dyes

  • Cho Jae Young;Oh Hwan Sool;Yoon Seok Beom;Kang Myung Koo
    • Proceedings of the IEEK Conference
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    • 2004.08c
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    • pp.675-679
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    • 2004
  • The existing conjugated blue emitting material polymer which has been used for the two-wavelength method white-emission has good stability and low operating voltage as merits, but the imbalanced carrier transport has been indicated as problem area. We have introduced a novel blue emitting material having perylene moiety unit with hole transporting ability and blue emitting property and triazine moiety unit with electron transporting ability into the same host chain. We have synthesized N-[p-(perylen-3-y1)pheny1]methacry1 amide (PPMA) monomer and [N-(2,4-dipheny1-1,3,5-triazine)pheny1 methacry1 amide] (DTPM) monomer having blue light-emitting unit and electron transport unit, respectively by three steps. A novel non-conjugated blue emitting material Poly[N -[p­(perylene-3-y1) pheny1] methacry1 amide-co-N-[P-(4,6-dipheny1-1,3,5-triazine-2-y1]pheny1]methacry1 amide] (PPPMA-co-DTPM) copolymer having electron transporting unit was synthesized by the solution polymerization of PPMA and DTPM monomers with an AIBN initiator and showed high yield of $75{\%}$. It was very soluble in common organic solvents, and the fabrication of the thin film using a spin coating method was very simple. The PPPMA exhibited a good thermal stability.

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The Design of an Automatic System for Dairy Cattle Breeding I - The Choice of Temperature Sensor for Body Temperature Measuring - (낙농의 자동화 시스템 구성 I - 체온 감지 온도센서의 선정 -)

  • 김형주;정길도;한병성;김용준;김동원;김명순
    • Journal of Biosystems Engineering
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    • v.23 no.1
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    • pp.83-90
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    • 1998
  • In this paper the automatic system for dairy cattle has been desisted such as body temperature measuring unit, feed supplying unit and temperature control unit. Since e disease is strongly related to the body temperature of cattle, early detection of the abnormal temperature would prevent the severe problems which nay occur in dairy farms. An electronic component AD590J is used as temperature sensor for the system, The device is highly robust against the noise since the output signal is the current so it can be applied to a long distance sensing The resolution of signal is 0.1$^{\circ}C$ and the current is 10㎷ Also 12-bit A/D converter is desisted fir interfacing the sensor with a one-chip microprocessor. A temperature measuring experiment using the developed system has been done for measuring the temperature of human beings and the system was proven to be useful for measuring the body temperature of dairy cattle properly. A geared AC motor is used for the feed supplying unit The heater and fm are used as temperature control unit. The feed supplying unit and temperature control unit are well operating in the laboratory experiment.

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A Study on Characteristics of Apartment Housing Unit Plans (민영아파트 평면계획특성에 관한 연구 -서울, 수도권 및 신도시지역을 중심으로-)

  • 배정민;정유선;윤정숙
    • Journal of the Korean housing association
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    • v.12 no.2
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    • pp.1-12
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    • 2001
  • The purpose of this study is to analyze characteristics of apartment housing unit plans based on analyzing overall patterns of housing unit plans and identifying the types of unit plans according to the size and to provide the fundamental data for developing diverse dwelling unit plans of apartment. This study deals with apartment housing unit plans built between 1999 and 2000 in Seoul, the capital region and new town. The major findings of this study are as follows; 1) Most apartment housing unit plans have fixed and uniform layouts. Most apartment housing units have L-DK type meaning they have isolated living room space. Certain layouts(especially $60-85\textrm{m}^2$ sized unit plans) show a "trickle-down" phenomenon with respect to the areas of units according to time series. 2) New plan types are rarely proposed since 2000, especially in large-sized(area more than $120\textrm{m}^2$) and $60-85\textrm{m}^2$ sized plans. 3) Another feature of apartment housing unit plans is increase of the service are (balcony, entrance area, additional kitchen, and storage area), and introduction of masters space (composition of master bedroom, dressing room, powder room, path, and etc.) and etc.)

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The Influence of Unit Plan Shapes to the Energy Efficiency of Collective Housing Simulated by ECO2 Software (ECO2 프로그램을 이용한 공동주택의 단위세대 평면 형태에 따른 에너지 효율 평가)

  • Kim, Chang-Sung
    • KIEAE Journal
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    • v.15 no.5
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    • pp.89-94
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    • 2015
  • Purpose: Various policies to reduce the energy consumption have been carried out to save Earth environment against global warming and environmental pollution in many countries. Energy consumption of buildings in Korea has reached 24% of total energy consumption, and energy consumption of apartment has been continuously increasing. Therefore, Korea government has executed building energy efficiency rating certification system to control energy consumption of buildings. Method: This study was conducted to evaluate the energy performance of apartment unit plans according to the increasement of front width of unit plans, and tried to present the basic data to design more energy conscious unit plans for apartments. For the study, three shapes of unit plans -the 2Bay, 3Bay and 4bay unit- were selected for imput models. They were simulated using ECO2 software to assess building energy efficiency rating certification in Korea. Result: According to the results, in cases that balcony windows were not installed, the primary energy consumption of the 3Bay and 4Bay units were less than 2Bay unit, respectively, 0.1% and 2,5%. The primary energy consumption of the 3Bay and 4Bay units, in cases that balcony windows were installed, was less than 2Bay unit, respectively, 1.7% and 3.2%.

The Effects of Delirium Prevention Intervention on the Delirium Incidence among Postoperative Patients in a Surgical Intensive Care Unit (외과계 중환자실 수술 후 환자의 섬망 예방 중재가 섬망 발생에 미치는 효과)

  • Shim, Mi Young;Song, Suk Hee;Lee, Mimi;Park, Min Ah;Yang, Eun Jin;Kim, Min Soo;Kim, Yu Jin;Kim, Toona
    • Journal of Korean Clinical Nursing Research
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    • v.21 no.1
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    • pp.43-52
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    • 2015
  • Purpose: This study was aimed to develop the multicomponent intervention for preventing delirium among postoperative patients in a surgical intensive care unit (SICU). Methods: Using a quasi-experimental pre & post-test design with a non-equivalent control group, a total of 88 hospitalized patients in a SICU participated in this study. The 44 patients were allocated in each experimental and control group. The experimental group received the multicomponent intervention for delirium prevention including a delirium assessment and nursing intervention using a checklist, whereas the control group was provided with a standard care. The primary outcome of this study was the delirium incidence during the course of hospitalization. Results: There were no significant differences in the demographic and clinical characteristics between the two groups. The delirium occurred in 19.2% in the experimental group, whereas 38.6% in the control group ($x^2=4.526$, p<.05). Conclusion: The findings of the study demonstrated an effect of the multicomponent delirium prevention intervention in decreasing the delirium incidence rate over the standard care among the patients in SICU.