• Title/Summary/Keyword: 1-propanol

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Absorption of Carbon Dioxide into Aqueous AMP Solutions

  • So, Won-Seob;Suh, Dong-Soo;Park, Moon-Ki
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.1
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    • pp.79-84
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    • 1998
  • The rates of absorption of carbon dioxide into aqueous solutions of 2-amino-2-methyl-1-propanol (AMP) were measured using a semibatch stirred vessel with a plane gas-liquid interface at $25^{\circ}C.$ The absorption rates under the fast reaction regime were analysed using chemical absorption theory. The reaction was found to be first order with respect to both $CO_2$ and the amine.

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Absorption of Carbon Dioxide into Aqueous AMP Solutions

  • Won Seob So;Don
    • Journal of Environmental Science International
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    • v.2 no.1
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    • pp.79-84
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    • 1993
  • The rates of absorption of carbon dioxide into aqueous solutions of 2-amino-2-methyl-1 propanol (AMP) were measured using a semibatch stirred vessel with a plane gas-liquid interface at $25^{\circ}C$. The absorption rates under the fast reaction regime were analysed using chemical absorption theory. The reaction was found to be first order with respect to both $CO_2$ and the amine.

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Cytotoxic activity of 1-phenyl-2-alkylsulfonylamido propanol derivatives

  • Im, Cha-Euk;Chung, Mi-Ryang;Kim, Yong-Hyun;Yin, Chul-Bu
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.185.1-185.1
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    • 2003
  • The 20 alkylsulfonylamido propanol derivatives had been investigated for their cytotoxic activity against HT-29 colon cancer, Caki-2 renal cancer, A549 lung cancer, PC-3 prostate cancer, HL-60 leukemia cell using MTT assay. Cytotoxic activity was strongly influenced by the substituted alkyl chain length and the optimal alkyl chain length for cytotoxicity was C11. Some of alkylsulfonylamido porpanol derivatives showed stronger activity than reference compound, B13.

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The Measurement and Prediction of Flash Point for Binary Mixtures of Methanol, Ethanol, 2-Propanol and 1-Butanol at 101.3 kPa (Methanol, Ethanol, 2-Propanol 그리고 1-Butanol 이성분 혼합계에 대한 101.3 kPa에서의 인화점 측정 및 예측)

  • Oh, In Seok;In, Se Jin
    • Fire Science and Engineering
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    • v.29 no.5
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    • pp.1-6
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    • 2015
  • Flash point is one of the most important variables used to characterize fire and explosion hazard of liquids. The lower flash point data were measured for the binary systems {methanol + 1-butanol}, {ethanol + 1-butanol} and {2-propanol + 1-butanol} at 101.3 kPa. Experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured flash points were compared with the predicted values calculated using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The measured FP data agreed well with the predicted values of Raoult's law, Wilson, NRTL and UNIQUAC models. The average absolute deviation between the predicted and measured lower FP was less than 1.14 K.

Cyclohexanol Dehydrogenase isozymes produced by Rhodococcus sp. TK6 (Rhodococcus sp. TK6가 생산하는 Cyclohexanol Dehydrogenase의 동위효소)

  • 김태강;이인구
    • Microbiology and Biotechnology Letters
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    • v.27 no.2
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    • pp.124-128
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    • 1999
  • TK6 was able to produce NAD+ dependent cyclohexanol dehydrogenase(CDH). The production of CDH was increased rapidly at the logarithmic phase and maintained constantly after that. In order to investigate the inductive production of CDH by various substrates, the bacteria were grown in the media containing alicyclic hydrocarbons and various alcohols as a sole crabon souce. CDH was induced most actively by cyclohexanol. Cyclohexanone and cyclohexane-1,2-diol also induced remarkable amount of CDH but it was induced weakly by 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 2-propanol, and 2-methyl-1-propanol. The dehydrogenase of the bacteria grown in the media containing cyclohexanol were weakly active for various alcohols, but the dehydrogenase activity for cyclohexane-1,2-diol was twice as much as that for cyclohexanol. Activity staining on PAGE of the cell free extract of Rhodococcus sp. TK6 grown in the media containing cyclohexanol reveals at least sever isozyme bands of CDH and we nominated the four major activity bands as CDH I, II, III, and IV. CDH I was strongly induced by cyclohexanol, cyclohexane-1,2-diok, but its activity was specific to cyclohexane-1,2-diol and 1-pentanol. CDH IV was strongly induced by cyclohexanol and cyclohexane-1,2-diol, and its activity was very specific to cyclohexane-1,2-diol.

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Conformational Transition of Form II to Form Ⅰ PoLy(L-proline) and the Aggregation of Form Ⅰ in the Transition: Water-Propanol Solvent System

  • 김현돈
    • Bulletin of the Korean Chemical Society
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    • v.18 no.9
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    • pp.922-928
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    • 1997
  • The conformational transition of poly(L-proline) (PLP), Form Ⅱ → Form Ⅰ and the intermolecular aggregation of the product, Form Ⅰ, during and after the transition in water-propanol (1:7, 1:9, 1:15.7, and 1:29 v/v) were studied. For the study, the viscosity change and excess light scattering intensity were measured in the course of the transition which was determined by the Form Ⅰ fraction, fI of the sample solution. For the PLP sample of molecular weight Mv=31,000 the experimental results show that the reaction course is roughly divided into three regions: in the first region [fI=0.27 to 0.40 (- [α]D=400 to 330)], the conformational change of Form Ⅱ → Form Ⅰ occurs with decrease of viscosity, in the second region [fI=0.40 to 0.80 (- [α]D=330 to 120)], a partial side-by-side (p-S-S) type aggregation in which Form Ⅰ blocks interact with each other, which induces the increase of viscosity, starts to occur, and in the third region [fI=0.80 to 1.00 (- [α]D=120 to 15)], a side-by-side type (raft like) aggregation of Form Ⅰ or an end-to-end (E-E) type aggregation occurs according to the solvent situation, i.e., in a water-rich medium [water-propanol (1:9 or 1:7 v/v)], the (S-S) type aggregation with a gross decrease in viscosity occurs while in a water-poor medium [water-propanol (1:29 or 1:15.7 v/v), the (E-E) type aggregation with a large increase in viscosity occurs. The (S-S) type aggregation was promoted at high temperatures. Based on the structure of PLP, a reasonable mechanism for the (p-S-S) and (S-S) aggregation which occurs with the transition of Form Ⅱ → Form Ⅰ is considered. The suggested mechanism was also supported by the result of chain length effect of PLP for the aggregation.

Changes of Volatile Substances in Jindo Hong-Ju on Storage (진도(珍島) 홍주(紅酒)의 보존중(保存中) 휘발성분(揮發成分)의 변화(變化))

  • Jung, Ji-Heun;Kang, Sung-Hoon;Kim, Yong-Soon
    • Journal of the Korean Society of Food Culture
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    • v.8 no.3
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    • pp.295-299
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    • 1993
  • This research was carried out to investigate the changes of volatile substances which influence on liquor flavor while keeping the Hong-Ju on storage. The contents of total acid and ethanol were reduced on long storage. The volatile components in the Hong-Ju were shown in the order of acetaldehyde, fusel oil, acetate, furfural and methanol after a year, while other substances were increased except furfural, and methanol was not detected. After two years, the content of acetaldehyde was $21.4{\sim}58.4\;mg%$ which is the similar level of that of one year. However, fusel oil, whose main components are n-propanol, 2-methyl-1-propanol and 2-methyl-1-butanol was reduced to $0.71{\sim}1.03\;mg/ml$ which is about $4{\sim}6$ times than that of initial content, while furfural was reduced to $0.01{\sim}0.02\;mg/ml$.

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Protective effects of Erythronium japonicum and Corylopsis coreana Uyeki extracts against 1,3-dichloro-2-propanol-induced hepatotoxicity in rats

  • Seunghyun Kim;Hee-Ock Boo;Taeho Ahn;Chun-Sik Bae
    • Applied Microscopy
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    • v.50
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    • pp.29.1-29.6
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    • 2020
  • Erythronium japonicum (E. japonicum) and Corylopsis coreana Uyeki (C. coreana Uyeki, Korean winter hazel) have been shown to significantly decrease 1,3-dichloro-2-propanol (1,3-DCP)-induced generation of reactive oxygen species and CYP2E1 activity in HuH7, human hepatocytes. In this study, we expanded upon the previous study and investigated the effects of E. japonicum and C. coreana Uyeki extracts on 1,3-DCP-induced liver damage in rats. The pre-treatment of rats with these extracts alleviated a decrease in body weight and reduced 1,3-DCP-induced increase in catalytic activities of hepatic enzymes, such as aspartate aminotransferase and alanine aminotransferase, in the serum. Moreover, treatment with the extracts restored the 1,3-DCP-induced decreases in anti-oxidant enzyme activities, such as the activities of superoxide dismutase and catalase, in the rat liver. Histopathological studies also strongly supported the results of enzyme activities. These results suggest a possibility that the extracts of E. japonicum and C. coreana Uyeki can be a remedy for alleviating 1,3-DCP-induced liver damage in animals.

Novel Method for the Preparation of Mesoporous BaSO4 Material with Thermal Stability by Spray Pyrolysis

  • Nagaraja, Bhari Mallanna;Abimanyu, Haznan;Jung, Kwang-Deog;Yoo, Kye-Sang
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.1007-1012
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    • 2008
  • Spray pyrolysis has been found as an excellent method for the preparation of mesoporous barium sulfate at higher temperature. Ethylene glycol, a reducing agent, and solvents had good inhibition effect for the preparation of $BaSO_4$ nano particles. The $BaSO_4$ solution was sprayed at 500 & 800 ${^{\circ}C}$ using different solvents such as methanol, ethanol, propanol and n-butyl alcohol. $N_2$ adsorption-desorption isotherm revealed that $BaSO_4$ is micropore free, possessing narrow mesopores size distribution and high BET surface areas of 72.52 $m^2\;g^{-1}$ at 800 ${^{\circ}C}$ using propanol as an additive. Scanning electron microscopy (SEM) indicates that the morphology of $BaSO_4$ nano material shows uniform shell like particles. Transmission electron microscopy (TEM) proved that the resulting BaSO4 nano particles were uniform in size and the average particle size was 4-8 nm. The surface functionality and ethylene glycol peaks were assessed by Fourier transform infrared resonance (FTIR) spectroscopy. Low intensity ethylene glycol specific absorption peak was observed in propanol which proved that propanol had good inhibition effect on the structural morphology of nano particles.