• Title/Summary/Keyword: 1,3,5-trimethylcyclotrisilazane

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Preparation and Properties of Polyorganosiloxane Modified Maleated EPDM/EPDM Rubber Vibration Isolator (Polyorganosiloxane 변성 말레화 EPDM/EPDM 방진고무의 제조와 그 특성)

  • Kang, Doo-Whan;Kim, So-Mi
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.581-585
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    • 2010
  • The surface of Alnico, one of the industrial dust waste, was treated with 1,3,5-trivinyl-1,3,5-trimethylcyclotrisilazane (VMS) as a surface treating agent and used as the filler for vibration isolator rubber. Maleated EPDM prepared from bulk polymerization of EPDM with maleic anhydride was copolymerized with ${\alpha},{\omega}$-bis(3-aminopropyl)polydimethylsiloxane to obtain maleated EPDM-polydimethylsiloxane copolymer (MEPDM-PDMS). EPDM/Alnico/MEPDM-PDMS vibration isolator rubber was prepared from compounding with Alnico treated with surface treating agent, 25 and 50 phrs to EPDM, respectvely based on 1 to 10 wt% of MEPDM-PDMS to EPDM. From the measurement of the thermal properties to the rubber, the glass transition temperatures (Tg) for the rubber containing maleated EPDM-PDMS copolymer was slightly lower temperature, $33^{\circ}C$ than EPDM rubber, and also DMA results showed higher tan ${\delta}$ peak to the rubber prepared from compounding with EPDM-PDMS copolymer. From the results, rubber prepared using EPDM-PDMS copolymer had better vibration isolator property.