• Title/Summary/Keyword: 1,3,5-Triazine

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Differences in Response of Rice(Oryza sativa L.) Cultivars to Herbicides (제초제에 대한 벼 품종간 반응)

  • Shin, D.H.;Moody, K.;Zapata, F.J.;Kim, K.U.
    • Korean Journal of Weed Science
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    • v.16 no.2
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    • pp.140-149
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    • 1996
  • Three hundred rice(Oryza sativa L.) cultivars were screened for tolerance to butachlor [N-(buthoxymethyl)-2-chloro-N-(2,6-diethylphenyl) acetamide], thiobencarb(S-[(4-chlorophenyl)methyl]diethylcarbamothioate), and simetryn [N,N-diethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine]. The responses of the rice cultivars to herbicides differed depending upon the herbicides and their concentrations. New Sabarmati(BAS), Gora, PTB 18 were tolerant to butachlor, and Azucena, IR44707-31-1-3-2, ARC 7293 to thiobencarb, while Gora, ARC 7293, and Dudmona were tolerant to both herbicides. Response of rice to simetryn differed from its response to butachlor and thiobencarb. Inhibition of shoot growth and fresh weight increased as the temperature and herbicide concentration increased. There was a higher correlation among rice cultivars response to butachlor and thiobencarb in the greenhouse when laboratory studies were conducted at higher temperatures.

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The Changes of the Activity of Nitrogen-containing Herbicides in Soils -Part 1. Effects of Nitrogen-Containing Herbicides on the Urease Activity in Soils- (함질소제초제(含窒素除草劑)가 토양환경(土壤環境)에 미치는 영향(影響)에 관(關)한 연구(硏究) -제 1 보(第 1 報) 함질소제초제(含窒素除草劑)가 토양중(土壤中) Urease에 미치는 영향(影響)-)

  • Hong, Jong-Uck;Cho, Sang-Moon
    • Applied Biological Chemistry
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    • v.22 no.4
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    • pp.217-220
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    • 1979
  • Effects of nitrogen containing herbicides, Asulam(methyl-(4-aminobenzenesulphonyl)-carbamate), dimetametryne (2-methyl-4-ethylamino-6-(1,2-dimethyl propylamino)-S-triazine) and linuron (3-(3,4-dichlorophenyl)-1-metoxy-1-methyl urea) at rates of 0.5,2,4 mg/100g soil on urease activity were studied in urea added and unadded soil by incubating at $25{\pm}1^{\circ}C$ for 80 days. The enzyme activity was somewhat suppressed by asulam and dimetametryne in soils treated with urea. Unlike the above results, the enzyme activity in soil treated with linuron was kept higher as compared with that in soil treated with urea only.

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Application of TREECS Program to Predict the Fate of TNT and RDX from Firing Range (TREECS 프로그램을 이용한 화약류 오염 군 사격장 토양의 TNT와 RDX 유출 특성 연구)

  • Yu, Gihyeon;Jung, Jae-Woong;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.133-139
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    • 2015
  • Attention to munitions constituents such as 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in the firing ranges is increasing due to their toxicity and high mobility to the environment. It is helpful to use a systemic model to predict the amount of contaminants for the establishment of environmental management of firing ranges. This study employed Training Range Environmental Evaluation and Characterization System (TREECS) program to estimate the mobility characteristics of TNT and RDX via groundwater leaching, soil erosion and surface water runoff. The prediction results of the TNT and RDX migration with TREECS showed that 68% of initial TNT and 21% of initial RDX were discharged through the soil erosion and the 20% of initial TNT and 54% of initial RDX ran out the firing range via the groundwater leaching. The rest of the initial TNT and RDX moved to adjacent surface water via surface runoff. The data suggest that soil erosion and surface runoff occupying 80% of TNT to the total amount are important migration pathways. On the other hand, groundwater leachning occupying 54% to the total amount was also important pathway for RDX.

Studies on Durability and Polarization Properties of Poly(vinyl alcohol) Polarizing Films Prepared with Reactive Dichroic Dyes (반응성 이색성 염료를 사용하여 제조한 폴리(비닐 알코올) 편광필름의 내구성 및 편광특성에 관한 연구)

  • Choi, E-Joon;Choi, Seung Sock;Park, Il Hyun;Chang, Jin Ho;Back, Sang-Hyun;Park, Sang-Bong
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.66-73
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    • 2013
  • Three reactive dichroic dyes with 3,5-dichloro-2,4,6-triazine moiety were synthesized by reaction between dichroic dyes (such as congo red, direct black 22 or direct black 4) and cyanuric chloride. Poly(vinyl alcohol) (PVA) films were dyed with the obtained three reactive dichroic dyes. After 400% drawing of the PVA films, their optical properties were compared with an iodine-doped PVA film prepared in the same condition. Durability test was performed at $50^{\circ}C$ in 85% of relative humidity for 120 hrs. We found that compared with the iodine-doped PVA polarizing film, the relative durability of the PVA polarizing film dyed with the reactive dichroic dyes was greatly improved.

Simazine-induced Alteration of the Expression Levels of Apoptosis- and Steroidogenesis-regulating Genes in Testicular Cells (Simazine이 정소세포에서 Apoptosis와 Steroidogenesis 조절 유전자들의 발현에 미치는 영향)

  • Park, Ho-Oak;Ko, Jeong-Jae;Bae, Jee-Hyeon
    • Development and Reproduction
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    • v.15 no.2
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    • pp.159-166
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    • 2011
  • Simazine (6-chloro-N,N'-diethyl-1,3,5-triazine-2,4-diamine) is a triazine herbicide that has been applied worldwide including Korea for agricultural purposes. Simazine is the second most commonly detected pesticide in surfaceand ground-water in the United States, Europe and Australia. It has been shown that simazine is a potent endocrine disruptor in wildlife and laboratory animals. Although many endocrine disruptors can induce apoptosis in various types of cells, the effects of simazine on apoptosis and on the expression of Bcl-2 family genes are not known. Also it is unknown the effect of simazine on the expression of steroidogenesis-regulating genes in testicular cells. In this study, we investigated the effect of simazine on the expression levels of apoptosis- and steroidogenesis-regulating genes in testicular cells. We found that a low concentration of simazine can alter the mRNA expression levels of steroidogenesis-related genes and Bcl-2 family genes in mouse Sertoli cells and rat Leydig cells. Thus, our results suggest that simazine can disturb normal testicular development and reproductive function by altering the expression of genes that are critical for the regulation of apoptosis and steroidogenesis.

A Stable and Efficient Host Material Having Tetraphenylsilane for Phosphorescent Organic Light Emitting Diodes

  • Park, Hyung-Dol;Kang, Jae-Wook;Lee, Deug-Sang;Kim, Ji-Whan;Jeong, Won-Ik;Park, Young-Seo;Lee, Se-Hyung;Go, Kyung-Moon;Lee, Jong-Soon;Kim, Hyong-Jun;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.503-505
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    • 2008
  • A host material containing tetraphenylsilane, 9-(4-triphenylsilanyl-(1,1'4,1")-terphenyl-4"-yl)-9H-cabazole (TSTC), was synthesized for green phosphorescent organic emitting diodes. $Ir(ppy)_3$ based OLEDs using TSTC host and DTBT (2,4-diphenyl-6-(4'yl)-1,3,5-triazine) hole blocking layer (HBL) showed the maximum external quantum efficiency of 19.8 %, the power efficiency of 59.4 lm and high operational stability with a half lifetime of 160,000 h at an initial luminance of $100\;cd/m^2$.

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Preparation of $\beta$-Cyclodextrinized Cellulosic Fiber and Deodouring Property ($\beta$-시클로덱스트린화 셀룰로오스 섬유의 제조 및 소취성)

  • Choi, Chang-Nam;Hwang, Tae-Yeon;Ko, Bong-Kook;Kim, Ryong;Hong, Sung-Hak;Kim, Sang-Yool
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.635-641
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    • 2001
  • $\beta$-Cyclodextrine/benzoic acid complex was prepared and reacted with cyanuric chloride (2,4,6-trichloro-1,3,5-triazine). Identification of complex formation and reaction was checked by FT-IR, UV-Vis, and EDX. By reacting this material with cotton fiber, the deodourant fiber was prepared. The deodourizing property was evaluated by the concentration changes of aqueous ammonia solution after flowing ammonia gas through the column titled with deodourant fiber prepared. The deodourizing property was increased with an increase of concentration of $\beta$-cyclodextrine unit in the fiber. In the case of $\beta$-cyclodextrine/benzoic acid complex, the deodourzing property was much increased, comparing with the $\beta$-cyclodextrine only. It was considered to be the binding of aamonia gas caused by benzoic acid in the complex.

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Effect of Combined Application of Molinate and Simetryn on Bioefficacy of Echinochloa crus-galli and Bidens tripartita (Molinate와 Simetryn 혼합처리가 피, 가막사리 및 벼의 생육에 미치는 영향)

  • Choi, S.Y.;Chung, B.J.;Chae, J.C.
    • Korean Journal of Weed Science
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    • v.18 no.4
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    • pp.286-294
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    • 1998
  • This study was carried out to evaluate the interaction effect between molinate(S-ethyl N,N-hexamethylene-thiocarbamate) and simetryn(N,N'-diethyl-6-(methythio)-1,3,5-triazine-2,4-diamine) on weed bioefficacy and rice phytotoxicity in green house and paddy field. Combined application of molinate and simetryn showed synergistic herbicidal effect to Echinochloa crus-galli and additive herbicidal effect to Bidens tripartita, However, it showed synergistic phytotoxicity to rice. Combined application of molinate and simetryn reduced the flooding period desirable for controlling Echinochloa crus-galli by about 2~4days as compared to single application of molinate. It was concluded that the optimum combination of molinate and simetryn was 150g and 9g to 18g a.i./10a, respectively in viewpoint of bioefficacy and phytotoxicity.

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Dechlorination of Atrazine in Sediment Using Zero Valent Iron (영가철($Fe^0$)을 이용한 퇴적물내 Atrazine의 탈염소화)

  • Kim, Geon-Ha;Jeong, Woo-Hyeok;Choe, Seung-Hee
    • Journal of Soil and Groundwater Environment
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    • v.11 no.4
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    • pp.33-40
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    • 2006
  • Residual pesticides discharged from diffuse sources at agricultural area in association with suspended solid will be settled at downstream, and may degrade surface water quality. This research studied dechlorination kinetic of atrazine, one of triazine-category herbicide, using zero-valent iron (ZVI) in sediment. It can be observed from the experiments that buffer capacity of sediment helped pH maintained beutral, resulted in continuous dechlorination. Sediments were spiked with atrazine at 10, 30, and 50 mg atrazine/L of total sediment for batch experiments. Dechlorination constants were $1.38x10^{-1}/d$ for the initial concentration of 10 mg/L, $1.29x10^{-l}/d$ for 30 mg/L, and $7.43x10^{-2}/d$ for 50 mg/L while dechlorination constants of initial concentration of 50 mg/L without ZVI adding were estimated as $3.05x10^{-2}/d. Half lifes atrazine by ZVI were estimated as 5.03 d fur 10 mg/L, 5.38 d for 30 mg/L, and 9.33 d for 50 mg/L, respectively.

Herbicidal properties of picolinafen (제초제 picolinafen의 제초활성 특성)

  • Lee, Jong-Nam;Koo, Suk-Jin;Kim, Do-Soon;Hwang, Ki-Hwan;Kim, Dae-Hwang;Ko, Yong-Kwan;Chung, Keun-Hoe;Ryu, Jae-Wook;Woo, Jae-Chun;Koo, Dong-Wan
    • The Korean Journal of Pesticide Science
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    • v.10 no.4
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    • pp.351-358
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    • 2006
  • This study was conducted to evaluate herbicidal properties of picolinafen in terms of crop safety, weed control spectrum, application window, residual efficacy and resistant weed control. Herbicidal phytotoxicity of picolinafen to wheat and barley was greatest when applied at 0 days after sowing (DAS), but decreased significantly as plant growth advanced. Picolinafen showed greater activity against broadleaved weeds than grass weeds. Picolinafen showed highest activity when it was applied at early post emergence timing (5 to 15 DAS), and showed significantly decreased activity at 20 DAS application. The $LT_{50}$ values (the period from application required for residual control by 50%) was 9.3 and 6.5 days against Digitaria ciliaris and Brasica naus at 60 g ai $ha^{-1}$, respectively. Picolinafen showed similar activities against both triazine resistant and sensitive Amaranthus retroflexus. Collectively, picolinafen appeared to have a good fitness to control resistant broad leaved weeds control by early post emergence application.