• Title/Summary/Keyword: 1,1,1-TCE

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Electrical and Optical Properties of F-Doped SnO2 Thin Film/Ag Nanowire Double Layers (F-Doped SnO2 Thin Film/Ag Nanowire 이중층의 전기적 및 광학적 특성)

  • Kim, Jong-Min;Koo, Bon-Ryul;Ahn, Hyo-Jin;Lee, Tae-Kun
    • Korean Journal of Materials Research
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    • v.25 no.3
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    • pp.125-131
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    • 2015
  • Fluorine-doped $SnO_2$ (FTO) thin film/Ag nanowire (NW) double layers were fabricated by means of spin coating and ultrasonic spray pyrolysis. To investigate the optimum thickness of the FTO thin films when used as protection layer for Ag NWs, the deposition time of the ultrasonic spray pyrolysis process was varied at 0, 1, 3, 5, or 10 min. The structural, chemical, morphological, electrical, and optical properties of the double layers were examined using X-ray diffraction, X-ray photoelectron spectroscopy, field-emission scanning electron microscopy, transmission electron microscopy, the Hall effect measurement system, and UV-Vis spectrophotometry. Although pure Ag NWs formed isolated droplet-shaped Ag particles at an annealing temperature of $300^{\circ}C$, Ag NWs covered by FTO thin films maintained their high-aspect-ratio morphology. As the deposition time of the FTO thin films increased, the electrical and optical properties of the double layers degraded gradually. Therefore, the double layer fabricated with FTO thin films deposited for 1 min exhibited superb sheet resistance (${\sim}14.9{\Omega}/{\Box}$), high optical transmittance (~88.6 %), the best FOM (${\sim}19.9{\times}10^{-3}{\Omega}^{-1}$), and excellent thermal stability at an annealing temperature of $300^{\circ}C$ owing to the good morphology maintenance of the Ag NWs covered by FTO thin films.

Levels of Plasma Glucose and Lipid in Rats Fed Bread Supplemented with Natural Extracts (천연추출물이 첨가된 식빵을 섭취한 흰쥐의 혈당 및 지질수준에 미치는 영향)

  • Kim, Se-Wook;Han, Ah-Ram;Chun, Su-Hyun;Nam, Mi-Hyun;Hong, Chung-Oui;Kim, Bok Hee;Kim, Tae Cheol;Lee, Kwang-Won
    • Korean Journal of Food Science and Technology
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    • v.48 no.1
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    • pp.77-85
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    • 2016
  • In this study, 4-week-old rats were fed bread supplemented with Terminalia chebula (TC), Plantago asiatica (PA), Linder obtusiloba (LO), and Capsosiphon fulvescens (CF) ethanol extracts, to determine the decrease in blood glucose levels, as well as the anti-inflammatory and lipid-enhancing effects. Previous studies have demonstrated the antioxidative effects of these ethanol extracts. After sacrifice, the liver tissue, whole blood, and serum samples were collected for biochemical analysis. The results showed a significant decrease in blood glucose level, lipid peroxidation, malondialdehyde (MDA) level, HbA1c level, total cholesterol, and low-density lipoprotein (LDL)-cholesterol (p<0.05) and an increase in high-density lipoprotein (HDL)-cholesterol level in rats fed bread supplemented with LO and CF ethanol extracts (p<0.05). Therefore, the results of this study demonstrate that bread supplemented with LO and CF ethanol extracts can potentially affect the blood glucose level and lead to lipid enhancement.

APPLICATION OF A PILOT-SCALE FLUIDIZED-BED REACTOR FOR THE DECONTAMINATION OF GROUNDWATER

  • Ohlen, Ken;Lee, Seong-Taek;Hegemann, Wemer;Jang, Yong-Geun
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.77-80
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    • 2001
  • Groundwater, contaminated predominantly with aromatic compounds and chlorinated ethylene, could be biologically treated in a fluidized-bed reactor with immobilized cells. The decomposition efficiency for the aromatics was over 90% at the retention time of 2.5 h. The chlorinated ethylenes, especially trichloroethylene (TCE) and cis-dichloroethylene (DCE), could be decomposed only insufficiently. No anaerobic methane formation was observed for this groundwater even at a very low dissolved oxygen (DO) concentration of 0.75 mg/L. The variation of DO concentration resulted in an optimal value of 1.5 mg/L. The recycle of air waste could increase the utilization of oxygen. The amount of low boiling pollutants stripped out remained constant with the recycle, while for the higher boiling pollutants the stripping slightly increased. Using air instead of oxygen increases the flow rate of air waste, which is connected to a higher stripping of pollutants. In this investigation, the pollutant concentration in the air waste remained constant. The stripping of main pollutants did not exceed 0.3 %.

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Performance of Local Exhaust Ventilation Systems of Degreasing and Plating Workplaces (일부 탈지세척 및 도금공정 국소배기장치의 성능점검과 개선방안)

  • Han, Don-Hee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.8 no.2
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    • pp.178-185
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    • 1998
  • In order to evaluate and improve the performance of local exhaust ventilation systems for two TCE degreasing (A, B) and two electroplating (C, E) and one acid dipping & plating (D) operations located in Kimhae, the performance test was conducted with trace gases and a thermal anemometer (Kanomax 24-6111, Japan). For the inadequately designed systems, the improvement and redesigns in compliance with recommendation by ACGIH was suggested. The results of performance test for each system are as follows; 1. System of Workplace A was generally well-designed. Actual exhaust air flow rate was in excess of 68% above the recommended standard exhaust air flow rate. 2. System of Workplace B was very well-designed and completely enclosed. 3. All systems of Workplace C including hoods were poorly-designed and actual exhaust air flow rates were insufficient for open tanks. All systems should be upgraded according to ACGIH recommendations. 4. Supply and exhaust air flow rate of push-pull exhaust systems in Workplace D should be greatly increased. The width of flange of dipping tank hood should be increased with the value suggested. 5. System of Workplace E was well-designed. Actual exhaust air flow rate was in excess of 54% above the required.

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SYNTHESIS OF NANO-SIZED IRON FOR REDUCTIVE DECHLORINATION. 1. Comparison of Aerobic vs. Anaeriobic Synthesis and Characterization of Nanoparticles

  • Song, Ho-Cheol;Carraway, Elizabeth R.;Kim, Young-Hun
    • Environmental Engineering Research
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    • v.10 no.4
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    • pp.165-173
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    • 2005
  • Nano-sized iron particles were synthesized by reduction of $Fe^{3+}$ in aqueous solution under two reaction conditions, aerobic and anaerobic, and the reactivity of iron was tested by reaction with trichloroethene (TCE) using a batch system. Results showed that iron produced under anoxic condition for both synthesis and drying steps gave rise to iron with higher reduction reactivity, indicating the presence of oxygen is not favorable for production of nano-sized iron deemed to accomplish reactivity enhancement from particle sized reduction. Nano-sized iron sample obtained from the anoxic synthesis condition was further characterized using various instrumental measurements to identity particle morphology, composition, surface area, and particle size distribution. The scanning electron microscopic (SEM) image showed that synthesized particles were uniform, spherical particles (< 100 nm), and aggregated into various chain structures. The effects of other synthesis conditions such as solution pH, initial $Fe^{3+}$ concentration, and reductant injection rate on the reactivity of nano-sized iron, along with standardization of the synthesis protocol, are presented in the companion paper.

Development and Application of an In Situ Technology to Treat Various Soil and Groundwater Contaminants

  • Goltz, Mark N.
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.10a
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    • pp.89-110
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    • 2003
  • The limitations of conventional soil and groundwater contamination remediation technologies have motivated a search for innovative technologies; particularly in situ technologies that do not require extraction of contaminants from the subsurface. All engineered in situ remediation systems require that the contaminant be mixed with a remedial compound. Horizontal flow treatment wells (HFTWs), an innovative technology that consists of a pair of dual-screened treatment wells, were used at a trichloroethylene (TCE) contaminated site to efficiently achieve this mixing of contaminant and remedial compound in order to effect in situ bioremediation (McCarty et al., 1998). In this paper, the potential of HFTWs to treat chlorinated aliphatic hydrocarbons (CAHs) as well as other soil and groundwater contaminants of concern, such as nitroaromatic compounds (NACs), perchlorate, and methyl-tert-butyl ether (MTBE), is examined. Through a combination of laboratory studies, model analyses, and field evaluations, the effectiveness of this innovative technology to manage these contaminants is investigated.

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The Changes of Microstructure, Morphology, and Mechanical Properties of Solvent Treated PET POY (Partially Oriented Yarn) (폴리에스테르 부분배향사의 용매처리에 따른 내부구조 및 인장성질의 변화)

  • Shin, Hae Won;Ryu, Hyo Seon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.1
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    • pp.63-75
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    • 1993
  • Partially oriented polyester yarn (PET POY) was treated in the unrestrained state using various solvents at different temperatures. Interactions between PET POY & solvents were estimated by the changes of microstructure, morphology and mechanical properties. The correlation between the changes of microstructure & morphology and the changes of mechanical properties was also studied. TCE, Dioxane, O-DCB, DMF, and BA were found to be active solvents, while Iso-AA and water were found to be weak solvents. PET POY was affected mainly by the solvents when treated with active solvents and affected mainly by heat when treated with weak solvents. Changes by the solvent treatment in microstructure and morphology were : an increase in crystallinity, a change in birefringence, a shrinkage in length, and a change in DSC curve. As for the changes in mechanical properties, findings in the PET POY when treated with solvents were : a decrease in stress-at-break, a change in yield stress, an increase in strain-at-break & yield strain, and a decrease in initial modulus. Changes in microstructure and morphology directly affected the mechanical properties.

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A Study of the High Reliability in Plastic BGA Solder Joints (플라스틱 BGA 솔더접합부의 고신뢰성에 관한 연구)

  • Kim, Kyung-Seob;Shin, Young-Eui;Lee, Hyuk
    • Journal of Welding and Joining
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    • v.17 no.3
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    • pp.90-95
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    • 1999
  • The increase in high speed, multi-function and high I/O pin semiconductor devices highly demands high pin count, very thin, and high density packages. BGA is one of the solutions, but the package has demerits in package reliability, surface mounting problems due to the PCB warpage and solder joint crack related with TCE mismatch between the materials. On this study to verify the thermal fatigue lifetime of the solder joint FEM and experiments were performed after surface mounting BGA with different solder composition and reliability conditions. FEM showed optimum composition of Ag3.2-Sn96.5 and under the composition minimum creep deformation of the solder joint was calculated, and the thermal fatigue lifetime was improved. In view of temperature cycle condition, the conditions of $-65^{\circ}C$to $150^{\circ}C$ showed minimum lifetime and t was 1/3 of $0^{\circ}C$ to $125^{\circ}C$ condition. Test board was prepared and solder joint crack was verified. Until 1000cycle on soder joint crack was observed.

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Analysis by Environmental Factor of Similar Closed Non-sanitary Landfills (사용종료된 유사비위생 매립지들의 환경인자 분석)

  • Lee, Byungchan;Lee, Minhee;Park, Sangchan;Jeong, Seonki;Han, Yangsu;Yeon, Ikjun
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.6
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    • pp.27-33
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    • 2009
  • In this study, it was analysed physical characteristics, TS, moisture, C/N ratio, leaching test, and element analysis in landfill wastes of 10 years old without landfill pretreatment. The Organic material content was 7.2%~23.5% and soil was the main inorganic materials which it's rate was 54.1%~71.0%, in landfill wastes. The results of TS, VS, and moisture were represented 51.5%~68.1%, 23.6%~56.1%, 32.0%~48.4%, respectively. The analysis of hazardous materials did not indicate Hg, $Cr^{+6}$, CN, Organic Phosphorus, TCE and PCE, however the Pb of leaching materials showed 0.023~0.092 mg/L, which was the highest. As the result of the element analysis, C was 47.74%~56.72%, N was 4.09%~9.92%, the C/N ratio was 5.76~12.57 and the result of soils around landfill was the highest heavy material, Pb, 2.465 mg/kg~10.251 mg/kg. The objectives of this paper are to investigate states, stabilization of these closed landfills and to gain suitable data for post-closure care using some parameters through analysis of landfill environment.

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Formulation of Alternative Non-Aqueous Cleaning Agents to Chlorofluorocarbon Compounds for Cleaning Flux, Solder and Grease (Flux, Solder 및 Grease 세정용 CFC 대체 비수계 세정제 배합 연구)

  • Jung, Young Woo;Lee, Ho Yeoul;Lee, Myoung Jin;Song, Ah Ram;Bae, Jae Heum
    • Clean Technology
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    • v.12 no.4
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    • pp.250-258
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    • 2006
  • CFC compounds such as CFC-113 and 1,1,1-TCE, etc. have been used in various industries due to their excellent chemical stability, thermodynamic characteristics, non-inflammability and anti-corrosiveness. However, in oder to protect the earth environment, "the Montreal Protocol on substances that deplete the ozone layer" was adopted in 1989 for prevention of production and utilization of these CFC compounds and alternative cleaning agent have been required in the industry. The objective of this study is to develop non-aqueous cleaning agents that do not require major change of cleaning system, have excellent cleaning efficiency, are favorable to the environment, are harmless to the human body, and are not generated corrosive materials. In this work, non-aqueous cleaning agents have been formulated with glycol ether series and paraffinic hydrocarbon series with siloxane, and their physical properties and cleaning efficiencies were analyzed and compared with those of regulated materials. As a result of physical properties measurement of the formulated cleaning agents, it is expected that they may have good penetration ability into contaminated materials due to their properties with low density and low surface tension. Measurement of flash point and vapor pressure of the cleaning agents will be helpful for evaluation of their safety and working environment. The experimental results of cleaning flux, solder and grease by the formulated cleaning agents show that their cleaning abilities of soils were good and that there were no residues on the substance after cleaning. Therefore, alternative cleaning agents which have equivalent cleaning ability to regulating materials, good penetration ability and low hazard to human body, have been developed in this work.

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