• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.16 no.3
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• pp.211-221
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• 2006

This study was performed to compare with desorption efficiency and storage stability of CSC and CMS tubes for Ketones in workplace air. 1. The best desorbing solution for CSC tube was 1 % or 3 % dimethylformamide(DMF) in carbon disulfide($CS_2$). The desorption efficiencies were 96.40 % for cyclohexanone, 94.86 % for acetone, 96.96 % for methyl ethyl ketone(MEK), 103.44 % for methyl isobutyl ketone(MIBK), 100.17 % for methyl amyl ketone(MAK), 100.43 % for methyl butyl ketone(MBK), 97.01 % for toluene and 99.33 % for trichloroethylene(TCE). 2. The best desorbing solution for CMS tube was 1 % or 3 % DMF in $CS_2$. The desorption efficiencies were 96.42 % for cyclohexanone, 98.53 % for acetone, 99.67 % for MEK, 105.48 % for MIBK, 100.13 % for MAK, 100.13 % for MBK, 95.42 % for toluene and 98.15 % for TCE. 3. In the storage condition at room temperature($20^{\circ}C$), the recovery rates of cyclohexanone and MEK on CSC tube were rapidly decreased 30.9 % and 50.9 % after 4 weeks, respectively. The recovery rates of all of 6 ketones and 2 nonpolar solvents were shown over 80 % after 1 week in the storage condition of refrigerate temperature($-4^{\circ}C$), and were kept over 80 % after 4 weeks in the storage condition of freezer temperature($-20^{\circ}C$). 4. The recovery rates of cyclohexanone on CMS tube were 80.6 % for 1 week after and 60.5 % for 4 weeks after at room temperature($20^{\circ}C$). The recovery rates of cyclohexanone were shown 80.6 % for 1 week after and 60.5 % for 4 weeks after at $-4^{\circ}C$, and of 6 ketones and 2 non-polar solvents were kept stable over 85 % at $-4^{\circ}C$ and over 97 % at $-20^{\circ}C$ for 4 weeks after. In conclusion, the best desorbing solution was 1 % or 3 % DMF in $CS_2$ and more appropriate sorbent tube for ketones and non-polar solvents was CMS than CSC. We recommend CSC tube would be useful if the samples analyzed within 1 week because CMS tubes are more expensive than CSC tubes. However, if the storage time is needed more than 3 weeks, CMS tubes should be suitable and the storage condition should be below $-20^{\circ}C$.

• Journal of Veterinary Clinics
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• v.30 no.2
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• pp.87-94
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• 2013

This retrospective study reviewed the clinical and diagnostic features, therapeutic outcome and compilations of interventional ductal occlusion in 37 dogs with patent ductus arteriosus (PDA). Malteses and female dogs were over-presented. Bounding pulse and left basal continuous murmur were most common findings in physical examination, while the differential cyanosis was rarely observed. Left ventricular (LV) enlargement patterns and sinus tachycardia were common in the ECG. Typical radiographic findings included LV elongation and triple bumps indicating left atrial (LA), aortic and pulmonary dilation. Echocardiographic features were typical shunt flow at the ductus arteriosus and marked LV dilation with mild to moderate mitral regurgitation (MR). The 32 of 37 dogs were interventionally treated with either thromboemolic coils (TCE) or Amplatz canine ductal occluder (ACDO). Transient hemoglobinuria caused by incomplete closure was occurred in 2 dogs treated with TCE, although the hemoglobinuria was disappeared within a week of intervention. The dislodgement of occlusion device was occurred in 2 dogs with TCE and 1 dog with ACDO. However there were no significant complications associated with this dislodgement, since those were dislodged at the lower pulmonary vasculature. We also found that no serious complications and no further medical intervention in 29 dogs having long-term follow-ups.

• Journal of Digital Convergence
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• v.12 no.8
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• pp.283-288
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• 2014

The underground water quality of petroleum products storage cavern is influenced by that of dumping and landfill sites adjacent to cavern. From the chemical analysis of underground water sampled from landfill site, insignificant amounts of As, Cu and Pb were detected in a half of test samples while Cd, Hg, $Cr^{6+}$, $CN^-$, TCE, PCE and Phenol were not detected in all samples. All measurements of $COD^{Mn}$ were below $8.0mg/{\ell}$ that can be negligible for the contamination by organic matters. The total bacteria counted from 1st and 2nd microbiological analysis were $94.84{\times}10^4cells/m{\ell}$ and $146.26{\times}10^{-4}cells/m{\ell}$, respectively, and all counts of the sulfate reducing bacteria were less than $2cells/m{\ell}$. It can be suggested that the water quality adjacent to storage cavern can also be studied to improve the reliability of hydrogeologic stability of storage cavern.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.430.1-430.1
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• 2016

We present the concept of reducible fugitive material that conformally surrounds core Cu nanowire (NW) to fabricate transparent conducting electrode (TCE). Reducing atmosphere can corrodes/erodes the underlying/surrounding layers and might cause undesirable reactions such impurity doing and contamination, so that hydrogen-/forming gas based annealing is impractical to make device. In this regards, we introduce novel reducible shell conformally surrounding indivial CuNW to provide a protection against the oxidation when exposed to both air and solvent. Uniform copper lactate shell formation is readily achievable by injecting lactic acid to the CuNW dispersion as the acid reacts with the surface oxide/hydroxide or pure copper. Cu lactate shell prevents the core CuNW from the oxidation during the storage and/or film formation, so that the core-shell CuNW maintains without signficant oxidation for long time. Upon simple thermal annealing under vacuum or in nitrogen atmosphere, the Cu lactate shell is easily decomposed to pure Cu, providing an effective way to produce pure CuNW network TCE with typically sheet resistance of $19.8{\Omega}/sq$ and optical transmittance of 85.5% at 550 nm. Our reducible copper lactate core-shell Cu nanowires have the great advantage in fabrication of device such as composite transparent electrodes or solar cells.

• The Journal of Korean Physical Therapy
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• v.22 no.1
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• pp.9-17
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• 2010

Purpose: The purpose of this study was to compare the effects of Tai-Chi exercise (TCE) and resistance exercise (RE) when used as part of a community-based exercise program on improvement of physical function in elderly women with knee arthritis. Methods: Forty-seven women with knee arthritis participated in this study. They were assigned to one of two groups: the TCE group (n=22) or the RE group (n=25). Tai-Chi exercise and resistance exercise sessions were held for 1 hour per session, twice per week, for 8 consecutive weeks. At pre-treatment and post-treatment, subjects were tested using the following measurements: one-legged stand test (sec), a functional reach test (cm), a test of the strength of the knee extensor and flexor muscles, determination of the pathway of center of foot pressure and vertical ground reaction force for stance phase at pre and post treatment time points. An independent t-test and a ${\chi}^2$ were used to determine the significance of differences between group means using SPSS 12.0. Results: After 8 weeks of participation in the exercise programs, there were significant improvements for both groups in joint pain, difficulty of performing activity, muscle strength of knee extensor and flexor. Also, vertical ground reaction force increased at the loading response phase for both groups. The RE group was significantly different from TC group on the eyes-closed one-legged stand test (sec). Conclusion: Tai-Chi exercise and resistance exercise programs improve physical functioning and reduce pain and locomotion difficulties.

• Journal of Soil and Groundwater Environment
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• v.15 no.3
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• pp.34-43
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• 2010

The fate of hydrophobic organic contaminants (HOCs) in ground water is highly affected by the distribution and property of the carbonaceous materials (CMs) in subsurface sediments. CMs in soils consist of organic matters (e.g., cellulose, fulvic acid, humic acid, humin, etc.) and black carbon such as char, soot, etc. The distribution and property of CMs are governed by source materials and geological evolution (e.g., diagenesis, catagenesis, etc.) of them. In this study, the distribution and property of CMs in subsurface sediments near the Imjin river in the Republic of Korea and HOC sorption property to the subsurface sediments were investigated. The organic carbon contents of sand and clay/silt layers were about 0.35% and 1.37%, respectively. The carbon contents of condensed form of CMs were about 0.13% and 0.45%, respectively. The existence of black carbon was observed using scanning electron microscopes with energy dispersive spectroscopy. The specific surface areas (SSA) of CMs in heavy fraction(HFrCM) measured with N2 were $35-46m^2/g$. However, SSAs of those HFrCM mineral fraction was only $1.6-4.3m^2/g$. The results of thermogravimetric analysis show that the mass loss of HFrCM was significant at $50-200^{\circ}C$ and $350-600^{\circ}C$ due to the degradation of soft form and condensed form of CMs, respectively. The trichloroethylene (TCE) sorption capacities of sand and clay/silt layers were similar to each other, and these values were also similar to oxidzed layer of glacially deposited subsurface sediments of the Chanute Air Force Base (AFB) in Rantoul, Illinois. However, these were 7-8 times lower than TCE sorption capacity of reduced layer of the Chanute AFB sediments. For accurate prediction of the fate of hydrophobic organic contaminants in subsurface sediments, continuous studies on the development of characterization methods for CMs are required.

• Journal of Korea Water Resources Association
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• v.31 no.6
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• pp.667-674
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• 1998

Numerical models simulating the process of NAPL from contaminated soil or groundwater through steam injection can be a useful tool for designing and evaluating the cleanup strategy under various field conditions. One and two dimensional numerical analyses were conducted based on the governing equations describing the NAPL removal as a non-isothermal, multi-phase and multi component process. Relatively good agreements were obtained between the numerical results and the observations from one-dimensional laboratory experiment, except some discrepancy due to experimental difficulties. Simulation effectively identified the steam displacement process of xylene floating on the water table and TCE sinking on the aquifer bottom in a two-dimensional analysis. Overall, simulation models have a high potential in the design/appraisal of a system for field application of the technique as well as in the examination of complex processes such as vaporization which is hard to identify experimentally.

• Journal of the Korean Chemical Society
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• v.36 no.6
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• pp.796-801
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• 1992

An empirical Lewis basicity, DN, for eight mixed methanol solvents has been measured by the solvatochromic behavior of the [Cu(tmen)(acac)]$CIO_4$. The change of DN in mixed methanol solvents is not correlated with composition of the mixtures and divided into three groups: (1) dipolar aprotic solvents contribute mainly to the solvation of solute (MeOH-DMSO, MeOH-PY, MeOH-DMF), (2) two components of mixture contribute equally to the solvation of solute (MeOH-MeCN, MeOH-dioxane, MeOH-AC) and (3) methanol contributes entirely to the solvation of solute (MeOH-DCE, MeOH-TCE). The relationship between DN and Kamlet-Taft's $B_{KT}$ for mixed methanol solvents was found to agree well. These DN values also were a useful factor to analysis of reactivity for mixed methanol solvents.

• Journal of Soil and Groundwater Environment
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• v.18 no.6
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• pp.48-55
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• 2013

This study aimed at characterizing unsaturated zone at the source zone area contaminated by DNAPL and investigating feasibility of soil vapor extraction (SVE). Five boreholes with three multi-level screens at the depth of 3.0~4.5 m, 5.5~7.0 m, and 8.0~12.0 m were installed at the source zone. Pneumatic tests were performed to determine the permeability of porous medium. Permeability was estimated to be 81.6 to 203.7 darcy, depending on the applied solutions, which was contradicted by grain size analysis of cored soil samples leading to 3.51 darcy. This is due to air flow through gravel pack during the early stage of pneumatic test. Pressure-drawdown curve in the late stage also well showed the leaky aquifer type, indicating air leakage to the ground. Air flow tests were also carried out to investigate air flow connectivity between multi-level wells, indicating that the horizontal air flow was well developed between the lower screens of the wells, not between the upper and middle screens due to the leakage to the surface. For the SVE test, there was no noticeable variation in TCE vapor concentration between three different test runs: 1. 8 hours daily for 5 days, 2. 24 hours together with air blowing at another well (BH1), 3. five consecutive days. Even for five-day consecutive test, total amount of removed TCE was estimated only to be as low as 46.5 g.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.1B
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• pp.99-106
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• 2006

Due to both global warming and constructions of seadike/seawalls, continuously or abruptly rising tendencies of extreme high water levels have been detected at Kunsan and Mokpo harbors. This paper deals firstly with the separation of each effect, namely global warming effect and construction effect, on increases of water level quantitatively by a linear regression method. And then, it can be explained why and how the extreme high water levels had been risen just after constructions at both harbors. A numerical simulation of $M_2$ tidal constituent at Mokpo coastal zone shows that the tidal amplification by constructions is mainly due to the extinguishment of TCE at Mokpogu. The tidal flat effect makes the amplification more deepen at spring tide or extreme high tide, which results in the increase of inundation risk at Mokpo harbor. A frequency analysis method is applied, which is shown to be effective at such a site of having non-homogeneous tidal data due to constructions as Mokpo harbor.