• The Korean Journal of Pesticide Science
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• v.11 no.4
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• pp.299-304
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• 2007

Surveying, laboratory and field trial were performed to elucidate the causes of non-spinning syndrome of silkworm, Bombyx mori, abnormal symptoms of silkworm instars observed in certain sericultural fanning region. Mortality and growth of silkworm was still influenced by feeding the mulberry leaves sprayed with 10,000 fold diluted solution of standard spray of diflubenzuron WP (25%). Mortality and growth of silkworm fed with diflubenzuron-sprayed mulberry leaves with recommended spray solution were entirely affected even six weeks after spraying irrespective to the instars. Larval period of 5th instar and cocooning duration of silkworm was not affected in case 50m of buffer zone has maintained in near-by orchard field sprayed with diflubenzuron WP (25%). However, survival rate of pupae was not influenced in case 100 m of buffer zone has kept. Insect growth regulating insecticides were required to keep a certain distance of buffer zone when sprayed with water-diluted solution, 100 m from the application site at least in order to prevent contamination of the spraying drift by the chemicals.

• Journal of Applied Biological Chemistry
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• v.56 no.1
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• pp.53-57
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• 2013

In here, we investigated the quantitative analysis method of indole-3-acetic acid (IAA) and indole-3-butyric acid (IBA) with liquid chromatography-mass/mass spectrometry (LC-MS/MS) or gas chromatography-MS. Two ways of clean-up process were investigated for LC-MS/MS instrumental analysis of IAA, but both a simple dilution and hydrophile-lipophile balance (HLB) solid phase extraction (SPE) were not met the optimal recovery rates for quantitative analysis. On the other hand, the clean-up method for GC-MS was finally optimized through HLB-SPE from 250-folds diluted sample and methylation with trimethylsilyl chloride in methanol for 4 h. The limit of detection for methyl ester of IAA and IBA were both 1.4 mg/L, and recovery rates showed 93-107% from the concentrated liquid fertilizer.

• Clean Technology
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• v.20 no.2
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• pp.103-107
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• 2014

Acrylic acid is a commodity chemical which is applicable for various industries such as polymer and textile industry. Currently, it has been produced by chemical synthesis from petroleum. However, due to the high price of petroleum and global $CO_2$ emission, renewable materials such as sugar are interesting alternative carbon sources for the biological production of acrylic acid. For an economic production of acrylic acid from renewable carbon sources, a cost effective separation process for acrylic acid should be needed. In this study, reactive extraction by TOA (tri-n-octylamine) was used for the recovery of acrylic acid from its aqueous solutions. The effects of polarity of diluents and concentration of TOA on extraction equilibrium were investigated. The extraction efficiency was proportional to concentration of TOA and polarity of diluents and its value was more than 95% in the case of sufficient concentration of TOA. From IR spectroscopy, it was concluded that the ratio of (1,1) acid-amine complex was increased and the ratio of acid dimer was decreased with concentration of TOA. Equilibrium model based on IR spectroscopy was well fitted with experimental data.