• Title/Summary/Keyword: 흡착력

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Desmutagenic Effects of Maillard Reaction Products against Mutagenic Heterocyclic Amines (변이원성 Heterocyclic Amine에 대한 Maillard 반응생성물의 변이원성 억제효과)

  • KIM Seon-Bong;PARK Yeung-Ho;HAYASE Fumitaka;KATO Hiromichi
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.19 no.2
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    • pp.127-135
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    • 1986
  • Each molecular weight (Mw) fraction of melanoidins prepared from a D-glucose and glycine system, i. e., Mw below 1,000, Mw between 1,000 to 5,000 and Mw above 5,000 and nondialyzable and ozone-treated melanoidins were reacted with heat-induced mutagens such as Trp-P-1, Trp-P-2, Glu-P-1, Glu-P-2 and IQ at $37^{\circ}C$ for 30 min. The inhibitory effects of the melanoidins on the mutagens increased with increasing molecular weight. The reducing ability ana antioxidative activity of melanoidins also increased in proportion to the increase in molecular weight, whereas the mutagenic inhibitory effect decreased on reduction of the melanoidins with sodium borohydride. It was also observed that a part of Trp-P-1 was adsorbed to melanoidin molecules. On modification of amino groups of these mutagens with carbonyl compounds derived through the Maillard reaction such as diacetyl and glyceraldehyde, their mutagenic activities were remarkably suppressed. Accordingly, it is speculated that the mutagenic inhibitory action of melanoidins is due to their reducing ability and antioxidative activity, and electrostatic binding and carbonyl groups of the melanoidin molecules.

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Effects of Clay Minerals Treatment on the Physicochemical Characteristics and Growth Inhibition of Microoganism of Some Foods (몇 가지 식품의 이화학적 특성 및 균증식 억제에 대한 점토광물 처리의 영향)

  • Jeong, Ok-Jin;Woo, Koan-Sik;Kim, Kwang-Yup;Lee, Hee-Bong;Jeong, Heon-Sang
    • Korean Journal of Food Science and Technology
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    • v.37 no.1
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    • pp.23-29
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    • 2005
  • To investigate potential characteristics of clay minerals (illite, kaolin, zeolite, vermiculite, and bentonite) for food industry application, antioxidative properties of clay minerals, electron-donating ability (EDA), peroxide value (POV), and thiobabituric acid (TBA) were measured, and antimicrobial activity against several food spoilage microorganisms were evaluated by minimum inhibition concentration (MIC) method. Changes in components by cooking clay minerals added to stored rice were measured by GC-MS. DPPH (1,1-diphenyl-2-picrylhydrazyl) analysis results revealed bentonite has strongest EDA at 20.6%. Antioxidant activities measured based on POV were similar to DPPH results. Induction period of linoleic acid with vermiculite was longest among. TBA results revealed zeolite hasstrongest antioxidant ability. Growth inhibition against E. coli and S. aureuswas observed in illite, vermiculite, and zeolite. Aroma components indicated decrease in hex anal, pent anal, non anal, linoleate, stearic acid, and oleic acid when clay minerals were added to stored rice. These results indicate that several clay minerals have antioxidative and antimicrobial abilities and improve flavor profiles in stored rice.

Effect of pH on Physical Properties of Triethanolamine-Ester Quaternary Ammonium Salt Cationic Surfactant System (수용액의 pH가 Triethanolamine-Ester Quaternary Ammonium Salt 양이온 계면활성제 시스템의 물성에 미치는 영향에 관한 연구)

  • Kim, JiSung;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.479-485
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    • 2009
  • In this study, basic physical properties were measured for ASCO EQ85 cationic surfactant of triethanolamine-ester quaternary ammonium salt and effect of pH on softening performance on fabrics was investigated using zeta potential measurement and adsorption experiment by quartz crystal microbalance. The CMC of the surfactant was near $3{\times}10^{-3}mol/L$ and the surface tension at CMC was about 40 mN/m. The interfacial tension measurement between 1 wt% aqueous solution and n-dodecane measured by spinning drop tensiometer showed that interfacial tension slightly increased with an increase in pH but the equilibration time was not affected by pH. The surfactant adsorption was found to increase with an increase in surfactant concentration and was also affected by pH of surfactant solution. The friction factor for fabrics treated with ASCO EQ85 surfactant was shown to increase with pH and better softening effect was found under acidic conditions. Half-life for foams generated with ASCO EQ85 surfactant solution increased with pH, which indicated an increase in foam stability with pH.

A Study on Physicochemical Properties of Achyranthes japonica and Smilax china Extracts (쇠무릎과 청미래덩굴 부위별 추출물의 이화학적 특성에 관한 연구)

  • Jeong, Kap-Seop
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.7
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    • pp.3317-3326
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    • 2011
  • Physicochemical properties of Achyranthes japonica and Smilax china extracts were investigated for the purpose of functionality research on the natural bio-resources. Extraction contents were order of distilled water>methanol>ethanol solvent, the highest free aminoacids were proline from Achyranthes japonica, phosphoserine and glutamic acid from Smilax china, respectively. BI and TAC by spectrophotometric absorbance were order of methanol>ethanol>water in Smilax china leaf extract, but water>methaol>ethanol in Achyranthes japonica leaf extract. EDA was high in ethanol extract from Smilax china leaf and in methanol extract from Smilax china root, and in water extract from Achyranthes japonica. TBA value of Achyranthes japonica leaf and Smilax china leaf-ethanol extracts on olive oil was 82.1% and 84.0%, respectively, for that of an artificial antioxidant BHT. Antimicrobial effect was observed in Achyranthes japonica stem-methanol extract on Bacillus subtillis, in Smilax china leaf-ethanol extract on Bacillus subtillis, Vibrio vulnificus and Salmonella enterica, respectively. And the adsorption of Pb(II) on Achyranthes japonica was higher than that of Cd(II) on Smilax china under the same metal ion concentration.

The Antioxidant Activity of Yacon (Polymnia sonchifoliaty) and its Application to the Pork Patties as a Natural Antioxidant (야콘 착즙액의 항산화 활성 및 천연 항산화제로서 돈육패티에 이용)

  • Park, Jin-Sun;Kim, Hyeong-Sang;Chin, Koo-Bok
    • Food Science of Animal Resources
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    • v.32 no.2
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    • pp.190-197
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    • 2012
  • This study was performed to evaluate the extraction method (Yacon ethanol extracts; YEE, Yacon pressed extracts; YPE) and various levels (0.05-1.0%) of Yacon (Polymnia sonchifolia) on antioxidant and antimicrobial activities. In linoleic acid emulsion of YPE, there were higher iron chelation activity and antioxidant activity than those of YEE (p<0.05). A 1,1- diphenyl-2-picryl hydrazyl (DPPH) radical scavenging activity and reducing power of both extracts showed a higher rate at 0.5% level. Ground pork patties, which contain 0.5% YEE and YPE, were manufactured and BHT (0.01%) was used as a reference. Physicochemical properties and microbial counts of ground pork patties, containing a different type of Yacon, were evaluated during the 14 d of storage at $4^{\circ}C$. A pH level, and lightness (Hunter L), as well as the yellowness (Hunter b) values of treatments were not different from those of the control (p>0.05), but increased during storage, at $4^{\circ}C$. Lightness values of ground pork patties, with Yacon extracts, showed the highest. TBARS value of ground pork patties that contains Yacon increased with increased storage at $4^{\circ}C$ (p<0.05), and pork patties with YPE or YEE retarded the lipid oxidation, during refrigerated storage, as compared to that of the CTL. Thus, YPE could be used as a potential possibility to inhibit the lipid oxidation of processed meats, during the refrigerated storage.

Evaluation of Antioxidant Activities of Red Beet Extracts, and Physicochemical and Microbial Changes of Ground Pork Patties Containing Red Beet Extracts during Refrigerated Storage (레드비트 추출물의 항산화 활성 및 레드비트를 첨가한 돈육패티의 냉장저장 중 이화학적 성상 및 미생물의 변화)

  • Lee, Jun-Ho;Chin, Koo-Bok
    • Food Science of Animal Resources
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    • v.32 no.4
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    • pp.497-503
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    • 2012
  • This study was performed in order to evaluate the antioxidant activities of red beet extracts as well as the physicochemical properties and microbial changes of pork patties containing red beet during refrigerated storage. Red beet was extracted with water and ethanol. Red beet water extracts (RBW) and red beet ethanol extracts (RBE) were diluted with various concentrations (0.05~1.0%). DPPH radical scavenging activity and iron chelation activity of RBW showed a higher level than those of RBE (p<0.05). In particular, the iron chelation activity of RBW was over 53.4% at all levels. In addition, RBW at 1% had nearly 100% activity. On the other hand, the reducing powers of RBE were higher than those of RBW (p<0.05), and the antioxidant activity on linoleic acid emulsion of RBW was over 83% at all levels. Based on these model studies, 0.5% levels of RBW and RBE were added to ground pork patties (GPP), and the physicochemical properties and microbial changes of red beet GPP were evaluated during storage (0~14 d) at $4^{\circ}C$. The pH and microbial counts increased with increased storage time (p<0.05). Pork patties with BHT showed the lowest thiobarbituric acid reactive substances (TBARS) and microbial counts, and those with red beet had lower TBARS than the control (p<0.05). These results indicated that both red beet water and ethanol extracts could be used as natural antioxidants of pork patties during storage.

Influences of Addition of Jellyfish Powder to Bed Soil and Bacterial Community Structure of Bed Soil (해파리 분말의 상토 첨가물로서의 효과 및 상토의 미생물 군집 변화에 대한 연구)

  • Beck, Bo-Ram;Choi, Jae-Ho;Kim, Young-Rok;Cha, Ha-Eun;Do, Hyung-Ki;Hwang, Cher-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.2
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    • pp.227-234
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    • 2012
  • Recently, the population of toxic and/or unusable jellyfish is increasing during summer along the east coast of Korea, causing massive economical and ecological damage to fisheries, nuclear power plant and marine environment. To solve this problem, this study was carried out using jellyfish as a potential soil additive for horticulture. The jellyfish was solidified and homogenized, then mixed with a commercial bed soil. Allium tuberosum ROTH was planted to control bed soil (BS) and jellyfish powder mixed bed soil groups (Mixed bed soil, MBS), and following parameters were measured during five weeks: water content, electrical conductivity and growth of leaves. At the end of the experiment, bacterial community structures of each pot were analyzed by DGGE. The relative water adsorption of jellyfish powder was about 2.5 times greater compared to its dry weight. The water content of MBS group was significantly higher than BS group 6.5 to 14.2%, and the electric conductivity of MBS group was measured around 2.8 dS/m where BS group was resulted average of 1.8 dS/m. However, the leaves of BS group were grown 30% longer compared to MBS group. DGGE analysis of MBS group was shown in high number of phylum Bacteroidetes and increased diversity of Sphingobacteriia compared to BS group. Jellyfish powder as a soil additive surely will be a good candidate as humectant and microbiota stimulator, although there are several obstacles such as high electrical conductivity and residual alum salt which used for solidification of jellyfish.

Physical and Sensory Properties of Chiffon Cake Made with Rice Flour (쌀가루로 제조한 쉬폰케이크의 물리적.관능적 품질특성)

  • Kim, Ji-Na;Shin, Weon-Sun
    • Korean Journal of Food Science and Technology
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    • v.41 no.1
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    • pp.69-76
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    • 2009
  • This study was conducted to evaluate the physicochemical and sensory characteristics of chiffon cakes made with rice flour ranging from 20-100% in place of wheat flour. The water binding capacity of the rice flour was greater than that of the wheat flour and its fat binding capacity was lower than that of the wheat flour. The batter stability data indicated that the 100% treatment was better than the control, and specific gravity values and specific loaf volumes were lower in the samples with added rice flour. Texture analysis found no significant differences in hardness, adhesiveness, cohesiveness, gumminess, and chewiness between the control and the 100% treatment. In the case of crust color, the rice flour-added chiffon cakes did not show any significant differences for their 'a' values. In addition, their crumb color was not significantly different in terms of both their 'L' and 'a' values. According to the sensory evaluation, there was no significant difference in overall acceptability between the control and the rice flour-added chiffon cakes. The highest sensory scores were obtained by the 100% treatment for overall acceptance and moistness. However, flavor, cohesiveness, and brittleness were not significantly different. These study results show that wheat flour could be replaced by rice flour up to 100% in chiffon cake.

The Adsorption and Desorption of SO4-2 in the Garlic Field (마늘 재배지토양(栽培地土壤) 중 SO4-2의 흡(吸), 탈착(脫着))

  • Chang, Gi-Chul;Chang, Sang-Moon;Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.4
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    • pp.327-332
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    • 1987
  • Soil samples were collected from the paddy soils growing two crops of rice and garlic in Kyung-pook province. To obtain the basic information on the application of S-fertilizer in the garlic field, the adsorption and release amount of $SO_4{^{-2}}$ in subsoil samples were determined. The ranges of $SO_4{^{-2}}$ contents in surface and sub-soil were 59-117 and 34-102 ppm, respectively. The amount of $SO_4{^{-2}}$ adsorbed by soil samples was found to be more at lower pH and higher concentration of $SO_4{^{-2}}$. The $SO_4{^{-2}}$ adsorption constants in Freundlich equation tended to be higher at lower pH. It is apparent that most of $SO_4{^{-2}}$ was released in the first extraction. However, the lower the pH of extracted solution, the more the $SO_4{^{-2}}$ contents was released by distilled water.

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Gas Separations of Natural Zeolite by Chemical Treatments (화학처리에 의한 천연 Zeolite의 Gas 분리)

  • Im, Goeng
    • The Journal of Natural Sciences
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    • v.5 no.1
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    • pp.67-75
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    • 1992
  • In the our country, especially in Yeongil and Wolsung area, abundant authigenic zeolites are found from the tuffaceous sediments and volcanic rocks of Miocene age showing wide variation in their mineralogy and abundance from horizon to horizon. The principal zeolite species identified are clinopti-lolite. mordenite. heulandite. ferrierite, and erionite. etc. Zeolite minerals are widely used in many countries in the following applications; (a) in air separation adsorption processes; (b)as desiccants; (c)in inorganic building materials; (d)in papermaking; (e)in fertilizers; (f)as soilconditioners-this application is based upon the ability of the zeolite to ion exchange with soil nutrients; (g)in the treatment of radioactive wastes; and (h)as adsorbents for toxic gases, etc. In the present paper, using natural zeolite mordenite treated with IN hydrochloric acid or IN sodium chloride solution as column packings, separation characteristics of argon, nitrogen, carbon monoxide, and methane gases have been studied by gas chromatography. By the use of mordenite treated with hydrochloric acid solution, the tailing peak of methane showed from untreated mordenite was satisfactorily reduced, although it was difficult to separate it from carbon monoxide with a column activated at $300^{\circ}C$. Using a column activated at $350^{\circ}C$, methane could be separated from carbon monoxide easily but only carbon monoxide eluted as a bad defined peak. Mordenite treated with sodium chloride solution was generally similar to chromatograms obtained by using the untreated mordenite. Both the above chemical treatments of mordenite had little effect on the separations of argon and nitrogen. The separations and the HETP values obtained from natural zeolite mordenite treated with continuously hydrochloric acid and sodium chloride solutions were almost identical with those obtained with synthetic molecular sieve 5A zeolite. On the other hand, the efficiency of column was good in the range 20~3Oml/min of the carrier helium gas rate.

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