• Title/Summary/Keyword: 흡수 spectrum

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Seismic Fragility Analysis of Equipment Considering the Inelastic Energy Absorption Factor of Weld Anchorage for Seismic Characteristics in Korea (국내 지진동 특성에 대한 기기 용접 정착부의 비탄성에너지 흡수계수를 고려한 지진취약도 평가)

  • Eem, Seunghyun;Kim, Gungyu;Choi, In-Kil;Kwag, Shinyoung
    • Journal of the Earthquake Engineering Society of Korea
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    • v.27 no.1
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    • pp.69-75
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    • 2023
  • In Korea, most nuclear power plants were designed based on the design response spectrum of Regulatory Guide 1.60 of the NRC. However, in the case of earthquakes occurring in the country, the characteristics of seismic motions in Korea and the design response spectrum differed. The seismic motion in Korea had a higher spectral acceleration in the high-frequency range compared to the design response spectrum. The seismic capacity may be reduced when evaluating the seismic performance of the equipment with high-frequency earthquakes compared with what is evaluated by the design response spectrum for the equipment with a high natural frequency. Therefore, EPRI proposed the inelastic energy absorption factor for the equipment anchorage. In this study, the seismic performance of welding anchorage was evaluated by considering domestic seismic characteristics and EPRI's inelastic energy absorption factor. In order to reflect the characteristics of domestic earthquakes, the uniform hazard response spectrum (UHRS) of Uljin was used. Moreover, the seismic performance of the equipment was evaluated with a design response spectrum of R.G.1.60 and a uniform hazard response spectrum (UHRS) as seismic inputs. As a result, it was confirmed that the seismic performance of the weld anchorage could be increased when the inelastic energy absorption factor is used. Also, a comparative analysis was performed on the seismic capacity of the anchorage of equipment by the welding and the extended bolt.

Solvent Selection for the Detection of Siloxanes in Landfill gas (매립가스내 규소화합물류 검출을 위한 용매선택에 관한 연구)

  • Kim, Nack-Joo;Choi, Ju-Mi;Ji, Eun-Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.8
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    • pp.915-921
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    • 2007
  • As a preliminary measurement of siloxanes in landfill gas(LFG), this study was conducted to determine the best suitable solvent applicable to the extraction of siloxanes in the domestic landfill using liquid-absorption method. Three solvents of n-hexane, acetone, and methanol were tested and the results obtained from GC analysis for each solvent were compared to their properties. Results showed that the resolution in the GC spectrum was the best from methanol due to the lack of overlapping of the peaks between silane and solvent. The detected siloxanes concentration were varied at maximum 2.6 times depending on the types of solvent as well as extraction velocity and impinger steps. In total, the highest concentration of siloxanes was obtained from methanol, which showed ideal pattern in the absorption of each impinger step and the least relative standard deviation. Accordingly, it is concluded that methanol is the most suitable solvent for the extraction of siloxanes in the domestic landfill. However, it is considered that solvent suitability can vary depending on the waste components and landfill record in landfills.

A STUDY ON CHANGE OF COMPRESSIVE STRENGTH AND FLEXURAL STRENGTH OF DENTAL COMPOSITE RESIN AFTER WATER STORAGE (치과용 콤포짓트 레진의 수분 흡수에 따른 압축강도와 굴곡강도의 변화에 관한 연구)

  • Jeong, Nae-Jeong;Kim, Jung-Wook;Lee, Sang-Hoon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.1
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    • pp.146-153
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    • 2001
  • The difference of composition of composite resin may affect the mechanical properties of composite resin and the environment is important for the properties of materials. The composite resin restoration is always exposed to fluid in oral cavity and the composite resin matrix is able to absorb water, which is accompanied by some swelling of the composite The uptake of water by composites has been correlated with decreases in surface hardness and wear resistance. The purpose of this study was to investigate the effects of water storage in $37^{\circ}C$ distilled water after 7days, 30days, 60days, 120days on compressive strength and flexural strength of dental composite resin, Z-100(group 1) Spectrum(group 2), Clearfil AP-X(group 3), Pyramid(group 4), Heliomolar(group 5). The compressive and flexural strength were measured by instron machine. The following results were obtained: 1. There were significant reduction of compressive strength as water storage time increased, 7days, 30days, 60 days, 120days(p<0.05). 2. There were significant reduction of flexural strength as water storage time increased, 7days, 30days, 60days, 120days(p<0.05). 3. Group 1, 2, 3 -hybrid type showed higher compressive and flexural strength than group 5-microfine type which had lower filler contents.

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Numerical Analysis of Differential Absorption Lidar for Measuring Atmospheric Pollutants (대기오염 측정용 DIAL의 오차해석에 관한 연구)

  • Park, Jin Hwa;Yi, Yong Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.1
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    • pp.113-120
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    • 2000
  • In this study, we composed algorithm for DIAL(Differential Absorption Lidar). We investigated the absorption spectrum of $O_3$, $SO_2$ and $NO_2$ dependent on wavelengths using data base UV-Bank and determined the optimized wavelength model. Here, the selected optimal wavelengths are 292.00(${\lambda}_{on}$), 295.20 (${\lambda}_{off}$) for $O_3$, 299.38(${\lambda}_{on}$), 300.05 (${\lambda}_{off}$) for $SO_2$ and 448.00(${\lambda}_{on}$), 449.85(${\lambda}_{off}$) for $NO_2$. In particular, we established the supposed model of DIAL and simulated the error of measuring distance using the selected optimal wavelength. In the model-I with telescope of 300 mm diameter, laser energy of 3 mJ and transmission of 10000 shots, maximum distances are 4 km for $O_3$ measurement and 5 km for $SO_2$ and $NO_2$ measurements. Also, in the model-II with telescope of 600 mm diameter, laser energy of 30 mJ and transmission of 10000 shots, maximum distances are 13 km for $SO_2$ and $NO_2$ measurements.

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Characteristics of $CO_{2}$ Absorption and Degradation of Aqueous Alkanolamine Solutions in $CO_{2}$ and $CO_{2}-O_{2}$ System ($CO_{2}$$CO_{2}-O_{2}$ 시스템에서 알카놀아민류 흡수제를 이용한 $CO_{2}$ 흡수 및 흡수제 열화 특성)

  • Choi, Won-Joon;Lee, Jong-Seop;Han, Keun-Hee;Min, Byoung-Moo
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.256-262
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    • 2011
  • Amine can undergo irreversible reactions by $O_{2}$ and high temperature in amine scrubbing process and these phenomena are called "degradation". Degradation causes not only a loss of valuable amine, but also operational problems such as foaming, corrosion and fouling. In this study, using various chemical absorbents(MEA; monoethanolamine, AMP; 2-amino-2-methyl-1-propanol, DAM; 1,8-diamino-p-menthane), we examined the following variable. I) loading ratio of $CO_{2}$ at $50^{\circ}C$ and $120^{\circ}C$, ii) concentration variation and initial degradation rate constant of absorbent in $CO_{2}$ and $CO_{2}/O_{2}$ system, and iii) effect of degradation by $O_{2}$. The $CO_{2}$ loading of 20 wt% DAM was 400% and 270% higher than that of 20 wt% MEA and AMP at 50, respectively and was the largest the difference of $CO_{2}$ loading between absorption $(50^{\circ}C)$ and regeneration $(120^{\circ}C)$ condition. The initial degradation rate constant of 20 wt% DAM was $2.254{\times}10^{-4}cycle^{-1}$ which was slower than that of MEA $(2.761{\times}10^{-4}cycle^{-1})$ and AMP $(2.461{\times}10^{-4}cycle^{-1})$ in $CO_{2}$ system. Also, it was increased 30% by $O_{2}$ that effects on the degradation by $O_{2}$ was less than 100% increased. these degradation reactions was able to identify by formation of new peak in GC and FT-IR spectrum analysis.

Study on Analysis of Occupant Safety Index & Behavior Using Full-Scale Crash Test Data of Crash Cushion (충격흡수시설의 실물차량 충돌시험 데이터를 이용한 탑승자 안전도 및 충돌거동 분석에 관한 연구)

  • Joo, Jae Woong;Kum, Ki Jung;Jang, Dae Young;Kim, Bum Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2D
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    • pp.163-170
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    • 2008
  • According to the rules, a crash cushion is supposed to set up products that is satisfied with the standard of a performance test after performing the car crash test by road safety facilities and management guide. For development of crash cushion, performance should be estimated through the car crash test eventually. However, there is no reasonable design method which considers passenger's safety and only depend on crash test without an alternative plan. Therefore it incurs a loss materially and takes a lot. Therefore, we are asked to create a systematic design of the crash cushion. This study shows that a scientific basis of applying single degree of freedom when it designs the crash cushion after analyzing vehicle crash test data of crash cushion and also represents design of crash cushion through single degree of freedom response spectrum using calculated by crash test data on crash cushion.

Crystallographic and magnetic properties of (CoFe2O4)1-X(Y3Fe5O12)X ((CoFe2O4)1-X(Y3Fe5O12)X 분말의 구조적 특성과 자기적 특성)

  • Lee, Jae-Gwang;Chae, Kwang-Pyo;Jang, Joon-Sik;Lee, Sung-Ho;Lee, Yong-Bae
    • Journal of the Korean Magnetics Society
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    • v.13 no.1
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    • pp.1-5
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    • 2003
  • Magnetic and structural properties of $(CoFe_2O_4)_{1-x}(Y_3Fe_5O_{12})_x$ powders (0 $\leq$ x $\leq$ 1) grown by a conventional ceramic method were investigated using X-ray diffractormeter (XRD), scanning electron microscopy (SEM), Mossbauer spectroscopy and vibrating sample magnetometer (VSM). The XRD results for the powders annealed at 120$0^{\circ}C$ indicated that no other peak was observed except for the ones from cobalt ferrite and the garnet powder. SEM micrographs indicated that cobalt ferrite and garnet powders were aggregated and completely formed together. It was hard to identify which part of the powders was the garnet or the cobalt ferrite. Mossbauer spectra for powders grown separately and mixed mechanically consisted of sub-spectra of cobalt ferrite and garnet, however, powders annealed together had an extra sub-spectrum, which was related with the interaction between iron ions at the grain surfaces of cobalt ferrite and the garnet: cobalt ferrite and garnet particles were located very closely. The value of the saturation magnetization measured by a VSM as a function of composition ratio agreed very well with the ones based on the theoretical calculation.

Studies on the Electrochemical Behaviors, Spectrophotometric Determination of Heavy Lanthanide Ions and Heavy Metal Chelate Complexes with Bidentate Ligands(III) -Synthesis and Characterization of the Tetrakis(5,7-dichloro-8-quinolinato)(2-mercaptopyrimidinato) molybdenum(IV) Complex- (무거운 란탄이온의 전기화학적 거동, 분광학적 정량 및 중금속 이온과 두 자리 리간드 착물에 관한 연구(제 3 보): -테트라키스(5,7-디클로로-8-퀴놀리나토)(2-메르캅토피리미디나토) 몰리브데늄(IV) 착물의 합성 및 특성-)

  • Chang, Choo Hwan;Choi, Won Jong;Park, Keun Su;Son, Pyung Su;Suh, Moo Yul
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.417-424
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    • 1993
  • Eight-coordinate tetrakis molybdenum(IV) complexes containing 5,7-dichloro-8-hydroxyquinolinol(Hdcq) and 2-mercaptopyrimidine(Hmpd) has been prepared. $Mo(mpd)_4$, $Mo(dcq)(mpd)_3$, $Mo(dcq)_2(mpd)_2$, $Mo(dcq)_3(mpd)$ and $Mo(dcq)_4$ complexes have been isolated by thin-layer chromatography on silicagel plates. These complexes have been charaterized by $^1H-nmr$ spectrum and UV-Vis. spectrum. The chemical shift values of the protons ${\alpha}$ to the nitrogen in the ligands are shifted to down field. The relative intensities of the peaks which are positioned at the same proton of $Mo(dcq)(mpd)_3$ and $Mo(dcq)_3(mpd)$ are observed in 2:1 ratio, in case of $Mo(dcq)_2(mpd)_2$ appears in approximately a 1:1 ratio. The stereochemistry of the complexes in discussed in terms of their nmr spectrum and Orgel's rule. By vertue of the intensities (${\varepsilon}$>10,000~25,000) the low energy($16,600{\sim}19,800cm^{-1}$) bands are observed for the electronic spectra of the complexes are assigned as charge transfer bands.

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A Study on the Characteristics of Humic Materials Extracted from Decomposing Plant Residues -I. Chemical Properties of Humic Acids from Plant Residues Characterized by IR Spectra (식물성(植物性) 유기물질(有機物質)의 부숙과정중(腐熟過程中) 부식특성(腐植特性)에 관(關)한 연구(硏究) -1. 분광분석(分光分析)에 의(依)한 식물잔해(植物殘骸) 부식산(腐植酸)의 화학적(化學的) 성질규명(性質糾明))

  • Kim, Jeong-Je;Shin, Young-Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.3
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    • pp.251-259
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    • 1987
  • Humic acids extracted from decomposing plant residues were characterized by infrared(IR) spectra. The IR spectra were further interpreted by chemical analyses for oxygen-containing functional groups such as carboxyl, phenolic, alcoholic, carbonyl, and quinionic groups. 1. The IR spectra obtained in this study were divied into three categories: spectra of humic acids from grain crop straws of rice, barley, wheat and rye produced Type I, while that from wild grass hay yielded Type II, and those from forest tree litter of the deciduous and conifers were led to give Type III. 2. There were no significant changes in the absorption bands observed among humic acids extracted at various stages of decomposition of a given Plant material. 3. The absorption band at about $3,430cm^{-1}$ represents the presence of hydrogen-bonded hydroxyl groups, phenolic-OH groups being the major component. 4. A close relationship was found between the total acidity and the content of phenolic-OH groups of humic acids. The content of carboxyl groups maintains a direct relationship with the content of total hydroxyl groups, and such a close relationship also exists between the content of alcoholic hydroxyls and that of total hydroxyl groups. 5. Overlapping of the absorption bands of carbonyl groups and quinones renders it difficult to make differentiation between the two. 6. A variety of non-armoatic cyclic hydrocarbons appears to be a structural component as evidenced by a sharp absorption peak near $995-1000cm^{-1}$.

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Determination of Optical Constants of Amorphous $As_2S_3$ Thin Film by Transmission Spectrum ($As_2S_3$박막의 투과 스펙트럼을 이용한 광학 상수와 특성 조사)

  • 우성용;이상조;김건엽;곽종훈
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.18-19
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    • 2003
  • 비정질 As$_2$S$_3$박막에 레이저광의 조사에 대한 투과율 변화는 굴절률과 흡수계수 변화 등의 비선형 광학 특성에 대한 많은 정보를 제공해준다. 투과 스펙트럼을 측정하여 비정질 As$_2$S$_3$ 박막의 광학 상수를 결정하는 일은 간단하면서도 신뢰도 높은 값들을 얻을 수있게 한다. 본 실험에서는 비정질 As$_2$S$_3$ 박막을 진공 증착법을 이용하여 제작하고, 스펙트로포터미터를 사용하여 박막이론에 따른 굴절률, 흡수계수, 박막의 두께 및 조사된 레이저광에 의한 광학적 상수의 변화등을 측정하였다. (중략)

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