• Title/Summary/Keyword: 흡수 계수

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Absorption Characteristics of Water-Lean Solvent Composed of 3-(Methylamino)propylamine and N-Methyl-2-Pyrrolidone for CO2 Capture (3-메틸아미노프로필아민과 N-메틸-2-피롤리돈을 포함한 저수계 흡수제의 CO2 포집 특성)

  • Shuai Wang;Jeong Hyeon Hong;Jong Kyun You;Yeon Ki Hong
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.555-560
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    • 2023
  • Conventional aqueous amine-based CO2 capture has a problem in that a large amount of renewable energy is required for CO2 stripping and solvent regeneration in its industrial applications. This work proposes a water-lean absorbent that can reduce regeneration energy by lowering the water content in the absorbent with high absorption capacity for CO2. To this purpose, this water-lean solvent introduced NMP (N-methyl-2-pyrrolidone), which has a higher physical solubility in CO2 and a low specific heat capacity comparing to water, along with 3-methylaminopropylamine (MAPA), a diamine, into the absorbent. The circulating absorption capacity and absorption rate for CO2 of this water-lean solvent were measured using a packed tower. When NMP was added to the absorbent, the absorption rate was improved. In the case of the absorbent containing 2.5M MAPA was used, the maximum circulating absorption capacity was obtained when 10 wt% of NMP was included in absorbent. The overall mass transfer coefficient increased as the concentration of NMP increased. However, at loading values higher than 0.5, the increment in mass transfer coefficient decreased as the concentration of NMP increased. When the lean loading value is low, the mass transfer resistance due to viscosity of the absorbent is low, so the overall mass transfer coefficient increases with the addition of NMP. However, as the lean loading value increases, the viscosity of the absorbent increases, and the diffusivity of CO2 and MAPA decreases, resulting in sharply decreasing of the overall mass transfer coefficient.

Determination of the complex refractive index and thickness of MNA/PMMA thin film (MNA/PMMA 고분자박막의 복소굴절율 및 두께결정)

  • 김상열
    • Korean Journal of Optics and Photonics
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    • v.7 no.4
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    • pp.357-362
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    • 1996
  • The thickness and the spectrum of the complex refractive index in the region 1.5~4.5 eV, of an MNA/PMMA thin film fabricated by spin casting are determined. The film thickness and the refractive index in its transparent region is calculated by modeling the spectroscopic ellipsometry data. The extinction coefficient spectrum is obtained from the absorption spectrum in its non-transparent region. The best fit oscillator parameters of the classical Lorentz oscillator and a quantum mechanical oscillator are found. The complex refractive index spectrum by these oscillators are compared. The present technique can be applied to get the thickness and the complex refractive index of unknown polymer films and thus it will be useful in optical characterization of those films.

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Calibration Examination of Dose Area Product Meters using X-ray (X선을 이용한 면적선량계의 교정 연구)

  • Jung, Jae Eun;Won, Do-Yeon;Jung, Hong-Moon;Kweon, Dae Cheol
    • Journal of the Korean Society of Radiology
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    • v.11 no.1
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    • pp.37-42
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    • 2017
  • We measured the absorbed dose and the area dose using an ionization chamber type of area dose product (DAP) meter and measured the calibration factor in the X-ray examination. In the indirect dose measurement method, the detector was installed in the radiation part of the X-ray equipment, and the measured value was calculated as the dose at the exposure part. The instrument used to calculate the calibration factor was an X-ray equipment (DK-550R / F, DongKang Medical Co., Ltd., Seoul, Korea). The calibration method for the calibration factor was to connect the DAP meter (PD-8100, Toreck Co. Ltd., Japan) to the calibration dosimeter tube voltage of 70 kV, tube current of 500 mA, 0.158 sec. The reference dosimeter used a semiconductor (DOSIMAX plus A, Scanditronix, $Wellh{\ddot{o}}fer$, Germany). After installing the DAP meter on the front of the multi-collimator of the ionization chamber, the calibration factor of the dosimeter was obtained using the reference dosimeter for accurate dose measurement. Experimental exposure values and values from the calibration dosimeter were calculated by multiplying each calibration factor. The calibration factor was calculated as 1.045. In order to calculate the calibration coefficient according to the tube voltage in the ionization type DAP dosimeter, the absorbed dose and the area dose were calculated and the calibration factor was calculated. The corrective area dose was calculated by calculating the calibration factor of the DAP meter.

An Experimental Study on the Engineering Characteristics Analysis of Unsaturated Weathered Granite Soil (불포화된 화강풍화토에 대한 공학적 특성분석을 위한 실험적 연구)

  • Kim, Joon-Seok
    • Journal of the Society of Disaster Information
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    • v.16 no.3
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    • pp.577-585
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    • 2020
  • Purpose: The presence of the matric suction in unsaturated soil increases the stability of the slope, but the reduction of the matric suction due to precipitation can cause sudden slope failure, resulting in a major disaster. In this paper, engineering characteristics in unsaturated state were analyzed for granite weathering soil, which is the representative mountain soil of Korea. Method: Experiments and analysis were conducted on granulated weathering soil as unsaturated shear strength relationships for moisture characteristic curves, unsaturated injection curves, and matric suction under unsaturated conditions. Result: It was analyzed that a rapid change in the matric suction for volumetric water content occurs compared to the case where the particle size distribution is poor and the particle size distribution is good. A good case for the particle size distribution indicates a relatively small permeability coefficient at the same matric suction capacity compared to a poor case. The greater thematric suction, the greater the shear strength. Conclusion: For Korea's representative soil, granulated weathering soil, the functional characteristic curves, unsaturated permeability coefficients, unsaturated shear strength, etc., which are engineering characteristics in unsaturated state, were tested to secure each correlation.

Dynamic Deformational Characteristics of Subgrade Soils with Variations of Capillary Pressure and Water Content (모관흡수력 및 함수비에 따른 노상토의 동적변형특성 연구)

  • 김동수;김민종;서원석
    • Journal of the Korean Geotechnical Society
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    • v.18 no.5
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    • pp.109-122
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    • 2002
  • The water content of soil near the ground subgrade varies seasonally, and dynamic deformational characteristics of soil are affected by the variation of water content. Contrary to previous studies which used various specimens of different compaction moisture contents, the influences of water content and capillary Pressure on dynamic deformational characteristics of soil were investigated using the given specimen controlling the matric suction. RC/TS(resonant column and torsional shear) testing equipment was modified so that it can control water content with changing capillary pressure(matric suction). RC/TS tests were performed on subgrade soil collected in the KHC(Korea Highway Corporation) test road. In the field, the cross-hole tests were performed and the water contents were measured at the same site to verify the feasibility and applicability of RC/TS test results. As water content decreased, the tendency of increasing shear moduli in field was well matched with laboratory test results.

An Experimental Study on Heat and Mass Transfer Characteristics of the LiBr-Water Solution Film inside a Vertical Tube (수직관내 리튬브로마이드 수용액의 열 및 물질전달 특성에 관한 실험적 연구)

  • 강인석;유승광;이동진;김태진
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1994.05a
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    • pp.103-108
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    • 1994
  • 리튬브로마이드 수용액이 수직관내면을 따라 액막의 형태로 흘러 내릴때 수증기와의 흡수과정에 대하여 열 및 물질전달 특성을 실험하였다. 실험에서 열 및 물질전달계수는 막레이놀즈수를 30에서 200까지 변화시키면서 실시하였다. 일정한 냉방능력에서 시스템 압력을 변화시켰을 때의 열 및 물질전달계수를 측정하였다. 액막의 열전달계수는 레이놀즈수가 증가함에 따라 감소하였다. 최대 질량유량에서 최적의 막레이놀즈수가 존재하였다.

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The Study of Gas Permeability through the Polyimide Membranes according to Imidization (이미드화도에 따른 폴리이미드 막의 기체루과에 관한 연구)

  • 김남일;조한석;홍치선;남세종
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.10a
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    • pp.37-38
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    • 1991
  • 몇가지 dianhydride와 diamine을 사용하여 합성한 PAA막을 가열온도와 가열시간을 달리하여 이미드화를 달리하는 막을 제조하고 이압법에 의하여 투과계수와 확산계수를 측정하였다. 이로부터 얻은 흡수계수는 Dual-Mode Sorption Model에 의하여 상관시켰다. 이로부터 polyimide막에 있어서 이미드화에 따른 기체루과 특성과 화학구조에 의한 기체투과 특성의 일부를 규명하였다.

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Design of Wave Absorber for a Perfectly Conduction Sphere Using the Eigenfunction Series Solution form a Coated Sphere (코팅된 구의 고유함수 해를 이용한 완전도체구의 전파흡수체의 설계)

  • 심재은;전중창;김효태
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.4
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    • pp.18-24
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    • 1999
  • The design method of a wave absorber for a perfectly conducting sphere is presented. The backscattered field from a coated sphere can be represented as the sum of the reflected field and the creeping wave. The wave absorber for a curved surface has been designed from that the reflection coefficient of the reflected field is zero. For the design of wave absorber for a small sized conducting sphere, the creeping wave should be considered as well as the reflected field. The perfect absorbing conditions are numerically searched using the Newton-Raphson method from the backscattered field of the eigenfunction series solution from a coated sphere. The wave absorber designed by this method exhibits a superior performance of absorption to that designed from the plate type absorbing condition.

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Evaluation of the Output Dose of a Linear Accelerator Photon Beams by Using the Ionization Chamber TM31010 Series through TG-51 Protocol to Postal Monitoring Output of RPC for 5 Years (TM31010 계열의 공동이온전리함과 TG-51을 이용한 선형가속기광자선의 5년간 출력선량 평가)

  • Choi, Tae-Jin;Kim, Ok-Bae
    • Progress in Medical Physics
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    • v.22 no.2
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    • pp.92-98
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    • 2011
  • This study is to keep the accuracy and stability of the output dose evaluations for linear accelerator photon beams by using the air ionization chambers (TM31010, 0.125 cc, PTW) through the Task Group 51 protocol. The absorbed dose to water calibration factor $N_{dw}{^{Co-60}}$ was delivered from the air kerma calibration factor $N_k$ which was provided from manufacture through SSDL calibration for determination of output factor. The ionization chamber of TM31010 series was reviewed the calibration factor and other parameters for reduce the uncertainty within ${\pm}2%$ discrepancy and we found the supplied $N_{dw}{^{Co-60}}$ which was derived from Nk has shown a -2.8% uncertainty compare to that of PSDL. The authors provided the program to perform the output dosimetry with TG-51 protocol as it is composed same screen of TG-51 worksheets. The evaluated dose by determination of output factor delivered to postal TLD block for comparison the output dose to that of MDACC (RPC) in postal monitoring program. The results have shown the $1.001{\pm}0.013$ for 6 MV and $0.997{\pm}0.012$ discrepancy for 15 MV X rays for 5 years followed. This study shows the evaluated outputs for linear accelerate photon beams are very close to that of international output monitor with small discrepancy of ${\pm}1.3%$ with high reliability and showing the gradually stability after 2010.

Development of VPPE-BE Testing System to Evaluate Modulus under Post-Compaction Variation in Matric Suction for Unsaturated Compacted Soils (다짐지반의 모관흡수력 변화에 따른 탄성계수 평가를 위한 VPPE-BE 시험 시스템 개발)

  • Lee, Sei-Hyun;Seo, Won-Seok;Choo, Yun-Wook;Kim, Dong-Soo
    • Journal of the Korean Geotechnical Society
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    • v.24 no.5
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    • pp.117-127
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    • 2008
  • The volumetric pressure plate extractor (VPPE) was modified for the measurement of shear wave velocity ($V_s$) at various levels of matric suction as well as soil water characteristic curve (SWCC). A non-destructive technique with a pair of bender element (BE) was employed in order to measure the $V_s$ and the corresponding maximum shear modulus ($G_{max}$) of unsaturated soil specimens. Three types of soil were collected from different road construction sites in Korea. For all test soils, the variations in $G_{max}$ with the various levels of water content and matric suction were investigated using the developed apparatus. Compared with the preceding results from the suction-controlled torsional shear (TS) testing system and in-situ seismic tests, the feasibility fur evaluating modulus characteristics of unsaturated compacted soils with the developed VPPE-BE system was assessed. It was confirmed that the newly developed system would be potentially helpful in modeling seasonal variation of modulus.