• Title/Summary/Keyword: 흐름분리

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Separation of Nanomaterials Using Flow Field-Flow Fractionation (흐름 장-흐름 분획기를 이용한 나노물질의 분리)

  • Kim, Sung-Hee;Lee, Woo-Chun;Kim, Soon-Oh;Na, So-Young;Kim, Hyun-A;Lee, Byung-Tae;Lee, Byoung-Cheun;Eom, Ig-Chun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.835-860
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    • 2013
  • Recently, the consumption of nanomaterials has been significantly increased in both industrial and commercial sectors, as a result of steady advancement in the nano-technologies. This ubiquitous use of nanomaterials has brought up the concern that their exposure to environments may cause detrimental effects on human health as well as natural ecosystems, and it is required to characterize their behavior in various environmental media and to evaluate their ecotoxicity. For the sake of accomplishing those assessments, the development of methods to effectively separate them from diverse media and to quantify their properties should be requisitely accompanied. Among a number of separation techniques developed so far, this study focuses on Field-Flow Fractionation (FFF) because of its strengths, such as relatively less disturbance of samples and simple pretreatment, and we review overseas and domestic literatures on the separation of nanomaterials using the FFF technique. In particular, researches with Flow Field-Flow Fractionation (FlFFF) are highlighted due to its most frequent application among FFF techniques. The basic principle of the FlFFF is briefly introduced and the studies conducted so far are classified and scrutinized based on the sort of target nanomaterials for the purpose of furnishing practical data and information for the researchers struggling in this field. The literature review suggests that the operational conditions, such as pretreatment, selection of membrane and carrier solution, and rate (velocity) of each flow, should be optimized in order to effectively separate them from various matrices using the FFF technique. Moreover, it seems to be a prerequisite to couple or hyphenate with several detectors and analyzers for quantification of their properties after their separation using the FFF. However, its application has been restricted regarding the types of target nanomaterials and environmental media. Furthermore, domestic literature data on both separation and characterization of nanomaterials are extremely limited. Taking into account the overwhelmingly increasing consumption of nanomaterials, the efforts for the area seem to be greatly urgent.

A Method to Construct Control Flow Graphs for Java Programs by Decoupling Exception Flow Analysis from Normal Flow Analysis (예외 흐름 분석을 정상 흐름 분석과 분리하여 Java프로그램에 대한 제어 흐름 그래프를 생성하는 방법)

  • 조장우;창병모
    • Journal of KIISE:Software and Applications
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    • v.31 no.5
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    • pp.643-650
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    • 2004
  • Control flow graph is used for Performing many Program-analysis techniques, such as data-flow and control-dependence analysis, and software-engineering techniques, such as program slicing and testings. For these analyses to be safe and useful, the CFG should incorporate the exception flows that are induced by exceptions. In previous research to construct control flow graph, normal flows and exception flows are computed at the same time, since these two flows are known to be mutually dependent. By investigating realistic Java programs, we found that the cases when these two flows are mutually dependent rarely happen. So, we can decouple exception flow analysis from normal flow analysis. In this paper we propose an analysis that estimates exception flows. We also propose exception flow graph to represent exception flows. And we show that the control flow graph that accounts for exception flows can be constructed by merging exception flow graph onto normal control flow graph.

A Study on the Effect of Designated Domestic Traffic Separation Scheme(TSS) -Focused on the Marine Casualty & the Marine Traffic Flow- (국내 통항분리수역 설치 효과에 관한 연구 -해양사고 및 해상교통흐름을 중심으로-)

  • Kim, Chol-Seong;Jeong, Jae-Yong;Lee, Hong-Hoon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.17 no.1
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    • pp.61-68
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    • 2011
  • The "ship's routeing" system was adopted by IMO and has been operated on the major sea routes of all over the world for the prevention of marine casualty and the improvement of marine traffic flow. Thereupon, also in Korea, the "Hong-do" and "Bogil-do" sea routes on southern coast were designated to mandatory sea area by traffic separation scheme(TSS) in 2003, and the "Geomun-do" sea route on southern coast was designated in 2005. But there were few or no studies on the effect of designated traffic separation scheme in Korea. For this reason, in this paper, we evaluated the contribution of traffic separation scheme to the prevention of marine casualty and the improvement of marine traffic flow after designation of domestic traffic separation scheme using data of the marine casualties and ship's tracks from AIS information. The results of evaluation showed that on the contrary, the cases of marine casualties were increased on some sea routes and regular traffic flows were disturbed by some vessels after designation of traffic separation scheme. For the safer and better sea routes, alternative ideas such as reposition of ship's routing on "Hong-do" and "Bogil-do" sea areas were suggested.

The Effect of Temperature and Flow Rate of Eluent on the Separation of Adjacent Lanthanides (La : Ce, Ce : Pr, Pr : Nd) with Displacement Chromatography (치환크로마토그래피에서 온도와 용리액의 흐름속도가 란탄족 원소들 (La : Ce, Ce : Pr, Pr : Nd) 의 분리에 미치는 영향)

  • Ha, Yeong Gu;Song, Gi Hun
    • Journal of the Korean Chemical Society
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    • v.38 no.9
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    • pp.660-666
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    • 1994
  • The effects of temperature and flow rate of eluent on the separation of adjacent lighter lanthanide pairs (La : Ce, Ce : Pr, Pr: Nd) have been studied with displacement chromatography. Two serial columns packed with Amberlite 120 cation exchange resin are used for loading and separation. The retaining ion is $H^+$ ion and the eluent is 0.012M and 0.015M of EDTA solution. The columns and the eluent are maintained at the temperature of 90$^{\circ}C$ and pressurized to reduce vaporizing in the ion-exchange resin column. The eluated solution is analyzed directly with ICP-AES. The separation factors of the lanthanide pairs, La: Ce, Ce :Pr, and Pr: Nd, are 4.6, 2.8, and 1.9, respectively and are higher than that from theoretical calculation at 25$^{\circ}C$. When the flow rate is reduced from 2.5 ml/min to 1.5 ml/min, the HETP is reduced from 1.60 cm to 0.88 cm. The separation efficency can be improved at lower flow rate of eluent and higher operating temperature. The recoveries of pure lanthanides than 99.9% are 49∼77% from this separation.

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Experimental Study on Flow Characteristic of L-type Groyne (L형 수제주변 흐름특성 변화에 대한 실험연구)

  • Kang, Joon-Gu;Yeo, Hong-Koo;Kim, Sung-Jung
    • Journal of Korea Water Resources Association
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    • v.41 no.7
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    • pp.653-667
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    • 2008
  • The hydraulic model test for the L-type Groynes with "ㄱ" shape were conducted to analyze flow characteristics around these groynes. The results of model tests should be used for the fundamental information to design the L-type Groyne constructed in the field. Main hydraulic factors such as the velocity and thalweg line changes in main channel and separation area were analyzed in this study. The thalweg line is stream line where the maximum velocity occurs, and the separation area is a boundary of main flow and recirculation zone. Model tests with 5 different arm-lengths of the L-type Groynes were conducted changing the velocity. The LSPIV(Large Scale Particle Image Velocimetry) technique was used to measure and analyze the flow variation around the L-type Groynes. The velocity in main channel was increased 1.5 times and there was no effects of different groyne arm-length on the velocity changes. The width of thalweg lines $(T_{CL})$ was changed to $55{\sim}58%$ of chanel width, and the Froude number did not affect on the thalweg line $(T_{CL})$ and separation line $(S_h)$ changes.

Numerical study of dividing open-channel flows at bifurcation channel using TELEMAC-2D (TELEMAC-2D모형을 이용한 개수로 분류흐름에 대한 수치모의 연구)

  • Jung, Dae Jin;Jang, Chang-Lae;Jung, Kwansue
    • Journal of Korea Water Resources Association
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    • v.49 no.7
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    • pp.635-644
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    • 2016
  • This study investigates variation of flow characteristics due to variation of branch channel width and discharge ratio at bifurcation channel using 2D numerical model. The calculated result considering secondary flow is more accurate and stable than without considering one. The diversion flow rate ($Q_3/Q_1$) is reduced by flow stagnation effect according to the interaction of the secondary flow and flow separation zone in branch channel. The less upstream inflow or the lower upstream velocity, the bigger variation of diversion flow rate by changing branch channel width. At uniform downstream boundary condition, the rate of change in Froude number of downstream of main channel($Fr_2$)-diversion flow rate ($Q_3/Q_1$) relations is similar about -2.4843~-2.6675 when branch channel width ratio (b/B) is decreased. At uniform diversion flow rate ($Q_3/Q_1$) condition, the width of recirculation zone in branch channel is decreased when branch channel width ratio (b/B) is decreased. The less upstream inflow in the case of increasing branch channel width or the narrower branch channel width in the case of increasing upstream inflow, the bigger reduction ratio of recirculation zone width. At uniform inflow discharge ($Q_1$) condition, diversion flow rate, the width and length of recirculation zone in branch channel are decreased when branch channel width ratio (b/B) is decreased.

Numerical Modeling of Free Surface Flow over a Broad-Crested Rectangular Weir (사각형 광정위어를 통과하는 자유수면 흐름 수치모의)

  • Paik, Joongcheol;Lee, Nam Joo
    • Journal of Korea Water Resources Association
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    • v.48 no.4
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    • pp.281-290
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    • 2015
  • Numerical simulations of free surface flow over a broad-crested rectangular weir are conducted by using the volume of fraction (VOF) method and three different turbulence models, the k-${\varepsilon}$, RNG k-${\omega}$ and k-${\omega}$ SST models. The governing equations are solved by a second-order accurate finite volume method and the grid sensitivity study of solutions is carried out. The numerical results are evaluated by comparing the solutions with experimental and numerical results of Kirkgoz et al. (2008) and some non-dimensionalized experimental results obtained by Moss (1972) and Zachoval et al. (2012). The results show that the present numerical model can reasonably reproduce the experimental results, while three turbulent models yield different numerical predictions of two distinct zones of flow separation, the first zone is in front of the upstream edge of the weir and the second is created immediately behind the upstream edge of the weir where the flow is separated to form the separation bubble. The standard k-${\varepsilon}$ model appears to significantly underestimate the size of both separation zones and the k-${\omega}$ SST model slightly over-estimates the first separation zone in front of the weir. The RNG k-${\varepsilon}$ model predicts both separation zones in overall good agreement with the experimental measurement, while the k-${\omega}$ SST model yields the best numerical prediction of separation bubble at the upstream edge of the weir.

Energy Analysis in CO2 Membrane Separation Process via Heat Integration (열통합 기법을 통한 이산화탄소 막 분리공정 에너지 해석)

  • Kim, Seong Hun;Kim, Tae Yong;Kim, Beom Seok;Cho, Hyun-Jun;Yeo, Yeong Koo
    • Plant Journal
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    • v.12 no.2
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    • pp.24-30
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    • 2016
  • The membrane separation processes have received attention due to advantages such as compactness, modularity, ease of installation, flexibility of operation, lower capital cost and lower energy consumption. In this study, we evaluated accuracy of cross-flow, co-current and counter-current models. With the most accurate model, we identified the operating conditions of the two-stage membrane separation and examined the effects of permeance and selectivity of the membrane by simulation. Futhermore, power requirements and operating cost savings due to the introduction of the heat exchanger were investigated by applying heat exchanger network synthesis technique in the two-stage membrane separation using vapor sweep.

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Suitability of Counter-current Model for Biogas Separation Processes using Cellulose Acetate Hollow Fiber Membrane (셀룰로오스 아세테이트 중공사 분리막을 이용한 바이오가스 분리에 대한 향류 흐름 모델의 적용성)

  • Jung, Sang-Chul;Kwon, Ki-Wook;Jeon, Mi-Jin;Jeon, Yong-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.43-52
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    • 2020
  • As the membrane gas separation technology grows, various models were developed by numerous researchers to describe the separation process. In this work, the counter-current model was compared thoroughly with experimental data. Experimentally, hollow fiber membrane using CA module was prepared for the separation of biogas. The pure gas permeation properties of membrane module for methane, nitrogen, oxygen, and carbon dioxide were measured. The permeance of CO2 and CH4 were 25.82 GPU and 0.65 GPU, respectively. The high CO2/CH4 selectivity of 39.7 was obtained. the separation test for three different simulated mixed gases were carried out after pure gas test, and the gas concentration of the permeate at various stage-cut were measured from CA membrane module. Results showed that the experimental data agreed with the numerical simulation. A mathematical model has implemented in this study for the separation of biogas using a membrane module. The finite difference method (FDM) is applied to calculate the membrane biogas separation behaviors. Futhermore, the counter-current model can be considered as a convenient model for biogas separation process.